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FIITJEE INTERNAL TEST

IIT – JEE 2024

PHASE – IV (PET- 1) (MAIN)

(JR PINNACLE) (SET-A)


Time: 3 hours Maximum Marks: 300
INSTRUCTIONS: Test Date: 26.12.2022

Instructions to the Candidates


1. This Test Booklet consists of 75 questions.

Use Blue/Black ball Point Pen only for writing particulars. Use Pencil for all responses in OMR
sheet.
2. The question paper consists of 3 parts (Maths, Physics and Chemistry). Each part consists of
two sections.

3. Section I contains 20 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which Only One Option is correct.

4. Section II contains 5 Numerical type questions which have numerical answers.

Marking Scheme

5. For each question in Section I, you will be awarded 4 marks if you darken ALL the bubble(s)
corresponding to the correct answer(s) ONLY. –1 mark for wrong answer. In all other cases
zero (0) marks will be awarded.

6. For each question in Section II, you will be awarded 4 marks if you darken ALL the
bubble(s) corresponding to the correct answer(s) ONLY. In all other cases zero (0) marks
will be awarded.

Don’t write / mark your answers in this question booklet.


If you mark the answers in question booklet, you will not be allowed to continue the exam.

NAME:

ENROLLMENT NO.:

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PHYSICS
SINGLE CORRECT CHOICE TYPE (20)

1. Two particles of equal mass m at A and B are connected by a rigid light rod AD, lying on a smooth horizontal
table. An impulse J is applied at A in the plane of the table and perpendicular at AD. Then the velocity of
particle at A is:
J J 2J
(A) (B) (C) (D) zero
2m m m
2. ABC is a right angled triangular plate of uniform thickness. The sides are such that A
AB > BC as shown in figure I1, I2, I3 are moments of inertia about axis along sides
AB, BC and AC respectively. Then which of the following relations is correct?
I1 I3
4cm
(A) I1 = I2 = I3 (B) I2 > I1 > I3
(C) I3 < I2 < I1 (D) I3 > I1 > I2 B
3cm
C
I2

3. A rigid body can be hinged about any point on the x – axis. When it is hinged such that the hinge is at position
x, the moment of inertia I is given by I = 2x 2 − 12x + 27 . The x – coordinate of centre of mass is at x =
______.
(A) 3 (B) 0 (C) 9 (D) 3

4. A uniform rod AB of mass 1.6 kg and length 2m is hinged at point A and


other end is suspended by a vertical thread. If g = 10 ms–2 , Find the tension
in the thread, (in Newtons)

(A) 16 (B) 8 (C) 12 (D) None of these

5. A constant torque acting on a uniform circular wheel changes its angular momentum from A0 to 4A0 in
4 seconds. The magnitude of this torque is:
(A) 3A0/4 (B) A0 (C) 4A0 (D) 12A0

Space for rough work

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6. In the adjoining figure, a weight W is attached to a string wrapped round


a solid cylinder of mass M mounted on a frictionless horizontal axle at O.
If the weight starts from rest and falls a distance h, then its speed at that
instant is:
1
(A) proportional to R (B) proportional to
R
1
(C) proportional to (D) independent of R
R2

7. Four rods are arranged as square frame. Each rod has length l
and mass m . Find the moment of inertia of the arrangement about I1 I4
the axis shown (in the plane of the system).

2 2 10 2
(A) ml (B) ml I2
I3
3 3
8 2
(C) 3ml 2 (D) ml
3
8. A uniform rod is hinged at its lower end and is allowed to rotate in vertical plane. Rod is given an angular
velocity ω in its vertical position as shown in figure. The value of ω for which the force exerted by the hinge on
rod is zero in this position is

g 2g g 3g
(A) (B) (C) (D)
L L 2L L

Space for rough work

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9. Uniform rod AB is hinged at the end A in a horizontal position as shown in the figure. The other end of the rod
is connected to a block through a massless string as shown. The pulley is smooth and massless. Masses of
the block and the rod are same and are equal to ‘m’. Acceleration due to gravity is g. The tension in the thread
just after release of block from this position are

3mg 5mg mg 7 mg
(A) (B) (C) (D)
8 8 8 8
10. One end of a uniform rod of length l and mass m is hinged at A. It is released from rest from horizontal
position AB as shown in figure. The force exerted by the rod on the hinge when it becomes vertical is:

3 5
(A) mg (B) mg (C) 3 mg (D) 5 mg
2 2

11. A rod of length l slides down along the inclined wall as shown in figure. At the instant shown in figure, the
speed of end A is v, then the speed of B will be:

v sin β v sin α v cos β v cos α


(A) (B) (C) (D)
sin α sin β cos α cos β

Space for rough work

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12. A particle of mass 2kg located at the position (iˆ + ˆj ) m has a velocity 2 (+iˆ − ˆj + kˆ ) m/s. Its angular
2
momentum about z-axls in kg-m /s is:
(A) zero (B) +8 (C) 12 (D) – 8

13. A particle of mass m is projected with a velocity v making an angle of 45° with the horizontal. The magnitude
of the angular momentum of the projectile about the point of projection when the particle is at its maximum
height his:
3 3 3
(A) zero (B) mv /(4 2 g) (C) mv /( 2 g) (D) m 2 gh

14.

15.

Space for rough work

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16.

17.

18.

Space for rough work

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19. A light string is wound several times around a cylinder of mass M


and radius R. The free end of the string is attached to a fixed
point and the cylinder is held so that the part of the string not in
contact with it is vertical as shown in the figure. If the cylinder is
let go, the acceleration of centre of cylinder is N(2g/3). Value of N
is:
(A) 2 (B) 3
(C) 6 (D) 1

20. A spool of mass M and radius 2R lies on an inclined plane as shown in figure. A
light thread is wound around the connecting rube of the spool and its free end
carries a weight of mass in. Find the value of m so that system is in equilibrium

(A) 2 M sin α (B) 2 M cos α (C) 2 M tan α (D) 2 M cot α

NUMERICAL TYPE QUESTIONS (5)

21. A particle of mass m = 5 units is moving with a uniform speed v = 3 2 m in the XOY plane along the line
Y= X + 4. The magnitude of the angular momentum about origin is N*10 unit. Here N is
2
22. The moment of inertia of a body about a given axis is 1.2 kg-m . Initially, the body is at rest. Body is subjected
to an angular acceleration of 25 radian/sec2. The time taken by the body (in seconds) to attain a rotational KE
of 1500 Joules is

23. A lamina is made by removing a small disc of diameter 2R from a bigger disc of
uniform mass density and radius 2R, as shown in the figure. The moment of inertia
2R
of this lamina about axis passing through O and P is I0 and IP respectively. Both
IP P
O 2R
these axes are perpendicular to the plane of the lamina. The ratio to the nearest
IO
integer is

24. A disc is rotating with an angular velocity ω0 . A constant retarding torque is applied on it to stop the disc. The
ω0
angular velocity becomes after 15 rotations. How many more rotations will it make before coming to rest?
2
25. A uniform rod of mass m (2 kg) and length l is suspended by
means of two light. Inextensible strings as shown in the figure.
Tension in one string immediately after the other string is cut is
( g = 10 m/s2)

Space for rough work

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CHEMISTRY
SINGLE CORRECT CHOICE TYPE (20)
26. Least acidic among the following is
(A) CH3 COOH (B) CH2Cl COOH (C) CHCl2 COOH (D) CCl3 COOH

27. The most stable carbocation among the following is

(A) CH3 CH2 (B) CH2 CHO


+
CH CH3
(C) (D) CH3 CH CH3
H3C

28. Match the following:

COLUMN–I COLUMN–II

delocalization of π and
(A) Carbocation (I)
non bonding electrons

(B) Resonance (II) planar

(C) Free radical (III) pyramidal

(D) Carbanion (IV) paramagnetic

Correct matching is

(A) A – I, B – II, C – III, D – IV (B) A – II, B – I, C – IV,II ,D – III


(C) A – IV, B – III, C – II, D – I (D) A – II, B – I, C – III, D – IV

29. In which of the following case/s second canonical form makes the greater contribution (stable) to the
resonance hybrid?
O O CH3 CH3

(A) (B)
or or

O O
(C) Both the (A) & (B) (D) H3C or H3C
O O

Space for rough work

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30. Which of the following free radicals is most stable ?


• • •
(A) ( CH3 )3 C• (B) ( CH3 )2 CH (C) CH3 − CH2 (D) CH3

31. Decreasing order of –I power of groups (i) CN (ii) NO2 (iii) CHO (iv) F is :
(A) i> ii > iii > iv (B) ii > I > iii > iv (C) I > ii > iv > iii (D) iv > ii >i> iii

32. Among the following the most acidic compound is :


(A) HCOOH. (B) CH3COOH (C) CH3CH2COOH. (D) CH3 ( CH2 )2 COOH

33. Which of the following is not an electrophile?


(A) NH3 (B) BF3 (C) +NH4 (D) :CX2

34. Among the following which is correct?

(A) NO2 CN Cl
OH OH > OH > OH
>
O O O O
(acidic strength)

CH3

(B) CH3 IUPAC name is 2-ethyl-3-methylhex-1-en-4-yne

H3C CH2
.

(II)
NH2 O
F CO 2H

(C) In H3C the most basic nitrogen is (IV)


N N(I)
(III)
HN F
(IV)
CH3 CO 2Me

(D). All of these

35. Which of the following will allow free rotation about double bond? (arrows indicate the bond to be considered)

(A) (B) (C) (D)

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36. The increasing order of the acidic nature of


OH OH OH OH
NO2 CH3

NO2
NO2
I II III IV

(A) IV<II<I<III (B) IV<II<III<I (C) IV<I<II<III (D) II<IV<III<I

37. Which of the carbocation is least stable ( or difficult to form) ?


+
+
+
((A) ((B) ((C) ((D) +

CH3 CH3 CH3 CH3

38. Identify the compound that exhibits tautomerism


(a) 2-butene (b) Methanal
(c) 2-Pentanone (d) 2,2-dimethylpropanal

39. Choose the incorrect statement about free radicals


(A) They are formed by homolytic fission of covalent bonds
(B) They follow the same stability order as carbocations
(C) They are paramagnetic in nature
(D) They are diamagnetic species

40. Which of the following carbocation is more stable?

+ + +
C CH3 + C CH3 C CH 3
CH CH3
(B) CH 3
(A) CH3 C 2 H5 (D)
(C)

41. Which of the following can exhibits tautomerism?

O CH3
O

(A) (B) H3C NO2 (C) Both (A) & (B) (D)

CH3
O

42. Consider the following compounds.

O
O OH
CHO
(I) (II) (III) (IV)
CH OH
CH2OH CHO
O
Choose correct statements from the following?

(A) I, III are chain isomers (B) I and II are tautomers


(C) III and IV are positional isomers (D) I and IV are tautomers

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43. Consider the following compounds. “Which of the following statements are incorrect”.

N N
H NH2
I II III

(A) III is less basic than Cyclohexyl amine (B) II is more basic than I and III
(C) III is more basic than I (D) II is more basic than ethyl amine

44. In which of the following pairs, the first one is more stable than second?
CH2 CH2

(A)
,

CH3 Cl

(B) H3C CH CH2 CH3 , H3C CH CH2 NO2


H 3C C CH3 H3C C CH3
(C) ,
OH NO 2
(D) All of these

45. Incorrect order of basic strength of given amines is……….( Me= methyl , Et = Ethyl )
(A) Me2NH > MeNH2> Me3N > NH3 (in aqueous solution)
(B) Et2NH > Et3N > EtNH2> NH3 (in aqueous solution)
(C) Me3N > Me2NH > MeNH2> NH3 (gas phase)
(D) Me2NH > Me3N > MeNH2> NH3 (in gas phase)

NUMERICAL TYPE QUESTIONS (5)

46. Sum of degree of unsaturationof C4H8N2 and C4H8O is?

47. Number of chain isomers possible for n–Hexane is

48 The most basic nitrogen atom in the following molecule


H2 N C NH2
3 1
O

H2C NH2
2

49. How many of the following are more acidic than phenol,
OH

,
OH OH OH OH OH
NO2

, , , ,

NO2 OCH3 CH3 Cl NO 2

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50. Number of compounds/species which are aromatic

H
CH 2 N
N

(I) (II) (III) (IV)


N
N O
H
H

CH2
(V) (VI) (VII) + (VIII)
N N N
H
H

+ H

(IX) (X) (XI) (XII)

MATHEMATICS
SINGLE CORRECT CHOICE TYPE (20)

log(1 + ax) − log(1 − bx)


51. The function f(x) = is not defined at x = 0. The value which should be assigned to f at
x
x = 0, so that it is continuous at x = 0 is
(A) a – b (B) a + b (C) log a + log b (D) none of these

x −1
52. The function ƒ(x) = for x ≠ 1, ƒ(1) = 0 at x = 1 is
1 + e1/( x −1)
(A) continuous (B) discontinuous (C) not determined (D) none

sin2 ax
53. If ƒ(x) = for x ≠ 0, ƒ(0) = 1 is continuous at x = 0 then a =
x2
(A) 0 (B) 1 (C) ± 1 (D) 2

x− | x |
54. Let a function ƒ be defined by ƒ(x) = for x ≠ 0 and ƒ(0) = 2. Then ƒ is
x
(A) continuous no where (B) continuous everywhere
(C) continuous only at x = 1 (D) continuous for all x except x = 0

log(1 + x + x 2 ) + log(1 − x + x 2 )
55. Let ƒ(x) = , x ≠ 0, Then the value of ƒ(0) so that ƒ is continous at x = 0 is
sec x − cos x
(A) 1 (B) 0 (C) 2 (D) none

(4 x − 1)3
56. The value of p for which the function ƒ(x) = for x ≠ 0;
x  x2 
sin log  1 + 
p  3 
3
ƒ(x) = 12 (log 4) for x = 0 is continuous at x = 0 is
(A) 2 log 4 (B) 4 log 4 (C) 2 (D) 4

57.
is differentiable at
A) All points B) No point
C) All points except two D) All points expect at one point

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x
58. The set of all point, where the function f(x) = is differentiable, is
(1 + x )
(A) (–∞, ∞) (B) (0, ∞)
(C) (–∞, 0)∪(0, ∞) (D) none of these

 3 
59. f (x) =   is, ([.] denotes greatest integer function and {.} denotes fractional part)
 2 + { x} 
(A) continuous as well as differentiable in R (B) continuous but not differentiable in R
(C) increasing (D) decreasing

 ax 2 + b , 0 ≤ x ≤1

60. Consider two function y = f(x) and y = g(x) defined as f ( x ) =  2bx + 2b , 1 < x ≤ 3 and
( a − 1) x + 2a − 3 , 3 < x ≤ 4

 cx + d , 0 ≤ x ≤ 2
2


g ( x ) dx + 3 − c , 2 < x < 3
x2 + b + 1 , 3 ≤ x ≤ 4

. f(x) is continuous at x = 1 but not differentiable at x = 1, if
A) a = 1, b = 0 B) a = 1, b = 2 C) a = 3, b = 1 D) a and b are integers

 ax 2 + b , 0 ≤ x ≤1

61. Consider two function y = f(x) and y = g(x) defined as f ( x ) =  2bx + 2b , 1 < x ≤ 3 and
( a − 1) x + 2a − 3 , 3 < x ≤ 4

 cx 2 + d , 0 ≤ x ≤ 2

g ( x ) dx + 3 − c , 2 < x < 3
x2 + b + 1 , 3 ≤ x ≤ 4

g(x) is continuous at x = 2, if
A) c = 1, d = 2 B) c = 2, d = 3 C) c = 1, d = - 1 D) c = 1, d = 4

 ax 2 + b , 0 ≤ x ≤1

62. Consider two function y = f(x) and y = g(x) defined as f ( x ) =  2bx + 2b , 1 < x ≤ 3 and
( a − 1) x + 2a − 3 , 3 < x ≤ 4

 cx + d , 0 ≤ x ≤ 2
2


g ( x ) dx + 3 − c , 2 < x < 3
x2 + b + 1 , 3 ≤ x ≤ 4

If f is continuous and differentiable at x = 3, then
1 2 2 1 1 2 1
A) a = − , b = B) a = ,b=− C) a = , b = − D) a = 2, b =
3 3 3 3 3 3 2

 3 2
 2 sin 2x , if x = 0
 x
63. If the function f (x) =  0 , if x = 2 is continuous at x = 0, then the value of K is
 x 2 − 3x + K
 , if x ≥ 0, x ≠ 2
 1 − 3x 2
(A) 4 (B) 5 (C) 6 (D) none of these

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tan x
64. The set of all points of discontinuities of f (x) = is
x(x − 3)(x − 5)
 π 
(A) {0, 3, 5} (B) (2n + 1) : n ∈ Z
 2 
 π 
(C) {0,3,5} ∪ (2n + 1) : n ∈ Z (D) none of these
 2 

x −1
65. The function ƒ(x) = for x ≠ 1, ƒ(1) = 0 at x = 1 is
1 + e1/( x −1)
(A) continuous (B) discontinuous (C) not determined (D) none

 (4 x − 1)3
 x≠0
 x  x2 
66. The value of p for which the function f ( x ) =  sin log  1 + 
p  3 

 3
 12 ( log4 ) , x=0
is continuous at x = 0 is
(A) 2 log 4 (B) 4 log 4 (C) 2 (D) 4

 sin x if x ≤ 0
 x 2 + a if 0 < x < 1

67. f ( x) =  is continuous on R, then (a, b) =
 bx + 3 if 1 ≤ x ≤ 3
 −3 if x > 3
(A) (0,–2) (B) (–2,0) (C) (–1, –2) (D) (–2, –2)

68. f(x) = [x] + |x–1| then f(x), (where [.] denotes greatest integer function) is
(A) Continuous x = 0 (B) not differentiable at x = 0. 5
(C) discontinuous at x = 2 (D) differentiable at x = – 2

69. The set of all points where the function f(x) = x|x| is differentiable is
(A) (–∞, ∞) (B) (–∞, 0) ∪ (0, ∞) (C) (0, ∞) (D) [0, ∞]

  πx 
sin , x <1
70. The function f(x) =   2 
| 2x − 3 | [x], x ≥1

(A) is not continuous at x = 1
(B) is differentiable at x = 1
(C) is continuous at x = 1 but not differentiable at x = 1
(D) none of these

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NUMERICAL TYPE QUESTIONS (5)

(3 / x 2 )sin 2x 2 when x < 0


 2
 x + 2x + c 1
71. If ƒ(x) =  2
when x ≥ 0, ≠ then in order that ƒ be continuous at x = 0, the value of c is
 1 − 3x 3
 0 when x = 1/ 3

1 − cos 4x
72. If f(x) = for x ≠ 0; f(x) = a for x = 0 is continuous at x = 0, then a =
x2

(27 − 2x)1/ 3 − 3
73. The value of ƒ(0) so that the function ƒ(x) = is continuous at x = 0, is
9 − 3(243 + 5x)1/ 5

1 − e1 / x
74. The number of points of discontinuity of the function f(x) = are /is
1 − e−1 / x

75. The function (x2 – 1)|x2 – 3x + 2| + cos (|x|) is not differentiable at

Space for rough work

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