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This safety data sheet was created pursuant to the requirements of:
OSHA Hazard Communication Standard (29 CFR 1910.1200)
1. Identification
Product identifier
Supplier Address
IGM Resins US Inc.
3300 Westinghouse Blvd.
Charlotte, NC 28273, United States
T: +1-704-588-2500
F: +1-704-945-8728
2. Hazard(s) identification
Classification
Label elements
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Warning
Hazard statements
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H402 - Harmful to aquatic life
Other information
No information available.
3. Composition/information on ingredients
Substance
Not applicable.
Mixture
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Batch-to-batch variability occurs when the product has a set formula but there may be some very small differences among the
batches that occur during the production process.
4. First-aid measures
Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance.
Inhalation Get medical attention immediately if symptoms occur. Remove to fresh air.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open
while rinsing. Do not rub affected area. Get medical attention if irritation develops and
persists.
Skin contact May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see a
physician. Wash off immediately with soap and plenty of water for at least 15 minutes.
Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.
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Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section 8).
Symptoms Itching. Rashes. Hives. May cause redness and tearing of the eyes. Burning sensation.
5. Fire-fighting measures
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical.
Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
Specific hazards arising from the Product is or contains a sensitizer. May cause sensitization by skin contact.
chemical
Explosion data
Sensitivity to mechanical impact None.
Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear. Use personal protection equipment.
Personal precautions Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Ensure
adequate ventilation. Avoid contact with skin, eyes or clothing. Use personal protective
equipment as required.
Advice on safe handling Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory
equipment. Take off contaminated clothing and wash before reuse. Handle in accordance
with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing.
Do not eat, drink or smoke when using this product.
Storage Conditions Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Protect from
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sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Keep containers tightly
closed in a dry, cool and well-ventilated place.
Exposure Limits
Eye/face protection Wear safety glasses with side shields (or goggles).
Gloves
Duration of contact PPE - Glove material Glove thickness Break through time
Nitrile rubber 0.4 mm 60 minutes
Butyl rubber 0.4 mm 60 minutes
Skin and body protection Long sleeved clothing. Wear suitable protective clothing.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
General hygiene considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product.
Other information
Explosive properties No information available
Oxidizing properties No information available
Softening point No information available
Molecular weight 1400 g/mol
VOC Content (%) No information available
Liquid Density No information available
Bulk density No information available
Product Information
Inhalation Specific test data for the substance or mixture is not available. May cause irritation of
respiratory tract.
Eye contact Specific test data for the substance or mixture is not available. Causes serious eye irritation.
(based on components). May cause redness, itching, and pain.
Skin contact Avoid release to the environment. May cause sensitization by skin contact. Repeated or
prolonged skin contact may cause allergic reactions with susceptible persons. Causes skin
irritation. (based on components). Specific test data for the substance or mixture is not
available.
Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea.
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Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Itching. Rashes. Hives. Redness. May cause redness and tearing of the eyes.
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (dermal) 52,631.60 mg/kg
Component Information
Chemical name Oral LD50 Dermal LD50 Inhalation LC50
2-hydroxyethyl acrylate = 540 mg/kg ( Rat ) > 1000 mg/kg -
818-61-1
Acrylic acid = 1000 - 2000 mg/kg (Rat) > 2000 mg/kg (Rabbit) = 5.1 mg/L (Rat)
79-10-7
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Classification based on data available for ingredients. Irritating to skin.
Component Information
2-hydroxyethyl acrylate (818-61-1)
Species Rabbit
Exposure route Dermal
Exposure time 20 hours
Results Corrosive
Serious eye damage/eye irritation Classification based on data available for ingredients. Causes serious eye irritation.
Component Information
2-hydroxyethyl acrylate (818-61-1)
Species Rabbit
Exposure route Eye
Effective dose 50 µL
Exposure time Single exposure
Results Eye Damage
Component Information
2-hydroxyethyl acrylate (818-61-1)
Method OECD Test No. 429: Skin Sensitization: Local Lymph Node Assay
Species Mouse
Exposure route Dermal
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Results Sensitizing
Component Information
2-hydroxyethyl acrylate (818-61-1)
Method OECD Test No. 471: Bacterial Reverse Mutation Test
Species in vitro
Results Negative
Method OECD Test No. 475: Mammalian Bone Marrow Chromosome Aberration Test
Species in vivo
Results Negative
Component Information
2-hydroxyethyl acrylate (818-61-1)
Method OECD Test No. 422: Combined Repeated Dose Toxicity Study with the
Reproduction/Developmental Toxicity Screening Test
Species Rat
Results Not classified
Product Information
Chemical name Algae/aquatic plants Fish Toxicity to Crustacea
microorganisms
2-hydroxyethyl acrylate EC50 = 6 mg/L (72h, LC50: = 3.61mg/L (96h, > 100mg/L (72h, EC50: = 9.3mg/L (48h,
818-61-1 Pseudokirchnerella Pimephales promelas) Activated sludge) Daphnia magna)
subcapitata) NOEC = 0.86 mg/L (21d,
NOEC = 1 mg/L (72h, Daphnia magna)
Pseudokirchnerella
subcapitata)
Acrylic acid EC50: = 0.17 mg/L (96h, LC50: = 222 mg/L (96h, - EC50: = 95 mg/L (48h,
79-10-7 Selenastrum Brachydanio rerio) Daphnia magna)
capricornutum) LC50: = 27 mg/L (96h, LC50: = 47 mg/L (48h,
EC50: = 0.205 mg/L Salmo gairdneri) Daphnia magna)
(72h, Scenedesmus LC50: = 236 mg/L (96h,
subspicatus) Cyprinodon variegatus)
EC50: = 0.13 mg/L (72h,
Scenedesmus
subspicatus)
Component Information
2-hydroxyethyl acrylate (818-61-1)
Method Exposure time Value Results
OECD Test No. 301B: Ready 28 days 78% Biodegradation Readily biodegradable
Biodegradability: CO2 Evolution Test
(TG 301 B)
Component Information
Chemical name Partition coefficient
2-hydroxyethyl acrylate 0.21
818-61-1
Acrylic acid 0.46
79-10-7
Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
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products environmental legislation.
*Contact supplier for details. One or more substances in this product are either not listed on the US TSCA inventory, listed on the
confidential US TSCA inventory or are otherwise exempted from inventory listing requirements
Chemical name AICS DSL NDSL EINECS ELINCS ENCS IECSC KECL NZIoC PICCS TCSI TSCA
2-Propenoic X X - - - - X X X X X X
acid,
2-hydroxyethyl
ester, polymer
with
1,1''-methylenebi
s[4-isocyanatocy
clohexane] and
2-oxepanone
52404-33-8
2-hydroxyethyl X X - X - X X X X X X X
acrylate
818-61-1
Acrylic acid X X - X - X X X X X X X
79-10-7
Please note that the presence of a substance on an Inventory is not an indication that the substance can be supplied to that
country. Additional registration (REACH, K-REACH, ...) might be required.
Legend:
X - Listed
CBI - Confidential Business Information
EU-LVE - Low Volume exemption < 1T
LCP - Low concern polymer
PMN - indicates a commenced PMN substance
S - indicates a substance that is identified in a final Significant New Use Rule
US-LVE - Low volume exemption < 10 T annually of the active substance
US-PE - Polymer Exemption
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US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical name Hazardous Substances RQs Extremely Hazardous Reportable Quantity (RQ)
Substances RQs
Acrylic acid 5000 lb - RQ 5000 lb final RQ
79-10-7 RQ 2270 kg final RQ
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
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16. Other information
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
Ceiling Maximum limit value * Skin designation
Key literature references and sources for data used to compile the SDS
Agency for Toxic Substances and Disease Registry (ATSDR)
U.S. Environmental Protection Agency ChemView Database
European Food Safety Authority (EFSA)
EPA (Environmental Protection Agency)
Acute Exposure Guideline Level(s) (AEGL(s))
U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act
U.S. Environmental Protection Agency High Production Volume Chemicals
Food Research Journal
Hazardous Substance Database
International Uniform Chemical Information Database (IUCLID)
Japan GHS Classification
Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS)
NIOSH (National Institute for Occupational Safety and Health)
National Library of Medicine's ChemID Plus (NLM CIP)
National Library of Medicine's PubMed database (NLM PUBMED)
National Toxicology Program (NTP)
New Zealand's Chemical Classification and Information Database (CCID)
Organization for Economic Co-operation and Development Environment, Health, and Safety Publications
Organization for Economic Co-operation and Development High Production Volume Chemicals Program
Organization for Economic Co-operation and Development Screening Information Data Set
World Health Organization
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