COPYRIGHT RESERVEDeii UDHA(Sem-1)-

Ch (CC 1)
,INORGANIC

2019
Time: 3 housliot oii
FullMarks:70
Candidates are required to give their answers in
their own words as far aspracticable.

The figures in the margin indicate full marks.

Answer from all the Groups as directed.

Group-A
(Compulsery)

1. Answer the following questions2 2x10 20

(a) The correct sequence of elements in

R e the decreasing order of lonization Energy

iS

Na>Mg> Al> Si

RN 1/4, (Turm over)

 () Mg> Na> Al'si T8JEHYADO
(i) NO>NO NO
. i
(ii) Al> Mg> Na>Si Cii)NO<NO<NO
V Si> Mg> Al> Na (iv) NO>NO
NOnnih in)
b) The correct order of electron affinity among Out of BF CH, and SF, the molecules
os
thefollowingis having regulargeometry are

i) F>CH Brehsh ) BF and CH

o): B CRF bsupoi 2a1stbr:ad CH, and SF

ii) Cl>F>Brsi¢a st siw iets Gii) BF and SF
(v) BFa CH, and SF
.

(c) Whichofthe following has the highest dipole appearance ofcolourin solid alkali metal
The
moment? halides is generally due to:

CNH () Frenkle defect

(i) PH i) Schottky defect 9
prioioi s eWena (ii), Metal deficiency defects
ii SbHcu GHOH
s (iv) F centres
21
98v) AsH fieu9e 1oac3, (6)
correct orderofsolubility ofalkaline earth
(d) N-Obondlengthin NO NOand NOTspecles FERggThe
metal sulphatesinwateris
isin the order RT
i) Mg s Ca> Sis Ba H
() NO<NO <NO E

.tRN 1/4 (3) (Tumover)

RN-1/4 AContg
(2)

NO
N toS 2 No N0<NO
 (i) Ca> Mg> Sr> Ba (i) HF is a weak acid
(ii) Ba> Sr Ca> Mg fin) HF molecules are hydrogen bonded

(iv) None of these (v) Fluorine is highly reactive

(h Carborundum is the commercial name

Htter iGroup-B
of.
t e(Short-answer Type Questions)
511 vidubri 13rlirt
ALO Ssft eiAnswer any fourquestions of the following:
Sic 2 Why is BBr a better lewis acid than BF,? 5
(ii) Sio,
(iv) HPO
2bns HO8 (vi) 3. Deduce de Broglie equation. Calculate the de
Broglie wavelength ofanelectron moving with a
0 Which of the following does not exist ? speed nearly 1/10th that of light (3 x10 ms).
HCIO 5
()HCIO 4 What are silicates ? Draw the structure of
(ii) different types of silicates. 5
HCIO3iib isiei (
460) HCIO 5. Determine the structure and shape of the
ris Cotrary to otherhydrogen halides, hydrogen following molecules : 5

Fluoride is aliquid
because9m ()SF
t

) Size of F atom is
smal 8(b)F7
(5) (Tum over)
RN-1/4 (4) AContd. RN1/4