Professional Documents
Culture Documents
23, 3 (2002)
PAPER
Keywords: Frequency response characteristics, Carbon fiber, Polyurethane foam, FRUF composites,
Wood model
PACS number: 43.75.De, 43.75.Gh, 43.75.Mn
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Acoust. Sci. & Tech. 23, 3 (2002)
boards [4]. In comparison with them, a point of reinforcing . Carbon fiber reinforced polyurethane foam compo-
unidirectionally plastic foams with carbon fibers is the sites in which CF was uniformly oriented (CF/UF T1,
feature of our study. In this study, the bending strength, the T2 and T3). Three different sets of volume fractions of
vibrational properties and the frequency response char- components were prepared.
acteristics of this composite were measured and compared . Carbon fiber reinforced polyurethane foam compo-
with those of Sitka spruce for soundboard in order to sites in which CF was oriented only at the surfaces
investigate the aptitude as the substitute material for (CF/UF T5).
wooden soundboard. Furthermore, the validity of modeling The fiber filaments were tensioned and the both ends
the wood structure was discussed through comparison were tightly fixed in an aluminum mold (310 310
between the experimental results of the composites and 3 mm). The filaments were arranged unidirectionally and
Sitka spruce. were distributed uniformly in the mold in the productions
of GF/UF and CF/UF T1–T3 plates, and were placed only
2. EXPERIMENTAL at the surfaces in the production of CF/UF T5 plate. The
2.1. Glass Fiber (GF), Carbon Fiber (CF) and Poly- polyurethane liquid was poured in the direction perpendi-
urethane Foam (UF) for Composites and Their cular to bundles to avoid the disarray of fiber orientation.
Mechanical Properties After the pouring, the mold was covered, and the liquid
An E glass fiber (GF, Asahi Fiberglass Co.) and a was followed by foaming at 20 C.
polyacrylonitrile carbon fiber (CF, Pyrofil TR50S12L-AL, The target values of the density, the Young’s modulus
Mitsubishi Rayon Co.) were used to make fiber-reinforced and the flexural internal friction in the L direction (the fiber
composites. CF is composed of 12,000 filaments with a direction) were those values of Sitka spruce for the
diameter of 7 m and presents a thick bundle of filaments soundboard: s ¼ 0:38{0:47 g/cm3 , ELs ¼ 10{15 GPa and
by sizing. The densities of these fibers (f ) were QLs 1 ¼ 5:4{7:2 103 [5].
determined by the Archimedean method. The dynamic
Young’s moduli of the fibers (Ef ) were measured by a 2.3. Bending Strength of FRUF Composites and Sitka
tensile force oscillation method using Rheovibron DDV- Spruce
25FP, Orientec Co. Six samples of GF and twenty samples The bending strength of FRUF composites in the fiber
of CF were subjected to the measurement. The pre-load direction was measured by a three point bending test. The
forces applied were 150 gf for GF and 2,500 gf for CF. The size of specimen was 100 mm by 20 mm by 3 mm. The
measuring frequency was 110 Hz and the span was 60 mm. span and the head speed were 30 mm and 0.2 mm/min,
It was confirmed that the measuring frequency and pre-load respectively. The same test was also conducted for Sitka
forces did not influence significantly the experimental spruce with the same size.
results.
A polyurethane foam (UF, HM-1102, BASF INOAC 2.4. Vibrational Properties and Frequency Response
Polyurethane Co.) was used as the matrix material. The UF for FRUF Composites and Sitka Spruce
plates with eight kinds of densities (m ) were made by Square plate specimens of 105 mm by 105 mm by 3 mm
controlling the volume of polyurethane liquid poured into a were prepared from three types of FRUF composites and
mold (310 240 3 mm). Forming was conducted at were subjected to the measurements of the Young’s
20 C. After cutting eight rectangular specimens (105 modulus E, the flexural internal friction Q1 and the shear
20 3 mm) from each plate, their Young’s modulus (Em ) modulus G in both the L direction and the R direction
and flexural internal friction (Qm 1 ) were measured by a (perpendicular to the fiber direction). The two plates were
free-free flexural vibration method [5]. A square plate cut from a portion where the fibers were uniformly
specimen (105 105 3 mm) was cut from each plate and distributed and well oriented. The E and Q1 were
subjected to the measurement of shear modulus (Gm ) using measured by a free-free flexural vibration method. On the
a torsional vibration method [3]. other hand, the G was measured by a torsional vibration
method [3]. The frequency response characteristics of these
2.2. Production of Fiber Reinforced Polyurethane square plates were measured by the forced vibration
Foam (FRUF) Composite method. The center of the plate was excited by the sine
After measuring the mechanical properties of GF, CF wave sweeping the frequency range of 0.1–10 kHz, which
and UF, the following three types of unidirectionally fiber- was generated in a FFT analyzer, and the radiation sound
reinforced polyurethane foam (FRUF) composites were detected was inputted to the analyzer [3].
made: The vibrational properties and frequency response of
. Glass fiber reinforced polyurethane foam composites Sitka spruce for soundboard were measured by the same
in which GF was uniformly oriented (GF/UF). ways.
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T. ONO et al.: ACOUSTIC CHARACTERISTICS OF FRUF COMPOSITES
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Acoust. Sci. & Tech. 23, 3 (2002)
Table 1 Composition of FRUF composites, and characterization of fibers, matrix and FRUF composites.
Materials Composites
Samples Fiber Matrix c ELt ERt
3 3 3
f (g/cm ) Ef (GPa) VFf (%) m (g/cm ) Em (GPa) Gm (GPa) VFm (%) g/cm GPa GPa
GF/UF 2.38 70 7.3 0.289 0.320 0.135 92.7 0.442 5.41 0.345
CF/UF T1 1.95 228 5.3 0.365 0.434 0.188 94.7 0.449 12.5 0.458
CF/UF T2 1.95 228 6.2 0.370 0.441 0.192 93.8 0.468 14.5 0.470
CF/UF T3 1.95 228 7.9 0.378 0.454 0.256 92.1 0.502 18.4 0.493
CF/UF T5 1.95 228 5.4 0.321 0.364 0.157 94.6 0.408 12.7 0.385
GF: glass fiber, CF: carbon fiber, UF: polyurethane foam, VF: volume fraction, Suffix f: fiber, Suffix m: matrix of UF, Suffix t: value
calculated by rule of mixture, Suffix L: direction along grain, Suffix R: direction across grain.
those in CF/UF T3 exceeded the upper limit values of s spruce. The BL values for both materials linearly increased
and ELs . The ERt of CF/UF composite was slightly larger with increasing (r ¼ 0:980 for CF/UF composites and
than the Em , but smaller than the ERs . r ¼ 0:946 for Sitka spruce). The slope of regression line of
3.3.3. Surface reinforced CF/UF composite CF/UF composites was larger than that of Sitka spruce. A
T5 indicates the CF/UF composite reinforced only at larger increase of BL for CF/UF composites is caused by
both surfaces in order to attain higher elasticity keeping the increase of contact area between CF filaments and
low density. As expected, the CF/UF T5 was the lightest polyurethane foams due to the decrease of porosity. The
among CF/UF composites, and its ELt was in the range of BL values of CF/UF composites, which were smaller than
ELs . that of Sitka spruce in the low range, were high enough
for practical use.
3.4. Bending Strength of CF/UF Composites
FRUF composites should have a bending strength 3.5. Vibrational Properties of FRUF Composites
enough to sustain the tensile force of strings when they are Table 2 shows the densities and the vibrational
used as soundboards. GF and CF have extremely high properties of GF/UF and CF/UF composites as well as
tensile strengths of about 2.0 GPa and 3.5 GPa, respec- those of Sitka spruce (Sp). The values of f , EL =, EL =ER
tively. Calculated using these values by the rule of mixture, and EL /GLR were the resonant frequency, the specific
the bending strength of our CF/UF composite in the L Young’s modulus, the elastic anisotropy in the LR plane
direction, BLt , became more than 200 MPa. However, the and the influence of shear deformation on the deflection in
experimental values of BL were 60 to 160 MPa for CF/UF the L direction, respectively. As described before, wood
composites, while 80 to 130 MPa for Sitka spruce. shows large anisotropy i.e. large EL =ER and EL /GLR values,
Since the BL of CF/UF composite varied wider than which are important for the frequency response character-
that of Sitka spruce, the relationship between and BL istic of the soundboard. The values of =c indicate the
was investigated. Figure 3 shows relationship between the difference between the densities of plate and specimen in
values of BL and for CF/UF composites and Sitka FRUF composites. EL /ELt and ER =ERt are the differences
between the experimental and calculated values in Young’s
modulus.
3.5.1. Uniformly reinforced CF/UF composites
The of CF/UF composite varied widely irrespective
of the VFf order of T1, T2, and T3. This result indicates the
difficulty of making composites uniformly. The results of
=c show that the density of measured specimen is larger
than that of composite plate except for CF/UF T1-1. The
values of CF/UF T1-2, T2-1 and T3 exceeded the s . This
means that the CF filaments concentrate relatively high at
the central portion of composite plates, and it represents
that the VFf of measured specimens may be larger than that
of the plate, whereas their porosity may be smaller than
that of the plate.
Fig. 3 The relationships between the bending strength The EL values of the CF/UF specimens were smaller
in L direction, BL , and the density in CF/UF
composites and Sitka spruce wood, Sp.
than the ELt except for CF/UF T2-1. However, they were
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T. ONO et al.: ACOUSTIC CHARACTERISTICS OF FRUF COMPOSITES
larger than the lower limit value of ELs . Furthermore, the 3.6. Frequency Response Characteristics of CF/UF
EL of CF/UF T3-1 exceeded the upper limit value of ELs , Composites
15 GPa. These results suggest enough elasticity of the CF/ The sound power spectra and the 1/3-octave band
UF composites as soundboard materials. On the other hand, power spectra in CF/UF composites and Sitka spruce are
the ER values of all specimens were larger than the ERt , shown in Figs. 4 and 5, respectively. The dotted curve in
which were lower than the ERs . This increase of ER except Fig. 5 represents the frequency response characteristic of
for CF/UF T2-1 was attributed to the effects of disordered Sitka spruce to be standard. R1 and L1 indicate the resonant
CF filaments reinforcing the R direction. Considerably, peaks at the first mode in the R direction and in the L
large value of ER =ERt for CF/UF T2-1 may be due to high direction, respectively.
VFf , judging from a large value of =c . The frequency response characteristics of uniformly
The QL 1 values of all CF/UF composites were slightly reinforced CF/UF composites, especially for CF/UF T1-2
smaller than the lower limit of QLs 1 . The values of QR 1 and T2-2, were very similar to that of Sitka spruce. These
were slightly smaller than those of Qm 1 estimated from two specimens were considered to be the most appropriate
Fig. 2. Consequently, CF/UF composites exhibit almost the as materials for the soundboards.
same internal friction as Sitka spruce. Figure 6 shows the relationship between and overall
The GLR of CF/UF composites were slightly larger than power level Po for CF/UF composites. A negative linear
the Gm probably because of the reinforcement effect of correlation was observed between them. The Po value of
fibers. However, these values were still smaller than the Sitka spruce was plotted in the figure and it lay below the
GLR of Sitka spruce. Therefore, the EL /GLR of this CF/UF regression line. The smaller QL 1 values of CF/UF
composite was larger than that of Sitka spruce. composites are responsible for their larger Po values than
Consequently, CF/UF T1 and T2-2 specimens were the the Sitka spruce. This result suggests the advantage of the
closest to Sitka spruce in the vibrational properties, except CF/UF composites in sound volume over Sitka spruce.
for their higher EL =GLR values. Therefore, it was evaluated From these results, the following four characteristics
that the appropriate values of VFf were 5–6%. were observed:
3.5.2. Surface reinforced CF/UF composite (1) The frequencies at R1 peaks for CF/UF composites
The EL of CF/UF T5, which had almost the same VFf were lower than that for Sitka spruce.
as CF/UF T1, was smaller than that of T1, and no surface (2) Although almost the same frequency at the L1 peak
reinforcement effect was observed. This fact was ascribed was detected for both CF/UF composites and Sitka
to the disordered orientation of CF filaments. On the other spruce, the peak level of the composites was slightly
hand, the EL = of CF/UF T5 was comparable to that of higher.
Sitka spruce because of its smaller . In addition, the GLR (3) CF/UF composite had a clear peak in the frequency
of CF/UF T5 was the smallest among all of the CF/UF range from 5 to 7 kHz.
composites because no fibers reinforced the middle layer. (4) Sound pressure levels of CF/UF composites greater
Therefore, the surface reinforced CF/UF composite should reduced in high frequency range compared with Sitka
be different from wood in the response at high frequencies spruce.
due to its structure. The characteristic (1) is related to that CF/UF
composites have smaller ER or larger EL =ER compared
with Sitka spruce. The characteristic (2) is related to that
CF/UF composites have smaller QL 1 . The reason of the
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Acoust. Sci. & Tech. 23, 3 (2002)
Fig. 4 Sound power spectra of CF/UF composites and Sitka spruce wood by forced vibration.
characteristic (3) is not clear. The characteristic (4) is correspond to this biaxially reinforced composite, have
concerned with larger EL =GLR of CF/UF composites never been used for the soundboard of musical instruments,
compared with Sitka spruce. having higher and lower EL =. Surface reinforced CF/UF
CF/UF T5 was considerably higher in the relative level composite can be regarded as an approximate model of the
in the whole frequency range and greater in level reduction flat-sawn wood lumber having two large annual rings.
at high frequencies, compared with Sitka spruce. These Accordingly, it is natural that the acoustic properties of this
results are related to its small QL 1 and large EL =GLR . And, composite are different from those of wood for soundboard,
in comparison with uniformly reinforced CF/UF, CF/UF which is the quarter-sawn wood lumber. On the other side,
T5 was higher in the relative level in the R direction and in order to increase the GLR of CF/UF composite, it is
differed in the characteristic of high frequency range. necessary to consider a more complex model, which is
Accordingly, surface reinforced CF/UF is inferior to closer to the structure of real wood. However, technically it
uniformly reinforced CF/UF as the substitute material for is very difficult to produce the composite based on such a
soundboard. model.
From the above, uniformly reinforced CF/UF compo-
3.7. Wood Model for Soundboards site, as a first approximation, is considered to be an
Wood used for soundboards of musical instruments has appropriate model of wood for soundboard, having the
about 5 of cellulose microfibril angle, i.e. the angle insufficient frequency response characteristic in high
between longitudinal direction of crystalline cellulose and frequency range. Therefore, this composite can be expected
that of wood fiber. Therefore, it is rather natural that the ER as the substitute for wood for musical instrument sound-
of unidirectionally fiber-reinforced CF/UF composite is boards. The uniform arrangement of CF filaments and the
smaller than that of Sitka spruce. An additional arrange- improvement of the vibrational properties in the R
ment of the fiber filaments in the R direction can increase direction are the subjects for a future study.
the ER of CF/UF composite. However, this is not a proper
way since it may be accompanied by an increase of and a 4. CONCLUSIONS
large reduction of QR 1 in the composites. In fact, Unidirectionally fiber-reinforced composites for sound-
hardwoods, which have a relatively broad ray tissue and boards of musical instruments were developed using glass
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T. ONO et al.: ACOUSTIC CHARACTERISTICS OF FRUF COMPOSITES
Fig. 5 1/3-octave band power spectra of CF/UF composites and Sitka spruce wood. Dotted line: Sitka spruce wood. Arrows
L and R show the resonance point at the first mode in the L direction and that in the R direction, respectively.
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Acoust. Sci. & Tech. 23, 3 (2002)
arranged uniformly.
(4) From the result (3), the acoustic characteristic of wood
for soundboard in audible frequency range could be
represented using a simplified wood model composed
of unidirectionally oriented CF filaments and porous
structure of polyurethane foam without reproducing
all of the structures of real wood.
ACKNOWLEDGEMENTS
I would like to express my gratitude to H. Nonomura,
H. Sano and Y. Hirose of BASF INOAC Polyurethane
Chemical CO., Ltd. for making FRUF composites, and to
Fig. 6 The relationship between the overall power level, Prof. M. Miwa of Gifu University for his helpful advice,
Po , and the density in CF/UF composites. Open and to Lect. E. Obataya of University of Tsukuba for his
circle: Sitka spruce wood.
measurement on fibers, and to H. Takano of Gifu
University for measurements.
fiber and carbon fiber as reinforcement materials and REFERENCES
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[3] T. Ono, ‘‘Frequency responses of wood for musical instruments
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(3) In order to obtain CF/UF composites having almost for the soundboards of musical instruments’’, Mokuzai Gak-
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soundboard, appropriate volume fractions of CF
filaments were 5 to 6% and the filaments should be
142