219 Pv Censtont

PV Constant P Conatant
WoTkor a Constant press u r e protos,
2
w JPdv= P(V-v.) =(216S)0-04-O
W-12KJ
PV= (omatart
Pv'= Conatant
(aD09
O1

o.8 bar
|R =

2
: PV= C
W Pdv= d v P
c[uv]
/ 0.0y

o.8x 165)(o.1) n
W=.33KI|
 = 3

Pv
V
Ro. 608 bor
2

W JPdv
S CdV= c(ymN n+.

h+I2
W E P y h

1-n
B-R
-

W- 0(o.04)-(0.60o8)(o.D]xibS
- 1-3
W=-6:4 KT

-03 PVdiagamt - P:C

3
P Ht - PV= C

ba)

d - V=C

1 v (m3)
W9=O onstant Votume prou3.
Maa 4()= g)(4,ln(i)
|Wa-3 554.5 KJ|
kT
x )0)(1-2)
z
- 400
3-4Pa [v-v
(205 P-V dia qYam
((b4/ina)P

PVC

3 PC
v (t
proCess 1-24
PV C RV, =
V2

W-2 Pv, ln ( VV2

(1o
in1t
12n()n
9210.36 bt St Bt

W2-
1 1:92 Btu

W-3 o Comstant voUume procass

Wa-1P (V-V3) =R(V,-V»)

1o Lbf12in 4-0.8)3
in14),
4608 f . t Btu
48 bfJt

3 5.92 Btu
 Fom Soturatd wat - Pressue table

At P 1 /in= V = o.61614 4t/6

v333.6 5t3/L
AV m (Vg - V)

=(1 lb)( 333 6 -0.O1614) / 6 .

AV= 33 3-58 tS
=
0.61642 A/b
A t P= 4. bf /in
26 8 t3/

AV m ( - )
= ()tb (26:8 oo l642) t3/b

AV 26. 48 ft3
tAL
P= 10o /in S ¥= 0.01774
AtAt 443 4 t3/b
4
AV m (V -V})
(y.u3y-0.01444) S/
(4 b =

AV= 4. 42 tS) 00945 Sl

At P Soo 6S/in*>

AV m (%-)
( 1 6) (o.928 - 0 .
o1915) tSb
AV 0 91st3
in
incYeasel, the Change
#The pre ssure
Volume decveases
 T-V daqvam + From Satu1ats d
wota-Temperoture
P- Pa4oc) tal
At T 1ydC,
Pset=3-613 bar

m1kg
4= 0494x 10
9 05 m°|ka 0.5o 8m° I*a
9 < Vg Stat is two-phae lauid
vapo egiom
P=at = 3.613 bar
P-30MPa : 300bay

8320.4 av
//P =

Tc 31y.juc

00'C

V
nature talele
Watir-Tempe
Satu-vatud
rom
YO
bar= 0-J014MRa
Peot1.o14
At T= I00°c =
Compresed
Compresed
P-30 Ma> a t
Stato is
iqud Tegion
w a t e r table
From Cmpresed üguid
l60C
and T
At
At P 30M Pa
Io.29x 105 m/Kq
 P-10M -100ba
T 48c
T3y.14C

Tsat (l00bar)

V PresBuTve
P reue
-table.
lable
o
uoaatto
eTr-
-
Saturatud
Tsnt=31l06C

From

P 10MPa ús n
At State
Stotia

Tsat Superheatid opot

48S°C
T
romSuperheattd Vapo talbles
tables.

T=
48°c
MPa and
P = lo
At
/48S-480
By inkerpoation,

0-03166) 50-48/

03160+ (O-03394-
0
0-03189 mKa
19
From Saturatid e r

Rat(8oc) Témperatuve table

At T-80 C,
sat O-413 bav
80C
7V

3.404 m/a
two
0.4S Stat ts
X Phase ugpuid-Vapov.
bar
P=Peat =
o-y131

-
1.029N103)
+0.75(3-u4

l089)1x
103

2.55 m*Ka
 TVdiaqTam Fom Tob A-3,

TA P 20Ma At P- 20 Ma,
TT 406'c Sot 3 6 s . 2

Tsot 365-8'
T 406C>s t
Stata ú in Superheatd
Vopo
rOT Table A-4,
T- 4ooC,
At P= 2o MPa ond
0.oo994 m|a|

lablo A -3,
TVdiaqrant rom
At P DMPa
P20Mfa

Sat 36S 8'C

Tsat 365-8c

T 40°C < Isat

State di Compressed

igjuid
V

At P:20MPa and T=y0°c

rom Tabe A -S,

19=09992x 1o3 mIKa

v diagYaunt rom Tabe A 3,

At P2MPa,
P MPa
TA Sat212.4°c

212.4C 46'c < Isat

Tsat T
S t a t us Compressed

4oC uud
T y0 C,
Fvo Tada A-2, At
= 1004 xI0s m$|9
 T-V diaqvam P-voaqrom

T
100c
jooC

V V

0.25 mlK
= m 3

4 K

hom Table A-2, AE 10oC, 1643 m°i

1ou3S xio la, =

ad
4 <Vg Statt ie tioo -phase
apo
1:0Y3S* 103)
( 1643
0.25 1 :o43SxI0

T-v diaqram P
4o lbi/in
40 b$/in

Yom Tabl A -14E

at P L4o tbf/in

BBu/6b, ug =s%a.6 Bu/lb.

U Sy 89 U ucUg Tuoo-phase
308.45 Etu/lb uapud Vopoy.

u -U + (ug- uf) 0.S

(6a.6-S48 ) > 1 =
308-*S = 5489+
0:02s)
0 s(4.04)
-

O-02yS+
+ (Vg-V¢) =

3.S33 S/lb |
 Fre body aqram piston
FatnA
PA ma atm A =O
mg
PA P Patm + mg
A

Ibo KPa + (So Ka)(-31 mMs) IKPa

P -
(oolm2) looo N/m

P 14 KPa
A-2, a
T=l0o° C,
Table
rom
bay= 014 KPa
ofy
Cat=

1o435 x10 m ka
> Bat (10o°c
P 149KPa aud
Ligpud
Compresed
is 10S m*|k
Stat Ioy3Sx

=
(1oo'c)

(1ou3sx 10)
= (o-1)
V=m
10 Cm
1o
V I oy3Sx
V= 10y.35 3
3.28

P dMPa , T-300b'c

P as81kav

20 bar

81bar
Cot 8S 360C
P- 20 bav

T-300 C

V
Superheatid vapo Stote
2MPa and T 300C,
At P =

rom
Table A-4,
= 2742.1s KJ [ka|
T 200'c
P 2.SM Pa P ASbar

T
P , 1SSylmY

QSbar = P

Psat 15sybar 200C

T 200o'C

V
=
8 49.q
KI |ka
rem Table A -S,U

140F, 1 SO7
T

T= 170FF

V
o - At
110"F,
A 2E,
F o n n Table
ug= Io6S-y Bu /lb
u 1 2 t - 5B t u / l b ,
134-9s)
+0 S To6S.y
-

13t9S
U+ ( g -u4)
=

u
P Ioo
lb;/*,T=300° F 00biin

P 100 bR 32786 66.9S

lb7m
-66 AS bi
300F
300

V
laola A -2E,
em
a69 + Btu/b
h hy (327-86 °E) =

MPa, - 0:209S m3|ka

1s
-4E,
At
P S
P= MPa
1'sMPa, a
A
rom Tab
o.1313 m/ka
uperheatid

mS/Ka> a Vapo
= 0:2095

PSMPa

O-SMa

Tsot 198-32'e

heatzd
tabes,
table,

rom Super 9= o209s lk

S M P a and
At P
KT/ka
h 3299 IS
329

R-134 a at T- 6o°F, h= 124.4 Btulb.

(a) 160F,
A 1OE a T=
rom Takla ,

n-18 Btu/ b
ng Superheath d
124.4
Bulto> hg Vapo
h
A- 12E, At T= 166'Fand h 12.4Ru
From Tade
P-200&f/th

9 =0:2636 ts/tb
PA
314-63 b i / i n 1 6 0
214»63
-166 F

u-
42.| 8tu/lb
T 90F,
R13ua at
Tabl A lbE, at T-90'F,
Frorn
10SBtu!tb
ua
40: y2 Btu/Ub
,

u Btu/lb.
Bult, ha 3 5
uo 42 mixtuve
two -

Phase
Stati s
=
u<ug

42) >> = 0 S
40.92 +a( 10s-40
42.1=

N
V
13-7s - yo.42)
h he+r (hg-hg) 4o.424+0 S(
/l6.
h : 14-235 BBu
 Ammmia at T= 160'F. P = 60 lb/in

T' P 6o Ubsin* PA 60

- T l60'F
6o(hf
sat 30.9'F

20-19°F

Tabe A
60 hf.
IgE, at T= l66'F ad P= i n
From

u 6a4.uu Btullb .
Lb/tn
at T= OF, P=
Ammonia
P
3s f /
30-416l b
in
30.Y166

-o°F

V Tegiom
uid
Compiessed
s
State
Table A-13E, 42.32 Btu|lb
(o'F) =
U
ot/in,
T= 3so'F
R-22 at P-3so 35oF
P
2s0'F
T 3So
of/in

V
and
A -9E,
a t P: 3So lbf/in
Toble
rom inkTpolatiom,

3c0'F, B
T 143-14 Bu!lb|
u =
3 - 3 2 ) Fom labe A -3, at P Ybav
U = 2s53-6 KI|Ka

V 0. u62sm/tg
Con3stount Veume
219 =
O. u6as lk4 Pro C
FTomTaldl A - 4, at bpka Ta= 40o'c

and = 0. 46 2sm5]kg

U = 61.2 kJ/K9
ther balama eenatiom,

&U + AKE + APE

-W
A U =m -

2SS3 6
2961 a
=

Q Ho1 6 KJ |K

A-2E, a t T=
300'F
From Tablo 1180-2
1180-2 Btu /tlb.
BBu/tb.
(3-49 Btu/b, hg
26.1 3/.
hhf =

01us 3/b,
g= 6. 442 ft
0
V,h + , (hg-hs)
h=
269: #)
+0.9 (11802
2641

h 089.IS Bfu/b

Bullb
186.
2 - hg
=

O.01HYS)

0.9 ( 6:472 -
O.6194s
+

S/6
= S. 065
Ener bnlance eatim,

- W AUAKË+ DPE
AV + W
Q=

at U-U, + P[V-V
. =

m(ua- u) +P(v,-) |
m ua+ B 2) -(u,+P, 0)
At m[h2-h >O

= 1-03 b
S826SS

At h
=. m [ h h

089-15
. 0 3 1 1 8 02
-

At =
(o-3)
At=312.6 Sx_min
60S

At= S.21 min

 1 33-44/.
m
3 b
Stat 1 is Superheat ed Vapoí
romTabe A -4E,
23.9ft3/b,
At T 35o'F and V=
P o bf/in
l 6 . 9 Btu (Lb.
U
= 28 46 ts/tb.
3 b

Stat a Superheatud VapoY

YOm Table A -4E,
At P= 2o lbt/in
and 9,=2%-46 t3/,
T Soo°'E

l181 s Bhub

8-2 8-2 St5

3 lb
9.y t3/lb
3T2 Soo'F.
Stoh 3 is Superheatid VapoY
rom Talble A - 4E,

and V = 9u St3]t%,
At TaSoo'F
P 6o b f l i n

/ 4 8 6 BBu/ b .
3=

Pdv R(,-V)
W2
1BA
194i3 38-19) 448 Stlb
(20 in2 St2

W S0.64 Bu
Ene balanta
oytYosI-2,
wWi2 (AU),, + bPE2t 2
2 m(ua-) +W2

3(121.5 126.9) + So 64
12 a14 4u Btu

neYgy
balanca foY proUs 2-3

23 mUg-ua) + Wa3
(-72)
( 3 (173.6- U81s) +
23 80. Btu

TVdia9am
PV diaqram

PA T
3
50dE

2olbs/iA
350 F
3-64 FromTabl A -1E, foy CO,
Pc-34S atm, Tc= 239R , M =28.01b
bmel

=3oo/in2 atm 6.9

34S atm
in
500 °R
Te Te 239°R
=2
romigure A-2,

6.9 and TR -1> Z= |oS

At P
RT
P V= m
mRT P
Isus t - b f
Isus Lbmol
iR(SooR)
(1-os (iso l) 29-01 6
b mat

3soo b(1
in
V 8-6 3 |

and 106'C.
R-134a at 16bav
3-68
Fom Table A - 12 |V: 0.o1601 m
(a)
HguTe A-
R-134a,
Talb A-I, for
Form
P e 4 6 . 4bav
T c Tc344K
M lo2.03 Kg [Kmol
TR 100+ 3 = I
344

= 6 = 0.393

Fo Figuve A-!,
I 7 0.86
At P= 0.393 and TR=
 P9
9 = RT
RT P
/8314
n = 0.86 (02.63 (313)
6x IS

9 0-o1634 mTa
i reatir han he tabb valur by 2
TH

eation t
Tdel 3a
P RT
(231(343)
(o2.03
RL 6x10SS

9= 0-019 msk

than he table
volue oy 19
I yecte

3-76 W Pdv Pavg VJ-((u-v)

10,IKJ
W(29)v1o5 N
m2
(2-)L L

W= 0.5 KT|
Nhn) (1L0 m
m P (axo k)\
IL
8314 Nm
RT
k g k ) ( 2 0 0

29-91

m= 0.003S K
 V

T2 ( ) T =1600K.

ronm Table A-22

u (200 k)= 4 S6 KT/K

u

u (1600 K)= 1298.3 KJ/Ka

U2
balanCa euation,
Ene PE
-W =AU+ AKE+
=m
m u a -u + W
14a.S6]+0.S
248-3
E (o oo3s
= 4 SE KT

Patm A
P-Vdia9 ram
ma

A
T

BA Patm A +O
ma
B otmt A
Kg)(81)s. bar
[ So
ba + 2

E 1S bav
Fo a Constant volumne proo,

T
T
a
P
Ta T
Ta 600 ) ( ) -306 K
O e A -22

U u (600k) 434.4 KT |k
U U (300 K) Q14.04 KJ|K
=

bolanCe Eauation,
Ene83. AU+ KE + APE
-
AU m (ug-u
(a14-04-434 18)kT
/5gx 1K_\ Kg
(oo07

| =1 . 1 KT