Commodity Transportation Data Sheet

1 – PRODUCT AND COMPANY IDENTIFICATION

1.1. Product name, trade name and Ma ri ne Fuels, Ma rine Fuel Oi l, Marine Gas Oil, Ma rine Diesel Oil
synonyms Res idual Fuel Oi l, HFO, MDO, MGO, Bunker oil, Ma rine bunker oil.

1.2. Relevant identified uses of Fuel for use i n marine diesel engines, boilers, furnaces a nd other
the substance combustion equipment.

1.3. Detail of the supplier & testing Pl ease refer to the s upplier s tated on the safety data sheet. This product
company i s to be tested a t an Inspectorate laboratory. Company name:
Ins pectorate International Limited, 2 Perry Roa d, Witham, Essex, United
Ki ngdom (Registration Number 638315).

1.4. Emergency telephone number +1 703-527-3887

2 – HAZARDS IDENTIFICATION

2.1. Classification of the substance
Ma y be fa tal i f s wallowed and enter airways. Ca uses s kin irri tation. Ma y
Ca us e ca ncer. Ma y ca use damage to organs through prolonged and/or
repeated exposure.
DPD Cl a ssification: Xn; R20, Xi ; R38, Ca rc. Ca t. 1 a nd 3; R40, N; R45, Xn;
R48/21, N; R51/53, Xn; R63, Xn; R65
CLP Cl a s sification: As p. Tox. 1; H304, Ski n Irrit. 2; H315, Acute Tox. 4;
H332, Ca rc. 1B; H350, STOT RE 2; H350, Repr. 2; H361d, STOT RE 2.

2.2. Label elements

Ha za rd Preca utionary
Phra s es Phra s es
Repeated exposure may ca use skin P201 Obta i n s pecial i nstructions before use.
EUH066 drynes s or cra cking.
H304 Ma y be fa tal i f s wallowed and enter P260 Do not breathe
a i rways. dus t/fume/gas/mist/vapour/spray.
H315 Ca us es skin irritation. P301/310 IF SWALLOWED: Immediately ca ll a POISON
CENTER or doctor.
H332 Ha rmful if inhaled. P331 Do not i nduce vomiting since vomiting may
ca us e additional complications.
H350 Ma y ca us e ca ncer. P501 Di s pose of contents/container i n a ccordance
wi th l ocal regulations.
H361d Sus pected of damaging the unborn child. P280 Wea r protective gloves/eye protection.
H373 Ma y ca us e damage to organs through P308/313 If exposed or concerned: Get medical
prol onged or repeated exposure. a dvi ce/attention.
H400 Very toxi c to a quatic life. P332/313 If s kin irritation occurs: Get medical
a dvi ce/attention.
H410 Very toxi c to a quatic life with long lasting
effects.

3 – COMPOSITION/INFORMATION ON INGREDIENTS

3.1. Mixtures l i quid product of paraffinic-, naphthenic- a nd a romatic- hydrocarbons.

Composition is very complex a nd can vary due to blend proportions of
di fferent refinery s treams. Further va riations are due to different crude

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 s ources used i n refining. Components may contain s ulphur derivatives
a nd organic a cids.

3.2. CAS No. 68333-25-5; 92045-29-9; 68476-33-5; 68334-30-5.

4 – FIRST AID MEASURES

4.1. Description of first aid measures Eye contact – Immediately flush eyes with water for more than 10
mi nutes and make s ure eye lids a re open throughout the flushing process.
Seek medical advice.

Skin contact – Remove contaminated clothing. Wash skin with plenty of

wa ter a nd soap. Seek medical advi ce.

Inhalation – Seek fresh air i mmediately. Seek medical a dvice i f breathing

di fficulties continues.

Ingestion – Wa s h out mouth thoroughly and drink 2 glasses of water i n

s ma ll sips. Do not i nduce vomiting. Immediately ca ll a l ocal POISON
CENTER or a doctor.

5 – FIREFIGHTING MEASURES

5.1. Suitable extinguishing media Us e water fog/mist, foam, dry chemical or ca rbon dioxide (CO2).

5.2. Unsuitable extinguishing media Do not us e water stream, as i t may spread fire.

5.3. Advice for firefighters Wea r Self-Contained Breathing Apparatus (SCBA) with a chemical
protecti on s uit. Move containers from danger if it ca n be done without
ri s k. Avoid i nhalation of va pour and flue gases.

6 – ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective El i minate all sources of i gnition i n vi cinity of spilled material. Keep
equipment and emergency procedures di s tance from s ource. Stop l eak if this can be done without risk. Wear
gl oves. Keep unnecessary personal a way. Provi de good ventilation.

6.2. Environmental precautions Stop l eak if this ca n be done without risk. Prevent s pillage from entering
dra i ns and/or s urface water. Notify proper a uthorities i n case of
conta mination of soil or a quatic environment or discharge to drains.

6.3. Methods and material for Conta i n and absorb s pill with sand or other a bsorbent material a nd
containment and cleaning up tra ns fer to suitable waste containers. Wi pe up mi nor s pills with a cloth.

6.4. Reference to other sections See s ection 8 a nd 13.

7 – HANDLING AND STORAGE

7.1. Precautions for safe handling Avoi d a ll personal contact with the product. Do not breathe va pour or
fumes. Wash hands thoroughly a fter handling. Ensure that a ll
preca utions are ta ken to ensure minimizing spillage a nd overflows.

7.2. Conditions for safe storage, Store s afely, out of reach of children a nd a way from food, medicine etc.
including any incompatibilities keep in ti ghtly cl osed original packing.

8 – EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters No a pplicable occupational exposure limit exists for this material or i ts
components. Consult l ocal authorities for a ppropriate va lues.

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8.2. Exposure controls Wea r the personal protective equipment specified below.

Respiratory protection – Ens ure that s ufficient ventilation a nd mind the

wi nd direction. In the event if excessive a mount of H2S is measured
a bove 10 ppm a respiratory protection is required a nd most conform to
one of the following s tandards: EN 136/140/145.

Hand protection – Gl oves of nitrile rubber, approved by EN 374, i s

recommended. Cha nge gl oves often.

Eye protection – Wea r s afety goggles a pproved by EN 166 i f there is a risk

of eye s plash

9 – PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and State – Li qui d.
Chemical properties
Odour – Cha ra cteristic hydrocarbon.

Flash Point – Min. 60.5°C (141°F) (Pensky-Martens Cl osed Cup). Note -

thi s is a Ma rine Fuel and it is a lso a requirement that the Flash Point a lso
meets the SOLAS, Chapter II-1, Reg 4 requirements (which is a lso min.
60°C).

Density @15°C – 820 to 1020 kg/m³.

Kinematic Viscosity – 2 to 850 mm2/s .

Initial Boiling Point/Range – 150 to 600°C (302 to 1112°F).

10 – STABILITY AND REACTIVITY

10.1. Reactivity Thi s material is not expected to react.

10.2. Chemical stability Sta ble under normal conditions of storage a nd use.

10.3. Possibility of hazardous reactions None known a nd under normal storage conditions, hazardous reactions
wi l l not occur.

10.4. Conditions to avoid Avoi d heat, sparks, open flames a nd other ignition s ources.

10.5. Incompatible materials Strong oxi dising a gents.

10.6. Hazardous decomposition products Product decomposes i n fire conditions or when heated to high
temperatures, and i nflammable and toxic gases may be released

11 – TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects Likely routes of exposure – Ski n a nd eye contact are the primary routes
of exposure. Exposure may a lso occur through i nhalation or following
a cci dental ingestion.

Acute Oral Toxicity – The product does not have to be classified.

Acute Dermal Toxicity – The product does not have to be classified.

Acute Inhalation Toxicity – Ha rmful by i nhalation especially when

hydrogen s ulphide is present.

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 Skin corrosion/irritation – Expected to be slightly i rritating and may cause
reddening. Contact with hot material ca n ca use thermal burns which may
res ult in permanent skin damage.

Serious eye damage/irritation – Expected to be slightly i rritating.

Conta ct wi th hot material may ca use eye burns and/or blindness.

Respiratory or skin sensitisation - The product does not have to be

cl a ssified.

Aspiration Hazard – Note considered a n aspiration hazard but may ca use

chemi cal pneumonia if ingested or vomited.

Germ cell mutagenicity - The product does not have to be cl assified.

Carcinogenicity – Ma y ca us e cancer

Reproductive toxicity – Sus pected of damaging the unborn child.

STOT single exposure - The product does not have to be classified, but it
i s not expected to be a hazard

STOT repeated exposure – Ma y ca us e damage to organs through

prol onged or repeated exposure.

12 – ECOLOGICAL INFORMATION
12.1. Toxicity Very toxi c to a quatic life with l ong lasting effects.

12.2. Persistence and degradability Conta i ns substances which is not expected to be readily bi odegradable.
Ma y ca us e long-term a dverse effects in the aquatic envi ronment.

12.3. Bioaccumulative potential No da ta available.

12.4. Mobility in soil No da ta available.

12.5. Result of PBT and vPvB No da ta available.

assessment

12.6. Other adverse effects Spi lls may form a film on water s urfaces ca using physical damage to
orga nisms. Oxygen tra nsfer could also be i mpaired.

13 – DISPOSAL CONSIDERATIONS
13.1. Waste Treatment methods Uncl eaned packing a nd material is to be disposed of via a n a pproved l ocal
wa s te-removal scheme. Empty a nd clean packing s hould be disposed of
for recycl i ng.

14 – TRANSPORT INFORMATION
14.1. UN Number Not Appl icable. Product not classified as hazardous goods.

14.2. UN Proper Shipping Name Not Appl icable. Product not classified as hazardous goods.

14.3. Transport Hazard Class Not Appl icable. Product not classified as hazardous goods.

14.4. Packing Group Not Appl icable. Product not classified as hazardous goods.

Additional Information NOT CLASSIFIED AS HAZARDOUS FOR TRANSPORT (ADR, RID, UN, IMO,
IATA/ICAO)

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15 – REGULATORY INFORMATION
15.1. Safety, health and environmental Ca rci nogenic ca tegory 2. Special ca re should be a pplied to employees.
regulations/legislation specific for the other regulations may a pply to this material.
substance or mixture

15.2. Chemical safety assessment Chemi cal safety a ssessment has not been performed.

16 – OTHER INFORMATION

Vers ion Number 1.1

Effecti ve date 12 February 2018

Enterprise Burea u Veritas Commodities

Address 12km Na ti onal Road Athens-Lamia, Metamorfosi 144 52, Greece

Ema i l Veri fuel@bureauveritas.com

Tel +30 210 25 85 391

Di s claimer Thi s information is based on our current knowledge and is i ntended to

des cribe the product/material for the purpose of tra nsporting sample
bottl es containing this product to one of our VeriFuel l abs. It s hould not
therefore be construed as guaranteeing a ny s pecific property of the
product.

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