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Safety Data Sheet

According to Occupational Safety and Health(Classification, Labelling and


Safety Data Sheet of Hazardous Chemicals) Malaysia Regulations 2013

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

SECTION 1: Identification of the hazardous chemical and of the supplier

Product identifier
Product name : Unleaded Gasoline (Export RON 95)
Synonyms : Unleaded Petrol, gasoline, unleaded bulk, lead free motor spirit,
gasoline petrol, ULP LF grade fuel octane 50-100 motor fuel,
Lead Replacement Petrol , Premium Unleaded Petrol, Mogas
Unleaded Gasoil
Recommended use of the chemical and restrictions on use
Recommended use : Lead free motor fuel for Internal combustion engines, 2-stroke
and 4-stroke.
Restrictions on use : Solvent or detergent
Manufacturer or supplier's details

Plant Site
Company : Malaysian Refining Company Sdn. Bhd.
Address : Persiaran Penapisan,
76300 Sungai Udang,
Melaka,
Malaysia
Emergency telephone : (+606)-352 2444 (Fire Station Radio Operator)
number National Poison Centre:
+604-6570099 (Mon-Fri : 8.10 am - 5.10 pm)
+6012-4309499 (Mon-Fri : 5.10 pm - 10.10 pm) &
(Sat, Sun & Public holiday : 8.10 am - 5.10 pm)

SECTION 2: Hazards identification

Classification of the hazardous chemical


Flammable liquids : Category 2
Skin corrosion/irritation : Category 2
Germ cell mutagenicity : Category 1B
Carcinogenicity : Category 1A
Reproductive toxicity : Category 2
Specific target organ toxicity - : Category 3 (Central Nervous System)
single exposure
Specific target organ toxicity - : Category 2
repeated exposure
Aspiration hazard : Category 1
Hazardous to the aquatic : Category 2
environment- chronic hazard
Label elements
Hazard pictograms :

Signal word : Danger


Hazard statements : H225 Highly flammable liquid and vapour.
Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

H304 May be fatal if swallowed and enters airways.


H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H340 May cause genetic defects.
H350 May cause cancer.
H361fd Suspected of damaging fertility. Suspected of
damaging the unborn child.
H373 May cause damage to organs through prolonged or
repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements : Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
P281 Use personal protective equipment as required.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER or doctor/ physician.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 + P312 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P331 Do NOT induce vomiting.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam for extinction.
P391 Collect spillage.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Other hazards which do not result in classification


No information available.

SECTION 3: Composition and information of the ingredients of the hazardous chemical

Substance / Mixture : UVCB


Chemical nature : Gasoline
Components
Chemical name CAS-No. Concentration (%)
Light straight run naphtha 64741-46-4 >= 20 -< 30
MTBE 1634-04-4 >= 10 -< 20
Isomerate 64741-70-4 >= 10 -< 20
Iso-pentane 78-78-4 >= 10 -< 20
Reformate 68955-35-1 >= 10 -< 20
Benzene 71-43-2 >= 1 -< 3.5

SECTION 4: First aid measures

If inhaled : If unconscious, place in recovery position and seek medical


advice.
If symptoms persist, call a medical doctor.
Move to fresh air.
Consult a medical doctor after significant exposure.
In case of skin contact : If on skin, rinse well with water.
If on clothes, remove clothes.
If skin irritation persists, call a medical doctor.
In case of eye contact : Flush eyes with water as a precaution.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do NOT give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.
If symptoms persist, call a medical doctor.
Do NOT induce vomiting.
General advice : Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
Symptoms of poisoning may appear several hours later.
Most important symptoms : Vapours may cause irritation to eyes and respiratory tract at
and effects, both acute and high levels.
delayed Repeated and prolonged exposure may cause skin irritation or
dermatitis.
May cause asphyxiation in enclosed, poorly ventilated or low
lying area.
Severe intoxication by ingestion (>20g) can cause vomiting,
vertigo, drowsiness and confusion.

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Ingestion can cause irritation to stomach lining and also


resulting in chemical pneumonitis from aspiration.

SECTION 5: Firefighting measures

Extinguishing media
Suitable extinguishing media : Alcohol-resistant foam
Dry chemical
Carbon dioxide (CO2)
Unsuitable extinguishing : High volume water jet
media
Physicochemical hazards arising from the chemical
Specific hazards during : Do not allow run-off from fire fighting to enter drains or water
firefighting courses.
Special protective equipment and precautions for fire-fighters
Special protective equipment : Wear self-contained breathing apparatus for firefighting if
for firefighters necessary.
Specific extinguishing : Collect contaminated fire extinguishing water separately. This
methods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed off in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.

SECTION 6: Accidental release measures

Personal precautions, : Remove all sources of ignition.Use personal protective


protective equipment and equipment.
emergency procedures Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Ensure adequate ventilation.
Environmental precautions : Prevent further leakage or spillage if safe to do so.
Prevent product from entering drains.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for : Contain spillage, and then collect with non-combustible
containment and cleaning up absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).

SECTION 7: Handling and storage

Handling
Precautions for safe handling

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Advice on protection against : Take necessary action to avoid static electricity discharge
fire and explosion (which might cause ignition of organic vapours).
Use only explosion-proof equipment.
Normal measures for preventive fire protection.
Do not spray on a naked flame or any incandescent material.
Keep away from open flames, hot surfaces and sources of
ignition.
Advice on safe handling : Take precautionary measures against static discharges.
Avoid formation of aerosol.
Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Avoid contact with skin and eyes.
Storage
Conditions for safe storage, including any incompatibilities
Conditions for safe storage : No smoking.
Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Further information on : No decomposition if stored and applied as directed.
storage stability

SECTION 8: Exposure controls and personal protection

Control parameters
Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
MTBE 1634-04-4 TWA 40 ppm MY PEL
144 mg/m3
TWA 50 ppm ACGIH
Iso-pentane 78-78-4 TWA 600 ppm MY PEL
1,770 mg/m3
TWA 1,000 ppm ACGIH
Benzene 71-43-2 TWA 0.5 ppm MY PEL
1.6 mg/m3
TWA 0.5 ppm ACGIH
STEL 2.5 ppm ACGIH

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Biological occupational exposure limits


Components CAS- Control Biological Sampling Permissible Basis
No. parameters specimen time concentration
Benzene 71-43-2 S- Urine End of 25 µg/g ACGIH
Phenylmer shift (As creatinine BEI
capturic soon as
acid possible
after
exposure
ceases)
t,t-Muconic Urine End of 500 µg/g ACGIH
acid shift (As creatinine BEI
soon as
possible
after
exposure
ceases)
Individual protection measures, such as personal protective equipment
Eye/face protection : Eye wash bottle with pure water.
Tightly fitting safety goggles
Skin protection : Impervious clothingChoose body protection according to the
amount and concentration of the dangerous substance at the
work place.
Hand protection
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Respiratory protection : In the case of vapour formation use a respirator with an
approved filter.
Hygiene measures : Wash hands before breaks and at the end of workday.
When using do not eat or drink.
When using do not smoke.

SECTION 9: Physical and chemical properties

Appearance : Liquid
Colour : Yellow
Odour : Hydrocarbon-like
Odour Threshold : No data available
pH : 8.0
Melting point/freezing point : < -60.0 °C

Initial boiling point and boiling : 42.0 - 190.5 °C


range
Flash point : < -40 °C Method: closed cup
Evaporation rate : No data available
Upper explosion limit / Upper : Not applicable
flammability limit
Lower explosion limit / Lower : Not applicable
flammability limit
Vapour pressure : 61 kPa (37.8 °C)
Method: Reid vapor pressure (RVP)
Relative density : 0.7466 (15 °C)

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Density : 0.7466 g/cm3 (15 °C)


Method: ASTM D 4052
Solubility(ies)
Water solubility : Insoluble
Partition coefficient: n- : Not applicable
octanol/water
Auto-ignition temperature : 470 °C
Viscosity
Viscosity, dynamic : 0.401 mPa.s (20 °C)Method: ASTM D 445
Viscosity, kinematic : 0.460 mm2/s (40 °C)Method: ASTM D 445
Molecular weight : No data available

SECTION 10: Stability and reactivity

Reactivity : Hazardous polymerisation does not occur.


Chemical stability : Stable under normal conditions.
Possibility of hazardous : No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid : Heat, sparks, flame and build-up of static electricity.
Incompatible materials : Strong oxidizing agents
Hazardous decomposition : Fumes, smoke, carbon monoxide
products

SECTION 11: Toxicological information

Acute toxicity
Components:
Light straight run naphtha:
Acute oral toxicity : LD50 (Rat): 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): > 5.61 mg/l
Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg
MTBE:
Acute oral toxicity : LD50 (Rat): 4,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 85 mg/l
Exposure time: 4 h
Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg
Isomerate:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): > 5.2 mg/l
Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg
Iso-pentane:
Acute oral toxicity : LD50 (Rat, male and female): > 2,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): > 23.5 mg/l
Exposure time: 4 h
Acute dermal toxicity : Remarks: No data available
Reformate:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): > 5.2 mg/l
Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg
Benzene:
Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg
Acute inhalation toxicity : LC50 (Rat, female): 43.7 mg/l

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Acute dermal toxicity : LD50 (Rabbit): > 8,260 mg/kg


Skin corrosion/irritation
Components:
Light straight run naphtha:
Species : Rabbit
Result : Skin irritation
MTBE:
Species : Rabbit
Exposure time : 4h
Result : Skin irritation
Isomerate:
Species : Rabbit
Exposure time : 24 h
Result : Skin irritation
Iso-pentane:
Species : Rabbit
Exposure time : 4h
Result : No skin irritation
Reformate:
Species : Rabbit
Exposure time : 24 h
Result : Skin irritation
Benzene:
Species : Rabbit
Exposure time : 4h
Result : Skin irritation
Serious eye damage/eye irritation
Components:
Light straight run naphtha:
Species : Rabbit
Result : No eye irritation
MTBE:
Remarks : No data available
Isomerate:
Species : Rabbit
Result : No eye irritation
Iso-pentane:
Species : Rabbit
Result : No eye irritation
Reformate:
Species : Rabbit
Result : No eye irritation
Benzene:
Species : Rabbit
Result : Eye irritation
Respiratory or skin sensitisation
Components:
Light straight run naphtha:
Exposure routes : Inhalation

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Remarks : No data available


Exposure routes : Skin contact
Species : Guinea pig
Result : Not sensitising
MTBE:
Exposure routes : Inhalation
Remarks : No data available
Exposure routes : Skin contact
Remarks : No data available
Isomerate:
Exposure routes : Inhalation
Remarks : No data available
Exposure routes : Skin contact
Species : Guinea pig
Result : No evidence of skin sensitization.
Iso-pentane:
Exposure routes : Inhalation
Remarks : No data available
Exposure routes : Skin contact
Species : Guinea pig
Result : Not sensitising
Reformate:
Exposure routes : Inhalation
Remarks : No data available
Exposure routes : Skin contact
Species : Guinea pig
Result : No evidence of skin sensitization.
Benzene:
Exposure routes : Inhalation
Remarks : No data available
Exposure routes : Skin contact
Species : Guinea pig
Result : Not sensitising
Germ cell mutagenicity
Components:
Light straight run naphtha:
Germ cell mutagenicity - : May contain benzene, a constituent that is classified as a
Assessment germ cell mutagen.

MTBE:
Germ cell mutagenicity - : No data available
Assessment

Isomerate:
Germ cell mutagenicity - : May contain benzene, a constituent that is classified as a
Assessment germ cell mutagen.

Iso-pentane:
Germ cell mutagenicity - : Not mutagenic in vivo and in vitro
Assessment

Reformate:
Germ cell mutagenicity - : May contain benzene, a constituent that is classified as a
Assessment germ cell mutagen.

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Benzene:
Germ cell mutagenicity - : In vivo tests showed mutagenic effects
Assessment

Carcinogenicity
Components:
Light straight run naphtha:
Carcinogenicity - : May contain benzene, a constituent that is classified as a
Assessment carcinogen

MTBE:
Carcinogenicity - : No data available
Assessment

Isomerate:
Carcinogenicity - : May cause cancer based on animal data.
Assessment

Iso-pentane:
Carcinogenicity - : No data available
Assessment

Reformate:
Carcinogenicity - : May cause cancer based on animal data.
Assessment

Benzene:
Carcinogenicity - : Known human carcinogen, may cause leukemia.
Assessment

Reproductive toxicity
Components:
Light straight run naphtha:
Reproductive toxicity - : Suspected human reproductive toxicant.
Assessment

MTBE:
Reproductive toxicity - : No data available
Assessment

Isomerate:
Reproductive toxicity - : Suspected human reproductive toxicant.
Assessment

Iso-pentane:
Reproductive toxicity - : Not classified as reproductive toxicant
Assessment

Reformate:
Reproductive toxicity - : Suspected human reproductive toxicant.
Assessment

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Benzene:
Reproductive toxicity - : No evidence of adverse effects on sexual function and fertility,
Assessment or on development, based on animal experiments.

STOT - single exposure


Components:
Light straight run naphtha:
Target Organs : Central Nervous System
Assessment : May cause drowsiness or dizziness.

MTBE:
Remarks : No data available

Isomerate:
Target Organs : Central Nervous System
Assessment : May cause drowsiness or dizziness.

Iso-pentane:
Assessment : May cause drowsiness or dizziness.

Reformate:
Target Organs : Central Nervous System
Assessment : May cause drowsiness or dizziness.

Benzene:
Remarks : No data available

STOT - repeated exposure


Components:
Light straight run naphtha:
Assessment : No specific organ toxicity following repeated exposure.
MTBE:
Remarks : No data available
Isomerate:
Remarks : No data available
Iso-pentane:
Remarks : No data available
Reformate:
Remarks : No data available
Benzene:
Target Organs : Central Nervous System, hematopoietic system
Assessment : Causes damage to organs through prolonged or repeated
exposure.
Aspiration toxicity
Components:
Light straight run naphtha:
Statement on Aspiration Tox. : May be fatal if swallowed and enters airways.

MTBE:
Statement on Aspiration Tox. : No data available

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Isomerate:
Statement on Aspiration Tox. : May be fatal if swallowed and enters airways.

Iso-pentane:
Statement on Aspiration Tox. : May be fatal if swallowed and enters airways.

Reformate:
Statement on Aspiration Tox. : May be fatal if swallowed and enters airways.

Benzene:
Statement on Aspiration Tox. : May be fatal if swallowed and enters airways.

Further information
Product:
Remarks : Symptoms of overexposure may be headache, dizziness,
tiredness, nausea and vomiting.

SECTION 12: Ecological information

Ecotoxicity
Components:
Light straight run naphtha:
Toxicity to fish : LL50 (Fish): > 1 - 10 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : LL50 (Daphnia (water flea)): > 1 - 10 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : ErL50 (Algae): > 1 - 10 mg/l
Exposure time: 72 h
Toxicity to fish (Chronic : NOEL (Fish): <= 2.6 mg/l
toxicity)
Toxicity to daphnia and other : NOEL (Daphnia (water flea)): <= 2.6 mg/l
aquatic invertebrates
(Chronic toxicity)
Toxicity to microorganisms : Remarks: No data available

MTBE:
Toxicity to fish : LC50 (Menidia beryllina (Silverside)): 574 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 472 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : IC50 (Pseudokirchneriella subcapitata (green algae)): 491
mg/l
Exposure time: 96 h
Toxicity to fish (Chronic : NOEC (Pimephales promelas (fathead minnow)): 299 mg/l
toxicity) Exposure time: 31 d
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 51 mg/l
aquatic invertebrates
(Chronic toxicity) Exposure time: 21 d
Toxicity to microorganisms : EC10 (Pseudomonas putida): 710 mg/l
Exposure time: 18 h
Isomerate:

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Toxicity to fish : LC50 (Fish): 1 - 10 mg/l


Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Crustaceans): 1 - 10 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : ErC50 (Algae): 1 - 10 mg/l
Exposure time: 72 h
Toxicity to fish (Chronic : NOEL (Fish): 2.6 mg/l
toxicity)
Toxicity to daphnia and other : NOEL (Daphnia (water flea)): 2.6 mg/l
aquatic invertebrates
(Chronic toxicity)
Toxicity to microorganisms : Remarks: No data available

Iso-pentane:
Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 34.05 mg/l
Exposure time: 96 h
Remarks: QSAR
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 2.3 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : ErL50 (Pseudokirchneriella subcapitata (green algae)): 25.12
mg/l
Exposure time: 72 h
Remarks: QSAR
Toxicity to fish (Chronic : Remarks: No data available
toxicity)
Toxicity to daphnia and other : Remarks: No data available
aquatic invertebrates
(Chronic toxicity)
Toxicity to microorganisms : NOEL (Tetrahymena pyriformis): 29.28 mg/l
Exposure time: 48 h
Remarks: QSAR

Reformate:
Toxicity to fish : LC50 (Fish): 1 - 10 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Crustaceans): 1 - 10 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : ErC50 (Algae): 1 - 10 mg/l
Exposure time: 72 h
Toxicity to fish (Chronic : NOEL (Fish): 2.6 mg/l
toxicity)
Toxicity to daphnia and other : NOEL (Daphnia (water flea)): 2.6 mg/l
aquatic invertebrates
(Chronic toxicity)
Toxicity to microorganisms : Remarks: No data available

Benzene:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 5.3 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 10 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata (algae)): 100 mg/l
Exposure time: 72 h
Toxicity to fish (Chronic : NOEC (Pimephales promelas (fathead minnow)): 0.8 mg/l
toxicity) Exposure time: 32 d

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Toxicity to daphnia and other : NOEC (Ceriodaphnia dubia (Water flea)): 3 mg/l
aquatic invertebrates
(Chronic toxicity) Exposure time: 7 d
Toxicity to microorganisms : IC50 (Nitrosomonas sp.): 13 mg/l
Exposure time: 24 h
Persistence and degradability
Components:
Light straight run naphtha:
Biodegradability : Result: Inherently biodegradable.

MTBE:
Biodegradability : Result: Not readily biodegradable.

Isomerate:
Biodegradability : Result: Inherently biodegradable.

Iso-pentane:
Biodegradability : Result: Readily biodegradable.

Reformate:
Biodegradability : Result: Inherently biodegradable.

Benzene:
Biodegradability : Result: Readily biodegradable.

Bioaccumulative potential
Components:
Light straight run naphtha:
Bioaccumulation : Remarks: Potentially bio-accumulative.
Partition coefficient: n- : log Pow: > 4
octanol/water

MTBE:
Bioaccumulation : Bioconcentration factor (BCF): 1.5
Partition coefficient: n- : log Pow: 1.06
octanol/water

Isomerate:
Bioaccumulation : Remarks: Potentially bio-accumulative.
Partition coefficient: n- : log Pow: > 4
octanol/water

Iso-pentane:
Bioaccumulation : Remarks: No data available
Partition coefficient: n- : log Pow: 4 (25 °C)
octanol/water

Reformate:
Bioaccumulation : Remarks: Potentially bio-accumulative.

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Partition coefficient: n- : log Pow: > 4


octanol/water

Benzene:
Bioaccumulation : Bioconcentration factor (BCF): 13
Partition coefficient: n- : log Pow: 2.13 (20 °C)
octanol/water

Mobility in soil
Components:
Light straight run naphtha:
Mobility : Medium: Soil
Remarks: No data available
MTBE:
Mobility : Medium: Soil
Remarks: High mobility in soils
Isomerate:
Mobility : Medium: Soil
Remarks: Based on the regional scale exposure assessment,
the multimedia distribution of the substance is 38.79% to
sediment and 24.91% to soil.
Iso-pentane:
Mobility : Medium: Soil
Remarks: Koc = 794.3 (20°C)
Reformate:
Mobility : Medium: Soil
Remarks: No data available
Benzene:
Mobility : Medium: Soil
Remarks: Koc = 134 (20°C)
Other adverse effects
Product:
Additional ecological : Toxic to aquatic life with long lasting effects.
information
An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal.
Components:
Light straight run naphtha:
Additional ecological : No data available
information
MTBE:
Additional ecological : No data available
information
Isomerate:
Additional ecological : No data available
information
Iso-pentane:
Additional ecological : No data available
information

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Reformate:
Additional ecological : No data available
information
Benzene:
Additional ecological : No data available
information

SECTION 13: Disposal information

Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
The product should not be allowed to enter drains, water
courses or the soil.

Contaminated packaging : Empty remaining contents.


Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

SECTION 14: Transport information

International Regulations

UNRTDG
UN number : UN 1268
Proper shipping name : PETROLEUM PRODUCTS, N.O.S.
Class : 3
Packing group : II
Labels : 3
IATA-DGR
UN/ID No. : UN 1268
Proper shipping name : Petroleum products, n.o.s.
Class : 3
Packing group : II
Labels : Class 3 - Flammable liquids
Packing instruction (cargo : 364
aircraft)
Packing instruction : 353
(passenger aircraft)
IMDG-Code
UN number : UN 1268
Proper shipping name : PETROLEUM PRODUCTS, N.O.S.
Class : 3
Packing group : II

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Labels : 3
EmS Code : F-E, S-E
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

SECTION 15: Regulatory information

Safety, health, and environmental regulations specific for the hazardous chemical
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous
Chemicals) Regulations 2013.
Occupational Safety and Health (Use and Standards of Exposure of Chemicals Hazardous to
Health) Regulations 2000.

The components of this product are reported in the following inventories:


REACH : Not in compliance with the inventory
DSL : This product contains the following components listed on the
Canadian NDSL. All other components are on the Canadian
DSL.
Isomerate
AICS : On the inventory, or in compliance with the inventory.
NZIoC : Not in compliance with the inventory
ENCS : Not in compliance with the inventory
ISHL : Not in compliance with the inventory
KECI : On the inventory, or in compliance with the inventory.
PICCS : Not in compliance with the inventory
IECSC : On the inventory, or in compliance with the inventory.
TCSI : Not in compliance with the inventory
TSCA : On TSCA Inventory.

SECTION 16: Other information

SDS preparation date : 10.02.2015


Revision Date : 30.11.2020
Sources of key data used to : CONCAWE - The oil companies’ European association for
compile the Safety Data Environment, Health and Safety in refining and distribution
Sheet (2017)
JAPAN NITE
ECHA - European Chemicals Agency
GESTIS database on hazardous substances - DGUV
Full text of other abbreviations

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

(Q)SAR - (Quantitative) Structure Activity Relationship


ACGIH - American Conference of Governmental Industrial Hygienists
AICS - Australian Inventory of Chemical Substances
ANTT - National Agency for Transport by Land of Brazil
ASTM - American Society for the Testing of Materials
bw - Body weight
C - Ceiling
CCHC - Chemicals Classification and Hazard Communication
CEIL - Ceiling
ChV - Chronic Toxicity Value
CMR - Carcinogen, Mutagen or Reproductive Toxicant
CPR - Controlled Products Regulations
DIN - Standard of the German Institute for Standardisation
DSL - Domestic Substances List (Canada)
ECx - Concentration associated with x% response
ELx - Loading rate associated with x% response
EmS - Emergency Schedule
ENCS - Existing and New Chemical Substances (Japan)
ErCx - Concentration associated with x% growth rate response
ERG - Emergency Response Guide
GHS - Globally Harmonized System of Classification and Labelling of Chemicals
GLP - Good Laboratory Practice
IARC - International Agency for Research on Cancer
IATA - International Air Transport Association
IBC - International Code for the Construction and Equipment of Ships carrying
Dangerous Chemicals in Bulk
IC50 - Half maximal inhibitory concentration
ICAO - International Civil Aviation Organization
ICOP - Industry Code of Practice on Chemicals Classification and Hazard
Communication
IECSC - Inventory of Existing Chemical Substances in China
IMDG - International Maritime Dangerous Goods
IMO - International Maritime Organization
ISHL - Industrial Safety and Health Law (Japan)
ISO - International Organisation for Standardization
KECI - Korea Existing Chemicals Inventory
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
MARPOL - International Convention for the Prevention of Pollution from Ships
MY PEL - Malaysian Permissible Exposure Limit
n.o.s. - Not Otherwise Specified
Nch - Chilean Norm
NITE - National Institute of Technology and Evaluation
NO(A)EC - No Observed (Adverse) Effect Concentration
NO(A)EL - No Observed (Adverse) Effect Level
NOELR - No Observable Effect Loading Rate
NOM - Official Mexican Norm
NTP - National Toxicology Program
NZIoC - New Zealand Inventory of Chemicals
OCSPP - Office of Chemical Safety and Pollution Prevention
OECD - Organization for Economic Co-operation and Development
PBT - Persistent, Bioaccumulative and Toxic
PICCS - Philippines Inventory of Chemicals and Chemical Substances
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of

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Safety Data Sheet

Unleaded Gasoline (Export RON 95)


Version 1.4 Release Date: 30.11.2020

Chemicals
SADT - Self-Accelerating Decomposition Temperature
SDS - Safety Data Sheet
STEL - Short Term Exposure Limit
TCSI - Taiwan Chemical Substance Inventory
TDG - Transportation of Dangerous Goods
TSCA - Toxic Substances Control Act (United States)
TWA - Time Weighted Average
UN - United Nations
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods
UVCB - Unknown or Variable Composition, Complex Reaction Products and
Biological Materials
vPvB - Very Persistent and Very Bioaccumulative
WHMIS - Workplace Hazardous Materials Information System
LLx - Loading rate associated with x% lethality effect

Disclaimer
To the best of PETRONAS knowledge, the information contained herein is accurate and
reliable as of the date of publication. Any use of information provided should be undertaken in
consultation with a professional with the appropriate expertise, as necessary in the
circumstances. No warranty, express or implied, is given as to the quality, accuracy, reliability,
applicability or completeness of the contents of this SDS. The information presented here
pertains only to the product as shipped. It is the responsibility of the customer to ensure that
any activities relating to the product comply with all federal, state or local laws. Any hazards
associated with any product regulatory requirements are subject to change and may differ
between various locations. Except to the extent required by law, re-publication or
retransmission of this SDS, in whole or in part, is strictly prohibited. PETRONAS does not take
responsibility for use, transportation, storage, handling, packaging or disposal of the product
that is beyond our knowledge and recommendation by this SDS.

Product Stewardship Advisory:


PETRONAS aims to increase awareness of all the hazards associated with the storage,
handling and use of its products. Thoroughly reviewing the accompanying Safety Data Sheets
and disseminating the information to all dependent and interested parties is an essential part
of any 'Responsible Care' programme.

MY / EN

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