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SAFETY DATA SHEET

This safety data sheet was created pursuant to the requirements of:
OSHA Hazard Communication Standard (29 CFR 1910.1200)

Issuing Date 25-Sep-2020 Revision date 22-Feb-2021 Revision Number 1.01

1. Identification
Product identifier

Product Name Photomer 6210

Other means of identification

Product Code(s) 10000423 10000424

Recommended use of the chemical and restrictions on use

Recommended use Acrylates.


Activator.
Production of UV inks, coatings and adhesives.

Restrictions on use No information available.

Details of the supplier of the safety data sheet

Supplier Address
IGM Resins US Inc.
3300 Westinghouse Blvd.
Charlotte, NC 28273, United States
T: +1-704-588-2500
F: +1-704-945-8728

Emergency telephone number

Emergency Telephone (US) +1 760 476 3962 ## 333 293


TF (US)+1 866 519 4752 ## 333 293

2. Hazard(s) identification
Classification

Skin corrosion/irritation Category 2


Serious eye damage/eye irritation Category 2A
Skin sensitization Category 1
Acute aquatic toxicity Category 3

Hazards not otherwise classified (HNOC)


Not applicable

Label elements

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Warning

Hazard statements
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H402 - Harmful to aquatic life

Other information
No information available.

3. Composition/information on ingredients
Substance

Not applicable.

Mixture

Chemical name CAS No Weight-% Trade secret


2-Propenoic acid, 2-hydroxyethyl ester, polymer 52404-33-8 80 - <100% *
with 1,1''-methylenebis[4-isocyanatocyclohexane]
and 2-oxepanone
2-hydroxyethyl acrylate 818-61-1 1 - <3% *
Acrylic acid 79-10-7 0.1 - <0.5% *

*The exact percentage (concentration) of composition has been withheld as a trade secret.

Batch-to-batch variability occurs when the product has a set formula but there may be some very small differences among the
batches that occur during the production process.

4. First-aid measures
Description of first aid measures

General advice Show this safety data sheet to the doctor in attendance.

Inhalation Get medical attention immediately if symptoms occur. Remove to fresh air.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open
while rinsing. Do not rub affected area. Get medical attention if irritation develops and
persists.

Skin contact May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see a
physician. Wash off immediately with soap and plenty of water for at least 15 minutes.

Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.

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Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section 8).

Most important symptoms and effects, both acute and delayed

Symptoms Itching. Rashes. Hives. May cause redness and tearing of the eyes. Burning sensation.

Indication of any immediate medical attention and special treatment needed

Note to physicians May cause sensitization in susceptible persons. Treat symptomatically.

5. Fire-fighting measures
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical.
Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.

Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.

Specific hazards arising from the Product is or contains a sensitizer. May cause sensitization by skin contact.
chemical

Explosion data
Sensitivity to mechanical impact None.

Sensitivity to static discharge None.

Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear. Use personal protection equipment.

6. Accidental release measures


Personal precautions, protective equipment and emergency procedures

Personal precautions Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Ensure
adequate ventilation. Avoid contact with skin, eyes or clothing. Use personal protective
equipment as required.

Other information Refer to protective measures listed in Sections 7 and 8.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

7. Handling and storage


Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory
equipment. Take off contaminated clothing and wash before reuse. Handle in accordance
with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing.
Do not eat, drink or smoke when using this product.

Conditions for safe storage, including any incompatibilities

Storage Conditions Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Protect from

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sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Keep containers tightly
closed in a dry, cool and well-ventilated place.

8. Exposure controls/personal protection


Control parameters

Exposure Limits

Chemical name ACGIH TLV OSHA PEL NIOSH


Acrylic acid TWA: 2 ppm (vacated) TWA: 10 ppm TWA: 2 ppm
79-10-7 S* (vacated) TWA: 30 mg/m3 TWA: 6 mg/m3
(vacated) S*

Biological occupational exposure limits


This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific
regulatory bodies.

Appropriate engineering controls

Engineering controls Showers


Eyewash stations
Ventilation systems.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Hand protection Impervious gloves. Wear suitable gloves.

Gloves
Duration of contact PPE - Glove material Glove thickness Break through time
Nitrile rubber 0.4 mm 60 minutes
Butyl rubber 0.4 mm 60 minutes

Skin and body protection Long sleeved clothing. Wear suitable protective clothing.

Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.

General hygiene considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product.

9. Physical and chemical properties


Information on basic physical and chemical properties
Physical state Liquid
Appearance clear
Color No information available
Odor Characteristic odor
Odor threshold No information available

Property Values Remarks • Method


pH No data available
Melting point / freezing point No data available
Boiling point / boiling range No data available None known
Flash point 94 °C / 201.2 °F Pensky-Martens Closed Cup (PMCC)
Evaporation rate No data available
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Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability or explosive No data available
limits
Lower flammability or explosive No data available
limits
Vapor pressure < 0.01 kPa
Vapor density No data available
Relative density 1.13
Water solubility No data available None known
Solubility(ies) Insoluble in water
Partition coefficient No data available
Autoignition temperature No data available None known
Decomposition temperature -
Kinematic viscosity No data available
Dynamic viscosity 8500 - 15000 mPa s

Other information
Explosive properties No information available
Oxidizing properties No information available
Softening point No information available
Molecular weight 1400 g/mol
VOC Content (%) No information available
Liquid Density No information available
Bulk density No information available

10. Stability and reactivity


Reactivity No information available.

Chemical stability Stable under normal conditions.

Possibility of hazardous reactions None under normal processing.

Hazardous polymerization Polymerization can occur.

Conditions to avoid Extremes of temperature and direct sunlight.

Incompatible materials Strong acids. Strong bases. Strong oxidizing agents.

Hazardous decomposition products None known based on information supplied.

11. Toxicological information


Information on likely routes of exposure

Product Information

Inhalation Specific test data for the substance or mixture is not available. May cause irritation of
respiratory tract.

Eye contact Specific test data for the substance or mixture is not available. Causes serious eye irritation.
(based on components). May cause redness, itching, and pain.

Skin contact Avoid release to the environment. May cause sensitization by skin contact. Repeated or
prolonged skin contact may cause allergic reactions with susceptible persons. Causes skin
irritation. (based on components). Specific test data for the substance or mixture is not
available.

Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea.

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Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Itching. Rashes. Hives. Redness. May cause redness and tearing of the eyes.

Acute toxicity

Numerical measures of toxicity

The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (dermal) 52,631.60 mg/kg

Component Information
Chemical name Oral LD50 Dermal LD50 Inhalation LC50
2-hydroxyethyl acrylate = 540 mg/kg ( Rat ) > 1000 mg/kg -
818-61-1
Acrylic acid = 1000 - 2000 mg/kg (Rat) > 2000 mg/kg (Rabbit) = 5.1 mg/L (Rat)
79-10-7

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Classification based on data available for ingredients. Irritating to skin.

Component Information
2-hydroxyethyl acrylate (818-61-1)
Species Rabbit
Exposure route Dermal
Exposure time 20 hours
Results Corrosive

Acrylic acid (79-10-7)


Species Rabbit
Exposure route Dermal
Effective dose 0.5 mL
Exposure time 1 hour
Results Corrosive

Serious eye damage/eye irritation Classification based on data available for ingredients. Causes serious eye irritation.

Component Information
2-hydroxyethyl acrylate (818-61-1)
Species Rabbit
Exposure route Eye
Effective dose 50 µL
Exposure time Single exposure
Results Eye Damage

Acrylic acid (79-10-7)


Species Rabbit
Exposure route Eye
Effective dose 50 µL
Exposure time 21 days
Results Eye Damage

Respiratory or skin sensitization May cause sensitization by skin contact.

Component Information
2-hydroxyethyl acrylate (818-61-1)
Method OECD Test No. 429: Skin Sensitization: Local Lymph Node Assay
Species Mouse
Exposure route Dermal
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Results Sensitizing

Acrylic acid (79-10-7)


Method OECD Test No. 429: Skin Sensitization: Local Lymph Node Assay
Species Guinea pig
Exposure route Dermal
Results Not a skin sensitizer

Germ cell mutagenicity No information available.

Component Information
2-hydroxyethyl acrylate (818-61-1)
Method OECD Test No. 471: Bacterial Reverse Mutation Test
Species in vitro
Results Negative

Method OECD Test No. 474: Mammalian Erythrocyte Micronucleus Test


Species in vivo
Results Negative

Acrylic acid (79-10-7)


Method OECD Test No. 476: In vitro Mammalian Cell Gene Mutation Test
Species in vitro
Results Negative

Method OECD Test No. 475: Mammalian Bone Marrow Chromosome Aberration Test
Species in vivo
Results Negative

Carcinogenicity No information available.


The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical name ACGIH IARC NTP OSHA
Acrylic acid - Group 3 - -
79-10-7
Legend
IARC (International Agency for Research on Cancer)
Group 3 - Not Classifiable as to Carcinogenicity in Humans
Component Information
2-hydroxyethyl acrylate (818-61-1)
Species Rat
Results Not Carcinogenic

Acrylic acid (79-10-7)


Method OECD Test No. 451: Carcinogenicity Studies
Species Rat
Results Not Carcinogenic

Reproductive toxicity No information available.

Component Information
2-hydroxyethyl acrylate (818-61-1)
Method OECD Test No. 422: Combined Repeated Dose Toxicity Study with the
Reproduction/Developmental Toxicity Screening Test
Species Rat
Results Not classified

Acrylic acid (79-10-7)


Method OECD 415
Species Rat
Results Not classified
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STOT - single exposure No information available.

STOT - repeated exposure No information available.

Aspiration hazard No information available.

Other adverse effects No information available.

Interactive effects No information available.

12. Ecological information


Ecotoxicity Harmful to aquatic life.

Product Information
Chemical name Algae/aquatic plants Fish Toxicity to Crustacea
microorganisms
2-hydroxyethyl acrylate EC50 = 6 mg/L (72h, LC50: = 3.61mg/L (96h, > 100mg/L (72h, EC50: = 9.3mg/L (48h,
818-61-1 Pseudokirchnerella Pimephales promelas) Activated sludge) Daphnia magna)
subcapitata) NOEC = 0.86 mg/L (21d,
NOEC = 1 mg/L (72h, Daphnia magna)
Pseudokirchnerella
subcapitata)
Acrylic acid EC50: = 0.17 mg/L (96h, LC50: = 222 mg/L (96h, - EC50: = 95 mg/L (48h,
79-10-7 Selenastrum Brachydanio rerio) Daphnia magna)
capricornutum) LC50: = 27 mg/L (96h, LC50: = 47 mg/L (48h,
EC50: = 0.205 mg/L Salmo gairdneri) Daphnia magna)
(72h, Scenedesmus LC50: = 236 mg/L (96h,
subspicatus) Cyprinodon variegatus)
EC50: = 0.13 mg/L (72h,
Scenedesmus
subspicatus)

Persistence and degradability No information available.

Component Information
2-hydroxyethyl acrylate (818-61-1)
Method Exposure time Value Results
OECD Test No. 301B: Ready 28 days 78% Biodegradation Readily biodegradable
Biodegradability: CO2 Evolution Test
(TG 301 B)

Bioaccumulation There is no data for this product.

Component Information
Chemical name Partition coefficient
2-hydroxyethyl acrylate 0.21
818-61-1
Acrylic acid 0.46
79-10-7

Other adverse effects No information available.

13. Disposal considerations


Waste treatment methods

Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
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products environmental legislation.

Contaminated packaging Do not reuse empty containers.

US EPA Waste Number U008

14. Transport information

DOT Not regulated

TDG Not regulated

MEX Not regulated

ICAO (air) Not regulated

IATA Not regulated

IMDG Not regulated

RID Not regulated

15. Regulatory information


International Inventories

*Contact supplier for details. One or more substances in this product are either not listed on the US TSCA inventory, listed on the
confidential US TSCA inventory or are otherwise exempted from inventory listing requirements

Chemical name AICS DSL NDSL EINECS ELINCS ENCS IECSC KECL NZIoC PICCS TCSI TSCA
2-Propenoic X X - - - - X X X X X X
acid,
2-hydroxyethyl
ester, polymer
with
1,1''-methylenebi
s[4-isocyanatocy
clohexane] and
2-oxepanone
52404-33-8
2-hydroxyethyl X X - X - X X X X X X X
acrylate
818-61-1
Acrylic acid X X - X - X X X X X X X
79-10-7

Please note that the presence of a substance on an Inventory is not an indication that the substance can be supplied to that
country. Additional registration (REACH, K-REACH, ...) might be required.

Legend:

X - Listed
CBI - Confidential Business Information
EU-LVE - Low Volume exemption < 1T
LCP - Low concern polymer
PMN - indicates a commenced PMN substance
S - indicates a substance that is identified in a final Significant New Use Rule
US-LVE - Low volume exemption < 10 T annually of the active substance
US-PE - Polymer Exemption
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AICS - Australian Inventory of Chemical Substances


DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
NZIoC - New Zealand Inventory of Chemicals
PICCS - Philippines Inventory of Chemicals and Chemical Substances
TCSI - Taiwan Chemical Substance Inventory
TSCA - Toxic Substances Control Act Frank R. Lautenberg Chemical Safety for the 21st Century Act (active rule)

US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

Chemical name SARA 313 - Threshold Values %


Acrylic acid - 79-10-7 1.0

SARA 311/312 Hazard Categories


Should this product meet EPCRA 311/312 Tier reporting criteria at 40 CFR 370, refer to Section 2 of this SDS for appropriate
classifications.

CWA (Clean Water Act)


This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).

CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).

Chemical name Hazardous Substances RQs Extremely Hazardous Reportable Quantity (RQ)
Substances RQs
Acrylic acid 5000 lb - RQ 5000 lb final RQ
79-10-7 RQ 2270 kg final RQ

US State Regulations

California Proposition 65
This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

Chemical name New Jersey Massachusetts Pennsylvania


2-hydroxyethyl acrylate X X X
818-61-1
Acrylic acid X X X
79-10-7
4,4'-methylenedicyclohexyl X X X
diisocyanate
5124-30-1

U.S. EPA Label Information

EPA Pesticide Registration Number Not applicable

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16. Other information
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
Ceiling Maximum limit value * Skin designation

Key literature references and sources for data used to compile the SDS
Agency for Toxic Substances and Disease Registry (ATSDR)
U.S. Environmental Protection Agency ChemView Database
European Food Safety Authority (EFSA)
EPA (Environmental Protection Agency)
Acute Exposure Guideline Level(s) (AEGL(s))
U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act
U.S. Environmental Protection Agency High Production Volume Chemicals
Food Research Journal
Hazardous Substance Database
International Uniform Chemical Information Database (IUCLID)
Japan GHS Classification
Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS)
NIOSH (National Institute for Occupational Safety and Health)
National Library of Medicine's ChemID Plus (NLM CIP)
National Library of Medicine's PubMed database (NLM PUBMED)
National Toxicology Program (NTP)
New Zealand's Chemical Classification and Information Database (CCID)
Organization for Economic Co-operation and Development Environment, Health, and Safety Publications
Organization for Economic Co-operation and Development High Production Volume Chemicals Program
Organization for Economic Co-operation and Development Screening Information Data Set
World Health Organization

Issuing Date 25-Sep-2020


Revision date 22-Feb-2021
Revision Note No information available.
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet

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