Name: .. Centre/Index No: School. Signature. PS25/1 CHEMISTRY Paper 1 July/August 2% hours WAKISSHA JOINT MOCK EXAMINATIONS Uganda Advanced Certificate of Education CHEMISTRY Paper I 2 hours 45 minutes Instructions to Candidates + Attempt all questions in section A and any six questions from section B. * All questions are to be answered in the spaces provided. + A Periodic Table with reievant atomic masses is supplied at the end of the paper. * Mathematical tables (3 figures) and non-programmable silent scientific calculators may be used. Mlustrate your answers with equations where applicable. Molar gas volume at s..p = 22.4 dm? For Examiner's Use Only LV} 243) 4) 5/6} 7-] 8] 9 | tof} ar] a2] a3} as} as | te | 17 | vot £ WAKISSIUA Joo Mock Esuminations 2 Turn Over 7 ‘Scanned with CamScannerCTION A (46 MARKS) this section. Attempt all question: = 1. Peroxodisulphate ions oxidise lodide ions according to the equations $205" (aq) + 217 (aq) —> 250%-(aq) + Ga) The rate equation for the redox reaction is given by Rate = [8,087] [I>] a (@ Ste twor which the rate of reaction above ca. F determived. (01 mark) (b) State the effect of the following changes on the rate. In each case give # reason for your answer. (Addition Iron (11) sulphate solution to the reaction mixture. ' (1% marks) G& of peroxodisulpha'e iant while the goncentrat3zn of Todide ions is halved. (1% marks) (iii) Using ice-cold solutions of both reactants. (1% marks) Complete the following equations and in each case name the mais organic product. 9 I (a) CH, C— NH, + WaOBr(aq) — NaOH(aq) Name of the product. (1% marks) ':cess NaBr(s)/ Conc. H.SO. (b) os CH ea OW, Cone. KMn0, / H2S0,, (©) (Clly)26 = CHER, a Name of the prowuct(s)..... © WAKISSILA Joint Mock Examinations? Scanned with CamScanner‘A Manganese is a transition element which forms stable compounds in oxidation states 42, +4 and +7. (@) Write the formula of the oxide of manganes' in oxidation stat (1% marks) (i) #2: (ii) 44 i) +7: n that takes place between: id. (01 mark) (b) Write an equation for th (i) oxide in +2 and dilute sulphu “(01 mark) (i) hot concentrated hydrochloric acid and the oxide in +4. (iii) oxide in +7 and dilute sodium: hydroxide solution. (01 mark) Methanoic acid in an organic solvent such as benzene dimerises. (a) State the; (type of bonds between the acid molecules in benzene. (4 mark) (ii) observed relative formula mass of methanoic aci (b) The vapour pressure of pure benzene at 30°C is 122mmHlg. Calculate the vapour pressure of a solution containing 0.092g of methanoic acid in 156g of benzene at 30°C. (2% marks) () Cémpare your answer in (b) above with the vapour pressure of pure benzene a 30°C. State the reason for your answer. (1% marks) Ammonium sulphate reacts with water as shown below. NH} (aq) + 1,00) — NH,(aq) + Hj0*(aq) The pH of an aqueous solution Of ammonium sulphate was found to be 6.24 at 25% Turn Over {0 WAKISSHA Joint Mock Examinations 2 3 Scanned with CamScannerCalculate the; (@)— @ concentration of hydroxonium ions in the solu (A marks) oe , (i) concentration of gdm? of ammonium sulphate in the solution. °C is 1.78 x 107$ moldm™*) (03 marks) (6) (i) _State what would happen to the pH of the solution js (a) if an equimolar solution of aqueous ammonia is added to it. ark) wo jive a reason for your answer in b (i): (1 mark) 6. (a) Define the term bond dissociation energy. (b) The bond energies of; C = 0, 463 KImol™* respectively. Calculate the enthalpy of the reaction. are 799, 391,615 and i NOH wv CH;COCH; + H,NOH ———> CH3C-CH3 + 1,0 (03 marks) ‘OWAKISSHIA Joint Mock Examinations _2 Scanned with CamScannerHOC, HCIO,, HCIO, and HCIO, th of the oso acids varies with oxidation state of Chlorine forms oxo (a) State how chi (01 mark) (6) Explain your answer in (a) (03 marks) (©) A solution containing HClO, was added to 1M sulphuric acid followed by Iron (U) sulphate solution. (1% mark) (i) State what was observed. (ii) Write an equation for the redox reaction that takes place. State what would be observed and write an equation for the reaction that would take place when each of the following substances are mixed. (@) Diethylamine and ice-cold: sodium nitrite in the presence of concentrated hydrochloric acid. (1% marks) Observatior a Equation: (b) Sodium benzoate solution and dilute hydrochloric acid. Observation:. Equatior (6) Benzene dinzoniy'n chloride and pheno (02 marks) Observatior Turn Over ‘© WWAKISSHA Joint Mock Examinations _2 Scanned with CamScannerEquation: “on belong to group LV of the periouic table. te the: formulae of stable chlorides of Tin and Carbon. (1%4marks) 9. ‘above with water. (02 marks) (b) Excess acidified Tin (I) sulphate solution was added to potassium dichromate solution. (State what was observed. (01 marks) (i) Write an equation for the redox reaction that took place. (01 marks) ‘© WAKISSHA Joint Mock Examinations_2 Scanned with CamScanner10, ML. SECTION B (54 MARKS} Attempt any six questions from thi What is meant by the term cell constant? (OL mark) 0) wgnesium chloride placed between scotional area 1.25664 x 10-3mé and 0.12m apart is ‘. When 0.05M Barium chloride solution is placed in the 1¢ was 93.922. =1 same cell, the Calculate the; (i) cell constant. (01 mark) (ii) (03 marks) () (i) Compare the molar conductivities of the electrolytes in (b) above. (OL mark) (id lain your answer. (03 marks) sts of carbon, 77.78%, hydrogen 7.41%. tae rest being oxygen, When, 195° and 76Ommlg, the distillate contained $3.i8% by mass of Q. the sre of water is 639mm, ine 46s empirical formula of Q. (02 Turn Over © WAKISSHA Joint Mock Examinations? Fl Scanned with CamScanner(b) © 12. (a) Gi)~ molecular formula of Q (03 marks) Q burns with a sooty Mame and gives no observable change with neutral Iron (II) chloride solution, Q reacts with ethanoic acid to form a sweet fruity smelling compound, Write the; (structural formula and IUPAC name of Q. (01 mark) (i) structural formula of an isomer of Q which does not react with sodium metal. (mark) Q was added to concentrated hydrochloric acid in the presence of anhydrous Zine chloride and the mixture warmed, (State what was observed. (% mark) (ii) Suggest a suitable mechanism for the reaction Yat takes place. (02 marks) Na, Aland P belong to period 3 of the Periodic Table. Write the formulae of the chlorides of each element and state the type of bond in the table below.(314 marks) Element Na Al P Formula(e) of chloride ‘Type of bond (© WARISSHA Joint Mock Examinations_2 8 OO Scanned with CamScanner *(b) State the trend in melting points of the chlorides in (a) above. Explain your answer. (2% marks) (©) Describe the reaction of the chlorides of; Na, il - (03 marks) s can be effected. 13. (a) Use equations to show the following conv: (i) 1,1 —dichloropropene to CH3CH = CHOH (03 marks) oH Gi) Bu2yne to CH,C-COOH (03 marks) CH,CHy Turn Over ‘© AKISSIA Joint Mock Examinations? 9 Scanned with CamScannerbe how 2-bromoethanol can be synthesized from (b) Without using equations deseril (conn ethanoic acid. vely at 760mmttg while an 14, Ethanol and cyclohexane boil at 78.4°C and 80.8°C re: i Is at 64.8°C, azeotropit (43% ethanol and 57% cyclohexane) be (@) (i) Define the term azeotropic mixt (01 mark) (i) State the type of deviation from Raoult’s in the ethanol-cyclohexane system, Explain your answer, (2% marks) (b) (i) Sketch a well-labelled boiling point composition diagram for ethanol- cyclohexane system. (2% marks) ‘© WAKISSHA Joint Mock Examinations_2 10 Scanned with CamScanner© (v) (ii) State the products of fractional distillation of a liquid mixture containing (02 marks) 50% ethanol. State any two methods by which the azeotropic mixture of ethanol and cyclohexane can be separated. (01 mark) Name the reagent that can be used to distinguish between each of the following Pairs of substances. State what would be observed in each case. (i) NiCO3(s) and BaCO;(s) (02 marks) Reaget Observations. (ii) KI(@q) and NaBr(aq) (02 marks) Reagent: Observations. Explain why; - | i hhite precipitates is formed in a brown solutio ssivm iodide ©) ations adied to an aqueous solution of Copper (Il) chloride. (2¥4marks) (ii) there is no observable change when hydrogen sulphide gas is pie acidified Nickel (ID) sulphate solution. Oy Turn Over nl © WAKISSHA Joint Mock Examination’? Scanned with CamScanner16. (a) Thema spectrum of chlorine atoms is shown in the figure below. % % abundance 20. 35 37 Isotopic mass (Name the most abundant isotope of chlorine, (01 mark) (ii) Calculate the average rel: ive atomic mass of chlorine. (02 marks) (04 marks) (b) Explain why the mass spectrum of chlorine gas has three peaks. mine relative atomic (02 marks) (©) State two advantages of usin, mass of elements, ig the mass spectrometer to ¢: © WAKISSHA Joint Mock Examinations? ili Scanned with CamScanner17. Different masses of a non-volatile “om water at 101.325 Kpa and the freezi pound X were separately dissolved in 250g of ing point of the resultant solution measured Mass of X in 250g of w: 5.0 | 100 | 15.0 | 200 | 25.0 pe ot water(g) | 5.0 | 100 | 1 oon reezing point (°C) 0.1L | 0.22 32 | -0.43 | -0.54 (a) (i) Plota graph of f mass of X in 250g of water. (2% marks) peal Turn Over ations_2 a WAKISSIIA Joint Mack Eswminations, Scanned with CamScannerUse your graph to determine the; (ii) freezing point of pure water. (01 mark) (iii) _ molar mass of compound X. (eryoscopic constant of water is 1.86°C Kg" mol") (b) Explain why cryoscopy is not a suitable method to determine the molar mass of: (ionic compounds with water as a solvent. (1% marks) (ii) short chain carboxylic acids dissolved in hexane. (UA marks) CWAKISSHA Joint Mock Examinations_2 4 z 1 Scanned with CamScannerTHE PERIODIC TABLE 2T[s[e[7[s 1 t/a to it | tte : to] 4 9 [10 3.0 | 140] 160] 19.0 ]202 ay}istas |e | a7 | a8 af si| pe] s | cl ar 37.0| 281 | 31.0] 321 35-4] 409 26 | 27 | 28 | a9 | 30 | 31 | 32 | oo | 34 | 25 | 36 ve | Co| si] cu] ze] Ga] Ge] as] Se | Be] Ks) 509] 2.0] 549| 558] su9] 53.7] 63.5] 657] 69.7| 72.6] 749] 19.0] 79.9] 0.8 a}alol alas Nb | Mo] Te | Re | Re gn] s3| on9| 101 | 103 Ag| ca} in| sa] sv| te] f | Xe) toe] aaa | sus} an9 | 322 | 138} 127 | 131 BR w| 79] so] 1] 2 | | a | 55 | o6 7 La | ne] om] w | Re | oe] te | pe | au] He] TH) ro | BE) Po | At] He 135 | 199 178 | 181 | aus | 186 | 190 | 192 | 195 307 | 209 |q209)c101a22] 1 srlryy oy | oo] a Se] ee] te] by) be] Pr] Tm | yb | Lo op | tao | ta | tas | tesy] 152 | 150 | 182 | 159 | 162 | 165 | 267 | 169 | 179 | 175) wl] »| or 93 | 96 | 95 | 96 | 97 | 98 | 99 | 100] x01 | 102| 109] Ac] Th | Pa Bp | Pa fam |cm| ox | cr | Bs | ve | My No | Lo] 2 U cin] 232 | 231 | 238 | 237 [een] aes|can| aan} 251 |esojasnicso}esa) 1.) \ingieates atomic number. \ 2 HE indicates relative atomic mass, 10 END 5 WAKISSIA Joint Mock Examinations. 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