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Class : XI
CHEMISTRY
Time Allowed: 1.5 hours Maximum Marks: 40
General Instructions:

1. This question paper contains two parts A and B. Each part is compulsory. Part A carries 12
marks and Part B carries 28 marks
2. Part-A has Objective Type Questions and Part -B has Descriptive Type Questions
3. Both Part A and Part B have choices.

Part – A:
It comprises of 12 very short answer type questions.

Part – B:

1. It consists of three sections- I, II and III.

2. Section I comprises of 3 questions of 2 marks each.
3. Section II comprises of 4 questions of 3 marks each.
4. Section III comprises of 2 questions of 5 marks each.
5. Internal choice is provided in 1 question of Section –I & 1 question of Section-II. You have to attempt
only one of the alternatives in all such questions.

Part –A (12 x 1 Marks)

1. Calculate the number of electrons which will together weigh one gram.

2. Calculate the mass and charge of one mole of electrons.

3. How many neutrons and protons are there in the following nuclei ?

4. Write the complete symbol for the atom with the given atomic number (Z) and atomic mass (A)
(i) Z = 17 , A = 35.
(ii) Z = 92 , A = 233.

5. Find energy of each of the photon which

(i) correspond to light of frequency 3×1015 Hz.

6. What is the maximum number of emission lines when the excited electron of a H atom in n = 6 drops to the
ground state?

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7. What is the basic theme of organisation in the periodic table?

8. Which important property did Mendeleev use to classify the elements in his periodic table and did he stick to
that?

9. What is the basic difference in approach between the Mendeleev’s Periodic Law and the Modern Periodic
Law?

10. On the basis of quantum numbers, justify that the sixth period of the periodic table should have 32 elements.

11. In terms of period and group where would you locate the element with Z =114?

12. In terms of period and group where would you locate the element with Z =114?

Part –B
SECTION –I (2 x 3 Marks)
1. What is the number of photons of light with a wavelength of 4000 pm that provide 1J of energy?

2. How much energy is required to ionise a H atom if the electron occupies n = 5 orbit? Compare your
answer with the ionization enthalpy of H atom ( energy required to remove the electron from n =1 orbit).

3. A) Explain why cation are smaller and anions larger in radii than their parent atoms?
(OR)
B) Consider the following species :
N3–, O2–, F–, Na+, Mg2+ and Al3+
(a) What is common in them?
(b) Arrange them in the order of increasing ionic radii.

SECTION –II (4 x 3 Marks)

1. How would you explain the fact that the first ionization enthalpy of sodium is lower than that of
magnesium but its second ionization enthalpy is higher than that of magnesium?

2. Describe the theory associated with the radius of an atom as it

(a) gains an electron
(b) loses an electron

3. (i) An atomic orbital has n = 3. What are the possible values of l and ml ?
(ii) List the quantum numbers (ml and l ) of electrons for 3d orbital.
(iii) Which of the following orbitals are possible? 1p, 2s, 2p and 3f

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SECTION –III (5 x 2 Marks)

1.
a. What is the lowest value of n that allows g orbitals to exist?
b. (i) Write the electronic configurations of the following ions:
(a) H– (b) Na+ (c) O2– (d) F–
(ii) What are the atomic numbers of elements whose outermost electrons are represented by
(a) 3s1 (b) 2p3 and (c) 3p5 ?
(iii) Which atoms are indicated by the following configurations ?
(a) [He] 2s1 (b) [Ne] 3s2 3p3 (c) [Ar] 4s2 3d1.
c. Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 m s–1.

2.
a. The increasing order of reactivity among group 1 elements is Li < Na < K < Rb <Cs whereas
that among group 17 elements is F > CI > Br > I. Explain.
b. Write the general outer electronic configuration of s-, p-, d- and f- block elements.
c. Would you expect the first ionization enthalpies for two isotopes of the same element to be
the same or different? Justify your answer.

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