PERHITUNGAN KETIDAKPASTIAN PENGUKURAN CARA TOP DOWN

1. Ketidakpastian Baku Asal Bias (uBias)

1 DARI 1 CRM
Parameter COD High CRM ERA Demand Cat. No P274-516
Nilai CRM 127 ±
Faktor Cakupan 2

Bias Lab rata-rata 0.762 mg/L

Bias Lab Relatif 0.60 %
Bias2 0.36

sd Bias 1.21 mg/L

sd Bias Relatif 0.95 %

sd Bias Relatif / √n 0.36 %

(sd Bias Relatif/√n) 2
0.13

u(Cref) 1.61 mg/L

u(Cref) Relatif 1.26 %
(u(Cref))2 1.60

uBias 1.44

1. Ketidakpastian Baku Asal Bias (uBias)

2 DARI >1 CRM

KODE CRM Nilai Tersertifikasi (mg/kg) U (mg/Kg)

CRM 1 (COD-Low) 50 2.51
CRM 2 (COD-High) 127 3.21
HASIL PENGUJIAN CRM DI LABORATORIUM
KODE CRM Nilai Terukur (mg/Kg) Bias Lab (mg/Kg)
CRM 1 (COD-Low) 49.79 0.2100
CRM 2 (COD-High) 127.667 0.667

RMSbias2 0.226
u(Cref)2 3.707
RMSbias2 + u(Cref)2 3.93

ubias 1.98
TOP DOWN

Hasil pengujian CRM di lab

3.21
nilai rata konsentrasi lab - nilai crm
(bias lab rata2 : nilai CRM) *100
mg/L No Konsentrasi (mg/L)
1 124.333
2 124.333
3 131.000
4 127.667
5 127.667
6 124.333
7 124.333
Rata-rata 126.24
Sd Bias
n 7

(nilai sd bias : nilai CRM)*100

nilai U CRM : faktor cakupan

(u(Cref) : nilai CRM)*100

K u(Cref) (mg/Kg) u(Cref) (%)

1.96 1.2806 2.56 u(cref) = U/K
1.96 1.6378 1.29 u(cref)% = (u(cref)/nilai CRM)*100
Rata-rata uCref 1.93
Bias Lab Terhadap CRM (%) Bias2 (%)
0.42 0.1764 bias lab = nilai terukur-nilai CRM
0.53 0.2758 bias lab thd CRM = (bias lab/nilai CRM) *100
Σ(biasi)2 0.4522
Σ(biasi)2/n 0.2261
RMSbias 0.48
gujian CRM di lab
Bias (mg/L)
2.667
2.667
4.000
0.667
0.667
2.667
2.667

1.21

f)/nilai CRM)*100