EXPERIMENT ~ 3 ‘Aim :- To analyse the given inorganic salt for acidic and basic radicals [(NH)2 COs] Preliminary Investigation Physical State Solid Colour White (Cu, Fe, Fe", Ni’, Mn?*,Co™ absent) Odour Ammonium smell (may be NH’) Solubility Soluble in water Flame Test No Characteristic flame (Pb", Cu", Ca, SP", Ba Za absent) (A) Identification of Acidic Radical (a) Prefiminary test : Experiment Observation Tnference T. Salt solution + dil H;SO, Colourless, colourless gas with brisk | Group A anion CO," may be effervescence which turn lime water | present) milky ‘Confirmative test } BaCl, Test: Salt solution + | White ppt of BaCO, CO," Confirmed BaCl, 2, MgSO, Test ; Salt solution + | White ppt of MgCO, CO; Confirmed MgSO, (B) Identification of Basie Radical 4a) Preliminary Test Experiment ‘Observation Inference I. Salt Solution + NaOH Heat ‘Smell of NH. 2. Place a red litmus on the mouth of | Red litmus tums blue Zero group present (NH may be) test tube. ° Confirmative test Experiment Observation Tnference TNessler's reagent test : Salt> Reddish brown ppt. is formed ‘NH; confirmed. Solution + NaOH + Nessler’s Reagent 2. NaOH test : ‘Smell of NH Salt Solution + NaOH + Heat Dense white fumes of NH,CI are ae Bring a glass rod dipped in cone. HCI | formed. NHj Confirmed. ‘Chemical Reactions : Acidic Radical Preliminary ‘Test :- 1 (WH, ),CO, + H,SO, —(NH,),SO,+CO, t+ H,O 2 Ca(OH), +O, > CaCO, + HO Confirmative Test 1, BaCl, Test (vH,),CO, + BaCl, > BaCO, 142NH,CI 2 MgSO, (NH, ),CO, + MgSO, —>MgCO, 4 +(NH,),SO, (CHEMISTRY PRACTICALS) Page No22 ‘Basie Radical (a) Preliminary Test 1. (NH,),CO,+2NaOH —>Na,CO, +2H,0+ 2H, + INH + Red itm > Litmas tens blue () Confirmative test 1. Nesler's Test K,Hlgl, —92K1 4 Hg I, (Nessler’s Reagent) High, + NH, —>NELHGL + HL 2NHLHigL + HO —> NH Hg Ou NH He \ 1 2 NwOH Test (WH,),CO, +240 —>Na,CO, +211,0 20H, > NH, }+HCI—+NH,CI (Dense white fumes) Result: The given inorganic salt contains following Acidic Radical: - COP Basie Radical: NI EXPERIMENT — Am To analyse the gven sl of ac and bse adel (NHAC Primary Tovetigation Phys tte sia Colour: white (Cu®*, Fe", Fe Ni", Mn”, Co” absent) Odour Amnon sel (NE ay be presen Sob 2 Soluble in vate Flame Test No characteristic lame (Cu”', Ca”, Ba"*,Sx",Pb"? , Znabsent) (3) entiation of Acide Radel f-Preinary tet Eaperiet Observation Tatars T—} Sota raTWTSO, salon —T Noses e eohal — Grey & )?,CH,COO",NO’s ,S0”,$* sabsent) Ts ac SO, et oka [Gay Bako (my) Tings dppetia N1LO11 [puget soe ch Became riven rset Wy Contiemative Ti Epeiner ‘ioeraion [Taare AiR eal Sa Soioa Cady oe pe Ceo AgNO» Doth pint | White tae i son 7] Cmte —] Rah onge par Oat 1) Sale Solid K:Cr0; (1:2) | is evolved * cone: 380, Heat 1) Pas these vapourthvough | Solton becomes NuoHl yellow ©) Ald acstie aid and teat | Yellow pp of tea acetate to yollow soluion | chromate i formed (CHEMISTRY PRACTICALS) Page No3dentification of Basic Radical Proliminary Test: Experiment ‘Observation [Inference T [Salt solution +NaOH'y | Smell of Ammonia | Zero group (NH) Heat May be | Place aved mus on the | Red Tims turns mouth of test tube blue Confirmative Test: Experiment Observation Inference T | Nessler Test: Salt solution + NaOH ‘Reddish brown pris | Nil Confirmed Nesslers reagent formed ‘NaOH Test: Salt Solaion + NaOH > Heat | Sinell of NH Ni Contirmed Bring a glass rd dipped in ail HC white dense fumes of NHiClave formed Frainioary Tat? 2NH,C1-+H,80, "NH, 80, +241 NHLOH HCl —+NHLCIs 1.0 (White dense fumes) Confirmative Test: AgNOstest —NILCT+2AgNO, > 2AgCI L+NHWNO, Cardy wiiteppO AgCl+ NH OH —HAg(NH,),]C1+ 21,0 (Diamine silver () Chloride) ‘Chromyl Chloride Test: K.ChO} +1960, —>K.S02C00, +10 INH-+ SO, —Y(NHYSO,+ 2HCt C10, :2HCl—+Cr,0,C1, *+H,0 (Vapour) CrO.4, +ANAOH — Na Cr, 2NUCL- 1.0 ‘Sat iusto Satin sor, PHCH COO), PHCHO, ¥CH,COONa (Leal Cont) ‘Chemical Reaetion for Basie Radical Preliminary Test: NH,Cl-+NaOH —>NaCl+ H,0+ NH, Confirmative Test: Nesser's Test: High, + NH, —>NH, Hgl + HI 2NHLHIgL + yO —>NH, +NIL He \ ° Hg 1 (lade of millon base) NaOH Test : NCI NaOH —> NaCl + H,0 + NH(g) (CHeMstRY PRACTICALS) Page No#NH, +HeI —> NHC. (Dense white fumes) Result: The given inorganic salt contains ‘Acidic Radical Cl Basic Radical NH EXPERIMENT -5 [Aim : To analyze the given inorganic sa for acidic and basi radical. PO(NO)s Preliminary Investigation Physical state Solid Colour CCreamish white (Cu, Co"’.Ni*Fe* Ma’ Fe absent) Odour No characteristic odour (NH; ,S* CH,COO absent) Solubility Soluble in water Flame Test Dall Bish white Name is obtained (Pb may be) (A) Identification of Acidic Radical a Prlindnary Experiment ‘Ohsersation Talerenes T Salt soliton Fa F;SO, sotaion — No gas is evolied | Group A (co? ,cH,C00 NOs S0?.S* absent) I Sais Cone" WSO, + Heat Trown Coloured gas | Group B (NOy may be presen) (NO is evolved ©) Conftemative ts Experiment ‘Observation Titers T Biphenyl amine et Deep be coloured | NO = confined sall Cone" HSO, -diphenyt amine | solution [Ring Test Brown rng formed ot | NOj -confnned Salts Freshly prepared FeSO, +Conc* | the junction of two gus H,SO, along the deo the est tube Identification of Base Radical a: Prliminary tes Expernent ‘Ohesrvaion Tite 1 [Satsoiaion-- NOH. ‘No Swell of ammonia | ero group [NH |absont 2] Salt Solution + cil HCT White ppt of PbCI, is | Tgrup [Pb may be) ter the above ppt and boil t with water | formed and divide int pats, |dentfication of Basie Radical a- Confirmative test: Experiment ‘Observation Taference T [kt test: 1 pat KE Pb (Yellow Ppt) Ph? Confirmed 2 | KsCi0, Test 2 par KO, Yellow ppc of PbCOyis | Pb™ Confirmed formed “Gheemical reaction for Acidic Radical Preliminary Test: Pb (NO;), + H;SO, —> PbS0, + 2HNO, Cu + HNO, — CulNOY: +2NO; + HL Confirmative Test: ‘Ring Test Pb (NOD, + H3S0, —> PHSO, + 2HNO, (F804 + 31 HNO) —> 3Fes (SOs + 48:0 +2NO (CHEMISTRY PRACTICALS) Page NosFeSO, NO —> FeS0,.NO (Nitroso ferrous sulphate) fi) Diphenyt amine ‘Test Cys NH + [0] —> (Cells) N=N (Cyl) + HO (Diphenyl amine hydeazine) (B) Identification of Basic Radial Proliminary Test: Pb (NO,), +2HCL —> Pcl; 4 + 2HNO, White) Confirmative Test D)KITest: PHCL +2KI —> Phls 4 + 2KCI i) K,C1Oy Test: PHC + K:Cr0, —> POCO, $+ 2KCI (Yellow ppt) Result: The given inorganic salt contains Acidic Radical NO Basic Radical Pb"? EXPERIMENT 6 ‘Aim : To analyze the given inorganic sal for acidic and basic radical, |CuSO,) Proliminary Investigation Physical state Solid Colour Blue (Cu*may be) dour + Nocharacteristic odour (absence of NHS ,CH;COO) Solubility + Soluble in water. Flame Test + Bluish green flame (Cu may be) (A) Edentifieation of Acidic Radical - Preliminary test: Observation Tnference Taper Tarren a 8380, satan | Ro pas evaed | pk (CoF 45.50" NO; CH,COO absent) 2 | Sars Cone" H.80,+ Heat | Nov evolved Group B anions (C1 Br \NO;.C,0% areabsent) (0) Contrmative test: Experiment Ohsersaton Taference 1] Biter: Sat Soliton = BaCl Sofaion | Wie Pp formed ‘SOF confined ‘Aa i HCL dil HNO, Ppt remains insoluble TY tend Rosine Tes = ‘White pt. Formed 30,7 confirmed Sal Soltion + Teal acetate solution ‘Ail amon acca Sclatow (CHCOONN,) | Ppt becomes soluble can pt entificaton of basi Radical a Proiinary test: Observation Taference T Salt salution + NaOH + heat Novell of ammoni [Zero Group, (NH; absen’) 2 | Sastoion rai, CT No white Pe Group, absent) J Above solaion + HS gx ‘Back pts formed Group, (CuP"7 POF way Be sesent) | Dissolve shove prin NO, Sotto as His 5 [Dive ie above soon in pan () Confirmative test : (CHEMISTRY PRACTICALS) Page NosExparimeat ‘Observation Taferense T_[NHOHtest: 1" part | Deep bule colour [Ga confirmed NH. OH. | Poussium Torosynide ext | Chocolate brown — [Cu confined Hind part + K,[Fe(CN)] | ppt of Copper ferocyanide is formes! Acidic Radical 1- BaCl;Test: CuSO, + BaCl, > Bas, ++ CuCl ‘White Pp 2-(CH,COO), Pb Test CuSO, + (CH,COO); Pb > PSO, 4 +2(CH,COO}, Cu (White Ppt) ps0, 1 +2CH;COONH, > (CH)COO) Po + (NHL):SO, (b) Basie radical Cu" +HS 9 Cus + 2H" Black ppt 3CuS + SHINO, —+Cu(OH), +2NO+4H,0+35 1. NHOH test (Cu(NO,), + 4NH OH —aCu(NH),(NO,), +40 Deepblue ppt 2. KuFWCNotest 2Cu(NO,), +K,[Fe(CN),] + Cu, Fe(CN), 1+ 4KNO, ‘Result : The given inorganic salt contains. Acidic Radical ~ SO; Basic Radical Cu EXPERIMENT 7 Aim : To analyz the given inorganic sl for acc and hase radical ALSO.) Preliminary Investigation Physical state Solid Colour White (Cu, Fe Fe" Ni, Ma?*, Coase) dour No characteristic nour (aes of NH; ,S*, CHCOO™) Solubility Solubie in water. . . Fame Test No characterises flame (P)*, Sr, Cu", Ca, Ba"Ni°,Z"absent) (A) Mentiication of Acide Radical a Preliminary test: Experi aeration Taference 1) Sairotaion+ it Hs No gis is evolved] Group {co .s*,so7 no; cit,coo ) Absent J] Salt Cone" HS, + Hear No gw evohed ‘Group Banions (ch .Br NO, .C,0; absent) =] Baty ‘White ppris Tome | Group C anion (5O.” aay be) (b) Confirmative te (CHEMISTRY PRACTICALS) Page No7Experiment ‘Observation Tnference T | Batis test Salt Solution + BaChy White Ppt SOP confirmed [Add dil HCL to above ppt pt remains insoluble 2 | Lead Acetate Test: Salt Solution +(CHsCOO), Pb. solution | White ppt. $03 coofirmed ‘Add CH COO NH to above ppt Ppt dissolves in 1B- dentification of Basie Radical (a) Preliminary test iment [Observation Taferanee T | Saltsolition + NAOH [No smell of NH] Zao heat Group, NH} absent) | Saltsolaion-rait- HOT [No Ppt ‘Group 1. PD" absent | Totheabove volution | No ppt pass HS g | Boil HS gus and add) | White gelatinous | Group (AT may be) NHCl+NHOH & | ppe divide the Solution in to pars, (b) Confirmative test: Experiment ‘Observation Tnference T [Take test T* part + dil + HCI 2 drops of — | Blue ppt floats over ‘AI vonfirmed ‘ue tismus + NH,OH. colourless solution 2 [Ammonium chloride Test Formation of white ‘AT confirmed Ind part + NHCI + Boil the solution gelatinous pp. ‘Acidic Radical 1. BaCl; test Al {S0,), + BaCh —»BaSo, 4 +2AIC1, White pe 2. (CHLCOO): Po test: Al,(S0,), +(CH,COO), Pp —» PbSO, 4 +AI(CH,COO),, White ppt PbS0, 4 42CH ,COONH, —XCH,COO), Pb-+(NH,), 50, Basie Radical Al,(SO,), + NH,OH —»ANOH), & H(NH,),80, AMOH), +3HCI AICI, +3H,0 AlCl, +3NH,OH —» Al(OH), 443N#1,C Wiite pe ‘The given inorganie salt contains. Acidic Radical ~ SO? Basle Radical AI" Resul EXPERIMENT - 8 (CHEMISTRY PRACTICALS) Page NOS.‘Aim : To analyze the given inorganic salt for acide and basic radical, ZnCl) Preliminary Investigation Physical state Solid Colour White (Cu, Fe" Fe" Ni", Ma", Co" are absent) dour [No characteristic above (S®, NIL}, CH,COO” absent Solubility Soluble in wate. Flaine Test, Green flashes (Za may be ) (A) Mentifiation of Acide Radical tPraliminay to aie oa hie 7] Satsang 80, Ties nonin [mA (Co ,s*.S0 No; c1,C00 aber) P| Salts Cone WSO, > Heat Colourless gas Raving Group B anions pungent smell which | (CT-may be ) tives white dense umes with lass rod dipped in NOH. (b) Contirmative test Experiment ‘Observation Thference ‘Giron shore test Salt + C0, (17 2)+ | Orangish ed or dks | CT Confirmed cone HS, + heat ‘orange vapour of chromyl chloride are evolved Pass the vapour in atest tube containing | Yellow solution of| [NaH solution NasCi0 jis obtained ‘Add CH,COOH + (CH.COO), Pbinto | Yellow pp of lead hove solution chromate is formed 2 AgNO, Test Salt Solution AgNO, White ppt. contre Dissolve ppt. in NHLOH. ppl becomes soluble, 1 Tenliication of Basie Racal (0) Preliminary test: Experiment ‘Observation [Inference TT Satt solution + OOH —[ No smell of NIB] Zeo Group, heat (wet; assent) | Saicsoiaion Fa HCT [No whe Per Group F(PO™ abseny J [Torte above sain —] Nope Grog, (Ga AR, pac HS pe a", PS absent) TP Bai above ‘opp Group iN iFe" reinve HS and ald Fe"AI" absent) NHUCI (9) + NELOH in ] White pps] Group Ta? my ovained bel HCl and divide ito 2 pats (©) Confiemative test = (cHensTRY PRACTICALS) Page NooExperiment Observation Taferenee T | KaRACN) Test: 1 part+ KAREN — | White ppc of zine Za conformed feroeyanide NaOH Test: 2" par + NaOH Bluish white pp Za confirmed ‘Chemical reaction for Acidic Radical Preliminary Test ZiCl, + H,80,—rZn80, + 3HC1 HCL NH,OH —+NH,CL+ 11,0 (White dense Fumes) Confirmative Test : 4) Chromyl chloride test: K,Cr,0, + H,80, > K,S0, +2Cr,0, + H,0 ZnCl, +H,80,— ZnSO, +2HCL C10, +2HCL °=-C10,C1, TH, (ved vapours of chrom! chloride) Cr0,C1, +4NaOH —+ Na,CrO, +2NaCL+ 1,0 Na,Cr0, + PCH COO), _,""—* PhCrO, +CH,COONa ii) Silver Nitrate Test ZnCl, +2AgNO, —>2AgCI 4 42n(NO,), ‘cory oer AgC1+2NH OH 91 Ag NH) }CL+ 2,0 [Diamine silver (1) chloride ) (Soluble complex} ‘Chemical reaction for Basie Radical (a) Preliminary Test : ZnCl, +S ZnS \s2HCL ZnS +2HCl ZnCl, + HS 7 (0) Confirmative Test 1 K,lFe(CN)\Test: ZnCl, + K,UFACN),) +Zn,{Fe(CN),) Ws4KCH 2 NaOH test ZnCl, + NoOH —»Zi(OH1), + 2NaCt Zn(OH),+2N@OH — —+Na,Zn0, +2H,0 Result: The given inorganic salt contains, Acidic Radical C Basic Radical Za EXPERIMENT - 9 ‘Aimn: To analyze the given inorganic salt or acidic and basic radical (Bal Preliminary Investigation Physical state Solid Colour White (Cu, Fe", Fe"™\NI®, Mn'*, CO are absent) Qdour No characteristic dour (NH;,CH,COO',S* absent Solubility + Soluble in water Physical Test Solid (CHEMISTRY PRACTICALS) Page No 10(A) tdenteation of Acide Radel Preliminary test: Eperiaet Oberon Terence 1 Saltsolition Fa FSO, No gus evoked] Group A (co? ,s*,s0} NO, CH,COO™ absem) 2 [Sas Cone FESO, + Hew Redish orange | Group B anion ‘vapours which ums | r-may bo) starch paper yellow © Confirmatve test Experiment Observation Inference 1] AgNO; Tests Sal Soliton -AgNO, ali pp BF confirmed Dissolve ppt. in NHOH Ppt. remains partially soluble 2 [wn0; Tear Orange ra vapour of i] BF confirmed Salt Soluion + MnO, + Cone, H:SO4s Heat 'B- Identification of Basie Radical (4) Preliminary test Experiment Observation Taference T | Salt slution-+ NaOH + heat ‘No smell of NH Zero Group, (WAT, absent) | Saltsohaion rai CT No white Ppr ‘Group T(PH™ absent 3 [Torthe above sofuion pass TES gas Nope Group WLC AS CI PO absent) | Boil above solution wo remove HS and ald | No pp ‘Group HITFE™, Fe™AT™ absent NH,CH(s) + NHOH in exess. i 3 Po above test tube pass HS gas No ppt Group Va CO™ NT Ma’ absent] © | Remove HS gas by boiling White pot ‘V group (Ca, Ba SP” may BO) Add [NHy}, COvt0 it (b) Contirmative test: ‘Experiment Observation | Taference T | Poxassium chromate test: | Yellow ppt Ba confitmed * part + KCrO, Z| Ammonia sulphate Test [No ppt ‘SF absent find part + (NH):S0, 3 [ Ammonium oxalate Test | No ppt Ca abent 1a part + ammo ‘oxalate test (NH,),C.0, | Flame test: Perform flame | Apple green flame | Ba” confirmed test with at ‘Chemical reaction for Acidie Radical Preliminary Test: BaBr, + H,SO,—>BaSO, + 2HBr H.S0,+2HBr—>SO, + Br, [+2HCL Starch + Br, —> Yellow Colour Confirmative Test: (CHEMISTRY PRACTICALS) Page No 111 Siver Nirate test Babir,+ 2AgNO,—»Ba(NO,), +2Agti-L (Yellow poo, 1) MO, Test: Bulir, + MnO, + 21,50, —» BaSO, + MnSO, + 211,0+ Br, t ‘Chemical reaction for Basie Radical Preliminary Test Babr, +(NH,),CO, —>BaCO, + 2NH Br BaCO, +2CH COOH —X(CH COO), Ba+CO, 1 +H,0 (CH,CO0), Ba + K,Cr0, —»2CH COOK + BaCrO, 4 1K.C0, Test (Yetlow ppt Result : The given inorganic salt contains, Acidic Radical Br Basic Radical Bu Confirmative Test: EXPERIMENT - 10 ‘Aim: To analyze the given inorgane salt for acidic and basic radical, (NHL).C.0, Preliminary Investigation Physical state Solid sniaiees Colour White (Ca, Fe", Fe" Ni", Mn’, Cote absent) ‘Qdour No characteristic adour (NH; .S* CH COO absent ) Solubility Soluble in water. Flame Test No characteristic lame (Ca"*,$r*,Ba'*,Pb',Cu'®, Zn absent ) (A) Identification of Acidic Radial tralia tet cet [Gene eae ate eee foo salsa. Jove” | (eg s* sof Noy cHt,c00" absent 7 ir cae Cote, Crop MBO? [otoatn’ | (Or may be he (Seamer | (Gt mente) me any i meat ‘arnoe four iscam (0 Contemative test: Epeieet Onsen ro T— caso Cote Fe Wane pect ecm —| (CSOF Jcontenes Sal Soaion 1 Ca eulas famed Z| KMn0, Test Pink colour of KMa.s_| (C,0}") Confirmed bow pt i HSOv Heat Ginchrged wih ction ‘Abts aluon of KM, cose B- Identification of Basie Radical (a) Preliminary test: (CHEMISTRY PRACTICALS) Page No12,Experiment Observation | Taferenee T | Sattsolaion + NaOH> — Swell of NH} Zero Group, eat (Wt; present) Pace red fms poperon | Re isms ems mouth to test be tue (©) Confirmative tt Experiment ‘Observation Taferense T | Toabove solaon, bring on glass od dipped | White dense of NHCTare | (WH: ) confirmed incon, HCL near mouth of tet ube formed ZT] Nessler’s Test » Solution + NaOH + Rest Brown pots | (VE) confinned Nessle's reagent formed ‘Chemical reaction for Acidie Radical Preliminary Test (NH, ),C0,+H,$0, H,C,0, +(NH, ):S0, HCO, C0, 1s60+H,0 Confirmative Test 4 CaCl, test (WH,),C,0, + CaCl, —>CaC,0, 4 42NH C1 Calou oxalate (White 0 CaCO, + H-S0, —rH,C.0, + CaSO, 2KMnO, + 3,50, —>2MnSO, + H,S0, +3H,0 +510} i) KMn0, Test C0, 10} 29200, + 11,0 Basie Radical 4) Preliminary test (WH) ,C.0,+ 2NaOH —> NCO, +2NH, 143 NH, T Red limus —> Blue liomus Confirmative Test: Nessler's Test K,Hely —2K1 Hel, Hil + NH —>NH: Hel + Bl 2NHLHgL + HO —>NH +N He \ ° He \ 3 (odide of millon base) [NaOH Test : NH,CI+ NaOH —> NaCl + H.0 + NH4(g) NEi, + HC! —> NH.CI (Dense white fares) Result: The given inorganic salt contains. ‘Acidic Radical ~ C,0,° Basic Radical (WH/;) EXPERIMENT 11 ‘Aim : To analyze the given inorganic sat for acidic and basic radical, Preliminary Investigation (CHEMISTRY PRACTICALS) Page No13Physical state Colour Qdour (absence of CH;COO , NH; S* ) Solubility Soluble in water lame Test [absence of Cu", Pb", Zn".Cu".Be) [Hdentification of Acidic Radical + Preliminary test: Experiment [ Observation [ Inference T | Saltsolution [No gasis [Group A HCL evolved (Co; ,S*.80} NO; CH,COO abser [Salt Cone | Colourless | Group B anvons H.S0.+Heat | pungent | CI-may be present selling gas que is volved which gives ‘white dense fumes of NHC (b) Confirmative test Experiment ‘Observation Tnference T | AaNO, Test ‘Caray white pp Ch confirmed Salt Solution + AgNO, Dissolve pp. in NOH, Pp become soluble Chron chloride txt: Salt KixCO%8) | Reddish orange vapours (1:2) + eone. H.SO, + heat of ehromyl chloride are evolved CF confirmed ass the vapourina este containing | Solution becomes Yellow NH.OH, ‘Ada (CH,COOH + PH(CH,COO), ‘Yellow ppt of lead chromates formed Be Haentification of Basie Radical Preliminary test Experiment ‘Observation Tnference T | Sal solution + NGOH sear ‘No smell of NE Zexo Group, (NH absent) Z| Salt sohaion > CT No white Pa Group 1 Pb absent 3} Pass FS gas though above NCI ‘No ppt. Group Tl, (Cu As? Cu”, Ph") absent | Remove TES aux by Boling © ad NIGCT OY [ No po “Group it [Re Fe",AP™ absent + NH,OH in excess 1 3 [Pass HS gas through above solution Black ppt ‘Group 1VINi™ or Co" May be Dissolve the pot by boiling with agua regia present) [Cone HCI+Cone. HNO}] evaporate to dryness & add water & divide in 2 parts ©) Confirmative test: Experiment ‘Observation Tference T [DG test: past = DMG | Rose pink ppt. | Ni-conformed 2 [ NaOH Test 2" part + NOW| Apple green ppi | Nix confirmed ‘Chremieal reaction Tor Acidie Radical Profiminary Test: (CHEMISTRY PRACTICALS) Page NodNiCl, + H,SO, + heat —>NiSO, + 2HCLT NH,OH + HCl—+NH,Cl+ H,0 (White dense fumes) Confirmative Test : i) AgNOs test NiCl, + 2AgNO, —+2AgCl 4 +Ni(NO,), Curdy white ppt AgCl + 2NH ,OH —>[Ag (NH); |Cl+H,O. (Diammine Silver (I) Chloride) 2) Chromyl chloride test (i) 4NiCI, +K,Cr,0, +7H SO, 9 2KHSO, + 2CrO,Cl, +3H 0+ 2NiHSO, Cr,0,C1, + 4NaOH > Na,CrO, +2NaCl+ HO (Sodium Chromate) Pb(CH,COO), + Na,CrO, —> PhCrO, +2CH,COONa Yellow Ppt Identification of Basic Radical Preliminary Test : NiCl, + H,S—»NiS 1+2HCI (black ppt.) 3NiS + 2HNO, + 6HCI—3NiCl, + 2NO+3S +H,O Confirmative Test : i) DMG test CH, - C = N - OH I + NiCI, +2NH OH —+2NH Cl+H,0+ DMG NiComplex CH, - C = N - OH (i) NaOH Test : NiCl, +2NaOH —> Ni(OH), +2NaCl Result : The given inorganic salt contains Acidie Radical C1 Basic Radical Ni?