CHEM 1014 Name ________________________

Exam II
John II. Gelder TA's Name ________________________
October 21, 1999
Lab Section _______

INSTRUCTIONS:
1. This examination consists of a total of 6 different pages.
The last page includes a periodic table and some useful
information. All work should be done in this booklet.

2. PRINT your name, TA's name and your lab section

number now in the space at the top of this sheet. DO
NOT SEPARATE THESE PAGES. You will receive 2
points for knowing your TA’s name AND laboratory
section number in which you are officially enrolled.

3. Answer all questions that you can and whenever called

for show your work clearly. Your method of solving
problems should pattern the approach used in
lecture/discussion. You do not have to show your work
for the multiple choice (if any) or short answer
questions.

4. No credit will be awarded if your work is not shown in

problems 3, 6b and 6c.

5. Point values are shown next to the problem number.

6. Budget your time for each of the questions. Some

problems may have a low point value yet be very
challenging. If you do not recognize the solution to a
question quickly, skip it, and return to the question after
completing the easier problems.

7. Look through the exam before beginning; plan your

work; then begin.

8. R e l a x and do well.

Page 2 Page 3 Page 4 TOTAL

SCORES _____ _____ _____ ______

(34) (36) (30) (100)
CHEM 1014 EXAM I PAGE 2

(16) 1. Complete the following table with the missing information.

(2 extra credit points)
Symbol # protons # neutrons # electrons charge
107 2+
46 Pd 46 61 44 2–
15 3–
7 N 7 8 10 –3
241
92 U 92 149 92 0
95 5+
42 Mo 42 53 37 +5

(6) 2. Balance each of the following equations.

a) 4Ag(s) + 2H2S(g) + O2(g) → 2Ag2S(s) + 2H2O(l)

b) MnO2(s) + 4HCl(aq) → Cl2(g) + MnCl2(aq) + 2H2O(l)

( 3 ) c) 4NH3(g) + 6NO(g) → 5N2(g) + 6H2O(g) BONUS: do not attempt until after

completing the exam!)

(12) 3. Write and balance the equation for each of the following.

a) A formation equation for CCl4(g).

2Cl 2 (g) + C(s) → CCl4 (l)

b) Write the formation for P2O5(s).

P 4 (s) + 5O2 (g) → 2P2 O 5 (s)

c) A combustion reaction for hexane, C7H14(l).

2C 7 H 14 (l) + 21O2 (g) → 14CO2 (g) + 14H2 O(l)

CHEM 1014 EXAM I PAGE 3

(24) 4. Calculate the mass, in grams, in each of the following;

a) 5.67 mol C7H14

5.67 mol C7 H 14  1 m o l  = 556 g C7 H 1 4

98 g

b) 4.72 x 10–6 mol NaCl

5 8 . 5 g 
4.72 x 10–6 mol NaCl  1 m o l  = 2.76 x 10–4 g NaCl

c) an atom of Ag

1 0 7 . 9 g A g   1 mol  –22 g per atom

 1 m o l   6 . 0 2 x 1 0 2 3 a t o m  = 1.79 x 10

d) 3.92 x 1024 molecules Br2.

1 mol   1 6 0 g  = 1042 g
3.92 x 1024 molecules Br 2 
6 . 0 2 x 1 0 m o l e c u l e s  1 m o l e 
2 3

(12) 5. Calculate the number of moles in each of the following;

a) 7.00 x 10–2 grams P2O5

7.00 x 10–2 grams P2 O 5  1 4 2 g  = 4.93 x 10–4 mol

1 mol

b) 8.15 x 1021 atoms Na.

1 mol
8.15 x 1021 atoms Na   = 0.0135 mol
6 . 0 2 x 1 0 2 3 a t o m 
CHEM 1014 EXAM I PAGE 4

(18) 6. Calculate each of the following;

a) the number of fluorine atoms in one molecule of PF5.

5 atoms of F in one molecule of PF5 .

b) the number of O atoms in 1 mol of O2.

6 . 0 2 x 1 0 2 3 O 2 m o l e c u l e   2 O a t o m s 
1 mol O2  1 mol  1 O 2 m o l e c u l e 

= 1.20 x 1024 atoms O

c) the number of N atoms in 2.5 mol of N2O5.

6 . 0 2 x 1 0 2 3 N 2 O 5 m o l e c u l e   2 N atoms 
2.5 mol N2 O 5  1 mol  1 N2O 5 m o l e c u l e 

= 3.01 x 1024 atoms N

d) the number of Cl atoms in 3.00 x 10–5 grams CCl4.

 1 mol  6 . 0 2 x 1 0 2 3 C C l 4 m o l e c u l e 
3.00 x 10–5 grams CCl4  1 5 4 g C C l 4   1 mol 
 4 Cl atoms  17 atoms Cl
 1 CCl 4 m o l e c u l e  = 4.69 x 10

(12) 7. Given the equation for the preparation of phosphoric acid H3PO4,

P4O10(s) + 6H2O(l) → 4H3PO4(aq)

Calculate,

a) the number of mol of water required to react with 2.5 mol of P4O10.

6 mol H2O
2.5 mol of P4 O 10  1 m o l P 4 O 1 0  = 15.0 mol H2 O

b) the number of mol of water required to produce 0.0455 grams of H3PO4.

6 mol H2O
0.0455 grams of H3 P O 4  9 8 g H 3 P O 4   4 mol H 3 P O 4  = 6.94 x 10– 4 mol
1 mol

a) the number of grams of P4O10 required to react with 45 g of H2O.

1 mol P4O 1 0 284 g P4O 1 0

45 grams of H2 O  1 8 g H 2 O   6 m o l H 2 O   1 m o l P 4 O 1 0  = 118 mol
1 mol
CHEM 1014 EXAM I PAGE 5

IA Periodic Table of the Elements VIIIA

1 2
1 H He
1.008 IIA IIIA IVA VA VIA VIIA 4.00
3 4 5 6 7 8 9 10
2 Li Be B C N O F Ne
6.94 9.01 10.81 12.01 14.01 16.00 19.00 20.18
11 12 13 14 15 16 17 18
3 Na Mg Al Si P S Cl Ar
22.99 24.30 IIIB IVB VB VIB VIIB VIII IB IIB 26.98 28.09 30.97 32.06 35.45 39.95
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.38 69.72 72.59 74.92 78.96 79.90 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.62 88.91 91.22 92.91 95.94 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.9 137.3 138.9 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 (209) (210) (222)
87 88 89 104 105 106 107 108 109
7 Fr Ra Ac Rf Db Sg Bh Hs Mt
(223) 226.0 227.0 (261) (262) (263) (262) (265) (266)

58 59 60 61 62 63 64 65 66 67 68 69 70 71
Lanthanides Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.1 140.9 144.2 (145) 150.4 152.0 157.2 158.9 162.5 164.9 167.3 168.9 173.0 175.0
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Actinides Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.0 231.0 238.0 237.0 (244) (243) (247) (247) (251) (252) (257) (258) (259) (260)

Useful Information

6.023 x 1023

grams
mol = molar mass