CHEMISTRY MICKO-XI OICHIOMET (MOLE CONCEPT) " ASPECIALLY DESIGNED KIT FOR LEARNING" THEKEY — Basic principles ofsubjects. An outline of the topics to be discussed in class lectures. THEATLAS Basic layout of subject. A route map correlating different subtopics in coherent manner. EXERCISE! Introductory problems based on JEE to get first hand experience of problem solving. EXERCISE II A collection of good problems. QUESTION BANK Test your objective skill. EXERCISE II A collection of previous Fifteen years JEE problems. om) VIBRANT ACADEMY EXESMESIE (India) Pvt. Ltd. ‘@ unacademyINORGANIC CHEMISTRY, NA. (SODIUM SIR) 14 Sol. 12 Sol. 13 Ex. Sol. KEY CONCEPTS LAWS OF CHEMICAL COMBINATION Chemical reactions take place according to certain laws. These laws are called the Laws of Chemical Combination. “These are no longer useful in chemical calculations now but gives an idea of earlier methods of analysing and relating compounds by mass." Law of Conservation of Mass (Lavoisier (1774)) : During any physical or chemical change, the total mass of the products remains equal to the total mass of the reactants. Mass is conserved What weight of silver nitrate will react with 0.585g NaCl to produce 1.4359 AgCI and 0.85 g NaNO,? ‘AgNO, + NaCl—> AgCl+ NaNO, xgram 0.5859 1.4359 0.85g According to law of conservation of mass, x+0.585 = 1.435 + 0.85 or x=1.70 gram ‘Law of Constant Composition or Definite Proportions (Proust (1799)) : Ina given chemical compound, the elements are always combined in the same proportions by mass. 0.5gram silver is dissolved in excess of nitric acid. This solution is treated with excess of NaCl solution when 0.669 AgClis formed. (One gram metalic silver wire is heated in dry Cl,. 1.329 AgClis formed. ‘Show that these data confirm the law of constant proportion, In first experiment : Mass of Ag = 0.59, Mass of AgCl = 0.669, Mass of Cl = 0.66 =0.5= 0.169 Ratio of Ag: Cl= 0.50.16 = 3.125 ‘Second experiment : Mass of Ag = 1g Mass of AgCI = 1.32g Mass of Cl = 0.32g 1 Ratio of Ag: Cl= ay = 3.125 ‘Thus ratio of Ag: Cl in AgCI is constant. This confirms the law of constant compositions, Law of Mul le Proportions (Dalton (1803) : Whenever two elements form more than one compound, the different masses of one element that combine with the same mass of the other element are in the ratio of small whole numbers. N, and O, combine to form a number of compounds such as NO, N,O, NO,,N,O,, Show that these follow the law of muttiple proportion. Compound Mass ofitragen_-mass of oxygen mass of oxygen which combines with 28g of nitrogen NO 2B 16 16 NO 4 16 2 N,Q, 2B 48 48 N,O5 2B 80 80INORGANIC CHEMISTRY NA. (SODIUM SIR) ‘Mass of oxygen which combines with 28g nitrogen in different compounds is 16, 32, 48 and 8Ogram. Thus, the ratio of the masses of oxygen which combine with 28g of nitrogen is 1: 2: 3:5. Itis a simple whole number ratio. 1.4 Lawof Reciprocal Proportions (Richter (1792): When two elements combine separately with a fixed mass of a third element then the ratio of their masses in Which they do sois either same or some whole number multiple ofthe ratio in which they combine with each other. Ex. An oxide of copper contains 11.2% O, a chloride of copper contains 35.86% Cl and an oxide of chlorine contains 18.64% 0. Show that these data illustrate the law of reciprocal proportion. Sol. In copper oxide : % O= 11.2, %CU= 888 (One gram copper combines with 11.2/88.8 = 0.126 gram oxygen In copper chloride : C1 = 35.86%, Cu= 64.14% Ratio of mass of 0 : Cl which combines with one gram copper is 0.126 : 0.559 or 1:4.4 In oxide of chlorine O= 18.64% , Cl= 81.36% Ratio of mass of O : Clis 18.64 81.36 or 1:4.960r124.4 Thus ratio is nearly the same. This confirms the law of reciprocal proportion 1.5 Gay-Lussac’s Law of combining volumes : According to Gay-Lussac's law of combining volume, when gases react together, they always do so in volumes which bear a simple ratio to one another and to the volumes of the produets, if these are also gases, provided all measurements of volumes are done under similar conditions of temperature and pressure. Ex. 10litre of hydrogen and’ litre of Cl, are made to react to maximum possible extent. Whatis the final volume of reaction mixture? Pressure and temperature remain constant. Sol. H, eee Cee Hcl Initially: 10 3L 0 After reaction: (10-3)L 0 a Total volume after reaction 0-3 +6 = 131, 1.6 AVOGADRO’SLAW: ‘The volume of a gas (at fixed pressure and temperature) is proportional to the number of moles (or molecules of gas present). Mathematically we can write Ven Or Equal volumes of all gases under similar conditions of temperature and pressure contain equal number of molecules. Ex. 2Ha) + 0, — 2H,0(9) 2mole 1 mole 2mole 2 * 6.02 x 10% 1 «6.02 x 10% 2 * 6.02 x 109 molecules molecules molecules ‘The ratios of volume, moles or molecules are related by simple integers Le., 2:1:2.INORGANIC CHEMISTRY, NA. (SODIUM SIR) z 0} di) ) ” 0 ii w) ™ (vi) (vil) Ex. Sol. DALTON’S ATOMIC THEORY = Matter consists of tiny particles called atoms. ‘Atoms are indestructible. In chemical reactions, the atoms rearrange but they do not themselves break apart In any sample of a pure element, all the atoms are identical in mass and other properties. The atoms of different elements differ in mass and other properties. When atoms of different elements combine to form compounds, new and more complex particles form. However, in a given compound the constituent atoms are always present in the same fixed numerical ratio. MODERN ATOMIC THEORY : ‘Atom is no longer considered to be indivisible : Ithas been found that an atom has a complex structure and is composed of sub-atomic particles such as electrons, protons and neutrons. ‘Atoms of the same element may not be similar in all respects : Ex. Isotopes (?/Na, 7}Na) ‘Atoms of different elements may be similar in one or more respects : Ex. Isobars. (49a. #2ar) ‘Atom is the smallest unit which takes part in chemical reactions : Although atom is composed of sub- atomic particles, yet its the smallest particle which takes part in chemical reactions. The ratio in which atoms unite may be fixed and integral but may not be simple : For example, in sugar molecule (C,,H,,0,,), the ratio of C, H and O atoms is 12 : 22: 11 which is not simple. ‘Atoms of one element can be changed into atoms of other element : Ex. Artificial Nuclear Reactions ‘The mass of atom can be changed into energy : According to Einstein's equation E = mc? (E = Energy, m=mass, c= the velocity of light, ., 3 x 10" cm sec), mass and energy are inter-convertible. MOLE CONCEPT 41 Definition of mole : One mole is a collection of that many entities as there are number of atoms exactly in 12.gm of C-12 isotope. ‘mole = collection of 6.02 « 10®° species 6.02 « 10% = N, = Avogadro's No. ‘1 mole of atoms is also termed as 1 gm-atom, 1 mole of ions is termed as 1 gm-ion and ‘mole of molecule termed as 1 gm-molecule. or RK 4.2 Methods of Calculations of mole : Given number of substance (2) _Ifno. of some species is given, then no. of mole Na Calculate the number of moles in 6.02 x 10??molecules of NH,, Number of molecules = Number of moles * Ny 6.02 x 1072= x x 6.02 x 10%, x= 0.1 (0) _Ifweight of a some species is given, then Given wt Given wt. for atoms : no. of moles = “Atomig wi. : for molecules : no. of moles = iclecular wi.INORGANIC CHEMISTRY, NA. (SODIUM SIR) Ex. Calculate the number of moles in 49 gram H,SO, (molecular mass = 98). Sol. Number of moles = =05 zl als (©) _Ifvolume ofa gasis given along with its temperature (T) and pressure (P) Py use n= RT where R = 0.0821 lt-atm/mol-K (when Pis in atmosphere and Vis in lite.) — Donotuse this expression (PV = nRT) for solidsfiquids. © ‘mole of any gas at STP occupies 22.7 litre. But in general we use 22.4 litre? 2 © Gases do not have volume. What is meant by "Volume of gas"? Ex. Calculate the number of moles, molecules and atoms in 2 litre chlorine at 300K and 2.46 atmospheric pressure. Sol. First ofall, caloulate the volume of the gas at STP. PM _P2Ve tT P, = 2.46 atm, V, = 2 litres, T, = 300K, P, = one atm, V,=?, T, = 273K 2.46x2_1xVp 300 7 ays OF M2" 44772 litres 22.4 litre of the gas at STP contains moles 4.4772 litre of the gas at STP contains moles = = 0.2 (approx) Molecules = moles x N,.= 0.2 x 6.02 x 10%= 1.2 « 102° molecules chlorine molecules is diatomic Clatoms = Molecules x 2 = 1.2 x 10% x 2= 2.4 x 10% ‘Number is (eNaa\ ass)» Multiotied by | cong} /‘wumber in GS gram Particles Multiplied by a NaINORGANIC CHEMISTRY, NA. (SODIUM SIR) Ex, Sol. Sol. Ex. Sol. ‘43. Atomic weight : itis the weight of an atom relative to one twelvth of weight of 1 atom of C-12 © Be clear in the difference between 1 amu and 1 gm. (@) Average atomic weight = 5 % of isotope X molar mass of isotope. * The % obtained by above expression (used in above expression) is by number (i. its a mole%) ‘The relative abundance of the three isotopes of carbon C2, C*¥ and C*is given in the table. Isotopes Relative abundance(%) Atomic mass (amu) ce 98.892 12 ce 1.108 13.00335 cH 2x 107 14.00317 What is the average atomic mass of C ? 12 98,892 + 13.0335 1.108 +14.00317 «2%10- Aver mic mass = erage atomic mass a0 =12011u 44° Molecular weight : Itis the sum of the atomic weight of al the constituent atom. Average molecular weight where n,= no. of moles of any compound and M,= molecular mass of any compound. * Make yourselves clear in the difference between mole% and mass% in question related to above, © Shortcut for% determination i average atomic weightis given for X having isotopes X*& X* Average atomic weight - wt of X' difference in weight of X* & x® Calculate molecular mass of H,PO, Molecular mass of H,PO, = 3 x atomic mass of H + 1 x atomic mass of P + 4 atomic mass of O. = 31413144 x 16 = 98 amu Air is a mixture of nitrogen [N,] and oxygen [0,] contain 20% by mole of oxygen. 100 Find average molar mass of air EMPIRICAL FORMULA, MOLECULAR FORMULA: 5.1 Empirical formula : Formula depicting constituent atom in their simplest rato. ‘Molecular formula : Formula depicting actual number of atoms in one molecule of the compound 5.2 Relation between the two : Molecular formula = Empirical formula x n Molecular mass Empirical Formula mass Check out the importance of each step involved in calculations of empirical formula.INORGANIC CHEMISTRY, NA. (SODIUM SIR) 53 Vapour density = Vapour density : Ratio of density of vapour to the density of hydrogen at similar pressure and temperature. fer Vonourdensiy = aleeusr mass ® Can you prove the above expression? 2 ® Is the above parameter temperature dependent? Ex. The mass % of an organic compound is C = 57.8%, is 63. What is the molecular formula ? = 3.6% and rest is oxygen. The VD of the compound Sol. Element Mass % Atomic ratio ‘Simplest ratio Simplest whole number ce nae ee pena °o 38.6 x ™ 2x1=2 Empirical formula = C,H,0,, Empirical weight = 4 « 12+ 1342+ 16=83 ‘Molecular weight = 2 « VD = 166 Molecular weight _ 166 _ Empirical weight 63 Molecular formula = (Empirical formula), = (C,H,0,), = C,H, 6 STOICHIOMETRY : Stoichiometry pronounced ("stoy ~ key - om ~ e ~ tree") is the calculations of the quantities of reactants and products involved in a chemical reaction. Following methods can be used for solving problems. (@) Mole Method Ex. _ Howmany moles of methane are required to produce 22 gram CO, after combustion ? Sol. CH, +20,—> CO, +2H,0 ‘mole 44g 44 gram of CO, is produced from CH, 22.gram CO, is produced trom CH, = 22 =0.5 mole (©) Factor Label Method Ex. 2moles of Aand 3 moles of B are allowed to react according given reaction 2A +B —> C+D 2C +E —> 4F where E is in excess amount. Calculate moles of F form in the reaction. Sol teach tBee = eG ep 2moles 3 moles IR ‘mole 2c + E > 4F ‘1mole ex . 2moles (© POAC method } Balancing not required but common sense () use it with sight care.INORGANIC CHEMISTRY, NA. (SODIUM SIR) Ex. 31g of P, is completely react with 32g of O, and form P, O,, and P,O, Calculate mole ratio of P,O,, and P,O, formed Sol. Py + O,—> PiOq + PiOy w4mole 1mole amole — bmole POAC at P 4.x mole of P= 4 x mole P,O,, +4 * mole of P,O,, 1=da+ab (ty POAC at 0 2 mole of O, = 10 « mole P,O,9+ 6 * P,O, 2=10a+6b (2) a= 1/8 ;b= 18 (@) Equivalent concept to be discussed in stoichiometry-II later 7. CONCEPT OF LIMITING REAGENT. 74 Limit 1g Reagent : itis very important concept in chemical calculation. It refers to reactant which is present in minimum stoichiometry quantity for @ chemical reaction. It is reactant consumed fully in a ‘chemical reaction. So all calculations related to various products or in sequence of reactions are made on the basis of limiting reagent. % —__Itcomes into picture when reaction involves two or more reactants. For solving any such reactions, first step is to calculate LR. 7.2 Calculation of Limiting Reagent : (2) By calculating the required amount by the equation and comparing it with given amount. [Useful when only two reactant are there] (©) Bycalculating amount of any one product obtained taking each reactant one by one irrespective of other reactants. The one giving least product is imiting reagent. (©) _ Divide given moles of each reactant by their stoichiometric coefficient, the one with least ratio is limiting reagent. [Useful when number of reactants are more than two.] Ex. 20 gram CaCO, is treated with 20 gram HCI. How many gram of CO, are generated ? Which is the limiting reagent? Sol. CaCO,+ 2HCI_ © —> CaCl, +H,0 +O, 100 -2*365=73 44 (a)> 100 gram CaCO, produces CO,= 44 gram 44x20 20 gram CaCO, produces CO,= “>> =8.8 gram (0) © 73gram HC! produces CO, = 44 gram 20 gram HC! produces CO, = “429 = 12.08 gram 73 ‘Smaller amount (8.8 g) CO, is obtained from CaCO, Therefore CaCO, is the limiting reagent. HCl is the excess reagent. CO, obtained is 8.8 gram.INORGANIC CHEMISTRY, NA. (SODIUM SIR) Ex, Sol. Ex. Sol. actual yield —__aetual yiel ___400 theoretical maximum yield PERCENTAGE YIELD : The percentage yield of product = IF 1.42g of P,O,9 was obtained when 1.24 g of P, reacts with 1.92 g of O,. Calculate the % yield of the reaction. Py + 50, —> PO 1.249 1.929 0.01mole 0.06mole LR is Py; moles of P,O,.= 0.01 Mass of P, Oj. obtained = 284 0.01 = 2.84g 1.42 i 100 = yield of reaction = 555 50% CONCENTRATION TERMS : 9.1 General concentraction term : Mass (@)__Density = Fopipeg Unit: amfec 66 gram of a solute are present in 500 mL of solution. Whatis the concentration of the Solution in grams/ litre? _ w(in gram) 6 Viitrey 0.5 = 129% Density of any substance (©) Relative density = Density of refrence substance Density of any substance (solid/liquid) (©) Specific gravity = Density of water at 4° _Density of vapour_at some temperature and pressure (2) Vapour density= Density of Hp gas at same temperature and pressure 9.2 Forsolutions (homogeneous mixture) : Ifthe mixture is not homogeneous, then none of them is applicable. 2 ©) _Ciassity each given rato.as wi, wl, viv and comment on thelr temperature dependence. Ww) __wt of solute (@) — %ebymass [J = wi. of solution * 100 1X % by mass means 100 gm solution contains X gm solute ; «. (100-X)gm solvent } solution is prepared by adding 2g of a substance Ato 18g water. Calculate the mass percent of the solute. Total mass = 2+ 18 = 20g Mass of Ax 100 _ 2100 Total mass 20 Similarly, mass % of solvent may be calculated. =10% Mass % of A= Mass of the solvent x100 _ 18100 ‘Mass of the solution 200 (*) wt. of solute 100 ©) % |W] = volume of solution * 10° {for liq. solution) w % (¢ ‘means 100 mi solution contains X gm solute ]INORGANIC CHEMISTRY NA. (SODIUM SIR) * Tor gases % by volume Is Same as mole =) volume of solute Moles of solute (2) 7 : a (= TARTS 100 yes = MOREA E00 Moles of solute Total moles Ex. Calculate the mole fraction of ethylene glycol (C,H,O,) in a solution containing 20% of C,H,O, by mass. Sol. Suppose mass of solution = 100g Mass of ethylene glycol = 209 ‘Mass of water = 100 - 20 = 80g (€) Mole fraction (x) = 20 Molar mass of C,H,O,= = 55 = 0.922 w 80 Moles of H,0 = "= 75 Aaa Total moles = 0.922 + 4.444 = 4.766 Moles of glycol _ 0.322 totalmoles = 4.765 ~ ©0068 ‘Mole fraction of glycol = f water = Moles ofwater 4.444 _ Mole fraction of water = —“totai moles = 4765 70.992 ‘Mole fraction of water can also be calculated as 10.068 = 0.932 Mole of solute ©) — Molarity (M) = \jojume of solution in litre Ex, 49.grams of H,SO, are present in 100 mL aqueous solution. What is the molarity of H,SO, ? Molar mass of H,SO,= 98 180, grams) 49 Sol, Molarity (M) = Hoiar mass of solute x V(ltres) 980.1 Molesof solute (9) Molality (m) = assof solvent(inkg) Ex. 214.2g of an aqueous solution of sugar contains 34.2 gram suger. If molecular mass of sugar is 342, calculate the molality of the solution. Sol. Mass of solution = 214.2g Mass of sugar (w) = 34.29 Mass of solvent (W) = 214.2 - 34.2 = 180g = 0.18 kg w 34.2 Molality = mass of solvent (in kg) ~ 342x.18 = 0.55 Massof solute | 495 _ _Mass of solute Massof solvent” = Mass of solution (h) Parts per milion (ppm) = ge © _cerursevesverymuch confor inerneronversn ts vex heneyINORGANIC CHEMISTRY, NA. (SODIUM SIR) Sol. 10. Sol 9.3 Volume strength ofH,0,: H,0, : Labelled as ‘volume H,0, (fore.g. 20V H,0,),itmeans volume of O, (in litre) at 1 atm & 273K that can be obtained from 1 litre of such a sample when it decomposes according to 1 H,0,>H,0+ 50, Volume strength of H202 Molarity of H,0, TT : ee ear ee eee Calculate the M of 500 ml of "60 V HO, solution.” Volume strength of HzO2 _ _50 Molatity of H,0, = OTS SEN 2 = ‘SOME EXPERIMENTAL METHODS : 10.4 Formolecularmass determination : (@) Victor Meyer's process : (for volatile substance) Procedure : Some known weight of a volatile substance (w) is taken, converted to vapour and collected over water. The volume of air displaced over wateris given (V) and the following expressions are used =— RT Ser Me Pepi. ifaq. tension is not given if aq, tension is P* ‘Aqueous tension : Pressure exerted due to water vapours at any given temperature ©) __ tris comes in picture wnen any gas is collected over water. Can you guess why? Ina Victor Meyer apparatus 0.24 of a volatile compound displaced 100 mi of air over water at 27°C and 790 mm of Hg. Calculate molecular mass of compound (Aq. tension of water at 27°C = 30mm of Ha). wip 0.2760 (P=PV * (790-30)x0.1 M 24.63 = 49.26 (0) Silver salt method : (for organic acids) Basicity of an acid : No. of replacable H" ions in an acid (H contained to more electronegative atom acidic) Procedure : Some known amount of silver salt (w, gm) is heated to obtain w, gm of white shining residue of silver. Then if the basicity of acid isn, molecular weight of acid would be (wy 1 { 108 n ©) Trisis one good practical application of POAC. ’: Mya =) and molecular weight of acid = M,..—n(107)INORGANIC CHEMISTRY NA. (SODIUM SIR) & Sol. n. 0.607 g of a silver salt of basic organic acid was quantitavely reduced to 0.37 g of pure silver. Calculate the ‘mol. weight of the acid, AQA—> Ag 0.6079 0.379 POAC at Ag 3x mole of Ag,A= 1 x mole of Ag 3x0.607 0.37 324+A 108 A=207.535 Molecular weight of HyA= 210.535 g/mol ©) Dorotremember the formulas, derive them using the concept is easy. © Reference :NCERT EUDIOMETRY : [For reactions involving gaseous reactants and products) Eudiometry or gas analysis involves the calculations based on gaseous reactions or the reactions in which at least two components are gaseous, in which the amounts of gases are represented by their volumes, measured at the same pressure and temperature. Some basic assumptions related with calculations are Gay-Lussac’s law of volume combination holds good. According to this law, the volumes of gaseous reactants reacted and the volumes of gaseous products formed, all measured at the same temperature and pressure, beara simple ratio, No(g) +3Ha(g) —+ 2NHa(g) ol 3V0l 2a Problem may be solved directly is terms of volume, in place of mole. ‘The volumes of solids or liquids is considered to be negligible in comparison to the volume of gas. Itis due to the fact that the volume occupied by any substance in gaseous state is even more than thousand times the volume occupied by the same substance in solid or liquid states. 2H2(9) + O2(9) —> 2H0(0) 2mole — mole 2mole 2 vol. ‘vol. negligiable volume Airis considered as a mixture of oxygen and nitrogen gases only, f not specified. Nitrogen gas is considered as an inert gas. It Is due to the fact that nitrogen gas reacts only at very high temperature due to its very high thermal stability. Eudiometry is performed in an eudiometer tube and the tube can not withstand very high temperature. This is why, nitrogen gas can not participate in the reactions ‘occurring in the eudiometer tube. ©) Tre stoichiometric coefficient of a balanced chemical reactions also gives the ratio of volumes in Which gasesous reactants are reacting and products are formed at same temperature and pressure ‘The volume of gases produced is often given by mentioning certain solvent which absorb contain gases,INORGANIC CHEMISTRY, NA. (SODIUM SIR) Solvent ‘985 (es) absorb KOH CO, $O,, Cl, ‘Ammon Cu,Cl, co Turpentine oil 05, Alkaline pyrogaliol water NH, HCI Cuso, ICaCl, HO ©) creck outfor certain assumption which are to be used for solving problem related to this. Ex. 20 ml of a mixture of CO, CH, & N, exploded with excess of oxygen gave a contraction of 14 ml after ‘combustion. There was further contraction of 16 ml when residual gas treated with KOH. Find mole % of CO in the original mixture. Sol. CO* 30, > co, CH, +20, —> CO, + 2H,0(0) aaa a bea bo - Veontracton = Ve = Ve t4mi= 5 +20 (a) 16ml=a+b (2) b=4ml 12mi 20-a-b=4mi ¥ 7 = Mole % of CO = > 100 = 60%INORGANIC CHEMISTRY, NA. (SODIUM SIR) The Atlas ‘Chemical reaction represented Sometimes vanttately by performed in Balanced ‘Solution ‘chemical T equation ses a Molarity T shows Product and Product and | | Law of mass canbe reactant formulas| reactant ratios|.| conservation | related by. determined by volume fo T T serarived involving Badal + Elemental Formula analysis units a whic Telated to ‘ves related by rams by 4 Percent ‘Avogadro's Molar composition] number mass T used to caleate sei in Empirical [Stoichiometry formula T to caleuiate ives with molar mass a + ¥ Molecular Limiting Excess, Percent formula reactant reactant yield& VIBRANT ACADEMY wv unacademy EEISGMESIEM (India) Pvt. Ltd. PHYSICAL CHEMISTRY : NA (SODIUM SIR) ‘MOLE CONCEPT 2 10. 1. ASSIGNMENT-1 Mass of 10 atom of Hydrogen is - (A) 1.66 « 103g (B) 10° g (C) 10% g (0) 10° g Which of the following contains the largest number of atoms - (A) 11g of CO, (8) 4g of Hy (C) 8g of NH, (0) 8g of SO, Number of neutrons present in 1.7 g of ammonia is AN, (B)N,/10*4 (C)(Ny/10)x7 (D)N,* 107 Total no. of atoms in 44 gm of CO, is - (A) 6.02 x 1023 (B) 6.02 x 10% (C) 1.806 x 10% —— (D) 18.06 x 102 8 gm of O, has the same number of molecules as- (A) 7 gm of CO (8) 14 gm of CO (C) 14 gm of CO, (D) 12 gm of CO, Four containers of 2L capacity contains dinitrogen as described below. Which one contains maximum number of molecules under similar conditions. (A) 2.5 grmolecules of N, (8) 4 g-atom of nitrogen (C) 3.01 * 10% N atoms (D) 84 g of dinitrogen What is correct for 10 g of Caco, (A) It contains 1g-atom of carbon (8) It contains 0.3 g-atom of oxygen (C) It contains 12 g of calcium (D) None of these 4.0 g of caustic soda (NaOH) contains same number of sodium ions as are present in- (A) 10.6 g of Na,CO, (8) 58.5 g of NaCl (C) 100 mi of 0.5 M Na,SO, (0) 1mol of NaNO, The number of oxygen atoms present in 14.6 g of magnesium bicarbonate Mg(HCO,), is (A) BN, (8) O.6N,. (ON, (D) 0.5 Ny. One mole of P, molecules contains - (A) 1 molecule (8) 4 molecules (C) (1/4) * 6.022 = 102° atoms (0) 24.088 « 109 atoms Number of Ca‘? and CI- ion in 111 g of anhydrous CaCl, are - (A) Ny 2Nq 8) 2Nq, Ng (C) Ng, Ny (0) Noneow VIBRANT ACADEMY @ unacademy EEIDGIEEIEM (India) Pvt. PHYSICAL CHEMISTRY : NA (SODIUM SIR) MOLE CONCEPT. 10. ASSIGNMENT-2 Fillin the blanks (i) Gram-formula mass of sodiumbromide is. (ii) Relative atomic mass of Nitrogen is (i) Relative molecular mass of Nitrogen is. (iv) Mass of one atom of nitrogen is__amu. w). giisthe mass of one atom of nitrogen. ‘The number of electrons in the telluride ion Te® (Z = 62) is (a)50 (51 (sz (054 How many atoms are there in 100 amu of He ? (A) 25 ®) 9 (©) 100 (©) 200 How many atoms of hydrogen is presentin 196 amu H-SO, (aya (8)3 (4 5 ‘One atom of an element X' weights 6.643 x 10-23 g, The number of g-atom of Xn 4 kg of itis. @) 10 (8) 100 (©) 100 Ny (O) None of these 1 mole of diatomic element X, contains 30 moles of electron and 62 moles of neutron respectively. ‘The isotopic formula of the elements (A) Sox (8) &x ©) 8x (O) None of these ‘The number of atoms presentin 64 g of O,(g)is. aa @) 4*Ny (© 2*Ny (©) None of these No. of electrons in 11.5 g Na*is (A) 55*N, 8) 5N © 1N, (©) None of these 1 g-atom of nitrogen represents - (A) 6.02 x 102 N, molecules (8) 22.4 lt. of N, at 1 atm and 273K (©) 11.21 of N, at t atm and 273 K (0) 28 gm of nitrogen ‘The mass of an electron is 9.11 * 10-8' kg. Molar mass of electron is (A) 1.5 10-8" gmot" (®) 5.5 * 10-4 gmot (©) 8.5 10-% g mot" (©) 9.11 « 108 gmor* tt)(& VIBRANT ACADEMY @ unacademy EEIDGIEEIEM (India) Pvt. PHYSICAL CHEMISTRY : NA (SODIUM SIR) MOLE CONCEPT. 10. ASSIGNMENT-3 Which ofthe following has the highest mass (A) 0.5 gatom of C (8) 1 moleof CH, (©) 8.0g0fH,0 ©) 3.011 x 10 atoms of nitrogen Which of the following sample contains the smallest number of atoms ? (A) 1g0fCO,(9) (8) TGOFCHig() —(C) 19 OFC,Hg(9) (0) TOF CH, (9) No. of neutrons in 74g of 97 is (A) 2* Ny (8) 34*N, (©) 40*N, 0) 4 ‘The number of moles of electrons in 4.2. of N*-ion (nitride lon) is (4) 03 (8) 21 3 09 ‘The number of g-atom of oxygen in 128 g of 0,(g) is (aya (68 16 (0)8* Ny ‘The number of molecules in 22.4 x 10-9 m3 of SO, gas at 1 atm & 273 Kis (A) 6.022 « 10% (8) 3.011 x 10% (©) 12.044 10% (OD) 3.011108 Number of moles in 1.89 H,0 is equal to number of moles in (1) 18g glucose (C,H;,0,) (lI) 6 gurea(NH,CONH,) _ ll) 34.2.9 sucrose (C,,H,,0,,) (A) att @ iu © ull ©) Hit For one formula unit of K,S0,, Al,(SO,),.24H,0, calculate () Numberof 0 atoms (ii) Number of Satoms (i) Number of K*ions (iv) Number of water molecule (v) Number of $0, ions Calculate the total number of electrons present in 18 ml of water. Calculate total number of atoms in 200 g CaCO. tt)INORGANIC CHEMISTRY, NA. (SODIUM SIR) 10. 1. 12, 13. 14, @ © e EXERCISE-I ATOMIC MASS & MOLECULAR MASS The average mass of one gold atom in a sample of naturally occuring gold is 3.257 x 10-%g. Use this to calculate the molar mass of gold in integer value. ‘The atomic wt. of A and B are 20 and 40. If x g of A contains Y atoms, how many atoms are present in 2xgofB. glass vessel weighs 50 gm when empty, 148.0 g when completely filed with liquid of density 0.98 gmi-* and 50.5 g when filled with an ideal gas at 760 mm at 300 K . Determine the molecular weight of the gas. Calculate the number of atoms of oxygen present in 88 g CO,. What would be the weight of CO having the same number of oxygen atoms? sample of gases contains 10 ml CH,, 20 ml C,H, and 30 ml CO, at constant temperature and pressure. What is the average molecular mass of sample ? CALCULATION AND APPLICATION OF MOLE CONCEPT. Calculate (a) Number of nitrogen atoms in 160 amu of NH,NO3. (b) Number of gram-atoms of S in 490 kg H,SO,, How many moles of Ca,(PO,), ill contain 0.20 mol of oxygen atoms? How many gm of HCI is needed for complete reaction with 69.6 g Mn0,? HCI+MnO, —+ MnCl, + H,0 + Cl, CChlorophyi, the green colouring matter of plants responsible for photosynthesis, contains 2.68% of magnesium by mass. Calculate the number of magnesium atoms in 2,00 9 of chlorophyll. Nitric acid is manufactured by the Ostwald process, in which nitrogen dioxide reacts with water. NO, (g) + HO (I) + 2 HNO, (aq) + NO (a) How many grams of nitrogen dioxide are required in this reaction to produce 25.2. g HNO;? What total volume, in litre at 600°C and 1 atm, could be formed by the decomposition of 16 g of NH,NO;? Reaction : 2 NH,NO, > 2N, +O, + 4H,0,9, Morphine contains 67.3% carbon, 4.6% nitrogen (by mass) and remaining are the other constituents. Calou- late the relative number of carbon and nitrogen atoms in morphine. ‘Apower company burns approximately 474 tons of coal per day to produce electricity Ifthe sulphur content of the coal is 1.30 % by weight, how many tons SO, are dumped into the atmosphere each day? EMPIRICAL & MOLECULAR FORMULA Given the following empirical formulae and molecular weights, compute the true molecular formulae Empirical Formula Molecular weight Empirical Formula Molecular weight cH, a © CHO 150 HO wu © Hgcl ane HE 80 2}INORGANIC CHEMISTRY NA. (SODIUM SIR) 15, 16. 17. 18, 19, 20. 24. 22. 23. 24, 25. 28. 27. 28. 29. What is the empirical formula of a compound 0.26g of which gave on complete combustion 0.88 gm of carbon dioxide and 0.18 g of water? 5.5 gm sample of an organic compound gave on quantitative analysis 1.4 g of Nand 3.6 g of C and 0.59 of H. If Molecular mass of the compound is 55 then calculate E.F and MF. LIMITING REACTANT Carbon reacts with chlorine to form CCl,. 36 g of carbon was mixed with 142 9 of Cl, Calculate mass of CCl, produced and the remaining mass of reactant. ‘A chemist wants to prepare diborane by the reaction 6 LiH + 8BF, —> 6LIBF, + BH, Ifhe starts with 2.0 moles each of Lit! & BF. How many moles of BH, can be prepared. ‘Sulphuric acid is produced when sulphur dioxide reacts with oxygen and water in the presence of a catalyst 250,(g) + 0, (g) + 2 H,0(I) + 2 H,SO,, If 5.6 mol of SO, reacts with 4.8 mol of O, and a large excess of water, what is the maximum number of moles of H,SO, that can be obtained? Potassium superoxide, KO, is used in rebreathing gas masks to generate oxygen. KO,(s) + H,0(l) > KOH (8) +0,(9) lf reaction vessel contains 0.16 mol KO, and 0.10 mol H,O, how many moles of O, can be produced? % YIELD & % PURITY OF SAMPLE AND MIXTURE ANALYSIS. Calculate the percent loss in weight after complete decomposition of a pure sample of potassium chlorate. KCIO,(s) > KCI(s) + 0,(9) ‘A sample of calcium carbonate is 80% pure, 25 g of this sample is treated with excess of HCI. How much volume of CO, willbe obtained at 1 atm & 273 K ? Cyclohexanol is dehydrated to cyclohexene on heating with conc. H,SO,, Ifthe yield of this reaction is 75%, how much cyclohexene will be obtained from 100 g of cyclohexanol ? eH 0 MEO Cag What size sample which contains 10% chlorine (Cl) should be taken for analysis if the chemist wishes to obtain a precipitate of AgCI which weighs 0.287 9? ‘A sample of calcium carbonate contains impurities which do not react with a mineral acid. When 2 g of the sample were reacted with the mineral acid, 246.3 ml of carbon dioxide were obtained at 27°C and 760 mm pressure. Calculate the % purity of the sample of CaCO,? (One gram of an alloy of aluminium and magnesium when heated with excess of dil. HCl forms magnesium chloride, aluminium chloride and hydrogen. The evolved hydrogen collected over mercury at 0°C has a volume of 1.12 itres at 4 atm pressure. Calculate the composition of the alloy. When 4 g of a mixture of N8HCO, and NaClis heated, 0.66 g CO, gas is evolved. Determine the percentage ‘composition of the original mixture. ‘Assample containing only CaCO, and MgCO, is ignited to CaO and MgO. The mixture of oxides produced weight exactly half as much as the original sample. Calculate the percentages of CaCO, and MgCO, in the sample. A.10 g sample of a mixture of calcium chloride and sodium chloride is treated with Na,CO, to precipitate calcium as calcium carbonate. This CaCO, is heated to convert all the calcium to CaO and the final mass of CaQ is 1.12 g. Calculate % by mass of NaCl in the original mixture.INORGANIC CHEMISTRY NA. (SODIUM SIR) 30. 34. 32. 33. 36. 36. 37. 38. 39. a. By the reaction of carbon and oxygen, a mixture of CO and CO, is obtained. What is the composition by ‘mass of the mixture obtained when 20 g of O, reacts with 12.g of carbon? ‘Amixture of Ferric oxide (Fe,O,) and Alis used as a solid rocket fuel which reacts to give AIO, and Fe. No other reactants and products are involved. On complete reaction of 1 mole of Fe,O,, 200 units of energyis released, () Write a balance reaction representing the above change. (i) What should be the ratio of masses of Fe,O, and Al taken so that maximum energy per unit mass of fuel is released. !) What would be energy released if 16 kg of Fe,O, reacts with 2.7 kg of Al ‘SEQUENTIAL REACTIONS 2PDS +30, > 2PbO+2S0, ; 380, + 2HNO, +2H,0 > 3H,S0, + 2NO According to the above sequence of reactions, how much H,SO, wll 1146 g of PbS produce ? ‘Sulphur trioxide may be prepared by the following two reactions S,+80,(g)->8S0J9) : 280,(g) + 0,(9) + 280,(9) How many grams of SO, willbe produced from 1 mol of S,? Sodium chlorate, NaCIO,, can be prepared by the following series of reactions 2KMnO, + 16 HCI 2 KCI + 2 MnCl, + 8H,0 + 5 Cl, 6CI, + 6 Ca(OH), -» Ca(ClO,), + 5 CaCl, + 6H,0 Ca(ClO,), + Na,SO, > CaSO, + 2 NaCIO, What mass of NaCIO, can be prepared from 100 mi of concentrated HCI (density 1.44 g/ml and 36.5% by mass) ? Assume all other substances are present in excess amounts. The chief ore of Zn is the sulphide, ZnS. The ore is concentrated by froth floatation process and then heated inai to convert ZnS to ZnO. 2ZnS +30, —_, 2700 + 280, ZnO +H,SO, <8, ZnSO, #H,0 2ZnSO, + 2H,0 8% , 22n+2H,SO, + 0, (a) What mass of Zn will be obtained from a sample of ore containing 291 kg of ZnS. (b) Calculate the volume of O, produced at 1 atm & 273 K in part (a. CONCENTRATION TERMS AND APPLICATION Calculate the molarity of pure water using its density to be 1000 kg m®, Calculate the molarity ofthe following solutions (@) 4g of caustic soda is dissolved in 200 mL of the solution (b) 5.3 of anhydrous sodium carbonate is dissolved in 100 ml of solution, (©) 0.365 g of pure HC! gas is dissolved in 50 mL of solution Density of a solution containing 9.8% by mass of sulphuric acid is 1.09 g/mL. Calculate the molarity of solution. ‘The density of a solution containing 40% by mass of HCIis 1.2 g/mL. Caloulate the molarity of the solution. 15g of methyl alcohol is present in 100 mL of solution. If density of solution is 0.90 g mL-*. Calculate the mass percentage of methyl alcohol in solution Units of parts per million (ppm) or per billion (ppb) are often used to describe the concentrations of solutes in very dilute solutions. The units are defined as the number of grams of solute per milion or per billion grams of solvent. Bay of Bengal has 1.9 ppm of lithium ions. What is the molality of Li* in this water? etINORGANIC CHEMISTRY NA. (SODIUM SIR) 42, 47. 51. 52. 53. 55. 56. 87. 58. 7M solution of KOH in water contains 30% by mass of KOH. What is density of solution in mimi, Find out the volume of 98% wiw H,SO, (density = 1.8 g/ ml) must be diluted to prepare 12.5 litres of 2.5 M sulphuric acid solution. Determine the volume of diluted nitric acid (d = 1.11 gmL~*, 19% wiv HNO.) That can be prepared by diluting with water 50 mL of conc. HNO, (d =1.42 gmL-1, 76% w/v). 60 mlofa" weight (d= % wiw alcohol by weight (d= 0.6 g/em®) must be used to prepare 200 cm? of 12% alcohol by 90 glcm®). Calculate the value of "x"? (a) Find molarity of Ca2* and NO; in 2M Ca(NO,), aqueous solution of density 1.328 g/mL. (b) Also find mole fraction of NO,” in solution. Calculate molality (m) of each ion presentin the aqueous solution of 2M NH,Cl assuming 100% dissociation according to reaction. NH,C! (aq) —> NH; (aq) + CI (aq) Given : Density of solution = 3.107 g/ml 2.463 litre of HCI(Q) at 1 atm and 300 K is dissolved in water so that final molarity of HCI is 0.05 M. Calculate volume (in litre) of water used. Assume no change in volume due to dissolution of HCI (g) What volume of 0.8 MAICI, solution should be mixed with 50 ml of 0.2 M CaCl, solution to get solution of. chloride ion concentration equal to 0.6 M? What volume of 0.20 MHSO, is required to produce 34.0 of H,S by the reaction, 8KI + SH,SO, -> 4K,SO, + dlp + H,S + 4H,0? VOLUME STRENGTH OF H,0, For'45.42 V" H,0, Solution having d = 1.136 g/ml calculate () Motarity of H,0, solution. {) Mole fraction of H,0, solution. '500 mi of a HO, solution on complete decomposition produces 2 moles of H,O. Calculate the volume strength of H,0, solution ? When 250 ml of 4M H,0, is mixed with 750 ml of 2M HO, and form a solution. Calculate volume strength of resultant HO, olution? EUDIOMETRY When 100 mlof a0, ~O, mixture was passed through turpentine, there was reduction of volume by 20 mi If 100 ml of such a mixture is heated, what will be the increase in volume? 10 mlof CO is mixed with 25 ml air having 20% O, by volume. What would be the final volume ifnone of CO and 0, is left after the reaction? Calculate the volume of CO, evolved by the combustion of 50 mi of a mixture containing 40% C,H, and 60% CH, (by volume) 10 ml of a mixture of CO, CH, and Nz exploded with excess of oxygen gave a contraction of 6.5 ml ‘There was a further contraction of 7 mi, when the residual gas treated with KOH. Volume of CO, CH, and Ny respectively is, 60 ml ofa mixture of nitrous oxide and nitric oxide was exploded with excess of hydrogen. If 38 mlof N, was formed, calculate the volume of each gas in the mixture.INORGANIC CHEMISTRY, NA. (SODIUM SIR) 20 mi of a mixture of C,H, and CO was exploded with 30 ml of oxygen. The gases after the reaction hada volume of 34 mi. On treatment with KOH, 8 mlof oxygen remained. Calculate the composition of the mixture. 10 ml of a mixture of CH,, C,H, and CO, were exploded with excess of alr. After explosion, there was contraction on cooling of 17 ml and after treatment with KOH, there was further reduction of 14 ml. What is the composition of the mixture?INORGANIC CHEMISTRY NA. (SODIUM SIR) [_EXERCISE-I1 | 10. 1. A plant virus is found to consist of uniform cylindrical particles of 150 A in diameter and 5000 A long, The specific volume of the virus is 0.75 om%Vg. If the virus is considered to be a single particle, find its molecular weight. [V = x1) P,S, + 80, —> P,O,) +380, Calculate minimum mass of P,S, is required to produce atleast 1 g of each product. Equal weights of mercury and iodine are allowed to react completely to form a mixture of mercurous and mercuric iodide leaving none of the reactants. Calculate the ratio by weight of Hg,l, and Hgl, formed (Hg = 200, 1 = 127) Nitrogen (N), phosporus (P), and potassium (K) are the main nutrients in plant fertilizers. According to an industry convention, the numbers on the label refer to the mass % of N, P,O,, and K,O, in that order. Calculate the N : P : K ratio of @ 30 : 10 : 10 fertilizer in terms of moles of each elements, and express it as xy: 1.0, In @ determination Of P an aqueous solution of NaH,PO, is treated with @ mixture of ammonium and ‘magnesium ions to precipitate magnesium ammonium phosphate Mg(NH,)PO,. 6H,O. This is heated and decomposed to magnesium pyrophosphate, Mg,P,0, which is weighed. A solution of NaH,PO, yielded 1.11 g of Mg,P,O;. What weight of NaH,PO, was present originally? One litre of milk weighs 1.035 kg. The butter fat is 10% (viv) of milk has density of 875 kg/m®. The density of fat free skimed milk is? ‘A 0.75 gm sample containing both NaCl and NaBr is titrated with 0.1 M AgNO,, using 42 ml. A second sample of the same weight is treated with excess silver nitrate and the mixture of AgCl and AgBris filtered, dried and found to weigh 0.7006 gm. Calculate the percentages of NaCl and NaBr in the sample. Chloride samples are prepared for analysis by using NaCl, KCI and NH,C! separately or as mixture. What ‘minimum volume of 5% by weight AgNO, solution(specific gravity = 1.02) must be added to a sample of 0.536 gn order to ensure complete precipitation of chloride in every possible case? 10 mL of gaseous organic compound contain C, H and O only was mixed with 100 mL of ©, and exploded under identical conditions and then cooled. The volume left after cooling was 90 mL.. On treatment with KOH a contraction of 20 mL was observed. if vapour density of compound is 23, derive molecular formula of the ‘compound, Fora hypothetical chemical reaction represented by 3A(g)—> C(g) + D(Q) the following informations are known Information (i) Att = 0, only 1 mole of Ais present and the gas has V.D. = 60. (ii) At t =30 min, the gaseous mixture consist of all three gases and has a vapour densi (iii) Molecular Mass of C = 200 Calculate (a) Molecular weight of Aand D. (0) Moles of each specie at 30 min. 105 mL water at 4°C is saturated with NH, gas, producing a solution of d = 0.9 giml. If the solution contains 30% NH, by wt. Calculate its volume.INORGANIC CHEMISTRY, NA. (SODIUM SIR) 2, 13. 14, 15, What volume of 0.2 M NaOH (in mi) solution should be mixed to 500 ml of 0.5 M NaOH solution so that 300 ml of final solution is completely neutralised by 20 ml of 2 M H,PO, solution. (One gm of charcoal adsorbs 100 ml 0.5 M CH,COOH to form a monolayer, and thereby the molarity of CH,COOH reduces to 0.49. Calculate the surface area of the charcoal adsorbed by each molecule of acetic acid. Surface area of charcoal = 3.01 x 10? mig, H,0, + 2«1 7M 1, 4 2KOH H,0, + 2KMnO, + 3H,S0, —““*¥ll_, K,S0, + 2MnSO, +30, + 4H,0 100 mi of H,0, sample was divided into two parts. First part was treated with KI. And KOH formed required 200 mi of W/2:H,SO, for complete neutralisation. Other part was treated with ust sufficient KMnO, yielding 6.72 it of O, at 1 atm & 273 K. Calculate (a) Moles of KOH produced (b) Moles of KMnO, used (€) Total moles of H,0, used in both reaction (¢) Volume strength of H,0, used. Consider the following set of reactions cH; . cu—l—o-n + AgNO; — Silver Salt— White residue (Xcess) If0.1 moles of silver satis taken & wt. of residue obtained is 54 g then what will be the molecular mass of CH, —(CH—CH--CH) cH ea | | - Br Br hnINORGANIC CHEMISTRY, QUESTION BANK SINGLE CORRECT 1. 10. 1. 12, How many hydrogen atoms are present in 0.1 mole of mohr’s salt (FeSO, . (NH,), SO, . 6,0)? (A) 10*Ny (@)14*N, (C)2*Ny (D)None of these Density of water at room temperature is 1 giml. How many molecules are there in a drop of water, if its volume is 0.05 mi? (A) 1.67 « 102 (8) 16.7 «102 (©) 6.023 x 10 (0) 1.67 x 102 8g of O, has the same number of molecules as (A) 7g0fCO (®) 14g0fCO (©) 28g0fCO (0) 12g0fCo, How many molecules are present in 12 L of liquid CC1,? The density of the liquid is 1.59 gem™. (A) 7.44 « 10 (B) 0.744 x 10% (©) 1.59% 10 (0) 15.9 10 ‘The mass of P,0,qproduced if 440 gm of P,S, is mixed with 384 gm of Opis P,S, +O, P,O, + SO, (A) 5689, (8)4269 (C)284g (0)396g Mass of sucrose C,H,,0 produced by mixing 84 g of carbon, 12 g of hydrogen and 66 It. O, at 1 atm & 273, K according to given reaction, is ls) +H,(9) +O, (G)—> CyHp20 (8) (A) 138.5, (B) 155.5 (C) 172.5 (0) 199.5 The minimum mass of mixture of A, and B, required to produce at least 1 kg of each product is (Given : At. mass of ‘A’ = 10 ; At. mass of 'B' = 120) 5A, + 2B, ——> 2AB, + 44.8 (a)2120 gm (8) 1060 gm (C)560 gm (0) 1660 gm For the reaction, 2x + 3y 42> 5w Initially if1 mole of x, 3 mole of y and 4 mole of zis taken. If 1.25 mole of w is obtained then % yield of this reaction is, (a5 (B)50 (C75 (0) None of these Ratio of masses of H,SO, andl, (SO,), in g each containing 32 g of S is (a)o25 (8)0.64 (0.86 (0) None of these ‘The percentage by mole of NO, in a mixture of NO,(g) and NO(g) having average molecular mass 34 is (a5 (B)20 (40 (075 ‘The vapour density of a mixture of gas A (Molecular mass = 40) and gas B (Molecular mass = 80) is 25. ‘Then mole % of gas B in the mixture is (A) 25 (B)50 (75 (0) None of these IF0.5 moles of BaCl, is mixed with 0.2 moles of Na,PO,, the maximum amount of Ba,(PO,), that can be formedis (A) 0.7 mol (8) 0.5 mol (©) 0.2mol (©) 0.1 mot LealINORGANIC CHEMISTRY NA. (SODIUM SIR) B. 14, 15, 16. 17. 18, 19, 20. 21. 22. 23. 24, 20 mi of 0.2 MAI,(SO,), is mixed with 20 ml of 0.6 M BaCl,, Concentration of AP* on in the solution willbe (a) 02M (8) 103M ©) 01M (©) 025M 25.4 g of iodine and 14.2 g of chlorine are made to react completely to yield a mixture of ICI and ICI, Calculate the ratio of moles of ICl and IC, win (8) 1:2 ©) 1:3 0) 2:3 74g of a sample on complete combustion gives 132 9 CO, and 54 g of H,O. The molecular formula of the ‘compound maybe (AVC Hy (8) C,H,0 (C)C,H,O, ()C,H,0, ‘The pair of species having same percentage (mass) of carbon is: (A) CH,COOH and C,H,,0, (B)CH,COOH and C,H,OH (C)HCOOCH, and C,,H,,0,, (D) C,H,,0, and C,.H,.0,, Density of a gas relative to air is 1.17. Find the mol. mass of the gas. [M,, = 29g/mol] (33.9 (8)247 (c)29 (0223 ‘Mass of one atom of the element Ais 3.9854 x 10° g. How many atoms are contained in 1 g of the element A? (A) 2.509 « 10 ©) 6.022 « 102 (©) 12.044 108 (0) None AL(SO,)3 xH,0 has 8.20% aluminium by mass. The value of x is a4 ®) 10 © 6 © 18 A spherical ball of radius 3 cm contains 66.66% iron. if density is 1.5 g/om?, number of mole of Fe present approximately is ay (8) 2 (©) 2 (©) None What is the number of moles of Fe(OH), that can be produced by allowing, 1 mole of Fe,S,, 2 mole of H,O and 3 mole of O, to react 2Fe,S, + 6H,0 + 30,—> 4Fe (OH), + 6S 2 (8) 1.34 (©) 352 (©) None (One mole mixture of CH, & air (containing 80% N, 20% O, by volume) of a composition such that when underwent combustion gave maximum heat (assure combustion of only CH,). Then which of the statements are correct, regarding composition of initial mixture.(X presents mole fraction) 3 A) X ©) Xen, = 3 cH, 1 (©) Xen, = —-Xo, () Data insufficient 6 6 ‘The vapour of an organic compound requires three times its own volume of oxygen for complete combustion and produces twice its own volume of carbon dioxide. Which of the following compounds would give these results? (A) CH,CHO (8) C,H,0H (©) CH,COOH (©) cH, ‘A mixture of KBr and NaBr weighing 0.560 g was treated with aqueous Ag" and all the bromide ion was recovered as 0.970 g of pure AgBr. The fraction by weight of KBr in the sample is (A) 0.25 (8) 02378 (©) 0.38 (©) 0.285INORGANIC CHEMISTRY NA. (SODIUM SIR) 25. 26. 27. 28. 29. 30. 31. 32. 33, 34, 36. CgH,OH (g) + O, (g)—> CO, (g) + H,0 (N) ‘Magnitude of volume change if 30 mi of C,H,OH (g) is burnt with excess amount of oxygen. is (a)30.mi (8)60 mi (C)20 mi (0)10 mi 10 lof a gaseous compound containing ’N' and’O" is mixed with 30 ml of H, to produce HO (0) and 10 ml of N, (g). Molecular formula of compound if both reactants reacts completely, is (A)N,0 (BNO, (C)N,0; (0)N,0, Equal volumes of 10% (v/v) of HCl is mixed with 10% (viv) NaOH solution. If density of pure NaOH is 1.5 times that of pure HCI then the resuttant solution be. (A) basic (@) neutral (C)aciaic (0) can't be predicted ‘The mass of CO, produced from 620 g mixture of C,H,0, & O,, prepared to produce maximum energy is (a)413.339 (8) 593.049 (€)440g (0)320g ‘Assuming complete precipitation of AgCI, calculate the sum of the molar concentration of all the ions if 2L of 2MAg,SO, is mixed with 4 L of 1 M NaCI solution is (aya. (B)2M (3m (25M ‘The % by volume of C,H; in a gaseous mixture of C,H,,, CH, and CO is 40. When 200 mi of the mixture is burt in excess of O,. Find volume (in ml) of CO, produced. (a)220 (B)340 (©)440 (0)560 What volumes should you mix of 0.2 M NaCI and 0.1 M CaCl, solution so that in resulting solution the Concentration of positive ion is 40% lesser than concentration of negative ion. Assuming total volume of solution 1000 mi, (A) 400 mi NaCl , 600 mi CaCl, (8) 600 mi NaCl, 400 mi CaCl, (C) 800 mi NaCl, 200 mi CaCl, (D) None of these ‘An iodized salt contains 0.5 % of Nal. Aperson consumes 3.9 of salt everyday. The number of iodide ions going into his body everyday is (ayto+ (8) 6.02 10+ (©)6.02« 10 (06.02 108 200 mi of a gaseous mixture containing CO, CO, and N, on complete combustion in just sufficient amount of ©, showed contraction of 40 ml. When the resulting gases were passed through KOH solution itreduces by 50 % then calculate the volume ratio Of Veo, ? Veo? Vy, in original mixture (Aarts (B)2:3:5 (14:5 (0)1:3:5 ‘2 litre of H, and 1.2litre of Cl, are mixed and exploded. The composition by volume of mixture is (A) 241itre of HCI (8) 0.8litre Cl, and 20.8 lit HCI (C) 08 titre H, and 22.4 lire HCI (©) 224 tre HCI ‘The mole fraction of a given sample of |, In CgH, is 0.2. The molality ofl, in C,H, is (A) 0.32 (8) 32 (©) 0.032 (©) 048INORGANIC CHEMISTRY, N.A. (SODIUM SIR) 36. T0500 miof 2M impure H,SO, sample, NaOH solution 1 M was slowly added and the following plot was, obtained. The percentage purity of H,SO, sample and slope of the curve respectively are s = 3 é 05 1 45 vol. of NaOH added uo (A) 50%,- 8) 75%,-4 (© 75%,-1 (©) None of these COMPREHENSION Question No. 37 to 39 (3 questions) NaBir, used to produce AgBr for use in photography can be self prepared as follows Fe + Br, —> FeBr, “0 FeBr, + Br, —> Fe,Br, (i) (not balanced) Fe,Br, + Na,CO,—> NaBr + CO, + Fe,0, (il) (notbalanced) 37. Mass of ron required to produce 2.06 x 10° kg NaBr (a)4209 (B)420kg (C)4.2 «10% kg (0)4.2% 108g 38. Ifthe yield of (i) is 60% & (ii) reaction is 70% then mass of iron required to produce 2.06 x 10° kg NaBr (A) 108 kg (8) 1059 (C) 10° kg (0) None of these 39. _Ifyield of (il) reaction is 90% then mole of CO, formed when 2.06 x 10° g NaBr is formed (a)20 (B)10 (c)40 (0) None of these Question No. 40 to 43 (4 questions) ‘A10 mlmixture of N,, a alkane & O, undergo combustion in Eudiometry tube. There was contraction of 2 ml, when residual gases are passed through KOH. To the remaining mixture comprising of only one gas excess H, was added & after combustion the gas produced is absorbed by water, causing a reduction in volume of 8m. 40. Gas produced after introduction of H, in the mixture? (HO (8)CH, (co, (O)NH, 41. Volume of N, presentin the mixture? 2m (84m (emi (28m Volume of ©, remained after the first combustion? (4m (2m (c)0 (28m 43, Identify the hydrocarbon. (aycH, BCH, OCH, (O)CHyp MORE THAN ONE CORRECT: 44. On complete oxidation, 1 mole of an organic compound gave 2 moles of water. The compound should be (A) Methanol 8) Propyne (©) Ethylene (©) but-t-ene iatINORGANIC CHEMISTRY NA. (SODIUM SIR) a. 46. 47. 49, 50. 51. 82. 53. Which of the following samples contain 2.0 108 atoms (A) 8.090, (8) 309Be (© 40g9C (0) 1.0gHe Two gases A and B which react according to the equation BAG) * PB) —> Cig) + Aig) to give two gases C and D are taken (amount not known) in an Eudiometer tube (operating at a constant Pressure and temperature) to cause the above. If on causing the reaction there is no volume change observed then which of the following statement is/are correct. )(a+b)= (6+) (8) average molecular mass may increase or decrease if either of Aor Bis present in limited amount (C) Vapour Density of the mixture will remain same throughout the course of reaction, (D) Total moles of all the component of mixture will change. A mixture of CH, (g) & O, having total volume 100 ml in an Eudiometry tube is sparked & itis observed that a contraction of 45 mls observed what can be the composition of reacting mixture. (A) 15 ml C,H, & 85 ml O, (B) 25 mi C,H, & 75 ml O, (C) 45 mi CH, & 55 ml O, (0) 55 mi C,H, & 45 ml O, [A mixture of 100 ml of CO, CO, and O, was sparked. When the resulting gaseous mixture was passed through KOH solution, contraction in volume was found to be 80 mi the composition of inital mixture may be (inthe same order) (A) 30 ml, 60 mi, 10 mi (8) 30 mi, 50 mi, 20 mi (C) 50 mi, 30 mi, 20 mi (0) 30 mi, 40 mi, 30 mi Solutions) containing 40 g NaOH is/are (A) 50g of 80% (wiww) NaOH (B) 50 g of 80% (wiv) NaOH [d,cp, = 1.2.g/ml] (C) 50g of 20 M NaOH [d,,,, = 1 g/ml, (0) 50g of 5m NaOH The incorrect statement(s) regarding 2M MgCl, aqueous solution is/are (4,49, = 1.09 g/ml) (A) Molality of Ci” is 4.44 m (B) Mole fraction of MgCl, is exactly 0.035 (C) The cone. of MgCl, is 19% wiv (D) The cone. of MgCl, is 19 « 10 ppm ‘An organic compound is burnt with excess of O, to produce CO,(g) and H,0(/), which results in 25% volume contraction. Which of the following option(s) satisfy the given conditions. (A) 10 mI C,H, + 110 mI, (8) 20 miC,H,0 + 80 mi O, (C) 10 mi C,H,0, + 50 ml O, (0)40 mi C,H,O, + 60 ml O, A sample of H,0, solution labelled as 56.77 volume has density of 530 g/L. Mark the correct option(s) representing concentration of same solution in other units. (Solution contains only H,O and H,O,) (aM (B) % “ 505 @)% > (C) Mole fraction of H,0, = 0.25 Solution(s) containing 30 g CH,COOH is/are (A) 50 g of 70% (wiv) CH,COOH (4, ,.= 1.4 g/ml] (B) 50 g of 10 MCH,COOH [,,, = 1 g/miy (C)50.g of 60% (wi) CH,COOH (0)50.g of 10m CH,COOH io)INORGANIC CHEMISTRY, N.A. (SODIUM SIR) 54, '2V'mlof 1 MNa,SO, is mixed with V' mi of 2M Ba(NO,), solution. (A) Molarity of Na’ ion in final solution can't be calculated as V is not known. (B) Molarity of BaSO, in final solution is 2/3 M. (C) Molarity of NO3 in final solution is 4/3M. (D) Molarity of NO} is final solution is 2/3 M. MATCH THE COLUM 55. One type of artifical diamond (commonly called YAG for yttrium aluminium garnet) can be represented by the formula YAl,O,.[¥ = 89, Al=27] Column I Column It Element Weight percentage “a oY () 22.73% ®) AL Q) 32.32% © o (R) 44.95% 56. The recommended daily dose is 17.6 milligrams of vitamin C (ascorbic acid) having formula C,H... Match the following, Given : N= 6 * 109 Column | Column tt (A) O-atoms present () 10 mole (©) Moles of vitamin C in 1 g of vitamin (@) 5.68% 109 (C) Moles of vitamin C should be consumed daily R) —-3.6* 10 87. Column | Column tt (A) Gramatom presentin one atom ) aN (8) N,gram atom contains atom @ 1m, (C) Number of protons in 1 g molecule of H, ® 4nN, (0) Number of electrons added to 32 gm O atom to convert itinto 0% (S$) Ny? 58, Column | Column It (A) 20VH,0, ®) 178M (8) 17.45%wivH,SO, @ 60791 (©) Purewater ® 15M (0) 5 %wiwNaOH (d=1.2 giml) (©) 555M 58. Column | Column tt (A) 10MMgo (P)— Wezyent = 1209 per 100 ml of solution (youn 1-20 g/ml) Solute : MgO Solvent: HO (8) 40%wivNaOH Q) Weston = 150g per 100 g solvent xouton = 1.6 gil) Solute : NaOH Solvent: HO (C) 8mCaco, R)— Weoxse 120 per 100 g of solvent Solute : CaCO, Solvent: HO (©) 0.6 molfraction of 'x' (S)— Weayent= 125 g per 100 g of solute (molecular mass = 20) in'Y" (molecular mass 25) Solute : X Solvent : ¥ castINORGANIC CHEMISTRY, NA. (SODIUM SIR) 60. Br, reacts with O, in either of the following ways depending upon supply of O, 1 Br, + 70, Br,0 3 Br, + 5 0,—+ Br 0, ‘Match composition of the final mixture for initial amount of reactants. a) 6) © ©) Column | (nitial reactants) 320 g Br, is mixed with 64 g of O, 160 g Br, is mixed with 8 g of O, 80 g Br, is mixed with 32 gO, 160 g Br, is mixed with 48 g 0, P) Q) ® ) Column tt (Final product) 1 mole Br,0,, 1 1 3 Mole (Br,0), 5 mole (Br,) ‘1 mole (Br,0), 1 mole (Br,0,) 1 1 J mole (Br,0,), “5 mote (0,) C3INORGANIC CHEMISTRY, NA. (SODIUM SIR) [EXERCISE-1I1| 1. 10. 1. Calculate the amount of Calcium oxide required when it reacts with 852 9 of P,O,, [EE 2005] 6Ca0 + P,Ojp—> 2Ca,(PO,), 20% surface sites have adsorbed N,. On heating N, gas evolved from sites and were collected at 0.001 atm and 298 K in a container of volume is 2.46 cm®, Density of surface sites is 6.023%10"/om? and surface area is 1000 cm, find out the no. of surface sites occupied per molecule ofN,. [JEE2005] Given that the abundances of isotopes “Fe, S*Fe and ®"Fe are 5%, 90% and 5%, respectively, the atomic mass of Fe is (A) 55.85 (B) 55.95 (©)55.75 (0)56.05 ——[JEE2009] Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water gave a solution of density 1.15 g/mL. The molarity of the solution is, (a)1.78M (8)200M (C)2.05M (0)222M — (JEE2011] ‘The volume (in mL) of 0.1 MAgNO, required for complete precipitation of chloride ions present in 30 mL of 0.01 M solution of [Cr(H,0),Ci] Cl, as silver chloride is close to [EE2011] 29.2% (wiw) HCI stock solution has a density of 1.25 g mL~". The molecular weight of HCI is 36.5 g mot ‘The volume (mL) of stock solution required to prepare a 200 mL solution of 0.4MHClis: [JEE2012] ‘A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of CO,. The empirical formula of the hydrocarbon is [JE Mains-2013] (AGH (BCH, (C)CsH, (D)C.H,, ‘The molarity of a solution obtained by mixing 750 mL of 0.5 (M) HCI with 250 mL of 2(M)HCI will be [VEE Mains-2013] (A)0.975M (B)0.875M (C)1.00M (0)1.75M. ‘The ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1 : 4. The ratio of number of their molecule is [EE Mains-2014] (A)7:32 (B)1:8 (€)3:16 (4:4 In Carius method of estimation of halogens, 250 mg of an organic compound gave 141 mg of AgBr. ‘The percentage of bromine in the compound is (at. mass Ag=108;Br=80) [JEEMains-2015] (A)60 (B)24 (C)36 (0)48 ‘Assertion : Nitrogen and oxygen are the main components in the atmosphere but these do not react to form oxides of nitrogen, [JEE Mains-2015] Reason : The reaction between nitrogen and oxygen requires high temperature, (A) Both the assertion and reason are incorrect (B) Both assertion and reason are correct, and the reason is the correct explanation for the assertion (C) Both assertion and reason are correct, but the reason is not the correct explanation for the assertion (D) The assertion is incorrect, but the reason is correctINORGANIC CHEMISTRY NA. (SODIUM SIR) 2 13. 14, 15, 16. 17. 18, 19, 20. 24. ‘A130 K and 1 alm, 15mL of a gaseous hydrocarbon requires 375 mL air containing 20% O,, by volume for complete combustion. After combustion the gases occupy 330 mL. Assuming that the water formed is in liquid form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon is [JE Mains.2016] (ACH, (B)CyHy (C)C Hy (D)C\Hyy ‘The mole fraction of a solute in a solution is 0.1. At 298 K, molarity of this solution is the same as its molality Density of this solution at 298 K is 2.0 g cm-®, The ratio of the molecular weights of the solute and solvent, {MWe ) lan) Is [VEE Advance-2016] On treatment of 100 mL of 0.1 M solution of CoCl,,6H,O with excess AGNO,, 1.2 * 10ions are precipitated The complexiis [EE Main-2017] (A) [CotH,0),Cl] Cly. HO (©) [Co(H,0),CL.] Cl. 2H,0 (C)I[Co(H,0),Cl,] 3H, (D)[Co(H,0),]C, ‘gram of a carbonate (M,CO,) on treatment with excess HCI produces 0.01186 mole of CO,. The molar mass of M,CO, in gmor is [JEEMain-2017] (a)1.86 (8) 1186, (©)843 (118.6 ‘The most abundant elements by mass in the body of a healthy human adult are: [JEE Main-2017] (Oxygen (61.4%), Carbon (22.9%), Hydrogen (10.0%) and Nitrogen (2.6%). ‘The weight which a 75 k person would gain if all *H atoms are replaced by 2H atoms is (A) 10 kg. (B) 15kg (C)37.5kg (0)7.5kg The ratio of mass percent of Cand H of an organic compound (C,H,O,)is 6 1. Ione molecule of the above compound (C,H,,) contains half as much oxygen as required to burn one molecule of compound C,Hy completely to CO, and H,0. The empirical formula of compound C,H,0, is: [JE Main-2018] (ANCHO, (B)CH,0, (C)CH,0 (O)C3H,0, ‘The ammonia prepared by treating ammonium sulphate with calcium hydroxide is completely used by NiCl,.GH,O to form a stable coordination compound. Assume that both the reactions are 100% complete. 11584 g of ammonium sulphate and 952 g of NiCl,,6H,O are used in the preparation, the combined weight (in grams) of gypsum and the nickel-armmonia coordination compound thus produced is (Atomic weights in g molt : H= 1, N= 14, O= 16, S = 32, Cl= 35.5, Ca= 40, Ni= 59) [JEE Advance-2018] Galena (PbS an ore) is partially oxidized by passing air through it at high temperature. After some time, the passage of air is stopped, but the heating is continued in a closed furnace such that the contents undergo self-reduction. The weight (in kg) of Pb produced per kg of O, consumedis, (Atomic weights in g mot: 0 = 16, S = 32, Pb = 207) [EE Advance-2018] For the following reaction, the mass of water produced from 445 g of C,,H,,,0,i8 C,H, .,(s) + 163 0,(g)—> 14C0,(g) + 110 H,0(() [JEE Main Online-2019] (a)8909 (8)4909 (C)4959 (0)4459 solution of sodium sutfate contains 92 g of Na* ions per kilogram of water. The molality of Na* ions in that solution in mol kg" is [JEE Main Online-2019] ws (B)4 (16 (O12 eo)INORGANIC CHEMISTRY NA. (SODIUM SIR) 2. 23. 24, 25. 26. 27. 28. 29. 30. 34. 32. 33, ‘An organic compound is estimated through Dumus method and was found to evolve 6 moles of CO,,4 moles of HO and 1 mole of nitrogen gas. The formula of the compound is [JEE Main Online -2019} (ANC HeNe (B)CHN, (OG HAN (D)C,.HN The volume strength of 1M H,0, is. [JEE Main Online -2019] (Molar mass of H,0, = 34.g mol") (A)5.6 (B) 11.35 (C)22.4 (0) 16.8 8g of NaOH is dissolved in 18 g of H,O. Mole fraction of NaOH in solution and molality (in mol kg-1) of the solution respectively are [JEE Main Online -2019] (ayo.167, 22.20 (B02, 11.11 (cyo.te7, 11.11 (0)0.2,22.20 25 mlof the given HC! solution requires 30 mL of 0.1 M sodium carbonate solution. Whatis the volume of this HCI solution required to titrate 30 mL of 0.2 M aqueous NaOH solution? [Online IIT Main 2019] (a) 125m (8) 75m (C)25mt (0)50mL, The percentage composition of carbon by mole in methane is, [JEE-Main Online 2019] (A) 20% (8)80% (©)75% (0)25% ‘The strength of 11.2 volume solution of H,0, is: [Given that molar mass of H=1 g mot and O=16 g mot] [JEE-Main Online 2019] (A)34% (8)3.4% (0) 13.6% (0)1.7% For a reaction, N,(g) + 3H,(g) -> 2NH,(Q) ; identify dihydrogen (H,) as a limiting reagent in the following reaction mixtures [JEE-Main Online 2019] (A) 56 g of N, +10 g of H, (8) 35g ofN, +8 gofH, (©) 14g 0fN, +4 gofH, (0)289N, +6 gofH, What would be the molality of 20% (mass/mass) aqueous solution of KI? [JEE-Main Online 2019] (molar mass of KI = 166g mol“) (ay (8)1.48 (©)1.35 (0) 1.08 ‘The minimum amount of 0,(g) consumed per gram of reactants for the reaction : [JEE-Main Online 2019] (Given atomic mass : Fe = 56, O = 16, Mg=24,P = 31, C = 12,H= 1) (A) 4 Fe(s) + 3 0,(g) > 2 Fe,0,(S) (B)C,H_(g) + 50,(9) + 3CO,(g) + 4H,0(1) (C) 2 Mg(s) + O,(g) > 2 Mg O(s) (0) P4(s) + 5 0,{9) > P,O0(8) ‘The mole fraction of a solvent in aqueous solution of a solute is 0.8. The molality (in mol kg~*) of the aqueous solution is [JEE-Main Online 2019] (A) 13.88 x 10 (8) 13.88 x 102 (C) 13.88 x 10-1 (0)13.88 5 moles of AB, weight 125 x 10-° kg and 10 moles of A,B, weight 300 x 10-° kg. The molar mass of A(M,) and molar mass of B(M,) in kg mol are [JEE-Main Online 2019] (A) M, = 5 « 10° and Mg = 10 x 10% (8) M, = 50 «10° and My (C) M, = 25 * 10-8 and Mg = 50 * 10° (0) My 25g of an unknown hydrocarbon upon burning produces 88 g of CO, and 9g of H,0. This unknown hydrocarbon contains [JEE-Main Online 2019} (A) 22 g of carbon and 3 g of hydrogen (B) 24 g of carbon and 1 g of hydrogen (C) 18 g of carbon and 7 g of hydrogen (D) 20 g of carbon and 5 g of hydrogen ‘The mole fraction of urea in an aqueous urea solution containing 900 g of water is 0.05. I the density of the solution is 1.2.g om-*, the molarity of urea solution is. [NT Advance 2019] (Given data : Molar masses of urea and water are 60 g mot and 18 g mot’, respectively)ANSWER KEY_ ASSIGNMENT-1 eee ase ae cme ceAys aA 0% oD tf AANSWER KEY_ ASSIGNMENT-2 Fill in the Blanks © (1039 (i)14 (i268 (wy 14 (4iN, D 3. A 4 c 5 B 6. c B 9 c 10. BANSWER KEY_ ASSIGNMENT-3 Baa a CA Cue er GTA 8 (40-5 C4; CZ | (N24; (WIE 9% 106.022 10 10. 10«N,INORGANIC CHEMISTRY, NA. (SODIUM SIR) 10. 1". 14, ANSWER, KEY EXERCISE-I 196.1699 2 —yatoms 3. 123g/mol 24.09% 108,129 8.33.33, 6 (a)4 ;(b)5000moles 7. 0.025 116.89 9. 1.33 1027 10. 27.69 50.14 litre 42001721 13. 123 (a) CoHy2, (DB) CgHyO5, (6) H2O;, (8) H9,Cl, (e)HAF, 18. CH CH,N, CsH_N 17. w.= 249; cc, = 154g 18. 0.25mole 56 20. 0.12 21. 30.18 4.48 litre 23. 61.59 orig 25. 50 28. l= 60%; Mg = 40%] 63%, 37% 28. CaCO, = 28.4%; MgCO, = 71.6% SNaCl=77.8% 30. 21:1 (i) Fe,0,+ 2Al—> Al,0, + 2Fe; (ii) 80: 27; (il) 10,000 units 470.4g 33. 640.0 15.979 35. (a) 117 kg; (b) 20.16 10° it. 36. 55.5 molL-! (a) 0.5 M, (b) 0.5 M, (c)0.2M 38. 1.09 39. 13.15 16.66% a. 2.7% 104 42. 1.306 1.736 litre 44, 200mi 45. 60 (a) [Ca®+]=2 molar [NO;]=4 molar; (b) 0.064 47. 0.667, 0.667 48.0 2k 5.56 ml 50. 25litre () 4M; (ii) 0.067 52. 45.42 53. 28.38 40 mi 30 mi 56.70 mi 87. Smi,2mi,3mi NO = 44 ml; NO = 16 ml 59. C,H, =6 ml, CO=14ml CH, = 4.5 ml, C,H, =4ml, CO, = 1.5 ml EXERCISE-II 7.092 « 107 4.1458 3. 0.832:1.00 4, 10:0.66:1 129 1.052 g/ml 7. 15.6%, 30.21% 8 33.33 ml 9 GH,O = 120, 160; (b)n, = 2 1 4 (a) m,= 120m, = 160; b= B+ NE s 7 166.6 ml 12. 250 13, 5x 10-9 m2 (a) 0.2; (b) 0.4 moles; (c) 0.45; (d) 51.1 'V° 15. 495 32]INORGANIC CHEMISTRY, NA. (SODIUM SIR) QUESTION BANK (tee Case 2 AR See Are ae Bee eae Grae eer ada Grae esa Beare aaa MO ean Manca teaig ae Diaa a cee Aneaaaneee A. (Cie Ae a eee caac ae ee aa Reese Ge Rea Ber ge. tee eeaiay- ee Acaaa amr G: 8B a0 Cae 0 oot Ce aac ae Cae ee: S00 Ce Or Bok Ce eee Bd Oe at Bad) C A 44 ABC 45 BC 4 AC 47, AB 48 AB 49 AC oD dee Diaeb1sat AC iaioa ea iat baat et baaaiuG! 55. (A) RB) >P.(C)>Q 56. (A) >R,(B) > Q,(C) >P 57. (A) Q, (B) 5, (C)>P, (D) R58. (A) > P.Q;(B)>P;(C) +S; (0) +R 59. (A) 9Q;(B) 9P:(C)>S;(0) +R 60. (A) 9 R,(B) 9, (C) +S, (0) 9P EXERCISE-IIT 1. 10089 ae ee ao: B68 6 8 Te ee a 0. 8 ae fa 12, Bonus a oy fee [Ne 16. \Wc 16. nr. JR 18. 2992.gm 19. 647 2. C 2B goes e) eee ae m4. a C 2 OA grease sheeneomaaees ee 30. eo} Soe ATaaeoseeee, 34, 2.98 eS