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GUIDELINE FOR
CHEMISTRY

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SYLLABUS 2022-23
S.No. CHAPTER NAME MARKS
1 Solution 7
2 Electro-chemistry 9
3 Chemical kinetics 7
4 D & f- block 7
5 Co- ordination compounds 7
6 Halo alkane & halo Arenes 6
7 Alcohol, phenol & ether 6
8 Aldehyde, ketone & carboxylic acid 8
9 Amine 6
10 Biomolecule 7
Total 70
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DELETED PORTION
 Out of 16 chapters of NCERT, 10 chapters are there .

 In physical chemistry : 2 chapters are deleted.

(solid state & surface chemistry )

 In Inorganic chemistry : 2 chapters are deleted

(metallurgy & p-Block )

 In organic chemistry : 2 chapters are deleted

(Polymer & chemistry in everyday life)

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DEFINITION :-
 MOLARITY, MOLALITY & MOLE FRACTION
 HENRY’S LAW AND IT’SAPPLICATION
 RAOULTS LAW
 IDEAL & NON-IDEAL SOLUTION
 AZEOTROPIC MIXTURE
 COLLIGATIVE PROPERTIES
 ABNORMAL MOLAR MASS
 VAN’T HOFF FACTOR
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Reasoning based questions on:-

 Solubility
 Temperature
 Osmosis
 Van’t hoff factor

 Numericals

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Colligative properties :-
(1) Relative lowering in vapour pressure (RLVP) of solvent

P0A −PS nB
 =
P0A nA + nB

(2) Elevation in boiling point (Tb) of solvent

wB
ΔTb = kb 1000
MBwA

ΔTb = kb  molality
Tb = Tb> 𝐓𝐛𝟎

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(3) Depression in freezing point (Tf ) of solvent

𝚫𝐓𝐟 = 𝐓𝐟𝟎 − 𝐓𝐟 = 𝐊𝐟 × 𝐦𝐨𝐥𝐚𝐥𝐢𝐭𝐲

(4) Osmotic pressure () of solution

 = CRT

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(5) Van’t hoff factor :-

𝟏−𝛂+𝐧𝛂
𝐢= = (1– 𝛂 + 𝐧𝛂)
𝟏

𝐢−𝟏
Degree of dissociation(𝛂) =
𝐧−𝟏

𝟏
𝐢= 𝟏+𝛂 −𝟏
𝐧
𝐧(𝐢−𝟏)
Degree of association(𝛂) =
𝟏−𝐧

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Electro-chemistry

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 Definition

 Batteries and corrosion

 Numerical

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CHEMICAL KINETICS

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 Definition
 Derivation
 Numerical

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DEFINITION:-
 Rate law
 Rate
 Specific rate constant
 Order
 Molecularity
 Pseudo-unimolecular Reaction
 Activation energy
 Threshold energy
 Collision theory

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d & f – Block

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1. Reasoning On Physical Properties

2. Magnetic Properties
3. Oxidation State
°
4. Ecell
5. I.E.
6. Catalytic, Interstitial, Complex & Alloy
FormationPreparation & Properties of K2Cr2O7
& KMno4
7. Electronic Configuration of Ln & Ac
8. Ln Contraction And Consequences
9. Comparison Between Ln & Ac
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Account for the following :

(i) Cr2+ is a strong reducing agent.

(ii) Ti3+ is coloured whereas Sc3+ is colourless in aqueous
solution.
(iii) Zn, Cd and Hg are not called transition elements.

When FeCr2O4 is fused with Na2CO3 in the presence of air it gives

a yellow solution of compound (A). Compound (A) on
acidification gives compound (B). Compound (B) on reaction
with KCl forms an orange coloured compound (C). An acidified
solution of compound (C) oxidises Na2SO3 to (D). Identify (A),
(B), (C) and (D).

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Co-ordination compounds

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 IUPAC
 VBT
 CFT
 ISOMERISM
 Werner’s theory

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Type of isomerism

(A) Structural isomerism (B) Stereoisomerism

Ionization Hydrate Coordination Linkage Geometrical Optical

MA2B2
MA2B4 M(AA)2B2
MA3B3
M(AA)2B2

M ABCD

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ORGANIC CHEMISTRY

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TOPICS MARKS
Optical isomers 2
IUPAC 1
Reasoning 6
Chemical test 2
Mechanism 3
Word problem 5
Inter-conversion/ 5
ABCD
Name reactions 3

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Definitions
1. Optical isomers
2. Chiral carbon
3. Racemic mixture
4. Enantiomer
5. Poly halogen compounds (Chloroform,
bromoform & Freon)
6. Commercial preparation of Phenol & Methanol

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IUPAC Naming

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REASONING

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CHEMICAL TEST

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MECHANISM

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1. Mechanism of SN1 & SN2.

2. Mechanism of preparation of Alkene to Alcohol.
3. Mechanism of preparation of Ethene from Ethanol.
4. When 3-methylbutan-2-ol is treated with HBr.
5. Mechanism of preparation of Ethanol to Ethoxyethane
6. Mechanism of an Ether with concentrated HI starts with
protonation of ether molecule.

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WORD PROBLEM

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An alkene 'A' ( Mol. formula C5​H10​) on ozonolysis gives a

mixture of two compounds 'B' and 'C'. Compound 'B' gives
positive Fehling's test and also forms iodoform on treatment
with I2 and NaOH. Compound 'C' does not give Fehling's test
but forms iodoform. Identify the compounds A, B and C.
Write the reaction for ozonolysis and formation of iodoform
from B and C.

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INTER- CONVERSION

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How will you bring about the following conversions in

not more than two steps ?
(i) Proapnone to Propene
(ii) Benzoic acid to Benzaldehyde
(iii) Ethanol to 3-Hydroxybutanal
(iv) Benzene to m-Nitroacetophenone
(v) Benzaldehyde to Benzophenone
(vi) Bromobenzene to 1-Phenylethanol
(vii) Benzaldehyde to 3-Phenylpropan-1-ol
(viii) Benazaldehyde to -Hydroxyphenylacetic acid
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Name Reaction
1. Friedel craft reaction
2. Fitting Reaction
3. Reimer-Tiemann Reaction
4. Kolbe’s Reaction
5. Rosenmund Reduction
6. Stephen reaction
7. Etard reaction Reduction
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8. Clemmensen Reduction reaction

9. Wolff Kishner Reduction
10. Aldol reaction
11. Cannizzaro reaction
12. HVZ reaction.
13. Hoffmann bromamide

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14. Carbylamine reaction

15. Cross aldol condensation
16. Gabriel phthalimide reaction
17. Coupling reaction
18. Sandmeyer reaction
19. Decarboxylation
20. Gattermann koch reaction

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BIOMOLECULES

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 Monosaccharides
 Glucose
 Chemical reaction of glucose
 Haworth structure
 Fructose
 Carbohydrates

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 Amino acid
 Protein
 Denaturation of proteins
 DNA
 RNA
 Nucleic acid
 Vitamins & Hormones
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Solid state

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 Classification of solids based on different binding forces:

molecular, ionic, covalent and metallic solids
 amorphous and crystalline solids (elementary idea)
 calculation of density of unit cell
 packing in solids & packing efficiency
 voids
 point defects

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 Point defects in the ionic crystal may be classified as

 Schottky defect
 Frenkel defect
 Metal excess defect due to anion vacancies
 Metal excess defect due to presence of extra cations
 F-Center
 Important questions of Exercise: 3,11,13,14,16,24
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Surface chemistry

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 Adsorption
 Differences Physisorption b/w Chemisorption
 Types of Colloidal solution
 Lyophilic and Lyophobic so
 Hardy Schulze Rule
 Tyndall’s effect
 Charge on colloidal particles
 Zeta Potential
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 Electrophoresis
 Coagulation
 Protection & Protective action
 Brownian motion
 Bredig arc method
 Peptization
 Important Questions Of
Exercise:2,5,8,12,14,15,23,25
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Metallurgy

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 Froth floatation method

 Depressants
 Leaching of alumina from bauxite
 Calcination,Roasting & Smelting
 Reaction in blast furnace
 Extraction of copper from cuprous oxide
 Zone refining
 Hall heroult process
 Van-Arkel process
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P-Block

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 Nitrogen preparation properties and uses

 Compounds of Nitrogen
 Preparation and properties of Ammonia
and Nitric Acid.

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 Sulphur ‐allotropic forms

 Compounds of Sulphur
 Preparation properties and uses of
Sulphur‐dioxide
 Sulphuric Acid: properties and uses
 Oxoacids of Sulphur (Structures only)

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 Preparation, properties and uses of Chlorine

and Hydrochloric acid
 Interhalogen compounds
 Oxoacids of halogens (structures only)
 Preparation and properties of xenon halide
and their structure

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POLYMER

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 Monomer of polymers and uses

 Low Density Poly Ethylene (LDPE)
 High Density Poly Ethylene (HDPE)
 PHBV
 Free radical polymerization of ethene

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Chemistry in everyday life

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 Drugs Examples and uses

 Antacids
 Tranquilizers
 Analgesics
 Antibiotics
 Antiseptic & Disinfectants
 Artificial sweetening agents
 Soap & Detergents
 Food preservatives
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