DAILY PRACTICE SHEET-10 CLASS – XII [CHEMISTRY] CHAPTER – CHEMICAL KINETICS

VINAY GUPTA –B1 JANAKPURI SHAHGANJ AGRA - 7302699469 , 9412161447,8958541623

TOPIC :- DETERMINATION OF ORDER OF REACTIONS

Q.1 Fill in the blanks :-
(i) In first order reaction , change in unit of concentration does not alter the value of ……………..
(ii) A plot of log [A] vs t is a ………………..with a slope equal to …………………….
(iii)Half life period of a …………order reaction ………….on the concentration of the reactants
Q.2 Name the order of reaction which proceeds with a uniform rate throughout.
Q.3 If the half life period of a first order reaction is 69.3 s. What is the value of of its rate constant [0.01s-1]
Q.4 A first order reaction is 50% completed in 1.26 × 1014 s. How much time would it take for 100%
completion?
(i) 1.26 × 1015 s (ii) 2.52 × 1014 s (iii) 2.52 × 1028 s (iv) infinite .
Q.5 For the reaction R → P, a graph of [R] against time is found to be a straight line with negative slope.
What is the order of reaction?
a) Second order b) Third order c) First order d) Zero order.
Q.6 Define the following terms: a) Half-life of a reaction(t½) b) Rate constant(k) .
Q.7 Time required to decompose SO2Cl2 to half of its initial amount is 60 minutes. If the decomposition is
a first order reaction, calculate the rate constant of the reaction.
Q.8 The rate constant of a reaction of zero order in R is 0.0030 mol L – 1 s – 1 . how long will it take for the
Initial concentration of R to fall from 0.10 M to 0.075 M . [8.3 s]
– 1
Q.9 The rate constant of a zero order reaction is 0.25 Mh . what will be the initial concentration of the
reactant if after 30 minutes its concentration is 0.075M? [0.2M]
Q.10 First order reaction is found to have a rate constant, k = 5.5x10 -14 /s. find the half-life . [1.26x1014 s]
Q.11 Show that in the first order reaction, time required for completion of 99.9% is 10 times of half life of
the reaction.
Q.12 Three-fourth of a reaction is completed in 32 minutes. What is the half life period of this reaction ?
[16 min]
Q.13 A reaction which is first order with respect to ‘A’ has rate constant 6 min-1. If we start with [A] = 0.5
mol L-1, when would [A] reach the value of 0.05 molL-1 ?[0.383 min]
Q.14 Time for half change for a first order reaction is 25 min.What time will be required for 99%
Reaction ? [166.16 mins.]
Q.15 The rate constant for first order reaction is 60/s. How much time will it take to reduce the
concentration of the reaction to 1/10 of its initial value ?[ 3.38 x 10-2 s]
Q.16 For a first order reaction, calculate the ratio between the time taken to complete ¾ of the reaction
and the time taken to complete half of the reaction. [2]
Q.17 Show that time required for the completion of 99% of the first order reaction is twice the 90% of
completion of the reaction.
Q.18 The half life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood
had only 80% of the 14C found in a living tree. Estimate the age of the sample.[1845 Years]
Q.19 The rate constant of a first order reaction is 6.9 X10-3s-1 . How much time will it take to reduce the
initial concentration to its 1/8th value?
(a) 100 s (b) 200 s (c) 300 s (d) 400 s
Q.20 A reaction proceeds by first order, 75% of this reaction was completed in 32 min. The time required
for 50% completion is
(a) 8 min (b) 16 min (c) 20 min (d) 24 min
Q.21 Point out the wrong statement:
For a first order reaction
(a) time for half-change (t1/2) is independent of initial concentration
(b) change in the concentration unit does not change the rate constant (k)
(c) time for half-change × rate constant = 0.693
(d) the unit of k is mole–1 min–1