SDS Product SF 05 English Version

Revision date : May 2022 SAFETY DATA SHEET
Revision : 2nd (second)
1. IDENTIFICATION
Product identifier : Smooth Fluid 05
Other means of : Synthetic Base Fluid (SBF), SF 05
identification
Recommended use of the : This product is the main component of synthetic base mud
chemical and restrictions on for drilling or drilling activities.
use
Manufacturer : PT Kilang Pertamina Internasional
Graha Pertamina
Jl. Medan Merdeka Timur No. 11-12
Jakarta Pusat 10110
Email: pcc135@pertamina.com
Emergency phone number : 135
2. HAZARD IDENTIFICATION
Classification : Carcinogenicity, Category 1B
Aspiration hazard, Category 1
Hazardous to the aquatic environment, long-term hazard,
Category 2
Acute toxicity, inhalation, Category 4
Specific target organ toxicity, repeated exposure, Category 2
Skin corrosion/irritation, Category 2
Flammable liquid, Category 3
Signal word : Danger
Hazard statement : Physical Hazard
H226 - Flammable liquid and vapour
Health Hazard
H304 – May be harmful if swallowed
H332 – Harmful if inhaled
H350 - May cause cancer
H373 – May cause damage to organs through prolonged or
repeated exposure
Environmental Hazard
H411 – Toxic to aquatic life with long lasting effects
Precautionary statement : Prevention
P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been
read and understood
P210 - Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P233 - Keep container tightly closed
P240 - Ground/bond container and receiving equipment
SAFETY DATA SHEET SMOOTH FLUID 05 1

P241 - Use explosion-proof/ electrical/ ventilating/ lighting/

equipment
P242 - Use only non-sparking tools
P243 - Take precautionary measures against static discharge
P260 - Do not breathe dust/ fume/ gas/ must/ vapours/ spray
P280 - Wear protective gloves/protective clothing/eye
protection/face protection
Response
P303+P361+P353 – IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/shower
P308 + P313 - IF exposed or concerned: Get medical advice/
attention
P314 - Get medical advice/ attention if you feel unwell
P370 + P378 – In case of fire: Use CO2/dry chemical
powder/foam to extinguish
Storage
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
Disposal
P501 - Dispose of contents/container in accordance with
national regulations
Pictogram :
Other hazards which do not : No data available

result in classification
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS/ EC List No. Concentration (%)
Distillates (petroleum), hydrocracked middle 64742-46-7 100
4. FIRST AID MEASURES

Necessary description
• In case of eye contact : Remove contact lenses. Rinse with normal saline/0.9% NaCl (if
available) or under running water for at least 15 minutes. If
irritation occurs, contact a doctor.
• In case of skin contact : Take off the clothes. Wash the affected skin area with soap and
water for 10-15 minutes. Wash clothes before use. Get medical
attention immediately if irritation persists.

• If inhaled : Move victim to open air for comfortable breathing. Check vital
signs regularly and take appropriate action. Immediately seek
medical treatment if irritation of the respiratory tract occurs.
• If swallowed : If swallowed immediately call / take to the doctor (medical
treatment) in case of an emergency condition. Do not induce
vomiting. If vomiting occurs, ask the victim to lean forward to
reduce the risk of aspiration.
Most important : No data available
symptoms/effects
Indication of immediate medical : Treatment is carried out according to symptoms.
attention and special treatment
needed, if necessary
5. FIRE-FIGHTING MEASURES
Suitable extinguishing : Foam, dry chemical powder, carbon dioxide (CO2), and
media water fog.
Unsuitable extinguishing : Do not use water jets on flammable products as they may
media cause sparks and spread fire. The use of foam and water at
the same time on the same surface should be avoided as
water can damage the foam.
Specific hazards
• Other explosion and fire : Incomplete combustion is likely to give rise to a complex
hazards mixture of particulates and solid and liquid gases in the air,
including carbon monoxide and unidentified organic and
inorganic compounds.
Flash point °C : Minimum 80 oC
Flammability value : Minimum 200 oC (auto ignition temperature)
Hazardous chemical : Carbon monoxide, carbon dioxide, hydrocarbon, and sulfur
composition dioxide
Special protective actions
for fire fighters
a. Foam : Spray to the origin of the fire in the same direction as the
wind
b. Dry chemical powder : Spray to the origin of the fire in the same direction as the
wind
c. Carbon dioxide (CO2) : Spray to the origin of the fire in the same direction as the
wind
d. Water fog : Use high pressure water fog to dispel smoke (trained
personnel only)
Special protective : In the event of a major fire or in a confined or poorly
equipment for fire-fighter ventilated space, wear complete fireproof protective

clothing and a self-contained breathing apparatus (SCBA)

with a full facepiece operated in positive pressure mode.
6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Keep unnecessary personnel away. Keep people away from
protective equipment, and and downwind from spills/leaks. Eliminate all sources of
emergency procedures ignition (no smoking, flares, sparks, or flames in the
immediate area). Wear appropriate protective equipment
and clothing during cleaning. Do not breathe mist or
vapour. Ensure adequate ventilation. Local authorities
should be notified if a significant spill cannot be contained.
Environmental precautions : Prevent product from entering sewers, rivers, drains, or
other bodies of water. If necessary dam the product with
dry soil, sand or similar non-combustible material. Notify
appropriate managerial or supervisory personnel of all
environmental releases.
Procedures : Report spills in accordance with applicable systems and
procedures. If a spill is expected to enter drains or rivers,
report it to the authorities immediately.
Methods and materials for : Large spills are covered with foam, if available, to limit the
containment and cleaning risk of fire. Do not use direct jets. Absorb spilled product
up with a suitable non-combustible material. Collect products
in an appropriate way. Transfer collected product and
other contaminated materials to suitable containers for
recycling, recovery or safe disposal. Dispose of the cleaning
material in the designated disposal area in accordance with
applicable regulations. Prevent further spills and leaks
whenever possible and safe.
7. HANDLING AND STORAGE

General Information : Wear protective gloves, wash thoroughly after handling
product and use good personal hygiene practices. Avoid
inhalation of vapors or mist.
Precautions for safe : Ensure adequate ventilation is provided if there is a risk of
handling vapour, mist or aerosol formation.
Conditions for safe storage : Keep away from heat sources, prevent accumulation of
(including any static electricity. Provide grounding.
incompatibilities) Only use joint, hydrocarbon-resistant pipes.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
• Exposure limit : No data available
• Biological exposure : No data available
indicator
Appropriate engineering
control
• Ventilation : Ensure adequate ventilation when handling the product.
Provide local exhaust ventilation at work station locations.
Individual protection
measures
• Eye and face protection : Use eye protection for chemicals (chemical type goggles).
• Skin protection : Wear work gloves that provide adequate chemical
resistance, particularly to aromatic hydrocarbons (gloves
made of PVA are not waterproof, and are not suitable for
emergency use), protective clothing and anti-slip shoes or
antistatic boots. It is recommended to use an apron.
• Respiratory protection : Chemical respirator with organic vapor cartridge and full
face shield.
• Hygiene practices : Apply good personal hygiene.
Wash hands during breaks and after work.
Do not eat or drink while using the product.
Do not smoke while using the product.
9. PHYSICAL AND CHEMICAL PROPERTIES AND SAFETY CHARACTERISTICS

Characteristic Test Result
Organoleptic (physical appearance, color, etc.) : Liquid, clear yellow
Odor : Characteristic
Odor threshold : No data available
pH : 6.263
Melting/freezing point : Maximum 5 oC at 101.325 kPa
Boiling point/boiling range : Minimum 175 °C
Flammability : No data available
Flash point : Minimum 80 oC
Evaporation rate : No data available
Lower/upper flammability limit and explosion limit : No data available
Vapor pressure : No data available
Vapor density : No data available
Density : 0.800 - 0.835 g/cm³ at 15 oC
Solubility
• Water solubility : Not soluble
• Other solubility

In 10% n.Octanol : Soluble

In 90% n.Octanol : Soluble
In 10% Iso Propyl Alkohol : Soluble
In 90% Iso Propyl Alkohol : Soluble
In 10% n-Hexane : Soluble
In 90% n-Hexane : Soluble
In 10% n-Heptane : Soluble
In 90% n-Heptane : Soluble
In 10% Toluene : Soluble
In 90% Toluene : Soluble
Partition coefficient (n-octanol/water) : No data available
Auto-ignition temperature : Minimum 200 oC
Decomposition temperature : No data available
Viscosity : 2.5 - 3.5 cst pada 40 °C
10. STABILITY AND REACTIVITY

Reactivity : No polymerization reactions occur
Chemical stability : Stable under normal condition
Possibility of hazardous : No hazardous reactions occur when handled and stored in
reactions accordance with applicable regulations
Conditions to avoid : Avoid heat, sparks, open flames and other ignition sources.
Avoid temperatures exceeding the flash point. Contact
with incompatible materials.
Incompatible materials : Strong oxidizer
Hazardous decomposition : Carbon monoxide (CO), carbon dioxide (CO2),
products hydrocarbon, and sulfur dioxide (SO2)
11. TOXICOLOGICAL INFORMATION

• Information about : Inhalation, skin contact or ingestion (accidental)
possible route exposure
Comprehensive toxicological/health information
• Acute toxicity* : Route of exposure:
a. Oral: OECD 401, no adverse effect observed LD50 5000
mg/kg bw (rat)
b. Inhalation: OECD 403, no adverse effect observed LC50
(4jam) 4.6 mg/L (rat)
c. Dermal: OECD 402, no adverse effect observed LD50 2000
mg/kg bw (rabbit)
• Skin corrosion/ : OECD 404, not cause skin corrosion or irritation. This statement
irritation is based on compounds or products having a similar structure
or composition.

• Serious eye : OECD 405, not cause eye irritation. This statement is based on
damage/irritation compounds or products having a similar structure or
composition.
• Corrosion / irritation of : No data available. May not cause damage or respiratory tract
the respiratory tract irritation. This statement is based on compounds or products
having a similar structure or composition.
• Respiratory or skin : No data available. May not cause respiratory or skin
sensitization sensitization. This statement is based on compounds or
products having a similar structure or composition.
• Germ cell mutagenicity : No data available. May not cause mutagenic. This statement is
based on compounds or products having a similar structure or
composition.
• Carcinogenicity* : Category 1B
• Reproductive toxicity : No data available. May not cause reproductive toxicity. This
statement is based on compounds or products having a similar
structure or composition.
• STOT-single exposure : No data available. May not cause toxic to specific target organs
after single exposure. This statement is based on compounds
or products having a similar structure or composition.
• STOT-repeated : Dermal route – systemic effects:
exposure* OECD 411, adverse effect on NOAEL 25 mg/kg bw/day
(subchronic, rat).
Inhalation route – systemic effects:
OECD 413, no adverse effect on NOAEC 1710 mg/m³
(subchronic, rat).
Inhalation – local effects:
OECD 413, adverse effect on NOAEC 880 mg/m³ (subchronic,
rat).
• Aspiration hazards : No data available. May not cause aspiration hazard. This
statement is based on compounds or products having a similar
structure or composition.
Symptoms related to the : No data available. Further testing has not been done.
physical, chemical, and
toxicological characteristics
Delayed and immediate : No data available. Further testing has not been done.
effects, and also chronic
effects from both short or
long term exposure
Numerical measure of : No data available. Further testing has not been done.
toxicity
Other in formation : No data available. Further testing has not been done.
*Note: Fuel oil toxicological effects data are accessed from the site echa.europa.eu on May 25, 2022

12. ECOLOGICAL INFORMATION

Ecotoxicity* : Shell report 6304 (1996):
No short-term toxic effects on fish at LL50 (96 hours) 1.13-
65 mg/L
No short-term toxic effects on aquatic invertebrates EL50
(48 hours) 7.385 - 210 mg/L
Non-toxic effects on algae and cyanobacteria EL50 (72
hours) 1.714 - 22 mg/L
Persistence and : No data available. Further testing has not been done.
degradability
Bioaccumulative potential : No data available. Further testing has not been done.
Mobility in soil : No data available. Further testing has not been done.
Other adverse effects : No data available. Further testing has not been done.
Biodegradability : OECD 306, % 28 hari → 87.76%
Toxicity on aquatic habitat : LC 50 – EPA 1619>450,000 mg/L
*Note: Fuel oil ecological data are accessed from the site echa.europa.eu on May 25, 2022
13. DISPOSAL CONSIDERATION

Disposal methods : This product is classified as hazardous and toxic substances so
its disposal must be in accordance with applicable government
regulations.
*Law information: this product sludge waste is classified as hazardous waste (except it is not proven
after TCLP (Toxicity Characteristic Leaching Procedure) testing), so that the disposal must follow valid
provision.
14. TRANSPORT INFORMATION

USA DOT
UN Number : Cannot be applied. Not classified as dangerous for
transportation
UN proper shipping name : Cannot be applied. Not classified as dangerous for
transportation
Transport hazard class(es) : Cannot be applied. Not classified as dangerous for
transportation
Packing group (if available) : Cannot be applied. Not classified as dangerous for
transportation
Environmental hazard : Cannot be applied. Not classified as dangerous for
transportation
Special precautions for user : Cannot be applied. Not classified as dangerous for
(UN Model Regulation) transportation
RID / ADR


transportation
transportation
transportation
transportation
transportation
transportation
IMO
transportation
transportation
transportation
transportation
transportation
transportation
ICAO / IATA
transportation
transportation
transportation
transportation
transportation
transportation

15. REGULATORY INFORMATION

Safety, health, and : - Peraturan Menteri Perindustrian Nomor 23/M-
environmental regulation IND/PER/4/2013 tentang Perubahan Atas Peraturan
(specific for the product in Menteri Perindustrian Nomor 87/M-IND/PER/9/2009
Tentang Sistem Harmonisasi Global Klasifikasi dan Label
question)
pada Bahan Kimia
- Peraturan Direktur Jenderal Basis Industri Manufaktur
No. 04/BIM/PER/I/2014 tentang Petunjuk Teknis dan
Petunjuk Pengawasan Pelaksanaan Sistem Harmonisasi
Global Klasifikasi dan Label Pada Bahan Kimia
- Peraturan Pemerintah Republik Indonesia Nomor 74
Tahun 2001 Tentang Pengelolaan Bahan Berbahaya dan
Beracun
- Keputusan Menteri Tenaga Kerja No Kep-187/Men/1999
tentang Pengendalian Bahan Kimia Berbahaya
- Peraturan Menteri Kesehatan Republik Indonesia Nomor
70 Tahun 2016 tentang Standar dan Persyaratan
Kesehatan Lingkungan Kerja Industri
- Peraturan Menteri Ketenagakerjaan Nomor 5 Tahun
2018 tentang K3 Lingkungan Kerja
- Standar Nasional Indonesia (SNI) 9030-1:2021 Perihal
Sistem Harmonisasi Global - Bagian 1: Klasifikasi Bahaya
Bahan Kimia
- Standar Nasional Indonesia (SNI) 9030-2:2021 perihal
Sistem Harmonisasi Global - Bagian 2: Lembar Data
Keselamatan dan Pelabelan Bahan Kimia
- ACGIH®. 2021. TLVs® and BEIs®
16. OTHER INFORMATION

Composing date : May 2022
Revision date : May 2022
Key/legend or acronym used : ACGIH - American Conference on Governmental Industrial
in the SDS Hygienist
ADR - European Agreement concerning the International
Carriage of Dangerous Goods by Road
ASTM - American Society for Testing and Material
BEIs® - Biological Exposure Indices
CAS No. - Chemical Abstract Service Number
EC No. - European Community Number
EL50 - Effective loading rate resulting in 50% effect
IMO - International Maritime Organization
ICAO/IATA - International Civil Organization Aviation/
International Air Transport Association
LC50 - Lethal Concentration 50%

LD50 - Lethal Dose 50%

LEL - Lower Explosion Limit
LL50- Lethal Load 50%
LOAEL - Lowest Observed Adverse Effect Level
NOAEL - No Observed Adverse Effect Level
NOEC - No Observed Effect Concentration
OECD – Organisation for Economic Co-operation and
Development, Test Guidelines for Chemicals
PG - Packing Group
PVA - Polyvinyl alcohol
RID - Regulation concerning the International Carriage of
Dangerous Goods by Rail
SCBA - Self Contained Breathing Apparatus
TCLP - Toxicity Characteristic Leaching Procedure
TLV - Threshold Limit Value
TWA - Time-Weighted Average
UEL - Upper Explosion Limit
UN - United Nations
USA DOT - United States Department of Transportation
Key literature references : The data above is cited from but not limited to information
and sources for data used in sources like result of laboratory analysis, DOT ERG No.128,
the SDS OSHA 29 CFR 1910.1200, European Chemicals Agency
(ECHA) Europa
NFPA : NFPA Health Hazard : 0 – Non-hazardous material,

exposure under combustible conditions will not present a
hazard beyond combustible materials
1 NFPA Fire Hazard : 1 – Materials that must be heated
before combustion occurs
0 0
NFPA Reactivity Hazard : 0 – Normally stable, even under
fire conditions, and are not reactive with water
NFPA Specific Hazard : –
Disclaimer
The information is composed based on current knowledge and intended to describe safety, health,
and environment hazard of the product. Therefore, it should not be construed as guarantee any
specific property of the product. All risks while using this product is the user’s responsibility. It is not
allowed to make change of this document, except there is legal consent.

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Revision date : May 2022 SAFETY DATA SHEET

Revision : 2nd (second)

SAFETY DATA SHEET SMOOTH FLUID 05 1

P241 - Use explosion-proof/ electrical/ ventilating/ lighting/

Other hazards which do not : No data available

4. FIRST AID MEASURES

SAFETY DATA SHEET SMOOTH FLUID 05 2

SAFETY DATA SHEET SMOOTH FLUID 05 3

clothing and a self-contained breathing apparatus (SCBA)

6. ACCIDENTAL RELEASE MEASURES

7. HANDLING AND STORAGE

SAFETY DATA SHEET SMOOTH FLUID 05 4

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

9. PHYSICAL AND CHEMICAL PROPERTIES AND SAFETY CHARACTERISTICS

SAFETY DATA SHEET SMOOTH FLUID 05 5

In 10% n.Octanol : Soluble

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION

SAFETY DATA SHEET SMOOTH FLUID 05 6

SAFETY DATA SHEET SMOOTH FLUID 05 7

12. ECOLOGICAL INFORMATION

13. DISPOSAL CONSIDERATION

14. TRANSPORT INFORMATION

SAFETY DATA SHEET SMOOTH FLUID 05 8

UN Number : Cannot be applied. Not classified as dangerous for

SAFETY DATA SHEET SMOOTH FLUID 05 9

15. REGULATORY INFORMATION

16. OTHER INFORMATION

SAFETY DATA SHEET SMOOTH FLUID 05 10

LD50 - Lethal Dose 50%

NFPA : NFPA Health Hazard : 0 – Non-hazardous material,

NFPA Specific Hazard : –

SAFETY DATA SHEET SMOOTH FLUID 05 11

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