I REVISION CAPSULE - CHEMISTRY

I
PHYSICAL CHEMISTRY

Multiplied by 0
Amountofa ----....-----r-­ Number
0 substance
(in gram)
Mo 1 arm ass of
entities
he
E = hv = -

Volume ofg as (in L) at STP

A= h
O Molecular mass
✓2mxK.E.
No. ofspectral lines produced when an electron drops from
Average relative mass of one molecule
n(n-1)
1 n th level to ground level = - --
- x mass of C-12 atom 2
12 Heisenberg's Uncertainty Principle (rue) (�p) � h/4rc
0
O Molecular mass = 2 xVD Nodes (n - 1) = total nodes,£ = angular nodes,
O Eq. wt. ofmetal
0
(n - £ - 1) = Radial nodes
wt. of metal
- - - - - X1.008 Orbital angular momentum : -J£ (£ + l) !.!___ = ,J£(£ + l)h
-
wt. of H 2 displaced 0 2rc
O (i) % ionic character
wt. of metal
0 Eq. wt. ofmetal =
. x8 Actual dipole moment
wt. of oxygen combmed x100
Calculated dipole moment
wt. of metal
x 35_5 (ii) Dipole moment is helpfu l in
wt. of chlorine combined
predicting geometry and polarity
0 Molecular formula = (Empirical formula)n ofmolecule.
Energy ofelectron in species with one Fajan's Rule: Following factors are helpful in increasing
electron. 0
covalent character in ionic compounds
-2rc 2 me-4Z 2
En =-- 2 - (i) Small cation (ii) Big anion
ATOMIC n h2 (iii) High charge on cation/anion
STRUCTURE For energy in SI system, (iv) Cation having pseudo inert gas configuration (ns2 p6d 10 )
-2rc 2 me4 Z 2 e.g. Cu+,Ag+,zn +2 ,Cd+2
En
n 2 h 2 (4rci:o) 2
=
0 M.O. theory:
2 (i) Bond order = ½(Nb-Na)
En = -13\2Z kJ mol-1 (ii) Higher the bond order, higher is the bond dissociation
n energy,greater is the stability,shorter is the bond length.
nh Formal charge (F.C.) on an atom in a Lewis structure
mvr = - 0
2rc = [total number of valence electrons in the free atoms]

- [total number ofnon-binding (lone pair) electrons]

n 2 h2 2
r= =o.529 [ �) A
4rc mZe
2 2
Z - _!_ [total number ofbonding (shared) electrons]
Total energy ofelectron in the nth shell 2
0 Relative bond strength: sp3 d2 >dsp 2 >sp3 >sp 2 >sp >p-p
e 2 ( kZe 2 1 kZe 2 0
= K.E. + P.E. = kZ- + 1--j = -- (Co-axial)> s - p> s - s> p - p (Co-lateral)
2rn \ rn 2rn

Join our Telegram channel - @Exambat

1
;_1e_�_1a_y�l 2
0

;_�_
Join our Telegram channel - @Exambat
Join our Telegram channel - @Exambat
Join our Telegram channel - @Exambat
Join our Telegram channel - @Exambat
Join our Telegram channel - @Exambat
Join our Telegram channel - @Exambat
Join our Telegram channel - @Exambat