Dimethyl Ether Production

Material balance
Dimethyl Ether Carbon
monoxide Hydrogen gas Material
Balance Energy Balance Reactor,
Separator, Mixer, Heater
 Propose

nonreactive reactive
- Heat of Reaction Heat of
Formation Reactive
Heat of Reaction Method
 % Conversion of
% Conversion of = 82.35%

Reactor

P= .
T = 259.85 oC
P=

T = 259.85 oC
Substances State

g 57180
l - - - -
g 97560
l - - - -
g 204000
l - - - -
g - - 113815.94
l - - - -
g - - 48788.13
l - - - -
g 12000 125816.94
l - - - -
:

=0+

=0+

=
:

=0+

=
6.79385

=0+

=
6.79385
:

=0+

=
6.91437 kJ/mol

=0+

=
6.91437 kJ/mol
:

=0+

=
8.12854 kJ/mol

=0+

=
12.74025 kJ/mol
:

=0+

=
57.55821 kJ/mol

=0+

=
57.55821
Substances State ( ) ( )
(kJ/h) (kJ/h)
g 2320047.888 57180 397662.8844
l
g 4418720.04 97560 662808.006
l
g 1410531.48 204000 1410531.48
l
g 113815.94 925157.4209
l
g 48788.13 621572.9732
l
g 12000 690698.52 125816.94 7241797.854
l
8839997.928 11259530.62
From Equation:
1.
2.
2 3.
2
From Equation: = ( )

=
Heat of Formation Method
 % Conversion of
% Conversion of = 82.35%

Reactor

P= .
T = 259.85 oC
P=

T = 259.85 oC
Substances State

g 57180
l - - - -
g 97560
l - - - -
g 204000
l - - - -
g - - 113815.94
l - - - -
g - - 48788.13
l - - - -
g 12000 125816.94
l - - - -
:

= + 0+

= +0+

=
:

= 0+

=
0+6.79385) 6.79385

= +0+

=
0+6.79385) 6.79385
:

= 0+

=
(0 + 6.91437) kJ/mol 6.91437 kJ/mol

=0+

=
:

= 0+

=
(-241.83 + 8.12854) kJ/mol -233.70146 kJ/mol

= 0+

=
(-201.2+12.74025) kJ/mol = -188.45975 kJ/mol
:

= +0+

=
57.55821) kJ/mol kJ/mol

= +0+

=
Substances State ( ) ( )
(kJ/h) (kJ/h)
g -34549424.11 57180 -5921870.716
l
g 4418720.04 97560 662808.006
l
g 1410531.48 204000 1410531.48
l
g 113815.94 -26598951.35
l
g 48788.13 -9194598.783
l
g 12000 -1517541.48 125816.94 -15911035.44
l
-30237714.07 -55553116.8
From Equation: =

=
 P= .
T = 59.85 oC

P=
T = 259.85 oC

Separator
87% recovery
P= .
) T = 59.85 oC

)
Substances State
g 57180 57180
l
g 97560 97560
l
g 204000 204000
l
g 113815.94
l 113815.94
g 48788.13
l 48788.13
g 125816.94 16356.2
l 109460.74
:

= 0+
=

= 0+
=
:

=0+
=

6.79385 kJ/mol

=0+
=

1.00540 kJ/mol
:

=0+
=

6.91437 kJ/mol

=0+
=

1.01427 kJ/mol
:

=0+
=

kJ/mol

= +

=
=

(49.3462-1)atm.( )( )
:

=0+

=
12.74025 kJ/mol

= +

=
=

(1.85050-35.27-0.41875)kJ/mol (49.3462-1)atm.( )( )

(-33.83825+0.12430)kJ/mol
-33.71395 kJ/mol
:

= 0+

= 0+

=
:

= +

(-10.79191-18.5+15.59969)kJ/mol (49.3462-1)atm.( )( )

(-13.69222+0.16586)kJ/mol
-13.52636 kJ/mol
Substances State ( ) (kJ/h) ( ) (kJ/h)
g 57180 397662.8844 57180 58049.7078
l
g 97560 662808.006 97560 98086.824
l
g 204000 1410531.48 204000 206911.08
l
g 113815.94 925157.4209
l 113815.94 -4672255.877
g 48788.13 621572.9732
l 48788.13 -1644840.575
g 125816.94 7241797.854 16356.2 128301.4676
l 109460.74 -1480605.375
11259530.62 -10706663.43 -7306352.748
From Equation: =

=-1.8
Substances State

N1
N6 41946.34 - -
N1
N6 71567.98 - -
N1
N6 149602.37 - -
N1 - -
N6 - -
N1 - -
N6 - -
N1
N6 12000 12000
= = :
= 0 kJ/mol

= = :
= = = 0 kJ/mol

= = :
= = = 0 kJ/mol

= :
= = 0 kJ/mol
Substances State

N1

N6 41946.34 0 -

N1 0

N6 71567.98 - -

N1

N6 149602.37 - -

N1 - -

N6 - -

N1 - -

N6 - -

N1 - -

N6 12000 0 12000 0
From Equation: =

=-1.0706663.43
P= P= .
T = 59.85 oC T = 259.85 oC

Heater
Substances State

g
l - - - -
g
l - - - -
g
l - - - -
g - - - -
l - - - -
g - - - -
l - - - -
g 12000 12000
l - - - -
:

=
:

=
kJ/mol

=
kJ/mol
:

=
kJ/mol

=0+

=
6.91437 kJ/mol
:

=
kJ/mol

=0+

=
57.55821 kJ/mol
Substances State ( ) (kJ/h) ( )
(kJ/h)

g 338674.056 2320047.888

g 653912.16 4418720.04

g 206911.08 1410531.48

l
g
l
g
l

g 12000 94130.52 12000 690695.52

1200000 1293627.816 8839994.928

From
So Q = 8839994.928
Q = 7.54637 kJ/h