E L E ME N T SF O N D A M E N T A UDXEC H I M I E 2 O O 5- 2 0 0 6 2,3, Mo,sse de HCLproduibe : o.qzo.

looo Rg = utZo flg

Equo.lion dquiLi bree. :

EXERCICES S E R I EL 2 No,CL + HzSoH -> NqzSOq + ZHCI

Mn2se.1 = qB. t g' rnoft ) M HcL = 36.Lrb g' rnoL-l

2-,4 \N Fe,S2 t x Oz * qFe2O3 r z SOz
2 rnoLe.s HeL (12.q2g) r'deessitent .l rnote H2Sol (C8.t g)

. q 8 . tg
bilcundeso.bornes de Fe. : \N = 2q (l) Donc t{xo %g nCt nd,c.essitenL tlloooo g_ .
+2.qzg
bilan des q.bomes de, S .. L = 2 rnr tZ) : 565 {Lg H2Soq, soib s6s lo.qz 6La,Eegdesot-rhion.
bilondes obome-s d)O : 2x = 3r/ * 2z (3)

Po,r subsbibution de, Lt) dons (z) r puisde. (z) do.ns (3) : 2,q. Mosse du $ilrn = voLurne du Filn x rna.s^sevolurnique dv Film
= S*rrfo.ce. x dpo,iSse.\-rt- x rnqsse votvmiqve.
w=Zut t Z= HrlI Lx= aa.{ .{ rn X
: 2rn. 3oo' 6. to-torrl . .l6lb g.--3
Les pLus pebibs coeFFicienbs sfoectrromeLrique.s sonb
: o.36 I
obbenuspour g = 2 => \A/ = H r Z = B, x = -{,1
Lo. ForrnuLe-,-1i.,itds tcH3\ z SiO doib !bre ubiLisde ici au
tt Fe.S2 + 44 Oz --> Z Fe."o3 r B So"
L\eu de Lq, fotmuLe, rnoLdc.rLqire E (Cu3) 2 SiO ] n .

2-,2. w C7H6a2+ xOz*rlCOz+zHzO Mt"rr3tzsio = ?e g'rno\it , Mtc*"l2SicL2 : t29 g'r''oL-l

bilc"ndesabornesdeCl q:7w 0) L equo.tion rndique. eue ,l rnoLe, (tzq q) de. (crr3)z SiCLz
bilo.n des abornes d' H '. lz = 6 w [z) d o n n e ' ' t m o L e - - u n ' ' b e i s( C r f 3 ) . S i O ( f U g ) . D o n . o , 3 6 g
bilan des abornes d' O : Zw + 2x = 2q r Z (3) de (cna\. sio ndc.e.ssite,

RrrsubSbibubion de, (r) do.ns (Z))puris do.ns [g) : 0.3c,g. = o163g (cn3)zsrcLz
# -

q=?wr.:3Wr 2w+2x= 17w =) 2x = 15w

2"5' hKcLo : ^cL"
Le.s plus pebibs coefFicienbs
stoechiorndbnqure-s tls nKcro = tl3ngr.
hncro3=
enbrers sont.obbenuspo\^r w =2 =7 X=.15t V =41t2=6

2 Cf H6Oz + 'lS or {t{ COs r 6 H2O t'\Kc{,o.} = 3/.r nxcLo3 = 3/+ (t/g nct ) = tl,{ ngLa

h ReLo,,r= 1993-.- = o.?2o rnoL

^3o{f;;L=T
ri g L z: \ h neLO q = Ll. O , ?2O = A , 88 m oL

t=
lvtcr-Sse de CL2 = 2.88 moL . Tl g.r1of zot{ 3 CtZ