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Safety Data Sheet

According to Occupational Health and Safety (Classification, Labelling and


Safety Data Sheet of Hazardous Chemicals) Malaysia Regulation 2013

PETRONAS Dynamic Diesel


Version 1.2 Release Date: 31.03.2016

SECTION 1: Identification of the hazardous chemical and of the supplier

Product name : PETRONAS Dynamic Diesel


Recommended use : Fuel oil

Manufacturer or supplier's details


Headquarters
Company : PETRONAS Dagangan Berhad
Address : Level 30, Tower 1, PETRONAS Twin Towers,
Kuala Lumpur City Centre,
50088 Kuala Lumpur,
Malaysia
Emergency telephone : Mesralink Contact Number: 1 300 88 8181 / 8282
number National Poison Centre:
04-6570099 (office hours)
012-4309499 (after office hours)

SECTION 2: Hazards identification

Classification of the hazardous chemical


Flammable liquids : Category 3
Acute toxicity (Inhalation) : Category 4
Skin corrosion/irritation : Category 2
Carcinogenicity : Category 2
Specific target organ toxicity - : Category 2 (Thymus, Liver, Bone Marrow)
repeated exposure
Aspiration hazard : Category 1
Hazardous to the aquatic : Category 2
environment - chronic hazard
Label elements
Hazard pictograms :

Signal word : Danger


Hazard statements : H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H351 Suspected of causing cancer.
H373 May cause damage to organs (Thymus, Liver, Bone
Marrow) through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements : Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
Safety Data Sheet

PETRONAS Dynamic Diesel

Version 1.2 Release Date: 31.03.2016

P241 Use explosion-proof electrical/ ventilating/ lighting/


equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
P281 Use personal protective equipment as required.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER or doctor/ physician.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 + P312 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P331 Do NOT induce vomiting.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam for extinction.
P391 Collect spillage.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification


No information available.

SECTION 3: Composition and information of the ingredients of the hazardous chemical

Substance / Mixture : UVCB


Chemical nature : Diesel fuel

Hazardous components
Chemical Name CAS-No. Concentration (%)
Diesel 68334-30-5 >= 90 - < 99

SECTION 4: First aid measures

If inhaled : If unconscious, place in recovery position and seek medical


advice.

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Safety Data Sheet

PETRONAS Dynamic Diesel

Version 1.2 Release Date: 31.03.2016

If symptoms persist, call a medical doctor.


Move to fresh air.
Consult a medical doctor after significant exposure.
In case of skin contact : If on skin, rinse well with water.
If on clothes, remove clothes.
If skin irritation persists, call a medical doctor.
In case of eye contact : Flush eyes with water as a precaution.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do NOT give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.
If symptoms persist, call a medical doctor.
Do NOT induce vomiting.
General advice : Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.Symptoms of poisoning
may appear several hours later.
Most important symptoms : No information available.
and effects, both acute and
delayed

SECTION 5: Firefighting measures

Extinguishing media
Suitable extinguishing media : Carbon dioxide (CO2)
Alcohol-resistant foam
Dry chemical
Unsuitable extinguishing : High volume water jet
media
Physicochemical hazards arising from the chemical
Specific hazards during : Do not allow run-off from fire fighting to enter drains or water
firefighting courses.
Special protective equipment and precautions for fire-fighters
Special protective equipment : Wear self-contained breathing apparatus for firefighting if
for firefighters necessary.
Specific extinguishing : Collect contaminated fire extinguishing water separately. This
methods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed off in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.

SECTION 6: Accidental release measures

Personal precautions, : Remove all sources of ignition.


protective equipment and Evacuate personnel to safe areas.
emergency procedures Beware of vapours accumulating to form explosive

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Safety Data Sheet

PETRONAS Dynamic Diesel

Version 1.2 Release Date: 31.03.2016

concentrations. Vapours can accumulate in low areas.Use


personal protective equipment.
Ensure adequate ventilation.
Environmental precautions : Prevent further leakage or spillage if safe to do so.
Prevent product from entering drains.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for : Contain spillage, and then collect with non-combustible
containment and cleaning up absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).

SECTION 7: Handling and storage

Handling
Advice on protection against : Take necessary action to avoid static electricity discharge
fire and explosion (which might cause ignition of organic vapours).
Normal measures for preventive fire protection.
Do not spray on a naked flame or any incandescent material.
Keep away from open flames, hot surfaces and sources of
ignition.
Advice on safe handling : Take precautionary measures against static discharges.
Avoid contact with skin and eyes.
Avoid formation of aerosol.
Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Storage
Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
No smoking.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.

SECTION 8: Exposure controls and personal protection

Control parameters
Components CAS-No. Value type (Form of Control parameters / Basis
exposure) Permissible
concentration
Diesel 68334-30-5 TWA (Inhalable 100 mg/m3 ACGIH
fraction and vapor) (total hydrocarbons)
Further information: Dermatitis, Confirmed animal carcinogen with unknown

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Safety Data Sheet

PETRONAS Dynamic Diesel

Version 1.2 Release Date: 31.03.2016

relevance to humans, Danger of cutaneous absorption, varies

Individual protection measures, such as personal protective equipment


Eye/face protection : Eye wash bottle with pure water.
Tightly fitting safety goggles.
Skin protection : Impervious clothing.
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hand protection
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Respiratory protection : In the case of vapour formation use a respirator with an
approved filter.
Hygiene measures : Wash hands before breaks and at the end of workday.
When using do not eat or drink.
When using do not smoke.

SECTION 9: Physical and chemical properties

Appearance : Liquid
Colour : Yellow to brownish
Odour : Hydrocarbon-like
Odour Threshold : No data available
pH : No data available
Melting point/freezing point : No data available
Initial boiling point and boiling : 163 - 370 °C
range
Flash point : 60 °C Method: ASTM D 93
Evaporation rate : No data available
Flammability (solid, gas) : No data available
Upper explosion limit : 5.0 %(V)
Lower explosion limit : 0.50 %(V)
Vapour pressure : 4 hPa (40 °C)
Relative vapour density : 4.5
Relative density : 0.81 - 0.87
Density : 0.81 - 0.87 g/cm3 (15 °C)
Solubility(ies)
Water solubility : Insoluble
Partition coefficient: n- : No data available
octanol/water
Auto-ignition temperature : >= 225 °C
Auto-flammability
Decomposition temperature : No data available
Viscosity, dynamic : No data available
Viscosity, kinematic : 1.5 - 5.8 mm2/s (40 °C)

SECTION 10: Stability and reactivity

Reactivity : Hazardous polymerisation does not occur.


Chemical stability : Stable under normal conditions.
Possibility of hazardous : No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid : Heat, sparks, flame and build-up of static electricity

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Safety Data Sheet

PETRONAS Dynamic Diesel

Version 1.2 Release Date: 31.03.2016

Incompatible materials : Strong oxidizing agents


Hazardous decomposition : Fumes, smoke, carbon monoxide
products

SECTION 11: Toxicological information

Acute toxicity
Product:
Acute inhalation toxicity : Assessment: The component/mixture is moderately toxic after
short term inhalation.
Components:
Diesel:
Acute oral toxicity : LD50 (Rat): 7,600 mg/kg
Acute inhalation toxicity : LC50 (Rat): >= 4.1 mg/l
Exposure time: 4 h
Acute dermal toxicity : LD50 (Rabbit): > 4,300 mg/kg

Skin corrosion/irritation
Product:
Remarks : May cause skin irritation in susceptible persons.
Components:
Diesel:
Species : Rabbit
Exposure time : 24 h
Result : Causes skin irritation.

Serious eye damage/eye irritation


Product:
Remarks : Vapours may cause irritation to the eyes, respiratory system
and the skin.
Components:
Diesel:
Species : Rabbit
Result : No eye irritation

Respiratory or skin sensitisation


Components:
Diesel:
Exposure routes : Skin contact
Result : No evidence of skin sensitization.
Exposure routes : Inhalation
Remarks : No data available

Germ cell mutagenicity


Components:
Diesel:
Germ cell mutagenicity - : Not considered germ cell mutagens
Assessment

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Safety Data Sheet

PETRONAS Dynamic Diesel

Version 1.2 Release Date: 31.03.2016

Carcinogenicity
Components:
Diesel:
Carcinogenicity - : Suspected human carcinogens.
Assessment

Reproductive toxicity
Components:
Diesel:
Reproductive toxicity - : No toxicity to reproduction
Assessment

STOT - single exposure


Components:
Diesel:
Remarks : No data available

STOT - repeated exposure


Product:
Target Organs : Thymus, Liver, Bone Marrow
Assessment : The substance or mixture is classified as specific target organ
toxicant, repeated exposure, category 2.
Components:
Diesel:
Target Organs : Thymus, Liver, Bone Marrow
Assessment : May cause damage to organs through prolonged or repeated
exposure.

Aspiration toxicity
Product:
Statement on Aspiration Tox. : The substance or mixture is known to cause human aspiration
toxicity hazards or has to be regarded as if it causes a human
aspiration toxicity hazard.
Components:
Diesel:
Statement on Aspiration Tox. : May be fatal if swallowed and enters airways.

SECTION 12: Ecological information

Ecotoxicity
Product:
Ecotoxicology Assessment
Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects.

Further information
The following percentage of the mixture consists of ingredient(s) with unknown hazards to the
aquatic environment: 10 %
Components:
Diesel:

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Safety Data Sheet

PETRONAS Dynamic Diesel

Version 1.2 Release Date: 31.03.2016

Toxicity to fish : LC50 (Fish): 2 - 100 mg/l


Exposure time: 96 h
Toxicity to daphnia and other : LL50 (Daphnia magna (Water flea)): 2 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EC50 (Algae): 2 - 100 mg/l
Exposure time: 72 h
Toxicity to fish (Chronic : Remarks: No data available
toxicity)
Toxicity to daphnia and other : Remarks: No data available
aquatic invertebrates
(Chronic toxicity)
Toxicity to microorganisms : Remarks: No data available

Persistence and degradability


Components:
Diesel:
Biodegradability : Exposure time: 28 d
Result: Inherently biodegradable.
Biodegradation: 57.5 %
Method: OECD Test Guideline 301

Bioaccumulative potential
Components:
Diesel:
Bioaccumulation : Remarks: Potentially bio-accumulative (Log Kow > 4)
Partition coefficient: n- : Remarks: No data available
octanol/water

Mobility in soil
Components:
Diesel:
Mobility : Remarks: No data available

Other adverse effects


Product:
Additional ecological : Toxic to aquatic life with long lasting effects.
information An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal.

Components:
Diesel:
Additional ecological : No data available
information

SECTION 13: Disposal information

Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.

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Safety Data Sheet

PETRONAS Dynamic Diesel

Version 1.2 Release Date: 31.03.2016

Send to a licensed waste management company.


The product should not be allowed to enter drains, water
courses or the soil.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on the empty drum.

SECTION 14: Transport information

International Regulation
UNRTDG
UN number : UN 1202
Proper shipping name : DIESEL FUEL
Class : 3
Packing group : III
Labels : 3
IATA-DGR
UN/ID No. : UN 1202
Proper shipping name : Diesel fuel
Class : 3
Packing group : III
Packing instruction (cargo : 366
aircraft)
Packing instruction : 355
(passenger aircraft)
IMDG-Code
UN number : UN 1202
Proper shipping name : DIESEL FUEL
Class : 3
Packing group : III
Labels : 3
EmS Code : F-E, S-E
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

SECTION 15: Regulatory information

Safety, health, and environmental regulations specific for the hazardous chemical

Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous
Chemicals) Regulations 2013.
Occupational Safety and Health (Use and Standards of Exposure of Chemicals Hazardous to
Health) Regulations 2000.

The components of this product are reported in the following inventories:


CH INV : On the inventory, or in compliance with the inventory.
TSCA : On TSCA Inventory.
DSL : This product contains the following components listed on the
Canadian NDSL. All other components are on the Canadian

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Safety Data Sheet

PETRONAS Dynamic Diesel

Version 1.2 Release Date: 31.03.2016

DSL.
Palm Methyl Ester (PME) 91051-34-2
AICS : Not in compliance with the inventory
NZIoC : Not in compliance with the inventory
ENCS : Not in compliance with the inventory
ISHL : Not in compliance with the inventory
KECI : Not in compliance with the inventory
PICCS : Not in compliance with the inventory
IECSC : On the inventory, or in compliance with the inventory.

SECTION 16: Other information

SDS preparation date : 10.02.2015


Revision Date : 31.03.2016
Sources of key data used to : CONCAWE - The oil companies’ European association for
compile the Safety Data Environment, Health and Safety in refining and distribution
Sheet
Full text of other abbreviations
(Q)SAR - (Quantitative) Structure Activity Relationship
ANTT - National Agency for Transport by Land of Brazil
ASTM - American Society for the Testing of Materials
bw - Body weight
CPR - Controlled Products Regulations
CCHC - Chemicals Classification and Hazard Communication
DIN - Standard of the German Institute for Standardisation
ECx - Concentration associated with x% response
ELx - Loading rate associated with x% response
EmS - Emergency Schedule
ErCx - Concentration associated with x% growth rate response
ERG - Emergency Response Guide
GHS - Globally Harmonized System
IARC - International Agency for Research on Cancer
IATA - International Air Transport Association
IBC - International Code for the Construction and Equipment of Ships carrying
Dangerous Chemicals in Bulk
IC50 - Half maximal inhibitory concentration
ICAO - International Civil Aviation Organization
ICOP - Industry Code of Practice on Chemicals Classification and Hazard
Communication
IMDG - International Maritime Dangerous Goods
IMO - International Maritime Organization
ISO - International Organisation for Standardization
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
MARPOL - International Convention for the Prevention of Pollution from Ships
n.o.s. - Not Otherwise Specified
Nch - Chilean Norm
NITE - National Institute of Technology and Evaluation
NO(A)EC - No Observed (Adverse) Effect Concentration
NO(A)EL - No Observed (Adverse) Effect Level
NOELR - No Observable Effect Loading Rate
NOM - Official Mexican Norm
NTP - National Toxicology Program
OECD - Organization for Economic Co-operation and Development
OPPTS - Office of Chemical Safety and Pollution Prevention

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Safety Data Sheet

PETRONAS Dynamic Diesel

Version 1.2 Release Date: 31.03.2016

PBT - Persistent, Bioaccumulative and Toxic substance


REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals
SADT - Self-Accelerating Decomposition Temperature
SDS - Safety Data Sheet
TDG - Transportation of Dangerous Goods
UN - United Nations
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods
vPvB - Very Persistent and Very Bioaccumulative
WHMIS - Workplace Hazardous Materials Information System
DSL - Domestic Substances List (Canada)
KECI - Korea Existing Chemicals Inventory
TSCA - Toxic Substances Control Act (United States)
AICS - Australian Inventory of Chemical Substances
IECSC - Inventory of Existing Chemical Substances in China
ENCS - Existing and New Chemical Substances (Japan)
ISHL - Industrial Safety and Health Law (Japan)
PICCS - Philippines Inventory of Chemicals and Chemical Substances
NZIoC - New Zealand Inventory of Chemicals
TCSI - Taiwan Chemical Substance Inventory
CMR - Carcinogen, Mutagen or Reproductive Toxicant
GLP - Good Laboratory Practice

Disclaimer
The information contained herein is based on our current knowledge and are presented in
good faith and believed to be accurate. The information is to be studied carefully upon
consultation of appropriate expertise, as necessary. No warranty, express or implied, is given
as to the quality, accuracy, reliability, applicability or completeness of the contents of this SDS.
The information presented here pertains only to the product as shipped. It is your responsibility
to ensure that any activities relating to the product comply with all federal, state or local laws.
Any hazards associated with any product regulatory requirements are subject to change and
may differ between various locations. Except to the extent required by law, re-publication or
retransmission of this SDS, in whole or in part, is strictly prohibited.

Product Stewardship Advisory:


PETRONAS wishes to create awareness of all the hazards associated with the storage,
handling and use of our products. Carefully studying the accompanying Safety Data Sheets
and disseminating the information to all dependent and interested parties is an essential part
of any Responsible Care programme.

MY / EN

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