Total Pages : 5 UDHC (6)-- Chem (CC-13)

2019-20
SEMFG
2022
a1U9
Full Marks: 70
or
Time:3 hours
the Groups as directed.
Answer from all
figures in the right-hand margin
The
indicate marks.
to give their answers
Candidates are required as practicable.
in their own words as far

GROUPA
(Compulsory).
2x 10

1. True and False:

represents the d' system.
(i) [Ti(H0),]
diamagnetic.
(i) Cu() is ps is same
ground state term for
(iii) The
as d
(Zurn Over)
 (2 3)
p*
(iv) The number of microstates for a 2. Calculate the magnetic moment for the
contiguration is 18. following:

(v) Stability of complex depends upon [NiCl] [Cu(NH,),l'. [Fe(CN)J:

the nature of the ligands.
FeCl3; [Fe(H,0)J3
(vi) Log Bvalue ofAgCl is more than Agl. How
3. What is magnetic susceptibility ?
does it vary with temperature ?
(vii)Ferrocene is an example of olefin
compleX. d-d transition.
4. Explain selection rule for
elec-
(viii) The ability ofa ligand to accept What is trans-effect ? Discuss
polarization
tron densSity from the metal atom into 5.
known as t-aci- theory of trans-effect
vacant p-orbitals is
dity. What is inert and labile complexes 2
6. Explain by giving examples.
(ix) Most of the cyclotriphosphazenes
have puckered ring structure. for the fol-
7.GiveIUPAC nomenclature
lowing
() The formula of trichloromethyl
silane is CiSiCH (a) Fe(CH
GROUPB (6) (CHJCr{(CO),

Answer anyfour questions: 5x4 (c) Ni(T-CH),

(Turn Over)
UDHC(6)-Chem(CC-13)
UDHC(6)-Chem(CC-13)
(Continued)
 (5)
4
12. (a) Explain the nature of bonding in
(a)Co(CO)(T-CH) M-COM-COcomplexes. 10

(e)ICCO),-Co-Co-(CO),] (b) Draw the structures for the follow

8. Discuss the nature of bonding in phos- ng complexes
Fe,(CO), Os,(CO),, Cr(CO)
phazenes.
Fe(CO) Mn,(CO) 5
9. Write short notes on 'Effective Atomic
Number' rule. 13. Explain the structure, preparation and
properties of silicones as inorganic
GROUP-C polymers.
Answer any two questions: 15x 2

10. What is stepwisë stability constant and

overall stability constant ? Discuss the
relations between them..
11. (a) Define paramagnetism, diamagne
tism, ferromagnetism and anti-ferroO
magnetism. 10

(b) Explain Cu*2 ions are coloured and

paramagnetic where as Zn*? ions are
colourless and diamagnetic. 5

GK-700
UDHC(6)-Chem(CC-13)
UDHC(6)-Chem(CC-13) (Continued)