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All: 1 Review: 0

1: Anal Chem. 1991 Sep 15;63(18):1984-9. Links

Related articles
Determination of dissolved selenium species in environmental water samples using Composition of chemical species of selenium contained
isotope dilution mass spectrometry. in selenium-enriched [J Nutr Sci
shiitake Vitaminoland
mushroom (Tokyo). 2005]
vegetables
Organic and inorganic selenium speciation in
Tanzer D, Heumann KG. [J MassbySpectrom.
environmental and biological samples 2008]
nanometer-
Institut für Anorganische Chemie, Universität Regensburg, Germany. Isotope dilution analysis of selenite and selenate in
[Anal Sci.
natural water using microwave-induced nitrogen 2003]
plasma
In order to clarify the species composition of selenium in environmental water
Review Metabolic pathway for selenium in the body:
samples, analytical methods have been developed for the selective determination of
[Food
speciation by HPLC-ICP MS with Addit Contam.
enriched Se. 2002]
different chemical forms of this element (selenite, selenate, and organic species
including trimethylselenonium) using isotope dilution mass spectrometry (IDMS). Review Review of 15 years of research on
The species analysis was made possible by means of chromatographic separation [Ecotoxicol
ecotoxicology and remediation of land Environ Saf. 2004]
contaminated by
procedures and an 82Se-enriched selenate, selenite, and trimethylselenonium spike
for the isotope dilution process. The total selenium concentration was determined » See reviews... | » See all...
after decomposition of organic compounds with a HNO3/HCIO4 mixture. Selenium
was measured in the mass spectrometer by producing negative Se- thermal ions for Recent Activity
detection. Precise determination at the parts-per-trillion level was achieved. This
new methodology was applied to different types of natural water samples
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(groundwater, pond water, river water, moorland lake water) with total selenium
concentrations in the range of 200 pg/g to 15 ng/g. Selenite and selenate have
been the only detected species in most of the investigated samples, with selenate Determination of dissolved selenium species in
dominating all except one. In samples with high contents of dissolved organic environmental water samples using isotope d...
carbon, however, different organoselenium compounds including
trimethylselenonium ions were additionally quantified in the range of 10-95 pg/g. In
these cases, the sum of all selenium species agreed well with the independently
determined total element concentration.
PMID: 1750700 [PubMed - indexed for MEDLINE]

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