Professional Documents
Culture Documents
Tagum College
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
In a Nutshell .................................................................................... 24
Q&A List .................................................................................... 25
Keywords Index ......................................................................... 26
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
4
DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
Penalties for Late The score for an assessment item submitted after the
Assignments / designated time on the due date, without an approved
Assessments extension of time, will be reduced by 5% of the possible
maximum score for that assessment item for each day
that the assessment item is late.
However, if the late submission of the assessment paper
has a valid reason, a letter of explanation should be
submitted and approved by the course coordinator. If
necessary, you will also be required to present/attach
pieces of evidence.
Return of Assignments / Assessment tasks will be returned to you within two (2)
Assessments weeks after the submission. This will be returned
through e-mail or via the Quipper.
For group assessment tasks, the course coordinatorwill
require some or few of the students for online or virtual
sessions to ask clarificatory questions to validate the
originality of the assessment task submitted and to
ensure that all the group members are involved.
Assignment You should request in writing addressed to the course
Resubmission coordinator your intention to resubmit an assessment
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
3
DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
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that usually found or encounter in crime scene, through this
subject you will know how to process and examinethis
different evidences. In addition, in this subject you will
experience on how to become an investigator and at the
same time a forensic chemist. So seat back, relax, and
enjoy every page of this module.
BIG PICTURE B
Week 4-5: Unit Learning Outcomes (ULO): At the end of the unit, you are
expected to
Metalanguage
The following are terms to be remembered as we go through in studying this
unit. Please refer to these definitions as supplement in case you will encounter
difficulty in understanding the explain the gunshot residue.
Paraffin test. To determine whether a person has discharged a firearm, the paraffin-
diphenylamine test is used.
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
4. COMPOSITION OF PRIMER
major primer elemental composition :lead (pb), barium
(Ba) or antimony (Sb)
trace element : aluminum (Al), sulfur (S), tin (Sn), or
calcium (Ca), potassium (K), chlorine (CI), or
silicon ( Si).
inorganic compound: mercury fulminates (present in
most ammunition manufactured in Eastern Europe
and used in middle East).
5. COMPOSITION OF GUNPOWDER
contain up to 23 organic compounds (carbon)
nitrocellulose is virtually always present along with nitrate and nitrogen containing
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
6. TYPES OF GUNPOWDER
SINGLE BASE - when the basic ingredient is
nitrocellulose.(originally known as guncotton, formula:
[C6H7(NO2)3O5]n, flashpoint:4.4°C (39.9°F).
DOUBLE BASED - nitrocellulose + 1 to 40% nitroglycerine
(nitric acid), produced by nitrating glycerol, formula:
C3H5N3O9.
TRIPLE BASED - nitrocellulose + nitroglycerine +
nitroguanidine.(colorless, crystalline solid that melts at
232°C and decomposes at 250°C, formula: CH4N4O2
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
form of disks, cylinders, cords, spheres, or plates of varying sizes. The term
“smokeless powder” is used to differentiate it from the earlier black powder, which
was quite smoky. Cellulose or glycerol nitrate combine with some stabilizers
(nitrobenzene or graphite nitrates, dichromate and oxalates)cellulose nitrate:
C12H14O4(NO3)6 + 6H2O+3N2+4CO2+8CO+H2 and glycerol nitrate:
C3H5(N)3)3+ CO2 +H2O + N2 +02.
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
specks, the location and the character of the blue specks and distribution and
location.
14. History. Was originated from Cuba when Dr. Gonzalo Iturrios first used
paraffin for collecting gunpowder residues from discharged firearm. In 1933,
Teodoro Gonzales of Criminal Identification Laboratory, Mexico City
introduced the test in US. This test the hands were coated with a layer of
melted paraffin.
14.1. FACTS with regard PARAFFIN TEST
Nitrates can’t easily be removed by ordinary washing of the hands
Because it is embedded to the skin it will stay for 72 hours
PT must be conducted within 72 hours
Appearance of tailing of blue specks
it is considered as a corroborative evidence
It is not conclusive
14.2. Consider:
Substances that provides a FALSE Positive Results
Fertilizers,explosives,tabacco,urine, cosmetics, food samples and cigarettes.
14.3. will these substances not give positive result for paraffin test?
if the hands of the subject person are contaminated with nitrates other than from
gunpowder, one will expect to find smudges or just a smear of blue color or a
conglomeration of blue specks. But nitrates from gunpowder appear blue specks
with tailings, because these particles were embedded into the hands with force.
14.4. False Negative results
Factors:
types of the caliber ammunition
Use of gloves
Length of the barrel
Age and efficiency of the gun
Direction of firing
Wind direction and velocity
Humidity
Lapsed of 72 hours
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
LENGTH OF BARREL’
a weapon of 2 inch barrel will deposit residue over a larger area than a weapon of 5
inch barrel (even if they are discharged from the same distance with the same
type of ammunition)
in a longer barrel, the hand is farther away from the
muzzle end of the gun .
it takes a bullet to travel in more time, thus using
up/burning up more, if not all, of the nitrates
DIRECTION OF FIRING
more powder residues will be obtained when the gun is
discharged pointing upward than downward
gunpowder residues have weight and will naturally fall down because of gravity.
WIND DIRECTION
in high velocity (strong wind), the powder residues will be
blown in the direction of the wind.
one is more likely to be positive for gunpowder nitrates if
there is no wind, or the wind direction is towards the
shooter.
15. DPA reagent is applied to cotton swabbing of the barrel and chambers of
the guns to determine if the firearm was discharged.
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
of gunpowder residue found on the clothing are the main factors considered in
determining the approximate distance of the shooter to the victim.
as the distance to the victim increases, the size of the pattern expands while
density decreases and vice-versa.
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
22.
CLASSIFICATION OF GUNSHOT DISTANCE
22.1. DIRECT/CONTACT WOUND. visible wound due to the flame of the
muzzle, gaping hole where
cloth is torn, blackening of
the area and presence of
partially burned powder in
entrance hole
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
22.3. 36 inches or more. Tattooing is seldom present and nitrates found is not
sufficient for GSR examination.
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
transit.
each specimen should be wrapped tightly and marked
clothing heavily smeared with blood should be dried thoroughly before packing
gun recovered from the scene of the crime and ammunition available should be
preserved
person suspected to have discharged a firearm should be subjected to a paraffin
test.
Let us try the following activities to check your understanding in this unit.
3. Paraffin is applied to allow the skin pores to open and release the nitrates
that may be present if a person fired a gun. Nitrates contain what chemical
element:
a. Nitrogen b. Potassium
c. Chlorine d. Phosphorus
4. Primer ignites when the firing pin hits the fire cartridge. The action is
known as:
a. Oxidation b. Explosion
c. Percussion d. Contact
5. The paraffin test can give false positive results or false negative results.
False negative results can happen when:
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
a. A person thoroughly washes his hands with soap and water within the 72
hour period following the firing of a gun.
b. A person fired a gun with his hands protected by gloves.
c. A person handles substances such as fertilizers, cosmetics or tobacco.
d. A personal actually fired a gun.
One is able to establish that a case of shooting is suicide from the following
findings, except;
The gun is found in the hand of the victim.
The wound of the victim is at the back of the head, particularly the nape.
The wound of the victim exhibited heavy gunpowder burns.
The amount of gunpowder in the hands of the victim indicate that the gun was fired
at close range.
8. Brass is used for cartridge and primer case. Brass is made up of the
following metallic elements:
a. Copper and zinc b. Aluminom and iron
c. Copper and aluminom d. Aluminom and zinc
When an autopsy was performed on a victim of shooting, it was found that there
were two entrance holes but one exit hole. This can be interpreted as:
Two bullets have entered the victim and exited at the same hole.
Two bullets have entered the victim but only one bullet was able to exit.
One bullet created two entrance holes in the victim
None of the above
10. A test for gunpowder is the reagent DPA. This stands for.
a. Diphenylalanine b. Diphynolamine
c. Diphenylamine d. dipyridoxineamine
Let’s Analyze
Let us try the following activities to know how deep your understanding about
the topics of this unit. At this juncture, you will be required to ELABORATE
your answers about the following questions: (10 points each)
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
1. Why do you have to wash the hands of the subject prior to obtaining the cast?
2. What is the purpose of the cotton layer added during paraffin wax casting?
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
In a Nutshell
Q&A List
You are free to list down all the emerging questions or issues in the provided
spaces below. These questions or concerns may also be raised in the LMS or other
modes. You may answer these questions on your own after clarification. The Q&A
portion helps in the review of concepts and essential knowledge.
Questions/Issues Answers
Keywords Index
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
Metalanguage
The following are terms to be remembered as we go through in studying this
unit. Please refer to these definitions as supplement in case you will encounter
difficulty in understanding the process of explosives, explosion and to explain fire and
arson investigation.
Essential Knowledge
The following are the general principle of explosive, explosion and to explain
fire and arson investigation.
Explosive. is any substance that may cause explosion by its sudden decomposition
or combustion. Reactive substance that contains a great amount of potential energy
that can produce explosion. Accompanied by light, heat, soundand pressure.
Potential energy. chemical energy (nitroglycerin or grain dust), pressurized gas (gas
cylinder or aerosol can) and nuclear energy (fissile isotopes).
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
powder and smokeless powder. Burn rate is less than 3000 ft/second. Black
powder is a mixture of potassium or sodium nitrate, charcoal, and sulfur.
Smokeless powder consists of nitrated cotton (nitrocellulose) or nitroglycerin and
nitrocellulose.
Among the high explosives, primary explosives are ultra-sensitive to heat, shock, or
friction and provide the major ingredients found in blasting caps or primers used
to detonate other explosives. Examples are DDNP (diazodinitrophenol),and lead
azide. Burn rates are 3000 –9000 ft/second.
5. CLASSIFICATION OF EXPLOSIVES
ACCORDING TO THE VELOCITY OF REACTION INVOLVED. the speed
of chemical reaction or detonation of the explosive determines the
classification of explosive. Low, primary and initiating and high explosive
LOW EXPLOSIVES - no detonation, low burning and used mainly as propellants like
black and smokeless powder, the rate of decomposition is a relatively slow
process and the wave produced is less than the speed of sound, launching
rockets, projectiles from guns and missile systems.
CLASSES OF LOW EXPLOSIVES.
Primer. An explosive (generally lead azide, mercury fulminate or
pentaerythritol tetranitrate (PETN) this upon detonation releases a great deal
of energy in a very short time.
Igniter. In gun propellants and safety blasting fuels, signal and distress
rockets and in firecrackers are used in mining and low power explosives.
when fired, the igniter will produce the equivalent of a match igniting,
exhausting through the hole. Compostion 1. potassium nitrate (KNO3) +
charcoal + sulfur 2. sodium nitrate (NaNo3) + charcoal +sulfur 3. sulfurless
black powder = KNO3
+charcoal 4. pyrodex = KNO3 + potassium perchlorate 5. (KclO4 potassium
perchlorate) + charcoal + sulfur + cyanoguanidine
Propellant (gunpowder). Are used in launching projectiles from guns,
rockets and missile system. Mixture of one more energetic materials (main
charger), plasticizers to improve processing characteristics, stabilizers to
increase storage life and inorganic additives to facilitate handling ignitability
and decrease muzzle mesh.
Kinds of Propellants
smokeless powder. The most widely used propellant is based on
nitrocellulose (NC). double NITROGLYCERINE (NG) + NC. triple NC + NG +
NITROGUANIDINE
Single base. nitrocellulose (NC) + diphenylamine (DPA) + dinitrotoluenee
(DNT) + dibutyl phtalate, NC + DPA + potassium sulfate (K2SO4), NC +
DPA + K2SO4 +DNT
Double base. NC + nitroguanidine (NG) + potassium nitrate (KNO3) + rthyl
centralite + graphite, NC + NG + KNO3 + et centralite + diethyl phtalate, NC
+ NG + et centralite + triacetin + Pb salicylate + pb stearate, NC + NG +
diethyl phtalate + 2-nitroDPA + lead salts + wax
Triple base. NC + NG + nitroguanidine + NaAIF (sodium, aluminum,
flouride) +Et centralite, NC + NG + nitroguanidine +NaAlF + dibutyl phtalate
+ 2-nitroDPA
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
9. High Explosives. These explosives have very fast or high detonating rate
like dynamites, TNT (trinitrotoluene) and Cyclonite (RDX). TNT flammable
used as high explosive and in chemical synthesis.
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
10.8.
Matter: atoms (molecules)
Air: 21 % Oxygen and nitrogen 75%
Oxidation: combination of elements and compound with oxygen producing stable
substances.(flammable substance and combustion)
Flaming: gaseous reaction where plume of hot gases rises by convection when air
and its oxygen is maintained by solid liquid in a close room.
Pyrolisis: decomposition of material
10.15. INCENDIARY FIRE. Largest and most obvious fire of all. Setting of fire
with intention to destroy the property.
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
10.18. ARSON. It is a crime against persons and property. It is the willful and
malicious burning of another’s property or the burning of one’s own property
with intent to injure or defraud the insurer of that property. It is the burning of
all kinds of buildings, structures, aircraft, watercraft, crops, forest land and
personal property.
Let’s Check
Let us try the following activities to check your understanding in this unit.
Fire and arson have the same elements. They differ only in that:
In fire it can be accidental, intentional, or natural.
Arson is the intent to bring damage to life and property with the use of fire.
None of the above.
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
The elements of fire are: combustible material, oxygen, and source of initial ignition.
To successfully put out a fire one must perform the following actions except;
Remove combustible material from the fire.
Use powerful equipment to deliver a big volume of water because water will
dissipate the heat which is an element of fire.
Deliver a supply of oxygen to the fire.
Ensure that the fire does not spread to surrounding flammable materials.
A. Investigation reveals that there are multiple areas of origin of the fire.
B. Investigation show the presence of accelerants in the crime scene.
A and B are indicative of arson.
Only A is indicative of arson
Only B is indicative of arson
A and B are not indicative of arson
For fire and arson investigation, the following are good working technique except:
Always work in pairs
Use trained accelerant detection dogs
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
Look for residuals among the burned and not burned sections of the structure.
Depend on trained dogs to perform all the work.
When there are fatalities in a fire, it is a good practice to presume that these victims
died in the fire:
True b. False c. It depends
Let’s Analyze
Let us try the following activities to know how deep your understanding about
the topics of this unit. At this juncture, you will be required to ELABORATE
your answers about the following questions: (10 points each)
1. What is the preferred container for packing and preserving remnants of a bomb
explosion? Why?
25
DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
In a Nutshell
Q&A List
You are free to list down all the emerging questions or issues in the provided
spaces below. These questions or concerns may also be raised in the LMS or other
modes. You may answer these questions on your own after clarification. The Q&A
portion helps in the review of concepts and essential knowledge.
Questions/Issues Answers
Keywords Index
26
DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
27
DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
Plagiarism is a serious intellectual crime and shall be dealt with accordingly. The
University shall institute monitoring mechanisms online to detect and penalize
plagiarism.
All borrowed materials uploaded by the teachers/Course Coordinators shall be
properly acknowledged and cited; the teachers/Course Coordinators shall be
professionally and personally responsible for all the materials uploaded in the
online classes or published in SIM/SDL manuals.
Teachers/Course Coordinators shall devote time to handle DED courses and shall
honestly exercise due assessment of student performance.
Teachers/Course Coordinators shall never engage in quarrels with students
online. While contentions intellectual discussions are allowed, the
teachers/Course Coordinators shall take the higher ground in facilitating and
moderating these discussions. Foul, lewd, vulgar and discriminatory languages
are absolutely prohibited.
Students shall independently and honestly take examinations and do
assignments, unless collaboration is clearly required or permitted. Students shall
not resort to dishonesty to improve the result of their assessments (e.g.
examinations, assignments).
Students shall not allow anyone else to access their personal LMS account.
Students shall not post or share their answers, assignment or examinations to
others to further academic fraudulence online.
By handling DED courses, teachers/Course Coordinators agree and abide by all
the provisions of the Online Code of Conduct, as well as all the requirements and
protocols in handling online courses.
By enrolling in DED courses, students agree and abide by all the provisions of the
Online Code of Conduct, as well as all the requirements and protocols in handling
online courses.
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DEPARTMENT OF CRIMINAL JUSTICE EDUCATION
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
Course Coordinators
Approved by:
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DEPARTMENT OF BUSINESS ADMINISTRATION EDUCATION
Bachelor of Science in Tourism Management Program
Mabini Street, Tagum City
Davao del Norte
Telefax: (084)655-9591 Local 116
Days
Monday Tuesday Wednesday Thursday F
Modality Synchronous Asynchronous Synchronous Asynchronous Syn
Teacher to
Type of Learner to Learner to Learner to Teach
Learner
interaction Content Learner Content
Uploading of Utilization of SIM Group Sharing Utilization of SIM Discussio
Learning Collab (Clarifi
Materials Videos Forum Videos New le
Zoom Collab
Discussion Self-directed Self-directed Forum
Collab Activities Consultation Activities Zoom
Forum
Suggested Zoom Supplem
Activities Activiti
Giving of
Formative Quiz
Assessment
Consulta
Giving of
Performance
Task
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