. Mcoscs? 7 Mots? £COa6Q> + MuNoa72 ()-4 MOCK + BNOACA) thoatgy Thond yet: weoter “V6 te product 40 fase Ahemal saity of metalnvvades & 2avonorer T AU rE Going down the Group © cation size ......%. charge density...¥ ne se to : share dens mena ba pont «+ polarization of anion ‘+ anion electron cloud is less distorted and compound become more stable to and harder to decompose. SOLUBILITY OF 2 COMPOUNDS more exo Dmore SLVELE 1 Solu ofa subsiance depends ont enalny change of solaion which then MsQus) Ey mag) 580*00) lependent on: bi erthalpy oof s0\ = aMhackby Os BSrydyasion — -AH Airy: ‘The lattice energy © MM®+SOr@) Enthalpy of hydration Alon = AHnys = AHL SOLUBILITY OF GROUP 2 SULFATES CLD v everey a ae Ee Le ae al 1g [2959 =10507 a6 |_| aa ie tteten 8a 2459 1273 [26 11 4S Of ah + Cation size increases ‘+ Hydration energy decreases more than lattice energy + Allsoln becomes more less exothermic/more endothermic down the group 2. BaSOs can be swallowed as “barium metal: without harming the patient although barium compounds are poisonous. This is because BaSOs is extremely insoluble. SOLUBILITY OF METAL HYROXIDES eversy Solubility of hydroxides «0.0%... down the Group. # Cation size increases Lyeraton + Lattice energy decreases more than hydration energy ae ‘* _Alfsoin becomes less endothermic more exothermic down the group * Solubility increases we Me Co Se Bo Re ‘main factor isthe size of the jon, For small negative ions like hydroxide, the lattice enthalpy falls faster than the hydration enthalpy of the positive ions. This means thatthe enthalpy of solution «will become less positive (or more negative). ‘© For large negative ions like sulfate the hydration enthalpy of the positive ions falls faster than the lattice enthalpy. ‘This means the enthalpy of solution will become more positive (or less negative.4 (a) Describe the observations if any that you would make when: ‘© 2 few drops of NaOH(aq) are added to BaCl,(aq) * NACL * BaCOWa = cvenusteas JR DMRUITE 1 9 few drops of H:50s(aq) are added to BaCh{aq)