Total Pages: 5 UDHB-Sem-IV-Ch (CC-10)

2021

Full Marks : 70.

Time:3hours
Answer from all the Sections as directed.

The figures in the right-hand margin indicate marks.

Candidates are required to give their answers in their

own words as far as practicable.

GROUP-A
sn(Objective Type Questions )u
(Compulsory)

1. Identify True/False statement of the following:

2x 10
(a) In physisorption, adsorbate held on the.
adsorbent surface due to covalent bond.

(b) The unit of specific conductance is siemen.

(c) CH,C0OH is a strong electrolyte.

(Turn Over)
 2) 3)

(d) Corrosion is a fast electrochemical reaction. () Ifsalt-bridge between two half cell is removed
then potential difference will be constant.
(e) Debye-Huckel Onsager equation is given by

AuA-bve. GROUP-B
Short Answer Type Questions)
Answer any four questions of the following: 5x 44

SnSn||S Sn

2. Find pH value for a hydrolysis of a salt contain-

0.059,
log2 ing weak acid and strong base.
E=- Nernst equation)
C
3. State Arrhenius theory ofelectrolytic dissociation.
In the abóve Nernst equation the value of n
is 2. 4. Deduce Fruendlich Adsorption isotherm equation.

(g) Solubility product of Ca,(PO), is répresent
by [Ca"T PO*
(i) When the concentration of the solution of an
electrolyte decreases the A decreases.
5. Find the relation between solubility and solubi-
lity product for (@)AgCrO, (6)AS,S, (©)AgCI
(a) PbCl, (e) BaCL. iita 1ttat DLS
6. At 298 K temp. the value of
AcH.coONa
Ha and

N&CIre 91.0, 426.16 and 126.45 Scm2 mol-

) Hydrolysis constant (Kh) for a salt containing
respectively. Calculate ^cHcooH
Kw
weak acid and weak base is Kh=-
KaxKb
Kax Kb 7. Deduce Nernst equation for the concentration
cell (n 2) without transport number.
UDHB-Sem-IV-Ch(CC-10) (Turn Over)
UDHB-Sem-IV-Ch(CC-10)
(Continued)
 nark (5)
4 ) Cas
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Mtiule 13. Explain any three of the following
8. Write five main applications of adsorption.
(a) Langmuir adsorption isotherm equation
9. Determine pH using hydrogen electrode.
(6) Kohlrausch's law
prun y equur
pluuhachs'cas
GROUP-C dtpauy ceilt feluht un * *hru.
Couuntu
(C) Polarisation
galuann
(Long Answer Type Questions)
Answer any two questions ofthe following: 15 x 2 (d) Mechanism of Buffer solution

10.(a) Deduce Gibb's Adsorption equation. 8

(6) Using BET equation discuss the application

of surface area measurement.

11.(a) Discuss the hydrolysis of a salt containing

weak acid and weak base.

(b) Deduce Henderson-Hazel equation for acidic

and basic buffer solution. 8

12.(a) State and explain Ostwald's dilution law.

(b) Deduce Nernst equation for the given cell1
reaction
Znzn aal|, aA,0)pt 1
atm.
GK-800

UDHB-Sem-IV-Ch(CC-10)

UDHB-Sem-IV-Ch(CC-10) (Continued),