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Energy 194 (2020) 116871

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Energy
journal homepage: www.elsevier.com/locate/energy

3D full-space triboelectric-electromagnetic hybrid nanogenerator for


high-efficient mechanical energy harvesting in vibration system
Jian He a, b, Xueming Fan a, Jiliang Mu a, Chao Wang a, Jichao Qian a, Xiucheng Li a,
Xiaojuan Hou a, Wenping Geng a, Xiangdong Wang c, Xiujian Chou a, *
a
Science and Technology on Electronic Test and Measurement Laboratory, North University of China, Taiyuan, 030051, China
b
Taiyuan Heavy Machinery Group Co.,LTD, Taiyuan, 030024, China
c
Sports Science Research Institute of the State Sports General Administration, Beijing, 100061, China

a r t i c l e i n f o a b s t r a c t

Article history: Mechanical energy with low frequency is a widely distributed energy in environment. Triboelectric
Received 7 August 2019 nanogenerator (TENG) and electromagnetic energy harvester (EMG) are considered as promising
Received in revised form methods to harvest low-frequency mechanical energy. In this study, a three-dimensional (3D) full-space
10 November 2019
triboelectric-electromagnetic hybrid nanogenerator (FSHG) based on a magnetic ball and Polystyrene
Accepted 27 December 2019
Available online 7 January 2020
(PS) spherical shells is presented. The external excitation can be transformed into the relative motion
between different units. The mover composed of the PS spherical shell 3 and a magnet ball transforms 3D
full-space mechanical energy into electrical energy through friction electrification and electromagnetic
Keywords:
3D full-space energy harvesting
induction effect. The results of experiments show that the performance of TENG and EMGs can be
Triboelectric nanogenerator influenced by the direction of external vibration and excitation frequency. The output performances of
Electromagnetic generator TENG and EMGs increase as the excitation frequency increases. The results show that the maximum
Magnetic sphere output power of TENG is 18 mW at an external loading resistance of 200 MU, and the maximum output
power of EMG is 640 mW at an external loading resistance of 1000 U. The FSHG demonstrates a quick
charging ability for capacitor and the capability to power hundreds of LEDs. After storing energy in the
capacitor, the DC signal can power a humidity/temperature sensor.
© 2020 Elsevier Ltd. All rights reserved.

1. Introduction as solar and thermal energy, which occurs in a variety of forms, for
instance, human activities, ocean tide and machine vibration. So far,
Energy is the essentials of human existence and the impetus of several approaches have been utilized to convert mechanical en-
civilization progresses. However, with the aggravation of global ergy into electrical energy, including electromagnetic induction
greenhouse effect and the boom in worldwide energy demands, generator (EMG) [10e13] and piezoelectric nanogenerator (PENG)
energy crisis is a grave challenge facing the world. Therefore, [14e16]. Most recently, triboelectric nanogenerator (TENG), as an
exploring clean and renewable alternative energy resources has innovative form of electricity generation, has been demonstrated
been a hot topic in the world today [1e3]. More and more the based on the triboelectric effect coupled with electrostatic induc-
power supply in these devices are needed and have attracted tion [17e20]. In the triboelectric process, electricity is generated by
considerable attention with the popularity of portable sensors the surface charge transfer due to the periodic contact-separation
[4e6]. Currently, the external power supply is largely dependent on between two materials possessing opposite tribopolarity.
Li-ion batteries which have limited lifespan and induce environ- Compared to other generators, TENG has shown advantages of high
mental pollution [7e9]. It is desirable to tap new energy resources output power, low cost and abundant choices of materials. Never-
and thus achieve self-powered device and system. theless, the energy conversion efficiency of TENG is still limited by
Mechanical energy is one of the most commonly available en- the energy loss during power generation as exists in other coun-
ergy in ambient environment and more accessible than others such terparts. Substantial amount of mechanical energy input is wasted
through heat dissipation, material deformation or kinetic energy. It
is necessary to hybridize the power generators with complemen-
* Corresponding author. tary operation modes to harvest the waste energy [21e24]. This
E-mail address: chouxiujian@nuc.edu.cn (X. Chou).

https://doi.org/10.1016/j.energy.2019.116871
0360-5442/© 2020 Elsevier Ltd. All rights reserved.
2 J. He et al. / Energy 194 (2020) 116871

strategy is similar to the introduction of multijunction solar cells to different diameters is divided into three inner spaces, which are
cover a broader wavelength range in the entire solar spectrum. On used to place copper coils, friction layers and magnetic ball. To
the other hand, the mechanical motions in 3-demensional (3D) explain for convenience, three plastic spherical shells are named by
space have frequently multiple degrees of freedom, such as the 1e3 from outside to inside. The No.1 plastic spherical shell can
running car over uneven road and the bodily movement of human. protect the inner components from damage by outside objects. The
The conventional energy harvesters usually scavenge the energy outer surface of the No.2 PS spherical shell is evenly distributed
along single direction. As the result, the energy from the directions with six coils, and the inner surface is adhered to the friction layers.
is wasted. Therefore, it is urgent to design a new device capable of The six copper coils are made by the same material and size. The
capturing the energy from multiple methods and directions, even outer diameter, inner diameter and height of the coil (self-making
full space. coil, wire diameter 0.07 mm, turns 3000) are 70 mm, 55 mm, and
In this study, we construct a 3D full-space hybrid nanogenerator 6 mm, respectively. To improve the contact area and the tribo-
(FSHG) capturing mechanical energy along different directions in electric effect, an inverted pyramid structure is prepared on the
3D space through triboelectric and electromagnetic operation surface of the silicone layer. The scanning electron microscope
modes, which consists of TENG module and EMG module. The (SEM) of inverted pyramid structure is showed in Fig. 1(b). The
TENG module is composed by a mover and two friction layers, and material of friction layers is vulcanized silicone rubber (RTV). The
EMG module is made up of a magnet ball and six copper coils. The RTV silicone rubber is similar to polydimethylsiloxane (PDMS),
magnet ball is placed in the Polystyrene (PS) spherical shell, which is easy to gain electrons. Fig. 1(c) presents the diameter of
forming a 3D full-space rotatable mover. In this article, the working the three PS spherical shell, which are 120 mm, 100 mm, and
principle of FSHG based on triboelectrification, electrostatic in- 60 mm, respectively. In order to facilitate the adhesion between the
duction and electromagnetic induction are demonstrated in detail. friction layer and the inner surface of the No.2 spherical shell, the
The output performance including open-circuit voltage and short- friction layer is prepared into a “willow” shape. The template of
circuit current of TENG and EMG in different vibration directions willow shape is generated by MATLAB and the schematic diagram
and measuring frequencies are also investigated, respectively. The of the complete friction layer structure and a piece of friction layer
FSHG can light up 200 commercial light-emitting diodes (LEDs) or are shown in Fig. 1(d) and (f), respectively. Fig. S1(c) and Fig. S1(d)
power a humidity and temperature sensor persistently. Compared show pictures of friction layer and friction layer electrodes. This
with other similar studies, the device developed in this article not structure can make both TENG module and EMG module scavenge
only can convert the external mechanical energy from all directions the excitation energy well from any orientations. As the core
[25e29], but also has a better output performance than the cor- component of the FSHG, the magnetic ball not only provide varying
responding devices [30,31]. The FSHG shows potential application magnetic flux to the coils, but also move with the No.3 PS spherical
in the self-powered diagnosis system of large mechanical vibration shell rotating between the negative friction layers.
equipment. The kinematics analysis of the magnetic ball and the No.3 PS
spherical shell is illustrated in Fig. 1(f). When there is no external
2. Experimental section excitation, the magnetic ball and the plastic ball remains mechan-
ical balance at the bottom of No.2 PS spherical shell (Fig. 1(f) (ⅰ)).
2.1. Fabrication of the hybrid nanogenerator Under this condition, the gravity of magnetic ball (Gs) and the
supporting force (Fsm1) provided by No.3 PS spherical shell are all
This hybrid NG mainly consists of TENG and EMG. For the sili- along the vertical direction, and can be expressed by the following
cone layer, the silicone and curing agent were mixed uniformly equation:
with a ratio of 100:2. After being mixed uniformly, the silicone was
evenly coated on an emery paper with pyramid construction, which Fsm1 ¼ Gs (1)
was firstly sprayed mold release agent. The silicone layer thickness
When the external excitation is applied to the FSHG, the mag-
is 750 mm. It was then leaved at room temperature for 12 h. After
netic ball and the No.3 spherical shell will produce a circular mo-
completely curing, the layer could be stripped off and then adhered
tion with a relative velocity of n. The centripetal force (Fc) applied
on the second plastic sphere inner surface by epoxy resin. To the
on the mover can be formulated by
part of EMG, six copper coils were prepared by ourselves and each
coil is about 3000 turns. The six copper coils were adhered on the
outside surface of the second plastic sphere. v2
Fc ¼ m (2)
r
2.2. Measurement system
where m is the mass of the magnetic ball and r is the radius of the
No.2 PS spherical shell.
The sample morphologies were characterized by a field emis-
When a certain angle q is deviated from the vertical direction as
sion scanning electron microscopy (ZEISS EVO18, Carl Zeiss Tena,
shown in Fig. 1(f) (ⅱ), a new mechanical balance can be formulated
Germany). The output voltage and current performance were
by
recorded by the KEITHLEY 2611B system electrometer. The machine
vibration is simulated using a crank connecting rod machine with
Fsm2 ¼ Gs cosq þ Fc (3)
alterable working frequency and constant vibration displacement.
The charging voltage of capacitor was recorded by the Mixed Merging Equations (Gs ¼ mg), equations (2) and (3), a new
domain oscilloscope (Tektronix MDO3104). equation can be expressed by

3. Results and discussion v2


Fsm2 ¼ mðg cos q þ Þ (4)
r
3.1. Device structure
where g is the Gravity acceleration. For the convenience of calcu-
The total structure schematic diagram of the FSHG is showed in lation, the values of g and r are 10 m/s2 and 50 mm.
Fig. 1. The FSHG formed by three PS spherical shell (Fig. S1) with When Fsm2 is greater than Gs, an inequality can be described as
J. He et al. / Energy 194 (2020) 116871 3

Figure 1. 3D full space triboelectric-electromagnetic hybrid nanogenerator structure: (a) Schematic diagrams of the FSHG internal structure; (b) Schematic diagrams of the
FSHG and SEM image of surface microstructure; (c) Diameter diagram of three PS spherical shells; (d) Schematic diagram of friction layers after fabricated; (e) The dimension of a
piece of “Willow” friction layer; (f) Mechanics analysis diagram of the FSHG.

The contact area between the spherical shell and the friction
Fsm2  mg > 0 (5) layer can be affected by the value of Fsm.
By combining equation (2) and the values of g and r, equation (5)
can be solved analytically as follows: 3.2. Working principle
q
v > sin (6) The working principles of EMG modules and TENG module are
2
illustrated in Fig. 2. When the FSHG is without external vibration,
As a result, when the value of q is between 0 and 90 , if there is no charge transfer in TENG. According to triboelectric se-
inequality (6) is established, the supporting force (Fsm2) is bigger ries, the PS sphere shell is more positive than silicone rubber.
than Gs. Therefore, electrons escape from plastic sphere onto silicone rubber
When the magnetic ball and the No.3 PS spherical shell moves to surface with external vibration, resulting the plastic sphere ball
horizontal position, a new equation can be had with positive charge and the silicone rubber layers with negative
charge (Fig. 2(ⅰ)). When the No.3 plastic sphere moves between two
v2 friction layers, the charge on the right electrode of silicone rubber
Fsm3 ¼ m (7)
r layer will flow to the left electrode of silicone rubber layer surface
To explain the condition that Fsm3 is greater than Gs, the through external circuit because of electrostatic induction and
inequality can be expressed electrostatic balance (Fig. 2(ⅱ)). With the plastic sphere moves back
to original position (Fig. 2(III-ⅳ)), the charge goes back to the right
Fsm3  mg > 0 (8) electrode of silicone rubber layers, forming a complete alternating
current in the external circuit. To EMG, the magnetic ball can rotate
By combining the initial conditions in Equation (7) and the
around frictional layers along with No.3 PS sphere shell and it will
values of g and r, the condition that inequality (8) holds can be
cause magnetic flux changes across six copper coils, inducing cur-
expressed as
rent flow according to Faraday electromagnetic induction.
pffiffiffiffiffiffiffi To obtain a more quantitative understanding of the EMG, the
v> 0:5 (9)
electromagnetic simulation is finished by using Maxwell 15.0. The
4 J. He et al. / Energy 194 (2020) 116871

Fig. 2. Working principle of the hybrid nanogenerator and simulation results of the magnetic sphere using Maxwell 15.0, respectively. (a) The charge generation process in
TENG modules. (b) Magnetic distributions of magnetic sphere at the original balance position of the No.2 sphere. (c) Distribution of magnetic flux in the FSHG with the magnetic ball
at different angles. (d) Calculated field strengths as a function of the different angles of magnetic ball.

magnetic flux density related to the distance between the magnetic magnetic ball at different angular position has litter effect on the
sphere and coil is investigated. As shown in Fig. 2(b), when mag- flux densities. In order to avoid mutual cancellation of inductive
netic ball stays at origin balance position, the magnetic field and current generated in coils, the connection of six coils are in parallel
magnetic induction lines distribution are central symmetry. The after rectifier bridges. So, whatever the motion of magnet ball is, it
maximum magnetic field strength at different positions is calcu- is guaranteed that there is at least one coil that can receive the
lated by simulation in Fig. 2(c), in which magnetic field strength of maximum change in magnetic flux.
the bottom coil position (EMG 6) is far greater than that at other
positions. Because the shape of magnet is a spherical, the directions
of magnetic flux lines generated during its motion are unsure. 3.3. Output characterization
Furthermore, the flux lines of magnetic ball at different angular
position are also exhibited in Fig. 2(d). The magnetic flux densities In order to quantitatively analyze the output performance of the
of the fixed point are plotted with different angular position device, a linear motor is used to generate mechanical vibration in
(0 ~360 ) of the magnetic ball in Fig. 2(e). The difference between lab experiments. The linear motor can produce reciprocating linear
the max magnetic flux densities and the min magnetic flux den- motion with different frequency (0e3 Hz) and constant displace-
sities is no more than 1 mT, which indicates that the rolling of ment (100 mm). A Keithley 2611B system electrometer is used to
measure the output voltage and current. First, the effects of
J. He et al. / Energy 194 (2020) 116871 5

different excitation directions on the output performance of the the ±Y axis, which is completed by rotating the nanogenerator
device power generation units (TENG and EMGs) are studied. 90 clockwise along the XY plane, EMG modules in the same spatial
Fig. 3(a) and (b) show the schematic diagrams of the X-axis and Y- position have similar output performance. For example, after
axis excitation direction in detail. The excitation with different di- rotating the nanogenerator 90 clockwise along the XY plane, EMG
rections is achieved by adjusting the angle between the device and 1 and EMG 5 are in the same spatial position, which is at the top of
the linear motor. Fig. 3(c) and (d) give the open-circuit voltage and the FSHG. The reason why the performance of EMG at the top of the
short-circuit current of TENG, respectively. Under the excitation FSHG always has the smallest output is that the magnetic flux (Ø)
frequency of 2 Hz, the open-circuit voltage (Voc) and short-circuit through the coil is the smallest. The load voltage and load power of
current (Isc) are 77 V and 0.7 mA, respectively, when the excitation TENG module and EMG modules under different resistances are
direction is X-axis. However, when the device is along with ±Y axis compared in Fig. 3(g)~(h). Fig. 3(g) shows the dependence of output
excitation vibration, the output voltage and current are 40 V and voltage and output power on the different values of external
0.3 mA, respectively. The results reveal that the TENG has the ca- loading resistance. The load power of TENG and EMGs can be
pacity of 3D full space energy harvesting. It is worth noting that the calculated as follows:
output performance of TENG decreases when the excitation di-
rection is along with ±Y axis. That is because the mover (consist of U2
P¼ (13)
the No.3 PS sphere and the magnet ball) rotates around silicone R
layers under the lower half of the No.2 PS sphere instead of be-
tween the two silicone layers. where U is the peak output voltage and R is the external resistance.
Fig. 3(e) and (f) give the open-circuit voltage and short-circuit As can be seen from Fig. 3(g), the maximal power of TENG
current of EMGs with different vibration direction. When vibra- module in the vibration direction of ±X axis is 18 mW at a resistance
tion direction is along the ±X axis, the output performance of EMG of 200 MU. When the vibration direction is ±Y axis, the maximal
1and EMG 3 is similar (Vpp: 4 V, Isc:1.8 mA). The voltage and current power of TENG module is 6 mW. Due to spatial symmetry of sphere
of EMG 6 are higher than those of EMG 1 and EMG 3 (Vpp: 4.75 V, structure, the output power of EMG is only tested in the excitation
Isc:2 mA). However, the output performance of EMG 5 is lower than direction of ±X axis. The maximal output power of EMG 1 is
others (Vpp:1.6 V, Isc:0.3 mA). When the vibration direction along 640 mW at an external loading resistance of 1000 U. Therefore, to
achieve the maximal output power of the hybrid nanogenerator,

Fig. 3. Orientation dependence of the output for EMG modules and TENG module. (a, b) Schematic diagram of excitation orientation. (c, d) Output voltage and current diagram
of TENG module with different excitation directions. (e, f) Output voltage and current diagram of different EMG module with different excitation directions. (g) The voltage and
power relationship diagram of TENG module with different excitation directions. (h) Voltage and power relationship diagram of EMG module (1, 5, 6).
6 J. He et al. / Energy 194 (2020) 116871

the best vibration direction is along ± X axis. Fig. 4(b)~(d) and Fig. S3. At a vibration frequency of 3 Hz, the
Since mechanical energy has a wide frequency distribution in voltage and current of EMG 6 are 2.95 V and 1.2 mA, respectively.
environment, especially in the low-frequency range, the study The output performance of EMG 1 is similar to that of EMG 6. With
about the dependence of output performance on working fre- the increase of frequency, the output performance of EMG 5 in-
quency is meaningful. In this study, the output performance of creases greatly. At a frequency of 1 Hz, the output voltage of EMG 5
triboelectric-electromagnetic hybrid nanogenerator has been is only 0.29 V. However, when the frequency is 3 Hz, the open-
tested in low-frequency range (1 Hz, 2 Hz and 3 Hz), as shown in circuit voltage and short-circuit current are 2.06 V and 0.6 mA. It
Fig. 4. Fig. 4(a) shows that the open-circle voltage (Voc) of TENG can be attributed to the moving position of magnet ball. As the
increases from 36 V to 88 V and the short current Isc increases from frequency increases, the magnet sphere will move upward away
0.27 mA to 0.95 mA with the frequency from 1 Hz to 3 Hz (Specific from the bottom and lead to an increase in magnetic flux across
output graph provided in Fig. S2). The voltage of TENG can be ex- EMG 5. The output performances of TENG module and EMG mod-
press as following equation [32,33]. ules increase with the increasing input frequency.

sS 3.4. Device application


V TENG
oc ¼ (10)
C
In order to demonstrate the capability of the hybrid nano-
where s is the transfer charge density, C is the capacitance, S is the
generator to harvest mechanical energy, some experiments have
contact area between the No.3 plastic sphere and friction layers. In
been completed. Firstly, each of the EMG modules, except EMG 5, is
this study, S is affected by the centrifugal force (Fc) generated by the
connected to 25 commercial light emitting diodes (LEDs) in parallel
magnetic ball moving speed v and the output performance of TENG
to form a water lamp displayed in Movie S1. All of EMG modules are
increases with the increase of input frequency.
without rectification. LEDs are lighted alternately in the dark
The electromotive force and induced current of EMG is formed
environment. As all of the electricity generation modules generate
by the changed magnetic flux through copper coil, which can be
asynchronous alternating current, it is necessary to store in energy
represented as [34].
storage devices by an external power management circuit, like
capacitors or batteries. Subsequently, some other experiments are
d4
V EMG
oc ¼  N (11) tested with a rectified circuit.
dt
Supplementary video related to this article can be found at
https://doi.org/10.1016/j.energy.2019.116871
V EMG To further study the charging capability of this FSHG, the
I EMG
SC ¼
oc
(12)
Rcoil charging characteristics of different modules have been investi-
gated. The seven different electricity modules are connected in
where N is turn’s number of the coil, ∅ is magnetic flux linkage, Rcoil parallel with each other by a rectifier circuit, as shown in Fig. 5(a).
is coil’s inner resistance. As the frequency of the input excitation The capacitor used in this experiment is 10 mF and the excitation
increases, d∅=dt increases gradually, resulting in an increase of frequency is 3 Hz. As exhibited in Fig. 5(b), the charging speed of
V EMG
oc and I EMG
SC . It can be seen that output performances of all EMG EMG modules is faster than that of TENG module. However, after
modules increase with the increase of excitation frequency from 60 s of charging time, the EMG charging voltage has become stable

Fig. 4. Electrical characterization of the hybrid nanogenerator with different vibration frequency. (a) Output performance of TENG with different frequency. (bed) Output
performance of different EMGs with different frequency.
J. He et al. / Energy 194 (2020) 116871 7

Fig. 5. Demonstration of the FSHG for energy scavenging. (a) The diagram of rectifying and charging circuit; (b) The charging curve of TENG module, EMG modules and the hybrid
NG with a capacitor of 10 mF. (c) The schematic diagram of the FSHG light up 200 LEDs connected in parallel. (d) Schematic diagram of a humidity and temperature sensor powered
by the FSHG.

and the TENG charging voltage is still growing. It means that the of high-frequency mechanical motion, while TENG is a feasible and
capacitor’s voltage from TENG module will be larger than that from effective method to harvest the low frequency mechanical motion.
EMG modules after a longer charging time. In addition, it can be The output power of TENG and EMG 1 are 18 mW and 640 mW at
found that in 60 s the voltage of capacitor charged by hybrid optimal loading resistances of 200 MU and 1000 U with an exci-
nanogenerator, EMGs and TENG reach 5.2 V, 4.1 V and 2.5 V, tation frequency of 2 Hz. According to the measurement results of
respectively. It indicates that the FSHG has the best charging per- different vibration frequency, the output performance of TENG and
formance than others. The charging curves of different capacitors EMG is improved with the increasing frequency. The maximal
shown in Fig. S4 demonstrate that the device can provide a stable open-circuit voltage of TENG module and EMG module are 88 V and
voltage output for small power electrical appliances. 3.75 V with an excitation frequency of 3 Hz, respectively. Further,
Furthermore, the FSHG can completely light up 200 LEDs (which the hybrid (FSHG) exhibits an excellent charging performance
are connected in parallel) with a diameter of 5 mm (the Movie S2 in compared to other individual modules. To prove its feasibility in
Supporting Information) after a rectifier circuit shown in Fig. 5(c). practical application, 200 LEDs connected in parallel can be lighted
To demonstrate the application of the FSHG in powering portable up by the device after a rectifier circuit. The FSHG can also power a
electrics by scavenging the mechanical energy, a digital humidity digital humidity and temperature sensor at the vibration frequency
and temperature sensor chosen for example. The digital humidity of 2 Hz with the assistance of a rectified circuit and a capacitor of
and temperature sensor is powered by the FSHG through con- 100 mF. The design of this new structure in this paper has great
necting a rectified circuit and a capacitor of 100 mF in Fig. 5(d) and potential application in machinal energy harvesting for human
Movie S3 (Supporting Information). At the beginning, the capacitor motion, ocean energy and so on.
is charged and the humidity and temperature sensor does not work.
After 4 s of vibration, the switch connecting capacitor and ther-
mometer is turned on, and it can work normally. After the initial Declaration of competing interest
stage, the humidity and temperature sensor can work constantly as
long as the external vibration is generated. The authors declare no competing financial interest
Supplementary video related to this article can be found at
https://doi.org/10.1016/j.energy.2019.116871

Acknowledgments
4. Conclusion
The work is supported by the National Science Foundation of
In summary, we have demonstrated a triboelectric- China (51675493, 51605449, 51821003), China Postdoctoral Science
electromagnetic hybridized nanogenerator for vibration energy Foundation (2017M621111, 2018T110207), 135 pre-research fund
harvesting. The device is a sphere structure with a diameter of (61406190504) and Shanxi “1331 Project” Key Subject Construction
120 mm. The combination of EMG and TENG can broaden the (1331KSC). Key research and development plan (2018YFF0300605),
working bandwidth of the device. EMGs are suitable for acquisition National Key R&D Program of China (2019YFF0301802).
8 J. He et al. / Energy 194 (2020) 116871

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[20] Xia K, Zhu Z, Zhang H, et al. Painting a high-output triboelectric nano-
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