1 .

The rate of a reaction may be expressed as the disappearance of reactants with respect to time. Student Response Value 1. False 2. Score: True 1/1 100% Correct Answer Feedback

2 .
The rate law for the reaction 3A C is Rate = 4.36 102 L mol1 hr1[A]2 What is the half-life for the reaction if the initial concentration of A is 0.250 M? Student Response Value A. 15.9 hr B. 0.0629 hr 0% Correct Answer Feedback

C. 91.7 hr D. 23.9 hr E. 0.0109 hr Score: 0/1

3 .
Refer to the Figure below and estimate the instantaneous rate of the ozone decomposition to O2 reaction at 40 hours into the reaction, in atm/hr.

Student Response Value A. 1.94 B. 38.5 C. 0.263 0%

Correct Answer

Feedback

D. 0.0102 E. 1.05 Score: 0/1

4 .
Initial rate data below were obtained for the following reaction:

A (g) + 2 B (g) C (g) + D (g)

What is the rate law for the reaction? Note: The "?" in the rate values should be "x" (times).

Student Response Value A. rate = k [A] B. rate = k [A][B] C. rate = k [A]2[B] 100%

Correct Answer

Feedback

D. rate = k [A]2[B]3 E. rate = k [A][B]2 Score: 1/1

5 .
A reaction is second-order with respect to the reactant R. Which of the following plots will produce a straight line? Student Response Value Correct Answer Feedback

A. [R] vs. 1/time B. 1/[R] vs. time 100%

C. [R]2 vs. time D. 1/[R]2 vs. time E. ln[R] vs. time Score: 1/1

6 .
A reaction mechanism is a collection of elementary steps. Student Response Value 1. False 2. Score: True 1/1 100% Correct Answer Feedback

7 .
The rate law for the reaction 3A 2B is rate = k[A] with a rate constant of 0.0447 hr 1. What is the half-life of the reaction? Student Response Value A. 0.0224 hr B. 0.0645 hr C. 15.5 hr 100% Correct Answer Feedback

D. 22.4 hr E. 44.7 hr Score: 1/1

8 .
The gas-phase reaction CH3NC CH3CN has been studied in a closed vessel, and the rate equation was found to be: Rate = [CH3NC]/t = k[CH3NC]. Which one of the following actions is least likely to cause a change in the rate of the reaction?

Student Response Value A. lowering the temperature B. adding a catalyst C. using a larger initial amount of CH3NC in the same vessel using a bigger 0% D. vessel, but the same initial amount of CH3NC E. continuously removing CH3CN as it is formed Score: 0/1

Correct Answer

Feedback

9 .
A rate constant obeys the Arrhenius equation, the factor A being 2.2 1013 s1 and the activation energy being 150. kJ mol1. What is the value of the rate constant at 227C, in s 1? Student Response Value A. 2.1 1013s1 0% Correct Answer Feedback

B. 6.7 1022 s1 C. 1.5 1011s1 D. 4.7 103s1 E. None of these choices is correct. Score: 0/1

1 0 .
Lowering the activation energy of a reaction will increase the rate of reaction by: Student Response Value Correct Answer Feedback

1. removing potential energy from the reactants. 2. spontaneously increasing the amount of reactants. 3. packing the created products in a favored arrangement. providing a new 4. reaction mechanism. Score: 1/1 100%

1 . The decomposition of hydrogen peroxide (H2O2) into O2(g) and liquid H2O produced the following data: time (min) 10.00 O2 volume (mL) 67.2 20.00 147 30.00 304 40.00 628 60.00 2769

What is the average rate in mL/min for the third ten-minute period of the reaction? Student Response 1. 7.98 mL/min 2. 10.1 mL/min 3. 15.7 mL/min 4. 6.72 mL/min Score: 2 . 1/1 100% Value Correct Answer Feedback

The rate law for the reaction 3A C is Rate = 4.36 102 L mol1 hr1[A]2 What is the half-life for the reaction if the initial concentration of A is 0.250 M? Student Response A. 0.0629 hr B. 23.9 hr C. 15.9 hr D. 0.0109 hr E. 91.7 hr Score: 3 . Which of the following statements would be correct regarding the following reaction? 1/1 100% Value Correct Answer Feedback

2 H2 (g) + O2 (g) 2 H2O (g)

Student Response

Value

Correct Answer

Feedback

0% A. The rate of O2disappearance is twice the rate of H2disappearance. B. The rate of H2disappearance is twice the rate of O2disappearance. C. The rate of H2O disappearance is twice the rate of O2disappearance. D. The rate of H2O

appearance is equal to the rate of O2disappearance. E. The rate of H2disappearance is equal to the rate of O2disappearance. Score: 4 . The rate equation for the decomposition of H2O2 is rate = k [H2O2] [I]. What are the units of the rate constant, k? Student Response A. L mol1time1
1 1 B. mol L time

0/1

Value

Correct Answer

Feedback

0%

C. L mol1time1 D. L mol1 time E. time1 Score: 5 . When the reaction A B + C is studied, a plot 1/[A]t vs. time gives a straight line with a positive slope. What is the order of the reaction? Student Response A. zero B. first Value Correct Answer Feedback 0/1

C. second D. third E. More information is needed to determine the order. Score: 6 . 1/1

100%

The rate of a reaction is determined by the rate of the fastest step in the mechanism. Student Response False Score: 7 . Cyclopropane is converted to propene in a first-order process. The rate constant is 5.4 102 hr1. If the initial concentration of cyclopropane is 0.150 M, what will its concentration be after 22.0 hours? Student Response A. 0.105 M B. 0.0457 M C. 0.127 M D. 0.492 M E. None of these choices is correct. Score: 1/1 100% Value Correct Answer Feedback 1/1 Value 100% Correct Answer False

8 . The greater the energy of activation, Ea, the faster will be the reaction. Student Response False Score: 9 . A reaction has an activation energy of 195.0 kJ/mol. When the temperature is increased from 200.C to 220.C, the rate constant will increase by a factor of: Student Response A. 1.1 B. 4.3 104 C. 3.2 D. 7.5 E. None of these choices is correct. Score: 1 0 . The number of molecules that can react on a catalyst binding site per unit time is known as the ______ number. Enter your answer in lower case. Student Response 1. turnover 1/1 Value 100% Correct Answer 1/1 100% Value Correct Answer Feedback 1/1 Value 100% Correct Answer False

Equals turnover (100%

Score:

1 . The decomposition of hydrogen peroxide (H2O2) into O2(g) and liquid H2O produced the following data: time (min) 10.00 O2 volume (mL) 67.2 20.00 147 30.00 304 40.00 628 60.00 2769

What is the average rate in mL/min for the third ten-minute period of the reaction? Student Response 1. 6.72 mL/min 2. 10.1 mL/min 3. 15.7 mL/min 4. 7.98 mL/min Score: 2 . If a reaction is zero order with respect to [B], tripling the concentration of [B] will result in: Student Response 1. a tripling of the rate 2. a nine-fold increase in rate 3. no change in the rate of reaction 4. a four-fold increase in rate 100% Value Correct Answer Feedback 1/1 100% Value Correct Answer Feedback

Score: 3 .

1/1

In the reaction 2A + B 2C + D, -[A]/t is found to be 5.0 M min1. What is the rate of reaction of B? Student Response A. 5.0 B. 10 C. 75 D. 2.5 E. Additional information is required. Score: 4 . Initial rate data were obtained for the following reaction: 1/1 100% Value Correct Answer Feedback

2 A (g) + B (g) C (g) + D (g)

What is the order with respect to reactant B? Please note that "?" in rate values should be "x" (times).

Student Response A. 0 B. 1

Value

Correct Answer

Feedback

C. 2 D. 3 E. 4 Score: 5 . 1/1

100%

For a 1st order reaction, a plot of concentration with respect to time produces a plot that is: Student Response 1. linear; m = 0 2. linear 3. non-linear 4. parabolic Score: 6 . A transition state is a species (or state) corresponding to an energy maximum on a reaction energy diagram. Student Response True Score: 7 . A reactant R is being consumed in a first-order reaction. What fraction of the initial R is consumed in 4.0 half-lives? 1/1 Value 100% Correct Answer True 0/1 0% Value Correct Answer Feedback

Student Response A. 0.063 B. 0.75 C. 0.87 D. 0.94 E. 0.13 Score: 8 . 0/1

Value 0%

Correct Answer

Feedback

Raising the temperature of a reaction elevates the rate of reaction by: Student Response 1. increasing the energy of activation 2. creating more molecules in the reaction. 3. decreasing the entropy of the system. 4. increasing the 100% number of molecules moving at a speed sufficiently high enough to produce a reactive collision. Score: 1/1 Value Correct Answer Feedback

9 . If the activation energy for the forward reaction is greater than the activation energy for the reverse reaction, the reaction is Student Response A. faster in the forward direction. B. faster in the reverse direction. C. exothermic. D. endothermic. E. spontaneous Score: 1 0 . A reaction which is catalyzed has a higher activation energy than the uncatalyzed reaction so it proceeds at a higher rate. Student Response False Score: 1/1 Value 100% Correct Answer False 1/1 100% Value Correct Answer Feedback