TotalPages 04

Roll No. ...a.M.2.3.!

GSa/M-22
1752
CHEMISTRY

Paper XIX (CH-305)

Physical Chemistry (Theory)
[Maximum Marks: 32
Time: Three Hours]

selecting two questions

Note Attempt Five questions in all,
Use of Log-
from each Unit. Q. No. 1 is compulsory.
allowed.
table and Non-programming calculator is

(Compulsory Question)
reactions. 2
1. (a) Give wo examples of photosensitized
?
(b) What is meant by thermodynamic probability
Illustrate with example. 2

(c) What is "Eutectic Mixture ? Calculate the degrees

of freedom of Pb-Ag system at puiecic point. 2

Detine ideal and non-ideal solutions ? Give one

(d)
example of each of them. 2

Unit I

2. (a) State and explain Stark-Einstein law of

photochemical equivalence. 3

(3-03/6) L-1752 P.T.O.

 a1nOsition of FHI vapours was carried
The photodecompo:
(b)
2070 A.
out with radiation
ol wavelength
Absorption
of each calorie gave 1.44
x
10 g of H,. Calculate
the quantum yield. 3
3. (a) Differentiate between fluorescence and

phosphorescence. Draw the jablonski diagram

depicting these processes. 4

(b)
(b) What do you mean by quantum yield of a

photochemical reaction ? Why the quantum yield of

phtosynthesis of HCI decreases if the vessel contains
small traces of Oxygen 2
4. (a) What are
photochemical reactions ? Give the main
points of difference between
photochemical reaction
and thermochenmical reaction.
3
(b) Write the important features of Maxwell-Boltzmann
Statistics. 3
5. (2)
(2) What do you understand by Partition Function ?
Show that the total partition function for a
system
may be expiessed as a product of translational,
rotationai. vibrational and
electronic partition
functions.
4
(b) Discuss Born-Oppenheimer Approximat1ion. 2
L-1752
2
 Roll No. ..l.e.M.2310 Total Pages 04

GSa/M-22 1752
CHEMISTRY
Paper XIX (CH-305)
Physical Chemistry (Theory)
Time Three Hours] [Maximum Marks: 32

Note: Attempt Five questions in all, selecting wo questions

from each Unit. Q. No. 1 is compulsory. Use of Log-

table and Non-programming calculator is allowed.

(Compulsory Question)
1. (a) Give two examples of photosensitized reactions. 2

(b) What is meant by thermodynamic probability ?

Illustrate with example. 2

(c) What is 'Eutectic Mixture' ? Calculate the degrees

of freedom of Pb-Ag system at sutecic point. 2

(d) Define ideal and non-ideal solutions ? Give one

example of each of them. 2

Unit I

22. (a) State and explain Stark-Einstein law of

photochemical equivalence. 3

(3-03/6) L-1752 P.T.O.

 (b) The photodecomp0uO of Hi vapours was carried

out with radiation0f wavelength 2070 A. Absorption

of each calorie gave 1.44x 10 g of H,. Calculate
the quantum yield.
3
3. (a) Differentiate between fluorescence and
phosphorescence. Draw the jablonski
diagram
depicting these processes. 4
(b) What do you by quantum yield of a
mean

photochemical reaction ? Why the quantum yield of

phtosynthesis of HCI decreases if the vessel contains
small traces of oxygen ? 2
4. (a) What are photochemical reactions ? Give the main

points of difference between photochemical reaction

and thermochemical reaction. 3

(b) Write the important features of Maxwell-Boltzmann

Statistics. 3

5. (a) What do you understand by Partition Function ?

Show that the total partition function for a system

may be expiessed as a product of translational,

rotational, vibrational and electronic partition

functions. 4

(b) Discuss Born-Oppenheimer Approximation.

L-1752 2
 Unit II

6. (a) Define "Gibbs Phase Rule'. How can you derive it

thermodynamically ? 3

(b) Draw a labelled phase diagram for water system.

7. (a) Define the terms 4%

(i) Phase

ii) Component
(ii) Degrees of Freedom.

(b) Discuss the application of Phase Rule in Pattinson's

process for the desilverisation of lead. 1%

8. (a) Define molal depression constant. Derive the

relationship between depression in freezing point

and molality of the dissolved solute. 4

(b) Calculate the osmotic pressure of 0.01 M solution

of canesugar at 27°C (R = 0.0821 litre-atm/degree/

mol). 2

9. (a) Give reasons for the following 4%

()
() The cquimolar solutions of NaCl and
cancsugar do not have the same boiling point.

(3-03/7) L-1752 3 P.T.O.

 (ii)T h e solution ot benzoic acid in benzene shows

less osmotic pressure than expected.

(ii) The relative lowering of vapour pressure is a

colligative property.
b) Out of one molar and one molal aqueous solutions,
which one is more concentrated and why ? 1%