PHysCAL

Total Pages-7 UDHC(S-6)-Chem(DSE-3)

2021
Full Marks : 70 &
ri
or ii Time:2 hours o sioid (
Answer from all the Groups as directed
The figures in the right-hand margin indicate marks

Candidates are required to give their answers in their

own words as far as practicable i

iovol GROUP-A O93irt

(Compulsory)
[Objective Type Questions]

1. Select the correct answer of the following: 10 x2

() The number of molecular orbitals formed by
linear combination of two atomic orbitals
iS

(a) 0

E-324het)
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 (2

(3.)
1
(c)2
()3 (6) 2

(i) Which of the following

3
(d) 4
rotational spectra will not give
Oxygen molecule 1s, t o
(a) HO
(6) NO a) Paramagnetic
() HCI ( Diamagnetic
co, (c) Ferromagnetic
(d) Anti-ferromagnetic
(iii) The degeneracy
of rotational energy (vi) The actual value of nuclear spin depends
1s given by levels
on
(a) JU+ 1)
(a) Mass number
(6) J(U+2)
(b) Atomie number
(2J+ 1)
(a) and (6) both
(a) None e (a) Sheilding effect ig
(iv) The fundamental vibrational
frequencies in (vi) Whenthe effective magnetic ficld experi-
IR spectrum of H,O is t
enced by the nucleus is less than that of
the applied field, the nucleus is said to be
1
(a) De-sheilded
UDHC(S-6)-Chem(DSE-3)
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UDHC(S-6)-Chem(DSE-3) (Turn Over)
 .(4) (5

(6 Sheilded 6 Isotropic.
(c)Relaxed (c)Different in all directions
(d) None ixu(d) None Y
R
(vii) Movement of nucleus is negligible during
GROUP-B
time taken by an electronic transition, it is
called. [ Short Answer Type Questions ]
() Franck-Condon principle Answer any three questions ofthe following:
(6) Born-Oppenheimer principle 10x3
a
(c) Lambert Beer law 2. Give quantitative description of non-rigid
rotor.
(d) None
3. Compare IR and Raman spectra applications.
(ix) Raman lines on the low frequency side of
excitation frequency are called
4. Explain the anharmonic and anharmonicity
(Stokes lines
(6) Anti-Stokes linesn, :5 Discussthe advantages of Raman spectroscopy
(c) Rayleigh line nšbsid over infrared spectroscopy. hzo
(d) All
6. Explain the following terms
(x) When the electron density of molecule is (a) Chromophores
symmetrical, polarizability
å ta oeil bp igt
is: ri (b) Degree of freedom.
a) An isotropic abliota-g
(
UDHC(S-6)-Chem(DSE-3)
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UDHC(S-6)-ChemDSE-3) (Continued)
 6) (7)

. Mention applications of NMR spectroscopy. 13. What is Raman spectroscopy ? How will you
explain Rayleigh lines, stokes lines and anti-
8. Write an essay on Born-Oppenheimer approxi- stokes lines in Raman spectrum?
mation.

9. Write short notes on any hwo of the following:

() Franck-Condonprinciple
(i) Chemical shift
(ii) Isotope effect.

GROUP-C
[Long Answer Type Questions]
Answer any one question of the following :
20 x1
10. Describe the potential energy curve for bonding
and anti-bonding molecular orbital.

11. What is ultraviolet spectroscopy ? Discuss the

origin and theory of ultraviolet spectrum.

12. Explain principle of NMR spectroscopy.

UDHC(S-6)-Chem(DSE-3) UDHC(S-6)-Chem(DSE-3) GK-600

(Continued)