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Magnetic Properties-Dr - Ramesh Singampalli
Magnetic Properties-Dr - Ramesh Singampalli
Magnetic field
❖ It is the portion of the space in which a magnetic body or a current-carrying body
can experience the magnetic force.
❖The strength or the intensity of magnetic field is denoted by H
❖Unit: Ampere/metre (A/m)
❖Magnetic field is produced by permanent magnets such as horse shoe magnet and
temporarily by electromagnets or superconducting magnets.
Magnetic moment
The magnetic moment of a magnet is a quantity that determines the torque it will
experience in an external magnetic field.
τ=μ×B
where τ is the torque and B is the external magnetic field, and μ is the magnetic
Dr. S.Ramesh, GITAM University 2
moment
✓Introduction
✓Fundamental definitions
✓Classification of magnetic materials
✓Weiss theory of ferromagnetism
Syllabus of
✓Domain theory of ferromagnetism
module III
✓Hysteresis
✓Soft and hard magnetic materials
✓Eddy current losses
✓Ferrites (structure and magnetic properties)
Applications: Transformer cores
Magnetostrictive sensors
Data Storage Dr. S.Ramesh , GITAM University 3
Magnetization
❖Magnetization is defined as the magnetic moment per unit volume developed inside
the solid.
It is denoted by M
μm Magnetic moment
M= =
V Volume
❖It is denoted by χ
❖In general, the vector M and H can have different directions and χ is a tensor.
However in isotropic mediums M and H point in the same direction and χ is a scalar
quantity.
❖It is a measure of the ease with which the material can be magnetized. Materials
B = μ0(H+M) (1)
Relative Permeability, μr
It is defined as the ratio of the absolute permeability of the material to the permeability
of free space. r =
0
μr is only a number and has no units
For air or vacuum, μr = 1
Relation between χ and μr
We know = 0 (1 + ) and r =
0
Thus, r = 1 +
Dr. S.Ramesh, GITAM University 8
Origin of magnetization
The magnetic properties of solids arise due to electrons undergoing different motions
in the atoms which give rise to magnetic dipole moments.
In general, it arises from three sources
1. Orbital motion of electrons
2. Electron spin
3. Nuclear spin
The magnetic moment due to nucleus is about 1/2000 of the magnetic moment of
electrons. So it is neglected. Major contribution comes from the spin of the
unpaired valence electrons.
Only unpaired electrons contribute to the total magnetic moment in an atom
Bohr Magneton
1. It is the natural unit for the measurement of atomic magnetic moments
eh
2. It is denoted by μB B =Dr. S.Ramesh,=GITAM
9.28 10 −24
A.m 2
4 m
University 9
Classification of magnetic materials
Solid are classified into three categories based on the magnitude and sign of the relative
permeability, μr
1. Diamagnetic; μr < 1
2. Paramagnetic; μr > 1
3. Ferromagnetic; μr >> 1
Based on the magnetic moment, solid are of two types
First group do not posses permanent magnetic dipole moments. Ex: Diamagnetic
materials where as second group posses magnetic dipole moments and further divided
into four groups depending on the interaction between them
➢Paramagnetic
➢Ferromagnetic
➢Antiferromagnetic
➢Ferrimagnetic Dr. S.Ramesh, GITAM University 10
✓ Paramagnetic materials: Atoms have randomly oriented magnetic moments
✓Ferromagnetic materials: Atoms have parallel aligned magnetic moments
✓Antiferromagnetic materials: When the magnitude of the magnetic moments of
the two sub-lattices are equal but oriented in opposite direction.
✓Ferrimagnetic materials: When the magnitude of the magnetic moments of the
two sub-lattices are not exactly equal but oriented in opposite direction.
Paramagnetic Ferrimagnetic
Ferromagnetic Antiferromagnetic 11
Diamagnetic materials
In a diamagnetic material the atoms have no net magnetic moment when there is no
applied field. However, when placed in a magnetic field, it acquires feeble magnetism
in a direction opposite to that of the field.
Ex: Inert gases, water, gold, silver etc
Salient features
✓They exhibit negative magnetic susceptibility, χ since the magnetization M is
directed opposite to the direction of the applied field H. The absolute value of
susceptibility is small and is of the order of 10-6.
✓As the diamagnetic susceptibility is negative, the relative permeability is slightly
less than unity. r = 1 +
✓The magnetic susceptibility χ is independent of temperature.
✓The magnetization M is a linear function of the field H.
✓They do not have significant engineering applications. However super conducting
materials which are perfect diamagnetic materials
Dr. L. N. Patro, (χ = -1) finds several applications.
GITAM University 12
Paramagnetic materials
Atoms have randomly oriented magnetic moments. So the net magnetization is zero.
However, when placed in a magnetic field, it acquires feeble magnetism in the direction
of the field.
Ex: Copper, Chromium, Platinum etc
Salient features
✓They exhibit positive magnetic susceptibility, χ since the magnetization M is in the
direction of the applied field H. The absolute value of susceptibility is of the order of
10-6.
✓The relative permeability is slightly more than unity.
✓The magnetic susceptibility, χ is strongly dependent on temperature.
χ = C/T (Curie law), C is a constant known as Curie constant
✓The magnetization M is a linear function of the field H, when the field is not too
strong.
Dr. S.Ramesh, GITAM University 13
Ferromagnetic material
•They exhibit spontaneous magnetization that is atoms have parallel aligned magnetic
moments aligned even in the absence of the external magnetic field.
•This implies that there is a strong internal field with in the material that makes the
atomic magnetic moments align with each other.
•The origin of the internal field is due to the strong interaction between the spins.
•Ex: Iron, Nickel, Cobalt etc.
Salient features
✓They exhibit very high value of magnetic susceptibility and is as large as 106.
✓Magnetization M does not vary linearly with the field H.
✓Because of the nonlinear relationship between B and H, the permeability of a
ferromagnetic material does not have a constant value. B = μH is not valid. In practice
the magnetic permeability is measured by either the initial value or the maximum
permeability value.
Dr. S.Ramesh, GITAM University 14
✓The ferromagnetic properties of the materials are direction dependent. The
magnetization is more easily obtained along certain crystallographic axes (easy axes)
then other axes (hard axes).
✓They are characterized by a characteristic temperature Tc known as Curie
temperature. They obey Curie-Weiss law
C
χ=
T-Tc
T < Tc ; ferromagnetic
T > Tc ; paramagnetic
Nμ oμ m2 C
χ para = =
3k B T T
Nμ oμ m2
C = Curie constant =
3k B
N is the number of dipoles each carring dipole moment, μ m
Physical significance
➢ χpara is positive
➢ χpara depends of temperature
M C
= = Where C is Curie constant
Hi T
C
χ=
T-Tc
T < Tc ; ferromagnetic
T > Tc ; paramagnetic
Dr. S.Ramesh, GITAM University 19
Diamagnetic Paramagnetic Ferromagnetic
Ex: Inert gases, water, Ex: Chromium, Platinum Ex: Iron, Nickel etc.
gold, silver etc etc
Dr. S.Ramesh, GITAM University 21
Antiferromagnetic materials
Antiferromagnetism arises in materials in which the magnetic moments are equal but
pointed in opposite direction. So the net magnetization is zero. When placed in a
magnetic field and the temperature is 0 K, the magnetization is still zero. However as
temperature increases, in the presence of field, the antiparallel alignment is disturbed
and magnetization increases .
Ex: Cr, MnO, Cr2O3
Salient features
✓They are crystalline materials which exhibit a small positive magnetic susceptibility.
χ is of the order of 10-3 and 10-5
✓The magnetic susceptibility increases with increase in temperature and reached a
maximum value at certain temperature called Neel temperature. Above this
temperature the material becomes paramagnetic.
Dr. S.Ramesh, GITAM University 22
Ferrimagnetic materials
Ferrimagnetism arises in materials in which the magnetic moments are not equal but
pointed in opposite direction. So the net magnetic moment is thus finite.
Ex: Fe3O4 (FeOFe2O3) , Barium ferrite (BaO.6Fe2O3)
Salient features
✓The magnetic susceptibility is large & positive.
✓The saturation magnetization is not as high as ferromagnetic materials.
✓They exhibit the phenomena of hysteresis.
✓Resistivity is very high compared to ferromagnetic materials
✓They find applications in high frequency devices.
Soft magnetic materials are easy to Hard materials retain their magnetism and are
magnetize and demagnetize. difficult to demagnetize
They have narrow and small hysteresis loop They have large hysteresis loop area.
area
Due to small hysteresis loop area, the power Due to large hysteresis loop area, the power losses
losses in those materials are low. in those materials are high.
The coercivity and retentivity are small. The coercivity and retentivity are small. So strong
So these materials reach saturation fields are required to reach the saturation
magnetization relatively at lower applied magnetization.
fields.
They find applications at higher frequencies These are used to make permanent magnets,
due to their low power losses. These are magnetic tapes, disks used in the entertainment
used to make electromagnets. and computer industry
Ex: NiFe alloys, Soft ferrites etc Ex: AlNiCo (Al + Ni+ Co+ Fe), CuNiFe (Cu + Ni
+ Fe) alloys, CoOFe2O3 etc.
Dr. S.Ramesh, GITAM University 34
Ferrites (structure and magnetic properties)
❖Ferrimagnetisms: The magnitude of the magnetic moments of the two
ferrimagnetism.
Ferrimagnetic
✓The corresponding materials exhibiting such behavior are known as
❖Composition:
✓Ferrites are the compounds of two metallic oxides of which one is ferric oxide Fe2O3
✓The general formula is MFe2O4 or MOFe2O3 in which M stands for metals such as Ni,
oxide Fe2O3, other common examples include manganese ferrite (MnFe2O4), Nickel ferrite
(NiFe2O4) etc.
✓Composite ferrites: Solid solutions of one simple ferrite in another Ex: Ni-Zn ferrite.
Ferrites: Structures
Among them, the most important structure is spinel. Spinel occurs in two forms
and B.
✓Divalent metal ions on A sublattice (A site ) are surrounded by four oxygen ions in a
tetrahedral coordination while trivalent metal ions on B site are surrounded by six
✓In normal spinel, the divalent and trivalent ions appear only on A sites and B sites
respectively.
✓In the case of inverse spinel structure, the divalent metal ions occupy octahedral sites
(B site) while Fe3+ metal ions are equally over tetrahedral sites and octahedral sites.
at Curie temperature. Above Curie temperature, they exhibit paramagnetic state. The
✓Resistivity is very high compared to ferromagnetic materials, which is of the order of 102 to
1010 ohm m
✓They are widely used in high frequency applications because they exhibit low power loss at
high frequencies.
✓Ferrites with narrow hysteresis loop form soft magnets. They are used in audio and television
transformers
M 1.4
r = 1 + = 1 + = 1+ −4
= 1+2000 = 2001
H 6.5 10
Magnetostrictive sensors
➢Sensor: Sensor is a device which detects a physical stimulus and converts into a
measurable signal.
➢Magnetostriction: when a ferromagnetic material is magnetized, its dimension
changes slightly that means it expands or contracts. The material reverts to the original
position on the removal of the field. This magnetically induced reversible elastic strain
is called magnetostriction.
➢Ferromagnetic materials show both positive and negative magnetostriction. Materials
showing negative magnetostriction contract when the magnetic field increases and the
converse is true for the materials exhibiting positive values of magnetostriction.
Dr. S.Ramesh, GITAM University 50
➢Iron shows positive magnetostriction in weak magnetic fields and negative
magnetostriction at strong magnetic fields. However Ni and Co shows negative
magnetostriction
➢The origin of magnetostriction is mainly due to rotation of magnetic domains under
the action of the applied magnetic field.
➢It is an inherent properly that will not degrade with time.
➢This process is reversible, so a change in magnetization can also be produced when
the dimension of the material are changes with an external force.
➢This bidirectional coupling between the magnetic and mechanical states of a
magnetostrictive material provides a transduction capability that is used for sensing
devices.