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Two source interference
Double-slit interference
Coherence
Intensity in double slit interference
Interference from thin film
Michelson’s Interferometer
Text Book:
PHYSICS VOL 2 by Halliday, Resnick and Krane (5th Edition)
TWO-SOURCE INTERFERENCE
Maximal constructive
interference of two
waves occurs when their
phase difference is 0, 2,
4 , … (the waves are in-
phase)
sin
y
sin tan
D
• Path difference:
y d
d sin S1b
D
DOUBLE-SLIT INTERFERENCE
y y m1 y m
D D
(m 1) m
d d
D
y
d
The spacing between the adjacent
minima is same the spacing between
adjacent maxima.
DOUBLE-SLIT INTERFERENCE
YOUNG’S DOUBLE SLIT EXPERIMENT
Problem: E 41-2
Problem: E 41-5
Problem: E 41-8
In an interference experiment in a large ripple tank
(see Fig 41-2) the coherent vibrating sources are
placed 120 mm apart. The distance between
maxima 2.0 m away is 180 mm. If the speed of the
ripples is 25 cm/s, calculate the frequency of the
vibrating sources.
DOUBLE-SLIT INTERFERENCE
Problem: E 41-11
For interference
pattern to occur, the
phase difference at
point on the screen
must not change with A WAVE TRAIN
time. OF FINITE LENGTH L
A WAVE TRAIN
OF FINITE LENGTH L
Resultant field E = E1 + E2
INTENSITY IN DOUBLE SLIT INTERFERENCE
Resultant of E1= E0 sin ωt & E2= E0 sin (ωt + )
= E sin(t + ) E2
E
= 2E0 cos sin(t + )
But = /2. So above eqn can be E
E0
written as, E1
ωt
E = 2 E0 cos(/2) sin(wt+/2)
INTENSITY IN DOUBLE SLIT INTERFERENCE
E = 2 E0 cos(/2) sin(wt+/2)
I 4 E cos
2
0
2
2
4 0 cos 2
2
where E2 is intensity due to single source
0 0
INTENSITY IN DOUBLE SLIT INTERFERENCE
2
where E 2 is intensity due to single source
0 0
Since 2dsin/ ,
2 d sin
4 0 cos
From above equation,
At maxima : 2 m or d sin m
At minima : ( 2 m 1) or d sin (m 1 )
2
where m 0, 1, 2, . . .
INTENSITY IN DOUBLE SLIT INTERFERENCE
INTENSITY IN DOUBLE SLIT INTERFERENCE
Problem: SP 41-2
Problem: E 41-15
• Hence, ct = nd
• nd Optical path.
Constructive interference:
2 d + (½) n = m n m = 1, 2, 3, . . . (maxima)
Destructive interference:
2 d + (½) n = (m+½) n m = 0, 1, 2, . . . (minima)
INTERFERENCE FROM THIN FILMS
WEDGE SHAPED FILM
Problem: SP 41-3
Problem: SP 41-4
Problem: E 41-23
A disabled tanker leaks kerosene (n=1.20) into the Persian
Gulf, creating a large slick on top of water (n = 1.33).
(a)If you look straight down from aeroplane on to the region
of slick where thickness is 460nm, for which wavelengths
of visible light is the reflection is greatest?
(b)If you are scuba diving directly under this region of slick,
for which wavelengths of visible light is the transmitted
intensity is strongest?
INTERFERENCE FROM THIN FILMS
Problem: E 41-25
d R R2 r 2
1
r
2 2
R R 1
R
Newton’s rings
Substituting d in
2d = (m - ½)
we get
r m 21 R
m 1, 2, . . . (maxima)
INTERFERENCE FROM THIN FILMS
Problem: E41-33
Problem: SP 41-6
⁕The finite width of slits is the basis for understanding Fraunhofer diffraction.
⁕According to Huygens’s principle, each portion of the slit acts as a source of light waves.
⁕Therefore, light from one portion of the slit can interfere with light from another portion.
⁕The diffraction pattern is actually an interference pattern.
⁕The different sources of light are different portions of the single slit.
SINGLE-SLIT DIFFRACTION
At point P1,
path difference between r1
and r2 is
(a/2) sin
2
x sin
INTENSITY IN SINGLE – SLIT DIFFRACTION
Phasor showing
a) Central maximum
b) A direction slightly shifted
from central maximum
c) First minimum
d) First maximum beyond the
central maximum
(corresponds to N = 18)
INTENSITY IN SINGLE – SLIT DIFFRACTION
From diagram,
E 2 R sin
2
Em
Also
R
Combining,
Em
E sin
2
2
sin
Or , E Em
where
2
INTENSITY IN SINGLE – SLIT DIFFRACTION
From the above eqn., for minima, sin 0
m where m 1,2,3,.....
or, a sin m where m 1,2,3,.....
INTENSITY IN SINGLE – SLIT DIFFRACTION
Problem: SP42-3
Problem: SP42-4
Problem: E42-11
a. Not resolved
b. Just resolved
c. Well resolved
DIFFRACTION AT A CIRCULAR APERTURE
Problem: SP42-5
Interference
Diffraction
sin α
2
I , DIF m, DIF α
Interference + Diffraction
2
sin α
I m cos 2
α
DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED
Adding all the phasors, we get the resultant E1 due to the first slit.
is the phase difference between the light waves at the point P,
emitted from bottom edge of the first slit and top edge of the
second slit. E2 is the resultant due to the second slit. E is the
resultant of E1 and E2.
DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED
From the figure,
E 2E1 sin
2
where
2 2
or ( )
Also sin sin cos .........( A )
2 2 2 2
and (d a) sin
2
a
Adding sin to both sides of above eqn, we get,
2
d sin which is
2
DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED
Substituting this in eqn( A ), we get,
sin cos
2
From sin gle slit diffraction, we have ,
the electric amplitude at P due to one slit,
sin
E1 Em
sin
E 2E1 sin ie, E (2Em ) cos
2
2
sin
m (cos)2
DOUBLE-SLIT
SINGLE-SLIT DIFFRACTION
INTERFERENCE PATTERN
PATTERN
DOUBLE-SLIT INTERFERENCE AND DIFFRACTION COMBINED
Problem: SP42- 6
Problem: SP42- 7
2
where N is the number of slits
N
Corresponding path difference is,
L
2 N
MULTIPLE SLITS
L
2 N
Also we know,
L d sin 0
From the equation, for given and
d sin 0
N d if we increase number of slits (N),
then the angular width of principal
sin 0
Nd maximum decreases. ie the
principal maximum becomes
0 sharper.
Nd
MULTIPLE SLITS
Width of the maxima: Other principal maxima
λ
d sinθ θ mλ
N
MINIMUM AT θ
+θ
mth PRINCIPAL
MAXIMUM AT θ
MULTIPLE SLITS
Width of the maxima: Other principal maxima
λ
d sinθ θ mλ
N
d sin cos
cos sin
m
1 N
d d cos
sin m N
m d cos m N
ANGULAR HALF WIDTH OF mTH
N d cos PRINCIPAL MAXIMUM AT
mth PRINCIPAL
MAXIMUM AT θ
MULTIPLE SLITS
Problem: SP43- 1
Problem: E43-5
Grating spectrometer
Problem: SP43-2
Problem: E43-9
Problem: E43-11
Δθ m
D
Δλ d cos θ
To achieve higher dispersion we must use a grating of smaller
grating spacing and work in higher order m .
DISPERSION AND RESOLVING POWER
Resolving power
Ability of the grating to resolve two nearby spectral lines so that
the two Lines can be viewed or photographed as separate lines.
To resolve lines whose wavelengths are close together, the lines
should be as narrow as possible.
For two close spectral lines of wavelength 1 and 2, just
resolved by the grating, the resolving power is defined as
1 2
R 1 2
2
DISPERSION AND RESOLVING POWER
Resolving power
We have,
Δθ m
D
Δλ d cos θ N d cos
Putting second equation in first equation,
N d cos
m
d cos
R Nm
Resolving power increases with increasing N
DISPERSION AND RESOLVING POWER Intensity patterns of two close
lines due to three gratings A, B, C.
Resolving power
N = 5,000
d = 10 m
R = 5,000
D = 1.0 x 10-4 rad/m
N = 5,000
d = 5 m
R = 5,000
D = 2.0 x 10-4 rad/m
N = 10,000
d = 10 m
R = 10,000
D = 1.0 x 10-4 rad/m
DISPERSION AND RESOLVING POWER
Problem: SP43-3
x-ray diffraction
producing Laue’s
pattern
X-ray tube
X-RAY DIFFRACTION
When a monoenergetic x-ray beam is
incident on a sample of a single crystal,
diffraction occurs resulting in a pattern
consisting of an array of symmetrically
arranged diffraction spots, called Laue’s
spots.
The single crystal acts like a grating
with a grating constant comparable
with the wavelength of x-rays, making A Laue pattern of a
the diffraction pattern distinctly visible. single crystal.
Since the diffraction pattern is decided Each dot
by the crystal structure, the study of represents a
the diffraction pattern helps in the point of
analysis of the crystal parameters. constructive
interference.
X-RAY DIFFRACTION
Problem: SP43-5
Problem: E43-25
TOPICS
▪ POLARIZATION OF ELECTROMAGNETIC WAVES
▪ POLARIZING SHEETS
z
▪ POLARIZATION BY REFLECTION
▪ DOUBLE REFRACTION
Text Book:
PHYSICS VOL 2 by Halliday, Resnick and Krane (5th Edition)
POLARIZATION
➢ Interference/Diffraction: gives an idea about the wave nature of the
wave but do not give the idea about the nature of the wave (i.e. the light
wave is longitudinal/transverse or they are vibrating linearly/circularly
etc.)
z
POLARIZATION OF ELECTROMAGNETIC WAVES
➢ Plane of Polarization:
➢ Plane of vibration:
POLARIZING SHEETS
➢ POLARIZATION by transmission
➢ The sheet transmit only those wave train components having electric field vector
vibrating parallel to this direction and absorb if vibrates perpendicular.
➢ P2 rotated about the direction of propagation then there are two different positions,
1800 apart, where transmitted light intensity falls to zero.
➢ At these positions the polarizing directions of P1 and P2 are at right angles to each
other.
POLARIZING SHEETS
Transmitted intensity:-
I = Im cos2 [Law of Malus]
2. A beam of light is linearly polarized in the vertical direction. The beam falls at normal
incidence on a polarizing sheet with its polarizing direction at 58.8 to the vertical. The
transmitted beam falls, also at normal incidence, on a second polarizing sheet with its
polarizing direction horizontal. The intensity of the original beam is 43.3 W/m2. Find
the intensity of the beam transmitted by the second sheet.
3. The magnetic field equations for an em wave in space are Bx = B sin (ky + t), By =
Bz = 0.
(a) What is the direction of propagation?
(b) Write the electric field equations.
(c) Is the wave polarized? If so, in what direction?
POLARIZATION BY REFLECTION
➢ If light is incident on the surface of a
dielectric material at polarizing angle
of incidence, (p= Brewster’s angle)
the reflected light is completely plane
polarized and the transmitted ray is
perpendicular to reflected ray.
POLARIZATION BY REFLECTION
n = tan p
➢ This expression is called Brewster’s law,
and the polarizing angle p is sometimes
called Brewster’s angle.
Problem: SP44-2
Problem: E44-12
When red light in vacuum is incident at the polarizing angle on a certain glass
slab, the angle of refraction is 31.8. What are (a) the index of refraction of the
glass and (b) the polarizing angle?
DOUBLE REFRACTION
• In optically isotropic substances (liquids, amorphous
solid such as glass, and crystalline solids having cubic
symmetry) the speed of light and the index of refraction
are independent of the direction of propagation in the
medium and of the state of polarization of light.
A view through a
BIREFRINNGENT CRYSTAL,
showing the two images that
result from the two different
indices of refraction.
DOUBLE REFRACTION
Unpolarized light incident on a birefringent
material (eg. calcite crystal) splits into an
ordinary (o) ray and an extraordinary (e) ray.
These two rays are polarized in mutually
perpendicular directions.
The o-wave travels in the crystal with the same speed vo in all directions. The
o-ray obeys Snell’s Law of refraction. The crystal has a single index of
refraction no for o-wave.
The e-wave travels in the crystal with a speed that varies with direction from
vo to ve. It does not obey the Snell’s Law. The index of refraction of the crystal
varies with direction from no to ne for the e-wave.
DOUBLE REFRACTION
Principal indices of refraction (no, ne) of some doubly refracting crystals for sodium light
4
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
INTRODUCTION
Concept of oscillators
5
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
Definition of a Black-Body
Black-Body Radation Laws
1- The Stefan-Boltzmann Law
2- The Wien‘s Displacement Law
3- The Rayleigh-Jeans Law
4- The Planck Law
6
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
7
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
• radiation is absorbed
• causes a heating of the cavity walls.
• The oscillators in the cavity walls vibrate
• cavity walls re-radiate at wavelengths
corresponding to the temperature of the cavity,
producing standing waves in the cavity. Some
of the energy from these standing waves can
leave through the opening. The electromagnetic
radiation emitted by the black body is called
black-body radiation.
8
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
9
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
11
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
P = Ae T 4
12
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
13
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
14
The Rayleigh-Jeans Law.
2 πck B T
This law tries to explain the distribution I (λ , T ) =
of energy from a black body. λ4
I (l,T) dl is the intensity or power per
unit area emitted in the wavelength
interval dl from a blackbody.
15
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
kB – Boltzmann's constant
T- equilibrium blackbody
temperature Rayleigh-Jeans Law
c- velocity of light.
* It predicts an energy
output that diverges
towards infinity as
wavelengths grow smaller.
The failure has become known as the
ultraviolet catastrophe.
16
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
18
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
19
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
E n
4hf 4
Transitions. hf 1
0 0
20
BLACKBODY RADIATION & PLANK’S HYPOTHESIS
21
Planck hypothesis
Planck law
Weins law- at low
wavelength
Rayleigh jeans law- at
high wavelength.
2 π hc 2 1
I(λ, T) =
λ5 hc
λk B T
e - 1
THE PHOTOELECTRIC EFFECT
T – Evacuated
glass/ quartz tube
E – Emitter Plate/
T
Photosensitive
material /Cathode
C – Collector Plate /
Anode
V – Voltmeter
A - Ammeter
32
THE PHOTOELECTRIC EFFECT
Experimental Observations
1. When plate E is illuminated by light of
suitable frequency, electrons are emitted
from E and a current is detected in A.
2. Photocurrent
produced Vs
potential difference
applied graph
shows that
maximum kinetic
energy of the
emitted electrons,
Kmax = e Vs
33
THE PHOTOELECTRIC EFFECT
35
THE PHOTOELECTRIC EFFECT
36
THE PHOTOELECTRIC EFFECT
38
THE PHOTOELECTRIC EFFECT
All the observed features of photoelectric effect
could be explained by Einstein’s photoelectric
equation.
1. Equation shows that Kmax depends only on
frequency of the incident light.
2. Almost instantaneous emission of photoelectrons
due to one -to –one interaction between photons
and electrons.
3. Ejection of electrons depends on light frequency
since photons should have energy greater than
the work function in order to eject an electron.
4. The cutoff frequency fc is related to by fc = /h.
If the incident frequency f is less than fc , no
emission of photoelectrons.
39
THE PHOTOELECTRIC EFFECT
E p c m c
2 2 2 2 4
49
THE COMPTON EFFECT
50
THE COMPTON EFFECT
56
THE COMPTON EFFECT
57
THE COMPTON EFFECT
64
THE COMPTON EFFECT
66
Q.
INTRODUCTION TO QUANTUM PHYSICS
TOPICS
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BE-PHYSICS-INTRODUCTION TO QUANTUM PHYSICS-2018-19 1
PHOTONS AND ELECTROMAGNETIC WAVES
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2
PHOTONS AND ELECTROMAGNETIC WAVES
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PHOTONS AND ELECTROMAGNETIC WAVES
De Broglie
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4
PHOTONS AND ELECTROMAGNETIC WAVES
de Broglie Hypothesis
h
Planck’s constant
h 6.63 1034 Js
de Broglie wavelength
p
and
h
frequency of the particle
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PHOTONS AND ELECTROMAGNETIC WAVES
m = mass, v = velocity
p=mv = 2me V
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6
Q. find the kinetic energy of the proton whose
de- broglie wavelength is 1fm.
Q. Find the de Broglie wavelength of (a) a 46 g
golf ball with a velocity of 30 m/s, (b) an
electron with a velocity of 107 m/s.
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Davisson & Germer experiment
Energy of the
electron beam,
the angle at
which they reach
the target , and
position of the
detector could be
varied.
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Results
For beam of 54eV energy have sharp maximum
in the electron distribution occurred at angle
50o .
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PHOTONS AND ELECTROMAGNETIC WAVES
2dsin𝜽 = 𝒏𝝀
d = 0.091nm
mv=(2mk.E)1/2 & 𝜽= 65o
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PHOTONS AND ELECTROMAGNETIC WAVES
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PHOTONS AND ELECTROMAGNETIC WAVES
Q. In the Davisson-
Germer experiment, 54.0
eV electrons were
diffracted from a nickel
lattice. If the first
maximum in the
diffraction pattern was
observed at = 50.0°,
what was the lattice
spacing a between the
vertical rows of atoms in
the figure?
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THE QUANTUM PARTICLE
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THE QUANTUM PARTICLE
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THE QUANTUM PARTICLE
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THE QUANTUM PARTICLE
Beat
Where k = k1 – k2 and = 1 – 2. frequency
The resulting wave oscillates with the average
frequency, and its amplitude envelope varies
according to the difference frequency.
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THE QUANTUM PARTICLE
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THE QUANTUM PARTICLE
ω
we have, υphase = = f λ
k
i.e., ω = k υphase = k υp
dω d ( kvp ) dυp
But υg = = =k + υp
dk dk dk
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31
THE UNCERTAINTY PRINCIPLE
In short ( x ) ( px) ≥ h / 4
Also ( E ) ( t) ≥ h / 4
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32
THE UNCERTAINTY PRINCIPLE
Locating an electron
The speed of an electron is measured to be
5.00 x 103 m/s to an accuracy of 0.0030%.
Find the minimum uncertainty in determining
the position of this electron. [0.386 mm]
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33
THE UNCERTAINTY PRINCIPLE
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INTRODUCTION TO QUANTUM PHYSICS
QUESTIONS
10. Which are the features of photoelectric effect-experiment
explained by Einstein’s photoelectric equation? [2]
11. Sketch schematically the following graphs with reference to
the photoelectric effect: (a) photoelectric current vs applied
voltage (b) kinetic energy of most-energetic electron vs
frequency of incident light. [1EACH]
12. Explain Compton effect. [2]
13. Explain the experiment on Compton effect. [5]
14.Derive the Compton shift equation. [5]
15. Explain the wave properties of the particles. [2]
16. Explain a wavepacket and represent it schematically. [2]
17. Explain (a) group speed (b) phase speed, of a wavepacket.
[1+1]
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INTRODUCTION TO QUANTUM PHYSICS
QUESTIONS
20. Show that the group speed of a wavepacket is equal to the
particle speed. [2]
21. Explain Heisenberg uncertainty principle. [1]
22. Write the equations for uncertainty in (a) position and
momentum (b) energy and time. [1]
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QUANTUM MECHANICS
TOPICS
MUJ 1
1
AN INTERPRETATION OF QUANTUM MECHANICS
2
|| is always real and positive,
proportional to the probability per unit
volume,.
If represents a single particle,
||2 the probability density
the probability per unit volume that the
particle will be found at any given point in
the volume.
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One-Dimensional Wave Functions and
Expectation Values
= Wave function for a particle moving
along the x axis
P(x) dx = ||2 dx is the probability to find
the particle in the infinitesimal interval dx
around the point x. The probability of finding
the particle in the arbitrary interval a ≤ x ≤ b is
b
Pab
a
2 dx
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7
The probability of a particle being in
the interval a ≤ x ≤ b is the area
under the probability density curve
from a to b.
The total probability of finding the particle is 1.
Forcing this condition on the wave function is called
∞
normalization: 2
dx 1
∫
-∞
The wave equation satisfied by is the Schrodinger
equation and can be computed from it. All the
measureable quantities of a particle, such as its
energy and momentum, can be derived from a
knowledge
MIT-
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MANIPAL of . BE-PHYSICS-QUANTUM MECHANICS-2010-11 8
8
eg, the average position at which one expects to
find the particle after many measurements is
called the expectation value of x and is defined by
the equation
x x dx
f (x) f (x) dx
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9
The important mathematical features of a physically
acceptable wave function (x) for a system are
(i) (x) may be a complex function or a real function,
depending on the system;
(ii) (x), must be finite, continuous and single valued
every where;
(iii) The space derivatives of , must be finite,
continuous and single valued every where;
(iv) must be normalizable.
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AN INTERPRETATION OF QUANTUM MECHANICS
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AN INTERPRETATION OF QUANTUM MECHANICS
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THE SCHRÖDINGER EQUATION
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THE SCHRÖDINGER EQUATION
2 d2
2
U E
2 m dx
The above equation is referred to as the one-
dimensional, time-independent Schrödinger
equation.
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14
Schrodinger’s equation can not be derived from
other basic principle of physics; it is a basic
principle in itself.
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PARTICLE IN A BOX
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PARTICLE IN A BOX
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PARTICLE IN A BOX
A Bound Electron
Q. An electron is confined between two
impenetrable walls 0.20 nm apart. Determine
the energy levels for the states n =1 ,2 , and 3.
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PARTICLE IN A BOX
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A PARTICLE IN A WELL OF FINITE HEIGHT
(PARTICLE IN A SQUARE WELL POTENTIAL)
Potential energy
I II III diagram of a well of
U finite height U and
E
length L. A particle is
trapped in the well.
0 L
The total energy E of
X the particle-well
system is less than U
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25
A PARTICLE IN A WELL OF FINITE HEIGHT
( x ) A e C x B e C x
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27
A PARTICLE IN A WELL OF FINITE HEIGHT
= A e C x for x < 0
I _
2 m (U E)
where C
=B e–C x for x > L
III
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28
A PARTICLE IN A WELL OF FINITE HEIGHT
d2 2m
II
+ E = 0
dx2 ћ 2 II
k2
General solution of the above equation is
ψII
2 mE 2 mE
F sin
x G cos x
k k
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A PARTICLE IN A WELL OF FINITE HEIGHT
wave function outside the potential well decay
exponentially with distance.
I II III
U E
0 L
Boundary conditions Boundary conditions
ψ I (0) ψ II (0) ψ II (L ) ψ III(L )
dψ I dψ II dψ II dψ III
dx x 0 dx x 0
dx x L dx x L
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A PARTICLE IN A WELL OF FINITE HEIGHT
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TUNNELING THROUGH A POTENTIAL ENERGY BARRIER
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TUNNELING THROUGH A POTENTIAL ENERGY BARRIER
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TUNNELING THROUGH A POTENTIAL ENERGY BARRIER
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TUNNELING THROUGH A POTENTIAL ENERGY BARRIER
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TUNNELING THROUGH A POTENTIAL ENERGY BARRIER
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MUJ 40
Q.
MUJ 41
MUJ 42
THE SCANNING TUNNELING
MICROSCOPE
Application of
Tunnel effect.
MUJ 43
THE SIMPLE HARMONIC OSCILLATOR
where ω k /m
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44
THE SIMPLE HARMONIC OSCILLATOR
total energy E = K + U = ½ k A2 = ½ m ω2 A2
(classically)
Classically, the particle oscillates between the points
x = A and x = – A, where A is the amplitude of
the motion.
In the classical model, any value of E is allowed,
including E = 0, which is the total energy when
the particle is in rest at x = 0.
The Schrödinger equation for this problem is
2 d2 ψ 1 2 2
2
m x ψEψ
2m dx 2
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THE SIMPLE HARMONIC OSCILLATOR
mω
where C and E 1
2
ω
2
( m / 2 ) x 2
ψ Be
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THE SIMPLE HARMONIC OSCILLATOR
MUJ 47
47
THE SIMPLE HARMONIC OSCILLATOR
U (x)
x
-3 -2 -1 0 1 2 3
x
-3 -2 -1 0 1 2 3
MUJ 49
49
THE SIMPLE HARMONIC OSCILLATOR
2
ψn
x
-3 -2 -1 0 1 2 3
MUJ 51
51
Comparison of energy of particle in a box and a
harmonic oscillator
MUJ 52
Problem # 03
• A quantum simple harmonic oscillator consists of an electron
bound by a restoring force proportional to its position relative
to a certain equilibrium point. The proportionality constant is
8.99 N/m. What is the longest wavelength of light that can
excite the oscillator?
MUJ 55
Which of the wave functions can not have
physical significance in the given interval (why
not ?).
MUJ 56
QUESTIONS – QUANTUM MECHANICS
[MARKS]
1. What is a wave function ? What is its physical
interpretation ? [2]
2. What are the mathematical features of a wave
function? [2]
3. By solving the schrödinger equation, obtain the wave-
functions for a particle of mass m in a one-
dimensional “box” of length L. [5]
4. Apply the schrodinger equation to a particle in a
one-dimensional “box” of length L and obtain the
energy values of the particle. [5]
5. Sketch the lowest three energy states, wave-
functions, probability densities for the particle in a
one-dimensional “box”. [3]
MUJ 57
QUESTIONS – QUANTUM MECHANICS
[MARKS]
6. The wave-function for a particle confined to moving
in a one-dimensional box is
MUJ 58
QUESTIONS – QUANTUM MECHANICS
[MARKS]
8. Sketch the potential-well diagram of finite height U
and length L, obtain the general solution of the
Schrodinger equation for a particle of mass m in
it.
[5]
9. Sketch the lowest three energy states, wave-
functions, probability densities for the particle in a
potential well of finite height. [3]
MUJ 60
MICHELSON’S INTERFEROMETER
Objectives:
Introduction
The instruments based upon the principle of interference are called interferometers.
These are basic optical tools used to precisely measure wavelength, distance, index of
refraction, and temporal coherence of optical beams etc. It is an amplitude-splitting
interferometers devised by Albert Michelson in 1890, the first American physicist to receive
the Nobel Prize (1907 for work in optics). Michelson and Morley used this interferometer in
their celebrated series of experiments designed to demonstrate the existence of the ether. It is
still an important instrument in today's laboratories and it is being widely used as an
instrument for measuring the wavelength of an unknown light source, to measure extremely
small distance and for investigating optical media.
Construction:
Construction of Michelson
interferometer is shown in Fig. 1. It
consists of two highly polished mirrors
M1 and M2. Two glass plates beam
splitter (BS) and compensatory glass
plate (CP), are placed parallel to each
other between the mirrors at an angle of
450. The rear side of glass plate BS is
semi-silvered such that the light from a
source is equally reflected and
Fig. 1 : Construction of Michelson’s Interferometer
E
Optical path
The rays falling on mirrors M1 and M2 are derived from the same source originally incident
on plate BS (see Fig. 1). The wave reflected from M1 and entering the eye crosses BS twice.
However the path of the other wave falling on the mirror M2, in the absence of compensating
plate CP, travels totally in air. Thus an extra optical path 2(μ -1)t is introduced where, 't' is
the thickness of the plate and ‘μ‘ is the refractive index of the BS plate for the
monochromatic light used. Presence of CP is not essential if fringes are produced with
monochromatic light. But it produces a serious problem when white light is used. Thus, it
becomes necessary to compensate for the extra optical path 2(μ -1)t for all wavelengths. This
is done by introducing another glass plate CP of same thickness as that of BS parallel to it.
Thus, the two waves will interfere constructively or destructively as per the following conditions of
path difference, Δ:
Types of fringes:
Path difference between the two rays can be varied by moving M1. Mirror M1 and the virtual image of
mirror M2 act as the two surfaces of an air film. The fringes formed in Michelson interferometer may
be circular, curved or straight depending upon the nature of the air film.
L2
P’’ L1
2d P’
θ
2d cos θ P’’ P’ ’ P
Hence, λ = 2(Δd)/N
Fig. 5
Procedure:
(I) Observation of circular fringes using He-Ne laser as the light source
1. Set the Michelson Interferometer on the table with coarse adjustable knob pointing
towards you.
2. Set the lab jack in front of microscopic objective holder and set the height using lifting
knob.
3. Place the He-Ne Laser source on lab jack, pointing the source towards the centre of fixed
mirror.
4. Turn the laser on and adjust the laser beam height using lab jack lifting knob until the
beam is approximately parallel with the top of the interferometer and strikes the mirror at
the centre.
5. Set the viewing screen opposite of the adjustable mirror M2. Note that the viewing screen
should be placed at 1-2meter from the adjustable mirror to get better resolution.
6. To get circular fringes, M1 should be exactly perpendicular to M2. In this position,
Michelson interferometer is said to be in normal adjustment. The setting needs that the
plane of BS exactly bisects the angle (45°) between the two mirrors.
7. Using coarse adjustment knob makes the distance of M1 and M2 from BS nearly equal.
8. When laser beam will be passing through beam splitter (BS) at 45° and observed in the
direction M2, four spots of the He-Ne Laser beam are seen on the viewing screen; two of
which are faint and two are intense as shown in figure. The faint spots are due to reflection
from un-silvered surface of BS and then from M1 and M2 respectively. The intense spots
(III) Observation of circular fringes using He-Ne laser as the light source
1. Perform steps 1-10 from procedure I.
2. Replace the laser with Na lamp and switch it on.
3. Put a ground glass screen in front of the lamp.
4. A fringe pattern should appear on the screen and only fine adjustments of the movable
mirror should be necessary. You can also view the pattern with naked eye or attaching a
telescope near coarse adjustment knob.
(IV) Determination of wavelength of Na lamp
Fig. 7
1. Using He-Ne laser as light source reproduce circular fringes similar to Fig. 7(a).
Orientation of M1 and M2' is shown in the bottom panel corresponding to each set
of fringes in Fig.7 (a-e).
2. Adjust the coarse micrometer such that images (a) to (e) are viewed in succession.
3. Set the fine micrometer to the middle of the scale.
4. Readjust the coarse micrometer as close as possible to image Fig. 7(c).
5. Use the fine micrometer to produce fringes of equal inclination.
6. Take pictures of the fringes in a similar way shown in Fig. 7.
Fig.7
1. Using He-Ne laser as light source turn the fine micrometer to move the movable mirror in
a direction such that only few interference circular fringes are visible.
2. Adjust the movable mirror a little such that M1 and M2' till you see curved fringes as
shown in Fig. 7(f). Orientation of M1 and M2' is shown in the bottom panel corresponding
Graph:
λ = ........ nm
Precautions:
1. When turning the fine adjustment knob to count fringes, always turn it one complete
revolution before you start counting. This will almost entirely eliminate errors due to
backlash in fine adjustment knob.
2. Always turn the fine adjustment knob in one direction either clockwise or anti-clockwise.
3. Direct eye exposure to laser should be avoided.
4. Observing laser interference fringes by reflecting mirror is prohibited.
5. Avoid touching any of the optics with bare hand.
TOPICS
1
ATOMIC SPECTRA OF GASES
3
EARLY MODELS OF THE ATOM
4
EARLY MODELS OF THE ATOM
5
EARLY MODELS OF THE ATOM
6
A Danish physicist named Neil Bohr in 1913 proposed the Bohr
Atomic Model for H2 atom - Nobel Prize in Physics in 1922
BOHR’S MODEL OF THE HYDROGEN ATOM
–e
Electric potential energy 2
me
of the H-atom is k ee
U F
v
r +e
ke= Coulomb constant r
Energy quantization
Substitute rn= n2 ao in
the total energy equation
k ee2 k ee2 1
En 2
2r 2 ao n
13.606 eV
En 2
, n 1, 2, 3, . . .
n
E1= –13.606 eV E1
En 2
n 13
BOHR’S MODEL OF THE HYDROGEN ATOM
Energy k ee2 Z2
En 2 n 1, 2, 3, . . .
2 ao n
Limitations of Bohr’s theory:
When spectroscopic techniques improved, it was found
that many of the lines in the H-spectrum were not
single lines but closely spaced groups of lines. The
lines appear split when the H-vapour was kept in
magnetic field.
15
ATOMIC SPECTRA OF GASES
16
𝟏 𝟏 𝟏
=𝑹 −
𝝀 𝒏𝟏𝟐 𝒏𝟐𝟐
ATOMIC SPECTRA OF GASES
SJ-Problem-42.1 (a) What value of ni is associated
with the 94.96-nm spectral line in the Lyman series of
Hydrogen ? (b) Could this wavelength be associated
with the Paschen or Balmer series ?
18
THE X-RAY SPECTRUM OF ATOMS
• X-rays are high energy photos (0.01 to 10 nm)
• When fast moving e interact with an atom, x rays are produced,
which are emw which is,
– Unaffected by electric ang magnetic field
– Penetrate through opaque material
– Travel in a straight line.
• Faster the e, more penetrating is radiation
• More number of e, more intense will be the x rays.
X-ray Spectrum:-
• Continuous spectrum
(Bremsstrahlung S)
• Characteristics spectrum
THE X-RAY SPECTRUM OF ATOMS
x-ray spectrum - To examine the motions of
electrons that lie deep within multi-electron atoms.
• when the atoms are
bombarded with high
energy electrons. TARGET: MOLYBDENUM
• continuous spectrum and X-RAY TUBE VOLTAGE:
∆V = 35 kV
characteristic spectrum. λMIN = 35.5 pm
• Sharply defined cutoff
wavelength (λMIN) is a
prominent feature of the
continuous x-ray
spectrum.
hc
e V hfMAX
Duane –
MIN
hc
Hunt MIN
formula e V
λMIN depends only on ∆V
23
THE X-RAY SPECTRUM OF ATOMS
The peaks in the x-ray spectrum have wavelengths
characteristic of the target element in the x-ray tube
and hence they form the characteristic x-ray
spectrum. When a high energy electron strikes a
target atom and knocks out one of its electrons from
the inner shells with energy Em (| Em | ≤ K, the vacancy
in the inner shell is filled up by an electron from the
outer shell (energy = En, n = integer).
24
X-RAYS AND THE NUMBERING OF THE ELEMENTS
f C Z 1
MOSELEY PLOT OF THE K X-RAYS
C is a constant.
Based on this
observation, the elements
are arranged according to
their atomic numbers in
the periodic table
X-RAYS AND THE NUMBERING OF THE ELEMENTS
E m Z 2e 4 1 1
f 2 3
2
h 8 oh n f2
ni
32 oh
X-RAYS
or f C Z 1 since b 1
.
THE X-RAY SPECTRUM OF ATOMS
A K x-ray results due to the transition of the electron
from L-shell to K-shell. A K x-ray results due to the
transition of the electron from M-shell to K-shell.
When the vacancy arises in the L-shell, an L-series (L,
L, L) of x-rays results.
28
Q. Which element has a Kα x- ray line whose
wavelength is 0.18 nm? (R=1.097*10^7m-1)
MOLECULAR SPECTRA
Molecular spectra
The energy of an isolated molecule can be divided into four
categories:
(1) Electronic Energy- (Change in electronics configuration)
• interactions between the molecule’s electrons and nuclei
• Have highest energies of several eV.
• Transition spectra – visible or uv region
(2) Translational Energy-
• motion of molecule’s centre of mass
• Related to internal structure of molecules
(3) Rotational Energy-
• Rotation of the molecule about its centre of mass
• Energy levels separation – 10-3 eV
• Transition spectra - Microwave region (WL = 0.1mm-1cm)
(4) Vibrational energy-
• Vibration of the molecule’s constituent atoms
• Energy level separation – 0.1 eV –
• Transition spectra - infrared region (1µm to 0.1 mm)
E = EEL + ETRANS + EROT + EVIB
36
ENERGY STATES AND SPECTRA OF MOLECULES
Rotational motion of molecules: A diatomic
molecule (m1, m2 = masses of the atoms, r =
internuclear separation) aligned along an x-axis has
only two rotational degrees of freedom, corresponding
to rotations about the y- and z-axes.
ω = angular frequency of
rotation about y-axis or z-axis
EROT = rotational kinetic energy of the
molecule about that axis
EROT 12 I 2
Moment of inertia of m1m2 2
I r r 2
the diatomic molecule
m1 m2
Reduced mass of the m1m2
diatomic molecule m1 m2
Magnitude of the classical angular momentum, L = I ω 38
ENERGY STATES AND SPECTRA OF MOLECULES
Rotational motion of molecules:
Quantized angular momentum of the molecule
L J(J 1) J = 0, 1, 2, . . . = rotational
quantum number
1
EROT 1
2
I 2
I 2
2I
EROT
L 2
J( J 1)
2
2I 2I
2
EROT J(J 1) J 0, 1, 2, . . .
2I
QUANTIZED ROTATIONAL ENERGIES OF A
DIATOMIC MOLECULE: E1=Ћ2/2I
39
ENERGY STATES AND SPECTRA OF MOLECULES
Rotational motion of molecules:
Selection rule for rotational transitions: ∆J = ±1
40
Q.
ENERGY STATES AND SPECTRA OF MOLECULES
Vibrational motion of molecules: Plot of potential
Model of a diatomic energy function for
molecule as a simple a diatomic molecule
harmonic oscillator
ro = EQUILIBRIUM
SEPARATION
43
According to quantum mechanics the vibrational
motions are quantized. The allowed vibrational energies
of the quantum harmonic oscillator are
v EVIB
E VIB v 12 h f v 0, 1, 2, . . .
5
11
2
hf
v = vibrational quantum number
f = frequency of the oscillator 4
9
2
hf
The lowest vibrational state has the
energy = (½) hf. Substitute f 1 k hf
3 7
2
2
h k 2 5
hf
E VIB v 2
1
v 0, 1, 2, . . . EVIB ΔEVIB
2
2
1 3
2
hf
Selection rule for the
allowed vibrational transitions: Δv = ±1 0 1
2
hf
44
Q.
LASER
LASER
Light Amplification by the Stimulated Emission of Radiation
50
LASERS AND LASER LIGHT
Spontaneous Emission: The average life time of the
atomic system in the excited state is of the order of
10–8 s. After the life time of the atomic system in the
excited state, it comes back to the state of lower
energy on its own accord by emitting a photon of
energy hf = E2– E1 (see figure).
In an ordinary light source the radiation of light from
different atoms is not coherent. The radiations are
emitted in different directions in random manner. Such
type of emission of radiation is called spontaneous
emission.
51
LASERS AND LASER LIGHT
Stimulated Emission: When a photon (stimulating
photon) of suitable frequency interacts with an excited
atomic system, it comes down to ground state before
its life time. Such an emission of radiation is called
stimulated emission. In stimulated emission, both the
stimulating photon and the stimulated photon are of
same frequency, same phase and are in same state of
polarization, they are emitted in the same direction.
In other words, these two photons are coherent. Thus
amplified radiation is got
by stimulated emission
(see figure).
52
LASERS AND LASER LIGHT
Population inversion: Boltzmann statistics gives the
population of atoms in various energy states at
temperature T.
nE2 E2 E1
exp
nE1 kT
k = Boltzmann constant. n(E1) = density of atoms with
energy E1 , n(E2) = density of atoms with energy E2 .
n(E2) < n(E1) if E2 > E1 (Figure a). This is the
normal condition in which the population of the atoms in
upper energy state is less than that in lower energy state.
For the stimulated emission rate to exceed the absorption
rate it is necessary to have higher population of upper
energy state than that of lower energy state. This
condition is called population inversion [n(E2) > n(E1)]
(Figure b). This is a non equilibrium condition and is
facilitated by the presence of “metastable states”. 53
Metastable state Population Inversion
56
Three Level LASER system
Four Level LASER system
Atom are pumped from level 1 to Level 4 (excited state) from there they fast decay
to level 3 (metastable state) through a non-radiative transition, and population
inversion is achieved between levels 3 and 2.
Ruby Laser
In ruby laser the lasing medium is a ruby crystal rod.
Ruby is Al2O3 doped with Cr3+. Cr3+ ions are the active
centres.
Population
inversion
achieved using
Optical
Pumping
He-Ne Laser
61