UDHA (Sem-II)-Chem

(CC-4)

2019141 t 91 eini
10
FullMarks: 701
E

09
Time :3 hours

Answer from all the Groups as directed.

Thefigures in the right-hand margin indicate marks.
Candidates are required to give their answers in their
own words asfar as practicable.

ebde GROUP-A
Answer all the questions

1. True and False d 2x 10

()The constituent particles in amorphous

Solids are arranged in aregular fashion.
(i) Bragg's equation of X-ray diffraction by
crystal is 2 sin 0 na.

(ii) Greater is the valency of the oppositely

charged ion of the electrolyte added, faster
is the coagulation.

(Turn Over
 C69

133ti i3A(2 )
(3

iv) Gels are of three types.

3 Write down differences between Lyophilic
and
(v) Rate of reaction depends upon the con
1yophilic sols. Colloroly
centration of the reactants. T
4 Define emulsions. What are the types
of emul-
(i) A catalyst initiates the reactions. sions 7 How it is prepared. Coloids

(vi) Reaction between sulphur dioxide and 5. Whatis zero order reaction? Explainby giving
eOxygen to form sulphur trioxide is an example. it Chanical Kinahy
example of heterogeneous catalysis. f
6 Calculate the rate constant of the first order
(vii)Medicines in colloidal form are easily reaction in which half life period is 20 minutes. nst
absorbed by the body tissues.
7Discuss the characteristics of enzymes used as
() In emulsion both dispersed phase and catalyst.
dispersion medium are liquid.
8. Define Activation energy. How is it determined
(x) Metallic bond is stronger than covalent graphically by using Arrhenius equation ? ekcneat
bond.< kiehet
n S
9Thermodynamically, derivelaw of mass action.
ts19it ed GROUP-B
GROUP-C
Answer any four questions 5x4
Answer any fwo questions 15 x 2
2. Define Law of Symmetry
and elements of
symmetry present in crystals. *2 10. Define second order reaction, Derive an expres-
sion for the rate constant for the reaction of
second order of the type 2A Product.
ChewwicalR
UDHA(Sem-lI)-Chem(cc-4)
(Continued) UDHA(Sem-)-Chem(CC.4) (Turn Over)
 (4

11. Define Le-Chatelier's principle by giving effects

of various factor on it.

12. Discuss the crystal structure of NaCl. Why the

diffraction pattern of NaCI and KCl are differ-
ent ?

13.Discuss the properties of colloidal solution

under following headings Collodad teT
3:1
(a) Brownian movement
(6) Tyndall effect
(c) Osmotic pressure.

Apeudy
La neal O53 gcm and the
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UDHA(Sem-1I)-Chem(CC-4) GK-2,00o