‫بسم هللا الرحمن الرحيم‬

ElSheikh Abdallah ElBadri University, Faculty of Pharmacy

Analytical, Chemistry
Semester 3
Assignment no. (3), Precipitation titration

1- A 0.32 g sample containing KCl ( mw = 74.6 ) is dissolved in 50 mL of water

and titrated to the Ag2CrO4 end point, requiring 16.2mL of 0.1 M AgNO3.

a- Calculate the number of moles of silver nitrate reacted with the KCl in the
sample?

b- Calculate the number of moles of KCl in the samples?

c- Calculate the mass of the KCl in the samples?

d- Report the percentage of the KCl w/w% in the sample

2- A 0.6712-g sample was determined by a Volhard titration to determine the

iodide (I –atomic weight = 126.9) contents. After adding 50 mL of 0.05619 M
AgNO3 to the sample and allowing the precipitate to form, the remaining silver
nitrate was back titrated with 0.05322 M KSCN, requiring 35.14 mL to reach the
end point.

a- calculate the total number of silver nitrate added to the sample?

b- Calculate the numbers of moles of the access silver nitrate?

c- Calculate the numbers of moles of the silver nitrate that reacted with the iodide
in the sample?

d- Calculate the mass, in grams, of the iodide in the samples

Report the percentage of iodide I – %w/w in the sample?