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Plastic & Wraps

Limit Potential Uses


Category of Chemical CAS Number Recommended Test Method
Component materials Processing for packaging material
Metals – Total
Cadmium compounds are used as pigments (especially in
Cadmium (Cd) 7440-43-9 red, orange, yellow and green) and in paints. It can also be
used as a stabilizer for PVC
Total heavy metals (Cd, Cr, Pb & Hg): EN ISO 16711-1
Lead (Pb) 7439-92-1 May be associated with plastics, paints, inks, pigments, and
surface coatings. If total of four heavy metals exceeds 100 ppm and Cr is
detected, test for CrVI.
Limit <100 ppm (Sum)
Mercury compounds can be present in pesticides and as
Mercury (Hg) 7439-97-6 contaminants in caustic soda (NaOH). They may also be used
in paints.
Though typically associated with leather tanning, Chromium Metal: IEC 62321-7-1:2015
Chromium Six [Cr(VI)] 18540-29-9 VI also may be used in pigments, chrome plating of metals, All other materials: IEC 62321-72:2015
and wood preservatives.

Alkylphenols (AP) and Alkylphenol Ethoxylates (APEO), including all isomers


104-40-5
APEOS are used as surfactants in the production of plastics,
11066-49-2
Nonylphenol (NP), mixed isomers elastomers, paper, and textiles. These chemicals can be
25154-52-3
found in many processes involving foaming, emulsification,
84852-15-3 Total: 100 ppm solubilization, or dispersion. APEOs can be used in paper
140-66-9 pulping, lubrication oils, and plastic polymer stabilization.
Octylphenol (OP), mixed isomers 1806-26-4 APs are used as intermediaries in the manufacture of
27193-28-8 APEOs and antioxidants used to protect or stabilize polymers. Textiles: EN ISO 21084:2019
9002-93-1 Biodegradation of APEOs into APs is the main source of APs
Octylphenol ethoxylates (OPEO) 9036-19-5 in the environment. APEOs and formulations containing All other materials: 1g sample/20 mL THF,
68987-90-6 APEOs are prohibited from use throughout supply chain sonication for 60 minutes at 70 degrees C, analysis
and manufacturing processes. We acknowledge that according to EN ISO 21084:2019
residual or trace concentrations of APEOs may still be found
9016-45-9 Total: 100 ppm at levels exceeding 100ppm and that more time is necessary
26027-38-3 for the supply chain to phase them out completely. This
Nonylphenol ethoxylates (NPEO) 37205-87-1 limit aligns with forthcoming EU legislation applicable to
68412-54-4 textiles and was set to provide suppliers direction for
127087-87-0
continuous improvement.

PVC - Polyvinyl Chloride


Beilstein Test to be used. If material is supposed to be
PVC (Polyvinyl Chloride) 9002-86-2 Usage ban PVC-free, but Beilstein test is positive, the FT-IR Test
should be used as a confirmatory test

Butylated Hydroxytoluene (BHT)


Used as an additive in plastics as an antioxidant to prevent
Dibutylhydroxytoluene (BHT) 128-37-0 Limit < 5ppm ASTM D4275
aging. Can cause phenolic yellowing of textiles.

Organotin Compounds
Dibutyl Tin (DBT) 1002-53-5

Dioctyltin (DOT) Various Class of chemicals combining tin and organics such as
butyl and phenyl groups.
Monobutyl Tin (MBT) 78763-54-9
Organotins are predominantly found in the
Monooctyltin (MOT) environment as antifoulants in marine paints, but they
Limit < 1 ppm each
can also be used as biocides (e.g., antibacterials),
Tricyclohexyltin (TcyHT) 36580-86-6 All materials:
catalysts in plastic and glue production, and heat
CEN ISO/TS 16179:2012
Trimethyltin (TMT) 5089-96-3 stabilizers in plastics/rubber.

Trioctyltin (TOT) In textiles and apparel packaging, organotins are


associated with plastics / rubber, inks, paints, metallic
Tripropyltin (TPT) 761-44-4 glitter, polyurethane products and heat transfer
Tributyl Tin (TBT) 56573-85-4 material.
Limit < 0.5 ppm each
Triphenyl Tin (TPhT) 668-34-8

Phthalates
Di-iso-nonylphthalate (DINP) 28553-12-0
Di-n-octylphthalate (DNOP) 117-84-0
Esters of ortho-phthalic acid (Phthalates) are a class
Di-isooctyl phthalate (DIOP) 27554-26-3 of organic compound commonly added to plastics
to increase flexibility.
Di-(2-ethylhexyl)-phthalate (DEHP) 117-81-7

Di-isodecylphthalate (DIDP) 26761-40-0 They are sometimes used to facilitate the


moulding of plastic by decreasing its melting
Butylbenzylphthalate (BBP) 85-68-7
temperature.
Dibutylphthalate (DBP) 84-74-2
Phthalates can be found in:
Di-iso-butyl phthalate (DIBP) 84-69-5 Limit < 500 ppm each All materials:
Total 1000ppm • Flexible plastic packaging CPSC-CH-C1001-09.4, analysis by GC/MS
1,2-Benzenedicarboxylic acid, di-C6-8- branched
71888-89-6 • Components (e.g., PVC)
alkyl esters (DIHP), C7-rich
• Plastisol print pastes
Bis (2-methoxyethyl) phthalate 117-82-8 • Adhesives
• Plastic sleeves
Di-cyclohexyl phthalate (DCHP) 84-61-7 • Polymeric coatings
Diethyl phthalate (DEP) 84-66-2
Find more information about additional Phthalates on the
Di-isooctyl phthalate (DIOP) 27554-26-3
REACH substances of very high concern (SVHCs) candidate
Di-n-hexyl phthalate (DnHP, DHP) 84-75-3 list, which is updated frequently.
Di-n-propyl phthalate (DPRP) 131-16-8
Di isopentyl phthalate (DIPP) 605-50-5
Dimethyl phthalate (DMP) 131-11-3
Dimethyl phthalate (DMP) 131-11-3

Coats RSL- Packaging 2021


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Phthalates continued
1,2-Benzenedicarboxylic acid, di-C7-
11- branched and linear alkyl 68515-42-4 Esters of ortho-phthalic acid (Phthalates) are a class of
esters (DHNUP) organic compound commonly added to plastics to increase
flexibility.
1,2-Benzenedicarboxylic acid
84777-06-0 They are sometimes used to facilitate the
Dipentyl ester, branched and linear
moulding of plastic by decreasing its melting temperature.
1,2-Benzenedicarboxylic acid, di-C6- Phthalates can be found in:
10-alkyl esters or mixed decyl and
68648-93-1 Limit < 500 ppm each • Flexible plastic packaging All materials:
hexyl and octyl diesters with ≥ 0.3%
of dihexyl phthalate Total 1000ppm • Components (e.g., PVC) CPSC-CH-C1001-09.4, analysis by GC/MS
• Plastisol print pastes
• Adhesives
1,2-Benzenedicarboxylic acid, mixed • Plastic sleeves
68515-51-5 • Polymeric coatings
decyl and hexyl and octyl diesters

Find more information about additional Phthalates on the


1,2-Benzenedicarboxylic acid, di-C6- REACH substances of very high concern (SVHCs) candidate
10-alkyl esters, and n-pentyl- 776297-69-9 list, which is updated frequently.
isopentylphthalate (nPIPP)

Bisphenols
Bisphenol-A (BPA) 80-05-7 Limit < 1 ppm

Bisphenol-S (BPS) 80-09-1 No limit set. BPA alternatives with known or suspected similar hazards
For informational purposes only. are used in the production of epoxy resins,
Bisphenol-F (BPF) 620-92-8 Please state if substance is used or polycarbonate plastics, flame retardants, and PVC.
is present in the material/product
Bisphenol-AF (BPAF) 1478-61-1 supplied.

Coats RSL- Packaging 2021


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