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https://doi.org/10.1007/s10586-018-1900-1
Abstract
For the inaccurate data predicting problem of the actual attainable maximum charge and discharge power of the lithium-ion
battery in practice for unmanned vehicles in the process of running, a combined constraint intelligence algorithm is proposed
based on the result of SOC, the battery voltage and the battery current. In view of the hysteresis characteristics of lithium-ion
battery presented in the charge and discharge process, a second-order RC hysteresis model was proposed in this paper. In
addition, we used the cubature Kalman filter algorithm to estimate the state of charge (SOC) of the battery based on this
model, which reduced both the model error and algorithmic error in the SOC estimation significantly. It is also of great
importance to accurately predict the state of power (SOP). Then the result of SOC, the battery voltage and the battery current
were settled as constraints to predict the actual attainable maximum charge and discharge power of the lithium-ion battery in
practice. Compared with the pulse discharge/charge test method and he hybrid pulse power characterization (HPPC) method,
the combined constraint intelligence algorithm proposed in this paper is of high accuracy in the process of predicting the
battery power.
Keywords Unmanned vehicle · Combined constraint intelligence algorithm · Lithium-ion battery · Power prediction ·
State of power · Hysteresis characteristics
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Cluster Computing
3.6 8
USABC test method is slightly less than the actual value,
6
and the test results are static peak power [11]. Japan Elec- 3.4
4
Voltage (V)
Current (A)
tric Vehicle Association (JEVS) power density test method 2
3.2
can get the charge and discharge capacity of batteries under 0
different current respectively for 10 s [12]. However, it does 3 -2
not take the power capability changes of battery into account 2.8
-4
Voltage (V)
Current (A)
3.4
However, this method is not suitable for estimating the peak 2
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Cluster Computing
3.4 -3
2 x 10 1
1.6
1.2
0.8
3.35
Voltage (V)
0.4
Error
SOC
0 0.5
-0.4
-0.8
3.3 -1.2
voltage error
-1.6 SOC
hysteresis main loop -2 0
hysteresis minor loop 0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2
5
3.25 Time (s) x 10
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
SOC Fig. 5 Error of hysteretic characteristics to SOC estimation
3.35
R1 R2
It
C1 C2
R0
OCV (V)
3.3
U1 U2
Ut
Uoc˄SOC ˅
hysteresis major loop
hysteresis minor loop
hysteresis model loop
3.25
0.2 0.3 0.4 0.5 0.6 0.7 0.8
Fig. 6 Equivalent circuit of second-order RC hysteresis model
SOC
Capacitance (F)
R2 5
0.012
ally tend to the OCVC of hysteresis major loop and during the C2
0.01 4
discharge process gradually tend to the OCV D of hysteresis 0.008 3
minor loop. Equation (1) is shown as below: 0.006
2
0.004
d OC Vc 0.002 1
d OC V + k (OC Vc − OC V ) , d S OC
≥0 0
=
0
d S OC dt 0 80 160 240 320 400 480 560 640 720 800
d OC Vd
d S OC d S OC + k (OC V − OC Vd ) , d S OC
dt <0 Time (s)
(1)
Fig. 7 Parameters identification curve
where k stands for the adjustment factor. Aiming at the bat-
tery chosen in this paper, k is set to 10.
In order to verify the accuracy of the above models, the
paper substitutes the data obtained from the hysteresis minor Uoc (SOC) represents the OCV of the lithium-ion battery
loop into (1), and the results are shown in Fig. 4. Error of to describe the hysteretic characteristics of the battery. The
voltage calculation results of hysteresis model and voltage terminal voltage Ut , the terminal current It , the internal resis-
error of the charge-discharge cycle test are shown in Fig. 5, tance R0 , Re , Ce and Rd , Cd are set to describe the static
where we can see the maximum voltage error is 0.0016 V. characteristics of the battery.
This model output is substantially close to the true value of The parameters of lithium-ion batteries change along with
the lithium-ion battery OCV. For further accuracy improve- the battery SOC during charging and discharging. In order to
ment, k can be segmented. improve the accuracy of the model, this paper uses recursive
In view of the accuracy, complexity and battery type, this least-squares algorithm to identify the parameters values of
paper uses the equivalent circuit of second-order RC hystere- the equivalent circuit model dynamically. The result of iden-
sis model to carry out SOP prediction as shown in Fig. 6. tification based on the pulse discharge data is shown in Fig. 7.
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⎛ ⎞ ⎛ ⎞
3 Multi-parameter SOP estimation based on S OC(m + 1) 10 0
combined constraint intelligence ⎝ Ue (m + 1) ⎠ = ⎜ T
⎝ 0 e− τ e 0
⎟
⎠×
algorithm Ud (m + 1) 00 e
T
− τd
⎛ ⎞ ⎛ ηT ⎞
Power prediction method proposed in this paper consid- S OC(m) − Qn
ers limitations of SOC of electric vehicles in service and ⎝ Ue (m) ⎠ + ⎜ T ⎟
⎝ R e (1 − e− τ e ) ⎠ It (m) (5)
battery cut-off voltage to the maximum peak power. The Ud (m) T
Rd (1 − e− τ d )
maximum allowable charge and discharge currents are calcu-
lated respectively from the SOC in current state and battery Ut (m)Uoc (S OC(m))Ue (m)Ud (m)R0 It (m) (6)
cut-off voltage, by using binary searching algorithm. The
maximum charge and discharge power is predicted by the We can use the discrete model above to predict the terminal
analyze results of the currents. voltage of the battery. Assuming discrete form of t can be
Battery SOC estimation should be done before bat- expressed as N sampling periods, the terminal voltage of next
tery peak power prediction [19,20]. Generally, SOC can t time is given by Eq. (7):
be obtained through the Kalman filter algorithm [21]. But
the accuracy of SOC estimation would affect the value of v [m + N ] = U OC V (S OC(m + N ))
maximum charge and discharge current [22,23]. So for the − Ue (m + N ) − Ud (m + N )) − R0 It (m + N ) (7)
proposed second-order RC hysteresis model of lithium-ion
battery, the cubature Kalman filtering algorithm is utilized It is assumed that the system input, charge and discharge
instead, which has better non-linear approximation and sta- currents are kept fixed within the T sampling periods, which
bility of filtering performance in comparison with the Kalman are expressed as It (m) = It (m+1) = It (m + N ). In order
filter algorithm. Moreover, it can greatly improve the accu- dis,volt
to seek the maximum discharge current i max,k , taking the
racy of SOC [24,25]. limitation of the discharge cut-off voltage into account, the
Assuming battery charges or discharges with a constant equation should be met Eq. (8):
current i k within a given time t, in this period t, the SOC
of the k th battery cell can be expressed as Eq. (2):
U OC V (S OC(m + N )) − Ue (m + N )
− Ud (m + N ) − R0 It (m + N ) − vmin = 0 (8)
ηn t
S OCk (t + t) = S OCk (t) − i k (t) (2)
Qn chg,volt
Similarly, the minimum charge current i min,k , taking the
where C, ηi , SOCk (t) and SOCk (t +t) stand for capacity, the limitation of the charge cut-off voltage into account, the equa-
coulombic efficiency of battery, the SOC of the k th battery tion should be satisfied Eq. (9):
cell currently and t later. Assuming charge efficiency ηi =
1, discharge efficiency ηi = η ≤ 1. If the limitation of SOC U OC V (S OC(m + N )) − Ue (m + N )
is set to SOCmin ≤ SOCk (t) ≤ SOCmax , SOC is no less − Ud (m + N ) − R0 It (m + N ) − vmax = 0 (9)
than SOCmin after discharged with the maximum discharge
current for t. Likewise, the SOC is no greater than SOCmax The state variable xk (t) is linearized within m ≤ t ≤ m + N
after charged with the maximum charge current for t. and the state equation is specified as (10), where coefficient
Assuming the battery, For each battery cell, which only con- matrix A and B are given by Eq. (11):
sidered SOC limitation, the maximum discharge current and
the minimum charge current are expressed as Eqs. (3) and (4). xk [m + 1] = Axk [m] + Bi k [m] (10)
where discharge current is set to positive, charge current is The current is maintained in prediction period m ≤ t ≤
set to negative (the maximum charge current represents the m + N , thus we can get Eq. (12):
minimum negative value in the algebraic).
⎛ ⎞
State equation and observation equation of the system can −1
N
be derived in (5) and (6), where the SOC is treated as a state xk [m + N ] = A N xk [m] + ⎝ A N −1− j B ⎠ i k [m] (12)
variable. j=0
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3.7
With the purpose of obtaining the maximum discharge cur- 5.9
rent and the minimum charge current of the battery, we need 3.5 4.9
Current (A)
Voltage (V)
to solve the Eqs. (8), (9) and (10) with binary search algo- 3.9
3.3
rithm. 2.9
dis,soc dis,volt
min(min i max,k , max i max,k ) , and the minimum charge
k k voltage curve
11
chg,soc chg,soc
current can be derives as: i min, k = min(min i max,k , max 3.3 current curve
k k 8
chg,volt
i max,k ).
Voltage (V)
Current (A)
3.2
The peak power of the battery pack in dynamic work can 5
be given by (13) and (14) with the peak current calculated by 3.1
2
the formulas above:
3 -1
0 3000 6000 9000 12000 15000
n n 18000
dis
Pmax = dis
i max vk (t + t) ≈ dis
i max vk (n + N ) Time (s)
160
Power (W)
n n
chg chg chg 140
Pmin = i min vk (t + t) ≈ i min vk (n + N )
120
k=1 k=1
n 100
chg U OC V (S OC(m + N )) − Ue (m + N )
= i min vk chg
80 constraint intelligence algorithm
−Ud (m + N ) − R0 i min 60
HPPC method
k=1 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
(14) SOC
(a)
70
Basing on the second-order RC hysteresis model of the bat- maximum discharge current
60
tery, the real-time prediction of the maximum charge and
discharge power can be obtained with combined constraint 50
Current (A)
10
Time (s)
In order to verify the accuracy of the proposed method for pre- (b)
diction of the peak power, the paper chooses the lithium iron
phosphate battery LP2770102AC of Tianjin Lishen Com- Fig. 9 Power and current in pulse discharge test. a Comparison of max-
imum discharge power, b comparison of maximum discharge current
pany to implement the pulse charge and discharge tests under
room temperature.
First, the charge and discharge tests of the battery are oper- The comparison of discharge power and the maximum
ated with constant-current pulse. This method can verify the discharge current of these two prediction methods are shown
prediction of actual maximum discharge and charge power in Figs. 9 and 10.
under static work environment. The voltage and current of Figure 9a is the comparison of the maximum discharge
constant-current pulse are depicted in Fig. 8. power of the battery discharge test, and b gives the maximum
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Cluster Computing
250 3.6 50
constraint intelligence algorithm current curve
voltage curve
200
HPPC method
3.4 30
Voltage (V)
Current (A)
Power (W)
150 3.2 10
100 3 -10
50 2.8 -30
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 2.6 -50
0 2000 4000 6000 8000 10000
SOC
(a) Time (s)
40
to strong simultaneously.
30
Finally, we used the constant power discharge method
20 to check the accuracy of the peak power obtained from the
hybrid pulse discharge method and the proposed model. This
10
method makes a group of batteries of same type, perfor-
0
0 1 2 3 4 5 6 7 8 9 10
mance and aging condition. And then measures the constant
Time (s) x 10
4
power discharge performance in terms of battery SOC of
(b) 10%, 20%… 90%, 100% respectively under the constant
temperature 25 ◦ C . Take the 50% for example to illustrate
Fig. 10 Power and current in pulse charge test. a Maximum charge
power, b maximum charge current
the test procedure: charges the battery to 50% SOC and dis-
charges with constant power and makes the battery terminal
voltage and the duration of each discharging recorded. Dis-
discharge current obtained from the combined constraint charge range from the rating power and increase by an order
intelligence algorithm. As can be seen from the figure, the of magnitude which sustains for 10 s of each discharge cycle,
peak power decreases with further discharge process, mainly until the battery terminal voltage reaches the discharge cut-
because its capacity and terminal voltage reduction. At the off voltage, and the power at this time is the output peak
end of the discharge, peak power drops off rapidly resulting power of the battery. If the discharge duration of one certain
from a sudden increase of the battery internal resistance. It is power value is less than 10 s, the power value of last dis-
noted from the comparison that the results of HPPC method charge duration between the one no less than 10 s and the
nearly has no difference between the proposed method’s at one less than 10 s will be selected to discharge continually
the middle range of the SOC, where the difference is brought to meet the cut-off voltage and cut-off period requirements.
about by the internal resistance or the accuracy of the battery Data obtained by the constant power discharge method is
model. However, at low and high SOC, the results obtained accurate, so that this method is often used to detect the accu-
from the HPPC is higher than the proposed method’s, racy of power prediction.
which shows the HPPC method does not take the limita- At present, power lithium-ion batteries are widely used
tion of the minimum SOC and the maximum current into in electric vehicles, where battery has dramatic change of
account. operating current. So the prediction of charge and discharge
As shown in Fig. 10a, which is similar to the discharge performance in dynamic environment is more significant
test, the charge power of HPPC is significantly higher than comparing with the static environment. This paper com-
the proposed method’s when the SOC > 90% resulting from pares and verifies the conventional hybrid pulse discharge
the absence of limitation of SOC and the maximum cur- method and the multi-parameter constraints power predic-
rent. In this case, the battery will be overcharged in terms tion methods under DST (Dynamic Stress Test) conditions
of large current, thus affects the battery life. As for the pro- DST condition has 5 test cycles, which consists of 14 steps
posed method, when the SOC is over 90%, the charge power of high-current charge and discharge process per cycle. Fig-
decreases to 0 promptly and protect the battery. Meanwhile, ure 11 shows the experimental process of terminal voltage
from the prediction of charge and discharge power, we can and terminal current of lithium-ion battery. The maximum
see the battery charge power and discharge power are con- discharge power and error of algorithm validation in DST
tradictory to each other. That is to say the SOC ranging from condition is depicted in Figs. 12 and 13.
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Cluster Computing
100
at this time.
(3) HPPC methods are widely used under static conditions
50
and prediction work environment without high accuracy
HPPC method
constraint intelligence algorithm requriment. For high accuracy, the internal resistance
0 constant power measurements
should be changed as the initial statement varies, which
0 2000 4000 6000 8000 10000 12000
Time (s) is neither of low computation or convenient to save as a
universal method. Therefore, in a dynamic work environ-
Fig. 12 Results of power in DST condition ment, it is necessary to utilizing a more accurate model
and at the same time taking more parameters constraints
0.02
HPPC method into consideration to predict the power.
0 constraint intelligence algorithm
-0.04
-0.06
-0.08
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