MATERIAL SAFETY DATA SHEET

No. MSDS : W-042

Revision : 00
Effective Date : 05/11/2009

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : WATER BASED PRIMER WBP-1621-01 SL BLACK

Product use : Base coat

Manufacture’s Name : PT. PROPAN RAYA ICC

Address : JL. GATOT SUBROTO KM 6.5 JATAKE

TANGERANG 15136 BANTEN - INDONESIA
TELP. : + 62-21-5919577 (HUNTING)
FAX. : + 62-21-5919022/24/25
E-mail : + projtk@propanraya.com

2. INGREDIENTS
% Max
INGREDIENTS COMPONENTS
(By weight) CAS# EINECS #

Acrylic emulsion 30 - -

Calcium Carbonate 35 471-34-1 -

1.2-benziathiazol-3 (2H)-one 0.018 2634-33-5 220-120-9

3-iodo-2-propinyl-butylcarbamate 0.0075 55406-53-6 259-627-5

Water 18 - -

3. HAZARD IDENTIFICATION
WARNING
Colored liquid. Can cause eye and skin irritation upon contact. Inhalation of vapors can cause anesthetic effect
leading to death in poorly ventilated areas. Risk Phrases - R 20/22 36 38 41 43 50/53
PROTECTIVE MEASURES
Avoid contact with the skin, eyes and wear proper skin protection.

4. FIRST AID MEASURES

GENERAL
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an
unconscious person.
EYES
Remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation
persists, seek medical attention.
SKIN
Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before
reuse; if irritation persists, seek medical attention.
INGESTION
Give two glasses of water for dilution; induce vomiting by sticking fingers down throat; never give anything by
mouth to an unconscious person; seek medical attention.
INHALATION
Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing,
administer CPR and seek emergency medical attention.

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5. FIRE FIGHTING MEASURES

GENERAL HAZARDS
Products of combustion include compounds of carbon, hydrogen and oxygen, including carbon monoxide.
EXTINGUISHING MEDIA
Carbon dioxide, water fog, dry chemical, chemical foam.
FIRE FIGHTING PROCEDURES
Self - contained respiratory equipment; cool containers to prevent pressure buildup and explosion when exposed
to extreme heat.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers can explode due to buildup of pressure when exposed to extreme heat. Vapors may cause a
flash fire or ignite explosively. Vapors may travel a considerable distance to a source of ignition and flash back.
HAZARDOUS COMBUSTION PRODUCTS
Smoke, fumes, oxides of carbon.

6. ACCIDENTAL RELEASE MEASURES

STEP TO BE TAKEN IN CASE MATERIAL IS RELEASE OR SPILLED: Evacuate and ventilate area; confine
and absorb into absorbent; place material into approved containers for disposal; do not discharge into lakes,
ponds, streams, or public waters.

7. HANDLING AND STORAGE

PRECAUTION TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use; protect
containers from abuse; protect from extreme temperatures. Keeps away from all sources of ignition. “Empty”
containers may contain residue, which may form explosive vapors. Do not weld or cut near empty container that
has not been professionally reconditioned. Use non-sparking tools when opening and closing containers.
Maintain well-ventilated work areas to minimize exposure when handling this material.

8. EXPOSURE CONTROL/PERSONAL PROTECTION

VENTILATION SYSTEM
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, Industrial Ventilation, A Manual of Recommended practices, most recent edition, for details. Use
explosion-proof equipment.
PERSONAL RESPIRATORS (NIOSH APPROVED)
If the exposure limit is exceeded, a half-face organic vapor respirator may be worn for up to ten times the
exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator
supplier, whichever is lowest. A full-face piece organic vapor respirator may be worn up to 50 times the exposure
limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier,
whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-face
piece positive-pressure, air-supplied respirator. Warning: Air-purifying respirators do not protect workers in
oxygen-deficient atmospheres.
SKIN PROTECTION
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to
prevent skin contact.
EYE PROTECTION
Maintain eye wash fountain and quick-drench facilities in work area. Use chemical safety goggles and/or full-face
shield where dusting or splashing of solutions is possible.
WORK/HYGIENIC PRACTICES
Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.

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9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Colored liquid
Flash Point : N/A
Odor : Mild
Solubility in water : Dispersible
PH : 8-9
Specific gravity : 1.35 ± 0.04 g/cc

10.STABILITY AND REACTIVITY

STABILITY CONDITION TO AVOID
Product is stable under normal operating and Extreme temperatures, open flames, spark.
storage conditions.
INCOMPATIBILITY (MATERIAL TO AVOID): strong oxidizers, strong acids, strong alkalis.
HAZARDOUS DECOMPOSITION OR BY PRODUCTS: Decomposition will not occur if handle and stored
properly. In case of a fire, oxides of carbon, hydrocarbons, fumes, and smoke may be produced.
HAZARDOUS POLYMERIZATION CONDITION TO AVOID
Will not occur. None

11. TOXICOLOGY INFORMATION

LD50 of Ingredient
HAZARDOUS LC50 of Ingredient Hazard RISK PHRASES
(Specify Species and
COMPONENTS (Specify Species) Symbol Full Text Section 15
Route)
1.2-benziathiazol-3 (2H)- 1.020 mg/kg 1.020 mg/kg R-22, 38, 42, 43, 50
Xn, N
one Oral - rat Oral - rat
3-iodo-2-propinyl- 300-500 mg/kg 300 - 500 mg/kg
Xn, N R-20/22, 36, 43, 50/53
butylcarbamate Oral - rat Oral - rat
INHALATION
The inhalation of solvent vapor or dust spray may cause irritation of the respiratory tract.
SKIN CONTACT
These components of the preparation have irritating properties. Prolonged or repeated contact with skin or
mucous membrane may result in irritation symptoms such as redness, blistering, dermatitis, etc cases of allergic
skin reactions have been observed.
EYE CONTACT
The liquid splashed in the eyes may cause irritation.
IGNESTION
Ingestion may cause nausea, weakness and central nervous system effects.

12. ECOLOGICAL INFORMATION

No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are
available. Based on the chemical composition of this product it is assumed that the mixture can be treated in an
acclimatized biological waste treatment plant system in limited quantities. However, such treatment should be
evaluated and approved for each specific biological system. The preparation has been assessed following the
conventional method of the Dangerous Preparations Directive 1999/45/EC and is classified for eco -
toxicological properties accordingly. See section 2 and 15 for details.

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13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: Dispose of in accordance with Local, State, and Federal Regulations. This
product may produce hazardous vapors or fumes in a closed disposal container creating a dangerous
environment. Refer to “40 CFR Protection of Environment Parts 260-299” for complete waste disposal
regulations. Consult your Local, State, or Federal Environmental Protection Agency before disposing of any
chemicals. Do not flush to sanitary sewer or waterway.

14. TRANSPORT INFORMATION

Proper Shipping Name : Coating solution
DOT Hazard Class : Non Hazardous
Label : Non Flammable
Hazard Symbol :-
Packing Group :-

15. REGULATORY INFORMATION

This product is classified according to EU regulation

RISK PHRASES: SAFETY PHRESES:
R10 Flammable S2 Keep out of the reach of children.
R20/21 Harmful by inhalation and in contact with skin S23 Do not breathe vapor and spray mist.
R38 Irritating to skin S24 Avoid contact with skin.
R65 Harmful: may cause lung damage if swallowed S26 In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice.
S28 After contact with skin, wash immediately
with plenty of soap and water.
S29 Do not empty into drains.
S37 Wear suitable gloves.
S51 Use only in well ventilated areas.
S57 Use appropriate containment to avoid
environmental contamination.

16. OTHERS INFORMATION

Notes and full R-Phrases text
R20/21 Harmful by inhalation and in contact with skin
R66 Repated exposure may cause skin dryness or cracking
R67 Vapours may cause drowsiness and dizziness
HMIS HAZARD RATINGS HEALTH 1 0 = Insignificant
FLAMMABILITY 0 1 = Slight
REACTIVITY 1 2 = Moderate
PERSONAL PROTECTIVE EQUIPMENT B Safety glasses, Gloves 3 = High
4 = Extreme
This information is based on our present states knowledge. It should not therefore be construed as
guaranteeing specific properties of the products described or their suitability for – a particular application.

Date of issue : November 5, 2009

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