Professional Documents
Culture Documents
Magnetic properties
La3+ (4f0) and Lu3+ (4f14), having no unpaired electron; these do not show
paramagnetism while all other tri positive ions of lanthanides are paramagnetic.
Complexes
Although the lanthanide ions have a high charge (+3), their large size (0.85 – 1.03
Angstrom) imparts them low charges density (charge to size ratio) with the result
they cannot cause much polarisation and hence do not have much tendency to
form complexes. Their complexes with unidentate ligands like β-diketones, oximes
and ethylene diamine tetra-acetate (EDTA) are fairly common.
Color in lanthanide
Color due to f to f transition. The lanthanide metals are silvery white. The trivalent
lanthanide ions are colored both in the solid state and in aqueous solution. The
colours are unchanged even on alteration of the anions indicating that they are
characteristic of the cations.
Oxid
ation 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
state
+2 Sm2+ Eu2+ Tm2+ Yb2+
+3 La3+ Ce3+ Pr3+ Nd3+ Pm3+ Sm3+ Eu3+ Gd3+ Tb3+ Dy3+ Ho3+ Er3+ Tm3+ Yb3+ Lu3+
+4 Ce4+ Pr4+ Nd4+ Tb4+ Dy4+
Antenna effect
• Weak light absorption by forbidden f-f transitions; molar absorption
coefficients ε are < 10 mol L-1 cm-1.
• Indirect excitation via attached ligands or via host lattice in order to get
sensitized luminescence.
• Sensitization is not only possible via energy transfer from triplet state of organic
ligands, but also by:
–Inorganic chromophores (e.g. MoO42-, VO42-)
Lanthanide phosphors
White light production
There are three “prime” colors corresponding to the three spectral responses of human vision
compact
fluorescent
lamp (CFL)
Security inks
Euro bills
Security inks
Under UV irradiation
Eu3+: red luminescence
Tb3+: green-yellow luminescence
Lewis Acids and Bases
https://achandra9.wixsite.com/ch-201
Characteristics of Lewis acids
Interpretation of hardness
Hard acid–base interactions are predominantly electrostatic; soft acid–base interactions
are predominantly covalent.