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cans are packed in cardboard outers to prevent Both physical and chemical changes occur during
damage to the cans during transport and handling, processing and, to a lesser extent, during storage,
and also as a convenient package for the supermarket. and it is these that determine the product quality in
terms of its sensory properties and nutrient content.
These changes, which can be either desirable or un-
Storage of Canned Food in the Home
desirable, are influenced by the time and temperature
0041 Canned food should be stored in a dry cupboard. of the process, the composition and properties of the
Most canned food is safe for at least 2 years, but food, the canning medium, and the conditions of
care should be taken to use the oldest cans first. storage.
Stock rotation is important at home as well as in the This article will consider the changes that can occur 0002
Canning
Table 1 The effect of heat processing on sensory quality tbl0001
R J Pither, Campden & Chorleywood Food Research
Association, Gloucestershire, UK Chemical/physicalreactions or Impact on sensory
changes occurring attribute
Copyright 2003, Elsevier Science Ltd. All Rights Reserved.
Flavor
Volatile loss (scalping oxidation) Loss of flavor
Volatile formation
Introduction Maillard Roasted flavor, bitterness
Oxidation Rancidity
0001 Canned foods are a significant component of the diet Pyracaines Roasted flavor
of most individuals in developed countries, offering Texture
food in a convenient form with year-round availabil- Cell membrane damage Loss of crispness
ity. The canning process relies on heat treatment for Cell separation Loss of firmness
Protein denaturation Gelling, firming
the destruction of microorganisms and preservation
Starch gelatinization Gelling
of the food, which is then generally considered to Color
have an indefinite microbiological shelf-life providing Natural pigment breakdown Bleaching
that pack integrity is maintained. The extent of the Loss of color
thermal processing, in terms of both temperature and Maillard reactions Browning
Others, e.g., metals and polyphenolic Discoloration
duration of the treatment, is dependent upon the
compounds
chemical and physical composition of the product.
846 CANNING/Quality Changes During Canning
giving rise to a complex mixture of low molecular by contamination of the product leading to an undesir-
compounds, including aldehydes, ketones, alcohols, able taint. One particularly unpleasant taint that has
acids, alkanes, alkenes, and alkynes. A certain level been found in a range of foods is the ‘catty taint.’ This is
of volatile compounds is generally considered caused by a heat-dependent reaction between natural
necessary to give characteristic odor and flavor prop- sulfur-containing compounds of the food and unsatur-
erties to many foods, but as many of the volatile ated ketones, such as mesityl oxide, which are wide-
compounds give rise to typical rancid or stale off- spread in many solvent-based products.
flavors, an ideal balance needs to be achieved in Examples of causes of catty taint in processed meat 0013
the food. products include: meat that has been stored in a cold
store painted with a material containing mesityl oxide
Maillard Reaction as a solvent contaminant, ox tongues that have been
hung on hooks coated with a protective oil, and pork
0008 In foodstuffs, reactions that occur between reducing
packed in cans where the side seam lacquer has been
sugars and amino acids or proteins are known as
dissolved in an impure solvent. Catty taint has also
Maillard reactions. A very important aspect of
been a problem in canned rice pudding, where the dye
the Maillard reaction in food preparation is the
used for printing on the rice sacks contained traces of
production of flavors and aromas. The rate of Mail-
mesityl oxide, which was picked up by the rice and
lard reaction increases with temperature, although
reacted with the trace amounts of hydrogen sulfide in
pH and water content also influence the reaction. the milk during processing.
The Maillard reaction can be split into three main
stages. The first is a condensation reaction between
the carbonyl group of a reducing carbohydrate and Texture
the free amino group of an amino acid or protein,
followed by rearrangement of the glycosylamines. Canning can bring about both desirable and undesir- 0014
These early Maillard reactions can lead to losses in able changes in texture of foods, primarily through
protein quality but do not give rise to flavors in the starch gelatinization, protein denaturation, and
food. pectin changes.
0009 The second stage, the advanced Maillard reactions,
Starch Gelatinization
involve many complex reactions and pathways.
The rearranged glycosylamines can degrade via a Starch gelatinization commences at a range of tem- 0015
multiplicity of routes, including dehydration, peratures dependent on the type of starch, i.e., pro-
elimination, cyclization, fission, and fragmentation, portions of amylose and amylopectin present, and the
which results in a pool of flavor intermediates and availability of water. The two components of starch
CANNING/Quality Changes During Canning 847
during the canning process by the union of mineral tein on heating releases the carotenoid astaxanthin,
elements that occur naturally in the flesh of seafood. which causes a change in color from natural blue–
0019 The formation of struvite is a rare event that grey to pinky red. Two types of isomerization, cis–
appears to occur sporadically. Although struvite has trans and epoxide, can also occur, giving rise to a
no odor or taste and is harmless, it does resemble slight lightening in color in canned fruits, e.g., pine-
broken glass and, therefore, is undesirable from the apple. (See Carotenoids: Occurrence, Properties, and
consumer’s point of view. Determination.)
848 CANNING/Quality Changes During Canning
stability. Aldehydes, produced by the breakdown of groups, red betacyanins and yellow betaxanthins.
sugars during canning, and ascorbic acid both accel- The most important pigment in this group is betanin,
erate the breakdown of the anthocyanins. These color the red pigment in beetroot which is often used as a
losses are a particular problem in canned red fruits, natural colorant. Betanin is susceptible to oxidation
e.g., strawberries. during canning, which leads to a loss of color, al-
0027 Anthocyanins can also be produced, as a result of though this is often not noticeable due to the large
excessive thermal processing, from leucoanthocyani- amount present.
dins, giving rise to defects such as red gooseberries The occurrence of a black ring discoloration in 0036
and pink pears. (See Phenolic Compounds.) canned beetroot is due to enzymatic oxidation of
polyphenols that occur during steam peeling, and
Tin and Iron not to betalain reactions.
0028 Both desirable and undesirable color effects can occur
in canned goods due to reactions involving metal ions. Changes in Nutritional Properties of
0029 Tin coating of the internal can surface produces a Foods
chemically reducing environment, which minimizes
oxidation and helps prevent color and flavor degrad- Both physical and chemical changes can occur during 0037
nutrients and physical loss of nutrients due to leach- Heating of milk results in the proteins being 0042
ing, there are many reactions that occur on canning precipitated by stomach acids as finely dispersed
that affect the availability of nutrients within the particles, making attack by digestive enzymes more
foodstuff and therefore their usefulness to the body. effective than in raw milk. This can also enhance
0038 If comparing the nutritive value of canned foods the formation of disulfide bonds, e.g., between b-
with that of fresh foods, it is also important to con- lactoglobulin and K-casein, which leads to greater
sider any changes that occur during conventional stability of the normally unstable b-lactoglobulin.
preparation and cooking techniques. The canning of legumes improves their digestibility
by unfolding the major seed globulins, as well as
Moisture
increasing nutritional availability by inactivation of
0039 The movement of water and solids during canning trypsin inhibitors.
can cause major changes in the nutritional status of
Lipids
the foodstuff. If the complete can contents are con-
sumed, these changes can be largely disregarded, but The nutritive value of the fat content of foods is not 0043
in products where the canning liquor is discarded, the generally significantly altered during normal heat
effects of dilution, dehydration, and loss of total processing. Hydrolysis reactions can occur, resulting
solids must be taken into consideration. Dilution or in separation of the fatty acids from the glycerol unit,
dehydration will affect the relative proportions of but this does not adversely affect the nutritional value
other constituents in the food, while soluble nutrients of the fat as the resulting free fatty acids are available
can be leached into the liquor. for digestion.
Saturated lipids are relatively stable, but unsatur- 0044
Proteins
ated lipids are prone to oxidation when heated in the
0040 Heating of proteins, as in canning, causes denatur- presence of oxygen or air. The exclusion of oxygen or
ation, i.e., rupturing of the hydrogen bonds and other use of antioxidants prevents the oxidation of lipids
noncovalent bonds, leading to changes in the during canning, so that losses in the nutritional value
conformation of the protein. The degree of protein of fats are unlikely to be significant. It is worth con-
denaturation depends on the level of heat treatment sidering the effects of lipid oxidation, however, as any
applied, but it can also be caused by oxidation and contact with oxygen during the history of the food
reaction with other food constituents, e.g., reducing can be sufficient for oxidation reactions to occur.
sugars and lipid oxidation products. The total level of The major effect of lipid oxidation is related to the 0045
crude protein is generally unaffected by canning, but flavor of food, but it can also result in the conversion
both desirable and undesirable changes can occur in of cis fatty acids to trans fatty acids. The nutritional
its nutritive quality and availability. Mild heating of value in terms of energy is similar for the two fatty
proteins leads only to changes in tertiary structure, acid types, but the trans fatty acids do not generally
which have little nutritional effect, although there is possess essential fatty acid activity. The availability
usually a loss in solubility. More severe heating, as in of the fat-soluble vitamins A, D, and E, as well as
canning of vegetables, results in the Maillard reaction vitamin C and folate, can also be reduced during
and the consequent loss in protein quality. These lipid oxidation.
reactions occur mainly between lysine and sugars
Carbohydrates
and cause a loss in availability of lysine, through
cross-linking, with a loss of up to 40% being seen Carbohydrates have numerous characteristic proper- 0046
on canning of potatoes. Canning of meat also leads to ties, and the effects of canning are therefore varied.
the reduction in availability of lysine and other essen- The levels of total and available carbohydrates have
tial sulfur containing amino acids and can lead to a been found to be largely unaffected during canning of
reduction in the digestibility of the meat. (See Protein: fruit and vegetables. In general, the effects of canning
Chemistry; Functional Properties.) on carbohydrates are related not directly to their
0041 The losses in protein availability that occur under nutritional value but to their interaction with other
normal canning conditions are, however, quite small food constituents and to the overall eating quality of
and not nutritionally significant for most people in the foodstuff.
developed countries, as lysine is rarely the limiting Losses on canning can be caused by reducing 0047
amino acid in the diet. Canning can, in fact, lead to sugars reacting with protein through the Maillard
improved protein availability and digestibility by reaction, which also causes a loss in availability of
denaturing antidigestive factors and by denaturing certain amino acids.
proteins. Some examples of advantageous effects of Gelatinization of the starch granules improves the 0048
heat processing are mentioned below. texture and, thereby, palatability of the food; it also
850 CANNING/Quality Changes During Canning
but slight further leaching of potassium and zinc does ation and oxidation, although it is stabilized in
occur. the presence of ascorbic acid, whereas pyridoxine
tbl0005 Table 5 Vitamin C content of fresh and canned peas and carrots (mg per 100 g)
Fresh 9 8 30 16
Stored for 7 days at ambient 3 4 17 16
Canned 2 3 20 12 11
Canned, stored for 6 months 2 2 15 2 10
Canned, stored for 12 months 2 3 8 5 5
(vitamin B6) can be lost through heat degradation and For most foods, the canning process replaces a
leaching. Losses of these two vitamins during canning conventional cooking process, and any mild reheating
of fruits and vegetables range between 30 and 80%. stage has no further significant effect on quality.
Losses on canning of meat can be very considerable, Losses in heat-labile nutrients such as vitamins can 0061