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Safety Data Sheet Microcheck MZ 20D

Revision date: 12/08/2019

1. Identification of the substance/mixture and of the company/undertaking

1.1Product details

Trade name : Microcheck MZ 20D

1.2 Application of the substance / the preparation: It is used as a preservative

1.3 Manufacturer/Supplier:
Melzer Chemicals Pvt. Ltd.
S. No. 132/2 & 3, Plot No. 22,
Gulmohar Park, ITI Road,
Aundh, Pune 411007, INDIA
1.4 Further information obtainable from
· Information in case of emergency:
Pune: TEL: +91 20 41004800; FAX: +91 20 41004845
Mumbai: TEL: +91 22 27889252 / 27871332; FAX +91 22 27889251

2. Hazards identification
2.1 Classification of the substance or mixture

Acute Toxicity Category 4

Aquatic acute toxicity Category 1
Aquatic chronic toxicity Category 1

GHS07: Harmful
H302: Harmful if swallowed

GHS09: Environmental hazard

H410: Very toxic to aquatic life with long lasting effects.

Signal Word: Warning

Precautionary Statement:
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid Release to the environment.
P391: Collect spillage.
P501: Dispose of contents/container to…in accordance with local/national/international regulations.
P301+312: IF SWALLOWED: Call a POISON CENTER/doctor/…/if you feel unwell
P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/
shower
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and
easy to do – continue rinsing

The full Text for all R-Phrases is displayed in Section 16

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Safety Data Sheet Microcheck MZ 20D

Revision date: 12/08/2019

3. Composition of Ingredients

Classification
Name EC No. CAS No. Content %
(67/54/EEC)
3-(3, dichlorophenyl)-1, 1-dimethylurea 206-354-4 330-54-1 19.5% H302; H410; H400

Additional information: For the wording of the listed risk phrases refer to section 16.

4 First Aid Measures

Inhalation
 Move the person to fresh air. Seek medical attention and bring these instructions.
Ingestion
 DO NOT INDUCE VOMITING! Immediately rinse mouth and provide fresh air. Immediately give a
couple of glasses of water or milk, provided the victim is fully conscious. Do not give victim anything
to drink if he is unconscious. If vomiting occurs, keep head low so that stomach content doesn’t get into
the lungs. Get medical attention.
Skin contact
 Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove clothing if
soaked through and wash as above.
 Burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected
area. Call an ambulance. Continue flushing during transport to hospital. Chemical burns must be treated
by a physician.
Eye contact
 Important! Immediately rinse with water for 15-20 minutes. May cause permanent damage if eye is not
immediately treated. Make sure to remove any contact lenses from the eyes before rinsing. Get medical
attention.
.

5 Fire fighting measures

Extinguishing media
 Small fires: Carbon dioxide, Foam, Dry powder and water spray.
Special fire fighting procedures
 Containers close to fire should be removed immediately or cooled with water. Keep run-off water out of
sewers and water sources
Specific Hazards
 Fire or high temperatures create: Carbon monoxide (CO), Nitrogen Oxides (NOx).
Protective Measures in Fire
 Self-contaminated breathing apparatus and full protective clothing must be worn in case of fire.

6 Accidental release measures

Personal Precautions
 Avoid contact with skin and eyes. Avoid inhalation of vapours and aerosol spray. Wear protective clothing
in Section 8 of this safety data sheet.
Environmental Precautions
 Do not allow ANY environmental contamination. Do not discharge into drains. Water courses or onto the
ground. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the
Environmental Agency or other appropriate regulatory body.
Spill Clean-up Methods
 Absorb in vermiculite, dry sand or earth and place into containers. Collect spillage in containers, seal securely
and deliver for disposal according to local regulations.
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Safety Data Sheet Microcheck MZ 20D

Revision date: 12/08/2019

7. Handling and Storage

Usage Precautions
 Avoid inhalation of vapours and spray mists. Avoid spilling, skin and eye contact. Persons susceptible to
allergic reactions should not handle this product.
Storage Precautions
 Store in tightly closed original container in a dry, cool and well-ventilated place. Avoid contact with
alkali, strong acid, oxidizing substances. Keep away from heat, sparks and open flame.
Storage class
 Store in cool and dry conditions. Store away from strong nucleophiles and alkali’s.

8. Exposure controls / personal protection

Ingredient Comments
No exposure limits noted for ingredient(s)

Protective Equipment

Engineering measures
 Provide adequate general and local exhaust ventilation.
Respiratory Equipment
 Generally not required. If necessary use Self-Contained Breathing apparatus (SCBA).
Hand Protection
 Use protective gloves made of: Nitrile rubber (NBR). Be aware that the liquid may penetrate the gloves.
Frequent change is advisable.
Eye Protection
 Wear approved safety goggles or face shield.
Other Protection
 Provide eyewash station and safely shower. Wear appropriate clothing to prevent any possibility of skin
contact.
Hygiene Measures
 Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating,
smoking and using toilet. Use appropriate skin cream to prevent drying of skin. Promptly remove any
clothing that becomes wet or contaminated.
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Safety Data Sheet Microcheck MZ 20D

Revision date: 12/08/2019

9. Physical and chemical properties

Physical State: Aqueous dispersion

Odour: Characteristic
Appearance: Aqueous dispersion
Colour: White to off-white
pH 1 % w/w 4.00 – 6.80
Vapour Pressure: Not available
Boiling Point: Not applicable
Freezing Point Not applicable
Melting Point Not applicable
Solubility in water Insoluble
Evaporation Rate: Not determined
Specific gravity (25ºC): 1.020 – 1.120
Flash point Not applicable, non-combustible

10. Stability and Reactivity

Stability
 Stable under normal temperature conditions and recommended use.
Conditions to Avoid
 Keep away from heat
Materials to avoid
 Avoid contact with oxidising agents, acids and alkali.

11. Toxicological Information

Health hazards Typical value

Acute toxicity
Oral route (LD50)
Inhalation route
Dermal route (LD50)
Irritation/ Corrosion
Skin
Eye
Skin sensitization
Genetic toxicity
Carcinogenicity (NOAEL)
2000 mg/kg bw (rat)
>2.32 mg/l of air (rat)
>2000 mg/kg bw (rat)
Non-irritant
Non -irritant
Not sensitizing
Non mutagenic
Not listed by OSHA
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Safety Data Sheet Microcheck MZ 20D

Revision date: 12/08/2019

12. Ecological Information

Eco-toxicity Typical value

Short term toxicity to fish (EC50) 14.7 mg/l (96 h)
Long term toxicity to fish (EC10) 1.19 µg/l (freshwater fish )
Short term toxicity to aquatic 1.4 mg/l (48h)
invertebrates (EC50)
Long term toxicity to aquatic 100-560 µg/l
invertebrates (EC10)
Toxicity to aquatic algae (EC50) 7.9-22 µg/l (96 h)
Bioaccumulation Non bio accumulative

13. Disposal Considerations

Disposal Methods
 Dispose of waste at an appropriate waste disposal facility according to current applicable laws and
regulations
For Large Spills
 Contain material and call local authorities for emergence Assistance
Product Disposal
 Dispose of at a supervised incineration facility or an appropriate waste disposal facility according to current
applicable laws and regulations and product characteristics at time if disposal
Empty Container
 Contaminated container should be cleaned and disposed of in the as the product in accordance with
applicable regulations.

14. Transport information

UN number 3082
Proper shipping name and description ENVIRONMENTALLY HAZARDOUS SUBSTANCES,
LIQUID, N.O.S. [3-(3, dichlorophenyl)-1, 1-dimethylurea
Class 9
Packaging group III
EmS code F-A, S-F
Marine pollutant Yes
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Safety Data Sheet Microcheck MZ 20D

Revision date: 12/08/2019

15. Regulatory Information

Signal word: Warning

Hazard statements:
H302: Harmful if swallowed
H410: Very toxic to aquatic life with long lasting effects.

16 Other Information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Only trained personnel should use this product
Precautionary Statement:
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid Release to the environment.
P391: Collect spillage.
P501: Dispose of contents/container to…in accordance with local/national/international regulations.
P301+312: IF SWALLOWED: Call a POISON CENTER/doctor/…/if you feel unwell
P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/
shower
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
and easy to do – continue rinsing

Abbreviations and acronyms:

IMDG: International Maritime Code for Dangerous Goods
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)-