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Solution to Advanced Level Problem Solving-2208

JEE 2022 | Chemistry
Solid State, Liquid Solution, Electrochemistry, Chemical Kinetics, Surface
Chemistry, Coordination Compounds, Metallurgy, Stereochemistry,
d-Block Elements, Aromatic Compounds, Environmental Chemistry &
Practical Organic Chemistry

1
1.(D) CO bond order 
Extent of synergic bonding (M  CO)
Correct sequence of CO bond order :
H3B  CO  CO  Fe(CO)5  [Mn(CO)5 ]
(CO bond order  3.0) B.O.  3.0 CO bond order  3.0 (CO bond order  3.0)

2.(B) 3.(D)
4.(D) A acts as cathode and B acts as anode because reduction potential of A is more
Anode is B  is negative electrode
 electrons flow from B to A
 e.m.f. = (1.33 – 0.77) V
P
5.(B) S1 : is a colligative property.
P
S2 : Entropy of solution is more than entropy of pure solvent
S3 : Due to association molar mass increases
S4 : Larger value of osmotic pressure is easily measurable

6.(D) 7.(BCD) 8.(D)

9.(AC) (A) G  H  TS  0 as S  0 SO H  ve
(B) Micelles formation will take place above TK and above CMC
(C) Read NCERT
(D) Fe3 ion will have greater flocculability power so smaller flocculating value.

10.(C) [Ni(CN)4 ]4 ;sp3 ; Tetrahedral complex.

11.(B) 12.(D)
1
13.(A) R 
kA
The k is halved while the A is doubled. Hence R remains 50

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14.(D) Volume of unit cell

 area  b  17.77  1016  7.41108  131.68 10 24 cc
Mass of unit cell
 V  d  131.68  0.805 1024  106 10 24 g

106 1024
 Number of SO2 molecule per unit cell   6.023 1023  1
64
15.(C)

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III III
16.(A) [Co(NH3 )4 CO3 ] ClO4 ,CO32 is acting as bidentate ligand, have coordination number of Co  6.
17.(C) 18.(A)

 HA
1e
19.(B) Reaction is H c  
0.059 2.1 104
 E log  0.0629V  0.063V
1 1.8  105
r 1.6
20.(A)   0858
r 1.864
So, it is CsCl type of unit cell
So 3 a  2  r  r 
2 1.864  1.6 
So a  Å  2  2Å  4Å
3
21.(C) 22.(ABD) 23.(A)
24.(AC) Physisorption requires low temperature and approx zero activation energy.
25.(B) Increasing order of ligands on the basis of their strength : Br  H 2 O  en
- en will absorb colour of maxm energy.
Colour Absorbed Colour
Blue Orange
Red Green
green Red
Green  Orange  Re d
Colours : 
Energy


So, [M(en)3 ]2 will absorb green colour and will transmit Red colour.
Similarly [M(H2O)6 ]2 and [MBr6 ]4 are Blue and green colour simultaneously.
26.(C) 27.(B)

28.(B) AgCl  1e  Ag  Cl E 0  0.2V

Ag  Ag   1e E 0  0.79V
1e
 Ag   Cl E 0  0.59V
AgCl 
0.059 0.059
E0  log K   0.59  log KSP
n 1
 KSP  1010
Now solubility of AgCl in 0.1M AgNO3
S S  0.1  1010  S  109 mol / L

Hence 1 mole dissolves in 106 L solution

Hence in 106 L amount that dissolves in 1 m mol.
29.(D) PT  PA0 XA  PB0 1  XA   PA0 XA  PB0  PB0 XA
 
PT  PA0  PB0 X A  PB0
This is an equation of straight line. If a plot between PT and X A is plotted, it will be straight line with
slope equal to PA0  PB0  30.(B)

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31.(B) Mn(CO)6 can act as reducing agent because the metal carbonyl is stable when EAN is equal to nearest
noble gas configuration.
 e
[Mn(CO)6 ]
[Mn(CO)6 ] 
EAN  37 EAN  36
(Less stable) (More stable)

32.(D) 33.(B)
0.059
34.(A) E0  E0  log KSP AgBr  E0   0.7257
Br  /AgBr/Ag Ag /Ag 1 Ag /Ag

0.059
And E0  E0  log KSP AgCl  E0   0.59
Cl /AgCl/Ag Ag /Ag 1 Ag /Ag

Now cell reaction is

Ag  Br   AgBr  1e 

AgCl  1e  Ag  Cl

1e
Br   AgCl 
 Cl   AgBr
Br  
log    0.005
0.059
0   0.7257  0.59  
1 
Cl 
 
35.(D) When all particle along one body diagonal are removed, these 2X particles from corner are removed,
one particle removed & 2Z particle removed.
1 1 15
Hence new arrangement, X particle   6   6  ; Y particle  3; Z particle  6
8 2 4
Hence formula  X15/14 Y3 Z6  X5/4 YZ2  X5Y4 Z8

36.(C) 37.(CD) 38.(B)

39.(BC) The pressure decreases due to the adsorption of gas molecules on the surface of charcoal.
4
40.(C)  t  0
9
4
  t for [CoCl4 ]2   18000 cm1  8000cm1
9
41.(C) 42.(B)

43.(A) H 2  2Ag  2H   2Cl

 2AgCl  
G 0cell reaction  2  130.79   2  109.56   42.46 kJ / mole  2f  Ecell
0

42460
 E 0cell    0.220V
2  96500
0.059 1
Now E cell   0.220  log  0.456V  456mV
2  0.014
44.(B) 24  1023 atoms weight 200g
200
6.023  1023 atoms weigh  6.023 1023  50.19g
24 1023
 Atomic mass of the element = 50.19
 1  1
Number of atoms per unit cell   8     6    4
8 2    
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4  50.19
  41.66g cm3

6.023 10  200 10
23

10 3

45.(D)

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46.(B) [Ni(dmg) 2 ] is square planar complex. It is extra stabilised because of hydrogen bonding.
47.(D) 48.(D)

49.(A) 0 

1000  K sol  K H2O 
S
1000   3.4  2.02   10 6
138 
S
5
S  1  10

50.(D) In1mole of M x O , mole of M 2 ion  y  mole of M3 ion  x  y

Applying charge balance, 2y  3  x  y   2  0  y  3x  2

M3 x  y x   3x  2   2x  2  2 1  x 
2
   
M y 3x  2 3x  2 3x  2

51.(D) 52.(ABD) 53.(D)

54.(AB)
When positive & negative colloids are added in suitable amounts, mutual coagulation takes place.

55.(A) [Cr(ox)3 ]3 will show optical isomers because of absence of plane of symmetry.
56.(C) 57.(A)
58.(A)  m   m  b c
260   m  0.5b ….(i)
250   m  b ….(ii)
On solving (i) and (ii), we get
 m  270 1cm 2 mol1

59.(A) Number of surface unit cells,

6   2
2
Area of crystal
   7.76  1015
Area of unit cell
 0.556 10  7 2

Total number of atoms on the surface  2  7.76 1015

2  7.76 1015
Moles of number of atoms on the surface   2.57  108 moles
6.023  10 23

60.(C)

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61.(C) Ni(CO) 4 : tetrahedral, sp3 hybridised

[Co(CO)4 ] : tetrahedral, sp3 hybridised
62.(C) 63.(D)
63.5  0.1 7200
64.(A) m  theoretical    0.4738g
96500
0.3745
 % efficiency =  100  79%
0.4738

65.(C) Total number of effective atoms of one type (present at corner)  1/ 8  8  1 and total number of effective
1
atoms of other type (present at face centers)   6  3
2
ra  Radius of corner atom ; rc  Radius of face centered atom
 4 3  4 3
1 3 ra   3  3 rc 
Packing fraction  
 2ra 3
2  rc  ra   2a  2  2ra
rc  ra r rc
 1.414  c  1   0.414
ra ra ra
4  3
  ra  3  0.414ra  
3
  
3  1  3  0.414    0.63
3
PF 
 2ra  3 6  

66.(B) 67.(BCD) 68.(B)

69.(AC)
Sulphur and gold sol  multimolecular colloid, egg albumin in water = macromolecule colloid, soap
solution associated colloid
70.(D)

71.(D) 72.(C)
73.(A) (1) AgCl  s   e  Ag s   Cl E 0  0.22V

(2) 1/ 2Cl2  e  Cl E 0  1.36V

We get
Ag  s   1/ 2Cl2  g   AgCl s  E 0cell  1.14V

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G  nEF0   1 965001.14   110kJ / mol

74.(C) In simple cubic crystal a  2r

Let the radius of interstitial atom is r '
Then 2  r  r '  3a  3  2r
r '  3r  r  0.732r
4 3 4
r    0.732r 
3

Packing fraction  3 3  0.73

 2r 3
75.(B)

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76.(C)

77.(C) 78.(C)

79.(A) Anode Zn  Zn 2  2e

Cathode 2H   2e  H 2

Cell Zn  2H H2  Zn 2 ; E0cell  0   0.76  0.76V

0.059 0.011
 0.701  0.76  log 2
2 H 
 
  H    10 2 M
 
 NaOH required is 0.01 mole = 0.4 grams
80.(B) S1 : For the crystallaographic dimensions as a  b  c and       90 simple & Body centered
unit cells are possible
S2 : Acc. To the diagram two different triangles can be observed
R radius of biggest circle
r1  radius of smaller circle
r radius of smallest circle
Using Pythagoras
  
R 2  r 2  2Rr  R 2  R 2 4  2  4 2  r 2  2 2  2 Rr 
 6  2 2  r  R  6  4 2  Rr  66  44 2
2
2
r2 64 2 
Size ratio    
62 2 
2
R

 
For point a Cs ion we have number of next neighbours of Cs  ion in CsCl structure is 6Cs  ions , i.e.
a1, a2, a3, a4, a5, a6.
C.N.of cation charge of cation 3
S4    3
C.N.of anion charge of anion 1
Now Co-ordination no. of A is as shown so of B is 2
81.(B) 82.(ABC) 83.(B)
84.(AC)
Blue color of sky is due to tyndall effect and ultra microscope is also based on the same principle of
light scattering.
85.(B) The complex does not contain any element of symmetry hence the configuration is asymmetric,
therefore, it is optically active.

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86.(A) 87.(D)
88.(A) Q  10  4825  48250 C
48250
No. of mole of Ag    0.5
96500
1 1
Ag  Cu   Ag   Cu
2 2
2.00 2.00
2  0.25 2  0.50
 Ag  
log    E  E 0  0.0591 log 2.00
 0.0591
Ecell  Ecell
0
 1 cell
1 Cu  
1/2 1  2.00 1/2
 
0.0591 2.50 0.0591  2.50 
E 2  Ecell
0
 log  E  E 2  E1   log 2  log 
1 1.751/2 1  1.75 
0.0591 0.0591 0.0591
 log1.41  log1.88  0.1492  0.2742    0.125  .0074V
1 1 1
89.(C) 0.2046 = (1 + )  1.86  0.1  1 +  = 1.1   = 0.1
[H+] = C  = 0.1  (0.1) = 10–2 (M)
pH = 2
90.(D)

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