You are on page 1of 158
4 Phystead “Nod etinay. Mmvalves the teat proces), _bhtel oil —Comprse of yariour pl at . — lL wlabionshigs. fo porwmime bors 1 Cu atch uri c Renal te Number 2+ SUD: pA TWis comyrdften of voafous * potrsimeters ca Mathematical Modeling = When alt these physizal wmode neod’s bo lox defmecl in ______ae_-forn _of- some _mathematt \ vor ae Vtkus — Gothen fq k_ | Difference bet” Trdepeindent “yanfabler ct desntoert verkabhe and pareunetee | Vonarncters ove, sean Hated tne Ho fin af logical pepe =e Ate noring shee. Sochaitie “ibn ae e_acts [S \ taken the outoud i? ine rvelaked \ ie not divectly Ha tnpul \ pelabl woith | input =D In Mathematical Modeling 0 Eownalisution JUevelbpment of eles of the poe 3) etn” £ | Choniten) orn nega J! Modeling | 6f- E, Diectillation. etc. => Bate “odel_ Formulation pda ciple a 2 Basis =i Mathematical Consistency of the Model Csxctem "be anderdefrred) Fie aphitalina Puscpose. ay Solunion, of the Medel Guotien 5) Verification .choul * Types of Similavitien bilusen. Model Aicd* toolnbype \) Kinemiatyce. omilovty 2= Avea Voladily accoleakien a) Geomeric sbimtl lily Stn fan “of length - : ae rb a cm, feck) JH ynerntc. “ong lov +. Fi ree Momevtburn, Chasstftcablon ef. Mothenertical Modolenra 2, Based on Base] on Based on— vaughn of Steute_ of- type of independer L pycess process variull == sf by | re 1c CO Complete rare ? ——f Cede saa Sag repnabicad ready) | pistvileuted tammped E Paramnchon Rigid, Ske chastic i fred — ero EE Crees ean Coty Ee. eben, prebaitishic oa wth = Chewnogs s) , | Modex pa \ Aral ial Numerica Coil Pp Analytical NumericoQ Rigid Rigid MOAI Moc 1) Based en variation of independent rearable 2a Tt tos uy whether ithe proces Mowtal to. toi Ma aly {me ot booth Sate fond space A) DP Medel = Te the locisic iprocess variable phages ousitla —talle A me £ space then ____ fs kino ic ed Res) — leet Farm Pp EC Pe brat T Gib LP Medel pe he“ psaces Troms only — with ime then it its Known as LP Medel woh eee -frrm_ope CI Ordinary a) _2 Based on state. of process | ch Stabe Medd. L Cote, Stake )i— dk ig hores chenges Yq proces Variable of Hn Uwe. The fonstusatn seep af stable mond! Wow (q\: Arnalycis dF _| process ile To. establish: Physical & ehemical Tiare | Ww es . 7 TS ta Gowetning Equations devexibing procen 1 v . Tdentifiation of —Tapul 4 put variables (2) Contvol vaniables ‘- Vanrible thal ee ee wethepangiens sf pcos —- LIU TOI a IE gual a | i eae fl —— fet bin Ti iplosens Jom [ws tess Shay __(CE)_Monipulated variables Maripulateal _ | vantables ane directly. affecting co =a | —— pene andi be. an id OES [4 tose - — “Gen Pion = Dl chats thes nes lb bat cau not bee hanged | aur _ Dy 3 > "a - - x ~ Pree —| Te Ca? (WA) Ttemediale Variables 2 | The vaniablen which ave velated to pees indivect : | TR roeass Ta segs Lan Ms Fy oO Ldentlfication and establishing of_ relationship constreyin€ of the. pwoce Xs ClO Dgsanic” Medel Co 2) HE can ——_te_foreied in the following manner @) Ta the farm of Defic ok Sei ! the fore af ©) An the fon of Vanteot ier a Xe complete t ___contalis PY Batic pravess -yoarable, Pe 2) Relatlnship between basic yantah __steady sterheconolHhon 3). comateaints: CbLd it pI mr) 4) Cibolo (oF +9 6beckive Function) : 5) Relattonshtp belween the baste vanrable _amadeey wnsbeady skate condtion . Bein (Basic Mathemalico Medel) t— TT iat ate Ha eee or | e io in Process Descmi ma a ‘aid mgin:_Pvocess Vaviable. 7 2 GE cere \ % aT Betti a C2] Variable i | SOT, crolations hip { Sa Shp : n_tiodianl ra joa d ; By “fC ny, Euan Fyndioy | Ae Volos akon for Spree TT _ — ——— = Dynanic Optimizers On| Rees fe = entror * —Nomoical Regid of Stochastic Modok _ Modeling of UmTo = ( Tingle. State €xtyaction =P Consider that benzoic acid CC ke cme _) . mb ts d , A A (R_ £m] go.) “using ——, as__solyent » (The tise! spat a wt P xe ond + . is puna ped. inte sethler Lane of ra-ffinate and. entyack -» Model the systero be find oul tohat iif *f Benrsic eid! has posed si ins Lhe Sclvewt " phase. te i (BA +t Eo luons) . — - or an => Pwixen- water \ } TSagjetn J | - ee creettinst) ec HN Ragen mh EERE SSF {Single Stage TS tilt of BAe iS Be “ Soctractio A gt wi1se<—vsahy— nts ec eee alee Deaf ot ky [rw BA tise soak Centra : ‘Py Feiss assump etons sto | love “taleen Lonitepsla DT Aw “fies. ‘rate, -aye. shod stat ! 2) The: solvent iti oi Toluene, 2) fel concentration maul: ema _ “canctank. u I Betathe. ry , , Muito ust He. eich cles Feom aN gH ue wal jek 4= =m ey —Tnpuk =o ubp uk of ebay ely = accunda bien i 2 cInput = output I oukpib of Be, by the lav of conservation of mass In_=ouk-_mesulls_in eq" (2) Oubibbale f= mains ete) ej) B.C = Row +S. min Ne RBC = pry Cr+ ms) Cx? Rit 5 | [| ht ms 4 = Gud hence [a Wee me Jett IG tm (ig Cie — I" \S cpm). 1 a= ee tt Re See = fms — the Frackton of benr0ic _qeid erbracked g Compute the feaghipn ef Bees aac AC could -be en Was tagle stage —solvewl_evtraction uring te values af | S = IR m=} . he Cr ot ka/g3 a = ae —— om ah + S.0 —_e ren of -sboae. ew ce 2 New for stage Le ae [pd ee Re 4 Sy = Bk . Sy Cs D_rlow fox sage TT. > ouk eas aS ete) =) New a oO egi rd eS by ———— ee Sm Ce ae ci Sma, = 4 ee = Ri nm, Cat Sm_) m Y, 2 a, [RE Sm) aR RO Y 22 m Crm he Sw \—=(0 == J=O = ie =i ate 4d, oan oD. RC + $009. SO, AS tm yest Xsq 77 I Hee A- sm = = a 2+ Bsmt ms Ry eS REPU, = Pau, ee ma aes Bo = : ea = — ae pp = Rh Sm Aa! i 7 [Ros Ce = Srp ch wis Dy Cs Pubo wn ¢ ris Ga 3 ees | FA _ EAs) Leytst > | 42 mee CRS) a5 - 6, = SY) : Ro Ey = ms CP mse : SE ee YAR alee Y : Es Semetnt as) [a vmes wed) pee - _€,= mS CR4-ms) ee EME ae ‘il = = wee \ : 7 po ea Al fe > 4+¢é 7% \ inet, [=e - ; - cx) ———Muthrpl and divide oy € i—1) ESE (ete oe) Cw =1 a EL = ok V2s xe J Salle £. Fo a Tage ie fe a aay > BL, SS IW@kh - ms Lg ——__—+. i CHzo4 3/48 — T J) Gt Vec ines pts T , | Ye OLE = Oe __| tse eek Tr Re || - Sa = orto. OLL0s a ‘y i . eo Ree Yys MRC CRE MSL T TES RE eS Ses <- Reo CR4 a bh te ee ao Ro Y,= canER fare): 3 =D 0.03)25° 4, 247 j= ©. 66 6S") -! €, 2 SY] ; Reo whet (Le x o-poesq . myx od Ee 7 7 &\ = [2 €=2 1. ike wed (Ey = ; | Qe 4 | we ne | 4 lto ww Leet of So veut ES SS is us ger = kn ted de shan os sec ef lef by wt solution of C jn” where Cts hema extrected Fes A _ tatu selage “rourlercunncal LO « fe ITE Ilya hak is hs teimposstian of Pinel see fiiwate ond enctre ct Cm Uy) sat 7 CE) Th m3 aud Ue oygnslie wef A, Be ¢ are ipo0 kg/m? 02 Egle aud 1200 ley / mie “ceope ctively c ———— =p [ER m [see of canier A {| S_vF [sec of colvout. B c Ka/m? of _coluite: Co DE a rot BB = 160 crPfeen 3 AECH Loo nike o = tooo kg |S : > 8B > %00 ky/m? So = l200tbo ine i Te calculate. | eS 344 ~ g Tse leo cre] to! my | Dex teT x gan I a i= 9 4 =), Solution of Ac = eo Fem [roc aoe ~ uxtot mfrec Terke (ns mC sec of iG CG alt Pee s Ya = hs nag Flew eel — po wi JQ 00 KX kez a "= L200 Xe Ealsec —U) |_ Mays flow outs 6 I “Siglo fal a= = One (ork = logos, bles | \ : Mas. slew vale of Wace) I » opt Oru pees =) ol + AOD. x ke Juce. ~—C3). Inf of Cine me oO.) = leon 6-260 UF 0-64 f+ 20% > [oe o OY = IV eon y I = 3-34 X10. we _——$-—= : = @&F == Nw ko pepo a RO = - 3S $C SC ae tars flo “yates fC a 29.6 Gs aq hte) Set - 2 lcat Fa fl = Mass puch A =, 041906 e sR =O-2eel Eales = Volumedinie ( vale_of a # on Gea “eta xis = (z.31xi6" J = 50, 000306 Tm [gee R= 3. 66 et wm? [sec =} Ets) Now to final rex ss Patoo f- Kg leer of C. bo riliee of feu’ wT Ye { O.040 6 SSaTT) ail | 2.66 KIO mn [fon eS Bom kom [te Sees oi ba Xl cet - : Akh cate a I FOS SAE a A = enh TERE ¥ U0. 2 See ts Seine! 17.568 Xo ® ms PR.ou x0 7 Ee YY = Wee CR+ ms) = 2 e EmRSt) ny ¥ yy ab pan tex teiers! a EF ce xfo tt 3CL-cx Wy) a0 2.90000 349 yp S17, BE Xe (0. 00086 — $270 00 UE ) Ae xt’ Ceccoorg) G20 ALISTER —y & Y= 3X $.66 Xto'xllog2 1Oxte C3 Goxiet 2 GHO43-)) aero 6.00 00008395 ya ea Cae) t guaposonSy— I At = Lal yo pee See ce ee ; 4 RCo _ | Ei. = be ie. nig@nu 7 See Wee eer te seu J r D240 SF T- OSE ee RT et Soir ej 2 5 of = 3.66 xIo SRC AE 0 5= er “Dbo 206 Zz exe 7 3 ——— | @ cs o = G 2 ! octet te = E€ = ditro.dé ote Ce-262 D+ o.2b1s 4] (ae 17607 otto l MG | 0. 5V1Y Fomeovel) By : a : —! ——— 2 SN 7 _ Pox Cress Comont = cott-ra ction. i Hes sumysttory Wy Solvent Flew vate i SAA ob tn Lath — sbogen Cre ok € aes Zz | + Gadcecclto 2) A\n ideabred flow £yskton s Comsiclered ® Sheasky State Cross Cr — Fie a aa Sgt) SSE R, XE Ry [SR tae oH als BA palonet (MaS Component halen : c foc ath stage \. | Set So ghage > —_____Tnput of kK Rt En steady stabe. : . —_ Stage + Re = Sy +R, ——(1) | _Stage 21 @ RA = $y, tea, — (2) — i Sad EASTER ~_t _ - Maret Ma ——(C4 ) Lek 4 Be IS) Subs Phding GS) 18 CD woe ge Re =i Su RY) m Bece C +S 3 MRC Therefore acc. ke eq (5) {i y= Re —_— (a See Tmlaoly Exam eq" @ X= Ya = 8) Phe I | =a NS ~ RZ Rc \ 2 sy, + Reve = Rms a = yo — tol 21) 7 js eat iae vn Prog tog ~ een ES i _ € = Stu) le = Ess | aR + mirc) ~ Ru L Rts Carns Se | ~ m RC ; peed! - BR : k eS a - E34 8 ff eEms ER rere ae ae ~ r _— * = Fost 10) j i Jo EF, | nS ms > Js is know that. + “dabicis at fol o-3, os asl = m SOS ta Dit “ni A ls wo eS er ETE ft eS He Sebel lb HE |. ers et oo 2 pi 4 ; Te eu elie] | nl ft. be od ( i So ae Z Bip mate sh foctin of 54 ° lute th sak cane be__exfiacted: ina two = ecxDss = _ veut “cdlvent eatractto _nirrceyical ae of 1S'= 6 Ri =!/8 and 62 OL kg lm? 4 the ati oy =) are ; \ | Givev)_. et — C=O ky lm ee EL YER = as . mS 36R . = 0675 =) = 207838) hs : rE Eft ciency Mm counter— current : > eri de m iat, . ee Lo cpals ofa vo wed gba ee 60 ly 60cm a] fe 9 Foc cig phe a ~ Solution of AL in ei Shere “te pe being cwbracted trond PB ino duo shoge. C035 -Coomker —-cusneck “Liquid Liquid extrac - _ tolumn The dir hy 23 “aud clensibies = of A, B ZG are _leo00, woo & S00 kyle _ ER a Att the quautities nae J ; eee store pp tke te ake £ Leaving frown Steg e | to stoge B wf &) Valloot PE LW final 4 Gdiclton. extracted 9 7 RCO =D @= [60 amie = éxie HAO —) Mast fata nat of | S56 BI 3): Ls bike ae race 30. [28 “gl ey ee | at RC. te aber? fe - aus Rs ers oi [. her ux eonsider 1 ws of A 3? I and Harefere 8 = Ulery eA) | : tes nd) Mas flow vote of- A . | 2 Roo kt = IRD % kyle (5y ~ i Mass low rake_of. . F : top: oro | = B64 + 1000% ECT) | ak mos Fe Flew rab CAFES o _2 4" (5) + €44C 6) Te [ABDI LOW LODO _ 2D) o.ytamn 7 (7) “Riven wncentration of selrbrnn = LoL. ol TE pep ee SUD A 2 0.04) Ff Qon =i ldoot |! — 0.04 = W3oxf-- | ns ac - 234K |e No \ (5 Mas flow vate ef A =) [206 We Xe S)VIDOOK Bs2TRUOy 2 6.04 sly — A) Mas flow rat of &C D oo. — (000% 27 oY —= [a00C-34 xe) 49 OMT 234 G20) | Dory — 23-40: 0374 205% 0346 | Eg [ys —Cia) ee _ RC Volumetric vie ate off ) i = Wet = oe : = 1 3-66x] a - “ct Ci —S ae _ | C= pF O-0uF Cents) ~ zoek ul FM ¢) TE eet Sao - | a oat ae ——— Fr ee oe a ik a a a A ee A | ; “awe cilfon., pipeline’ for lage 2— __ = a ROX 134 veo 7 =_ x = = al — _ Sy = mec Tethys oy FX RETR He a-t6efo! TE CCAED ro) — By = 0.123 I Tub xt 4 at . : a 2 tas 4 ea {m> ee N _ yee “ Y, = me © = . = Cems) — = eo : — Jp wR Cee lx wT) RTE ~ — — ce = _ = Sexo ST. Xe dD = at = | Myer =H EKO yo. 2 OE ee _ E = SCE) = ze = yy ~ —€ sextet pias - | SCONE SOUT 393 oo 4) | Ee = SLU J ‘ 7 f ge — ___—_+—___—-— - OA 2 Of Se - Zt _ ms - = 3 -46l Met ; pee io KG KO <= 0.762 mt © = tel Br Ene a" Fos So eye = va eres ee o2y 7 lolit e- ote | vented se SF 12 m= t/g C= 0.1 kg | m . | OCR YR = eee’ ms a 12 SOT PE ss Be ple hy = Rx (0.666C-) FT 5 SS —CrerteteD 5 S 2.3332 2p OST Ei = oy 6 yf oe Counter cument ger (SS lan) Crss cunnout 8 U7 Ce = Jap Cross Comet e-7 CS=6EY Multis e a Alosowp hint Join Dovivabon of _Kremsey = Brown. 24 uation. > Gary _kamel 6 fo Kem cer = Bro won eoralton_ uek os. _tombainimo las ts__fecd into the tase of o plote__ absorption tower where thee solute 55 tobe stripped. from the qas_ by the alsomption in Le te kg mel [s ‘of me oily whlch Is fed ot bop oft olwmn—,— / The ue im the enboang! ofl _ts X65 Ko- ke naoljr- ond the solute Oin the ent ger Fe Ya, The eq uilihatvn canshant deo Erm (mem humbev of plate) AS. given Oo y= me C4, = mt) Wl Ym ond ty Mitmwole froctions.6f the solute tn gat aliquid pare ~stapegbively . Shove | cox be ere eet Lo _ _obsorp Lion feccho belt . _ ip £ = ae Cand He iti en =f tdond i hes 60 edbeiey = aieoe —fiven by ae ee Baers ~ pgp Nerd ak i Ni}2——_ ~ — uae Vp me A= 7 = ate ' nid ~ Balance ever m lage. Goat Yr Lo nn . = Gann -F Lom pee saa Ee Cua Cmi= WS Liye a _ - (23 —] eae = Yat Gyo 3) —sS Xale = = Xnte =O) Also Given: that a Ure = km ao —= (5) Similonily cas Nia‘ Veh a — 6) Puk re value. of Vy, ond Xo in ae “6 from. Oren ssi) ‘ TEIN Gaal Bist Le [Len Nx ote. \ cee cS ee { i | =——— = men eee for Cm= A Shas Past ioe a 7 = S Biel ih a ie J 1 1 ~———Subskiheting from 8 and (9) in ea (2 du Ca 44 Vf Mm 8 oe Tite Aen my re Gry Yen =A J ite) a 1 yn ednoage “Em Gra. = Ent Gin ape oc cr a irene - oe : = Gotan ae: an) f I — Amtek ob Am=t Yenat a Gat t Bent at = Ben sy | = = Gar Cou. =m). ery Gua hina ia In adles 5 = Ga Sine = near —_— soak “GiBecin cat = Gay Ye ~ Lisa es 48) in {Gott G) i Sie cae a — | | I L T ‘ —~———_ Naw I ee ‘ Yar = Nowe Cont od Sha ! (Gar YW Cn yt Orn ! \- ' | ' | ' I We _ Se ap o———_Take the mean _y voter of Absorption ' | re there Am kA 4 $a ae tS ema fe Moy. “ Ceba’) Ae ' I " Ee Hae 1] | | _ Nie Inc + Ae ‘1 : ae ~ ae - aa er i Sed =e Baas us i Now- et A — a Vor Cl a Mint tO Sencte = al ne ecrp) = Bm : eg 7m Nims = (AY gy EP mt =O - : Ss eee Auni Equation _ Bu the method finite olifference’ | His con__loe_ eel o Ee ementony fare o ee REE. on, order or degree Villon AsE ='0. | a eereeringt fea / © _ | Since. C22) iy there. opercke by Er ~ Nar —Nn-n nt o. we vy +8. ane A aE— Nes 3d Na Ce cay -1) = © i = Yar vy Bt.) : ex nis — Soa a er 424, =o : | “E> = ott = Eto gd 7 New. eq ( Seat = ny Re Pe Operate .€90Go) with E! A Moa =" Crya)y Nowe AY | iM = OFA in LEAN, =O a NCE Ctaye + oS o ee ea See Aaa “6 | SE CE —)). he A y. : I a Ee beat A= 2 I C-ee—C +A So T EE CE—AD SE 1 Cea JF6 pes ceraysa : a= G = i ee Gta Ae A == Gad 2) Ties er ——Subshask aS 7) —@ cy ea p= Se aoa Q = G TaN = Gia tess = 42 F it —__ | orm lan ty | =~ - aL —Substracs Cay’ ) ) =i) iS —__ i Ne =‘ = On Cp —— 416A anita Ved = Noe Ctr A) ab 26 ) Divide (24) by (25) Parent o bog So EN =a waar “wet NC | += = Hence kremser — Broun es” is pros d *& ome Cnperiments ari cansifeol out on Hare _absoyptio: £ Neantn Let ste [ak ccbanasphecioe paiva he realy AL Gas vate of at bottom of, bower”. ft = 0-3 Y_ i Lose Preorder de botopope net I I Meee ) rau Canta vate ot top, ~ / . + Lo = ar msew The CO, iy —the—intet: a i315. ppm oe aud in the emit Qs ts 8 poem YS aes 7 \ find the. male fer chion_of CO, alesovbed fy peak CY = 2). mo on ght — a raickgt gate Oe Y = bo 2 2.94 ky Lins ON a contains as XGo™ Heo Fa Cet NaoH Tas lent aes kB — Crm ive) 4 C400 xe) = joe Tre = ooo + e260. ~_ {o.OD SF 2h) ky Tool, Mant bo = 3. ET 6 ae, Emel [mtg 1 roy 1 Sg Vv ! Pera £ b fy Preppy ss Zz x y 15, 4, v ~— 0 (216 X= Blxie" et j = saat “ste % | n x I 32K JO xX x | zL f ~ ONS ee | Z| AE Tote ; oe |x r a IP he Le “wlulticfage Distillation _ Can : Ta cenkind, islam aise tleution column _ NS fed with a “bina naire of- A¢ bh. - the velabvo volatility p¢ af the mickune, ic _comsauct - Devive ew di (ference uation thal pelates tle U'guicl — compasitim te the plabe pumba wn. Consi~ Auritig ovenadt- CfPicleney of-_loo-/. =D Reduce the equation fo a Liner ove. with tons tank coeffitients Let Arty be We wole frackion of mere_valatile, Component i ts Ta leaving ue plore Ay fe the molt fretron U of mow _velodile Lempment Vn product isithdvaun fren con oy YA dee Te wule frach'on a rove. wlable- componeutt=_1'A he NOdooun in ule rit ae Miquicl com osth'm Noe Hie ole | Fastin sf Muc ats the: “ht Sa “yn. WZ 0 he the comslant yy! (tow tak ce | Viquia down the column lee the contfan ———_l_v Low rate _o(- Von} the torn. Ona ZD Ne Wow rattan fps eer he of the pada odin ele frons the. _to toncl om sory = tpn balance “feo Wino = 05 = ee o Stuce ’ SS as a. Leal TOAD Xn ne u tL _ ? TEES = _sat substitvke. jen Tne a — - ee : yin FS OG 05% = -—_ + CDRA iS Ww ae = pan LET) =D C1) Hy =e WsCatn= = ON, en (Ro Pog —Dmp mmmerenie at Divide by ea Te) by. OCK ) > Vo ip pT Amt ote La) - —Dxp 6G.) + DAp nT! (5) | 9 | Matlipl Int Cay th a = 1Vxano + Xn Ah M- An] x8 Pann eC OGD To ——$ tn _ I - Lat Un. Mat DB f{OAp Any ry ie ee oO - a a 4 a os : ln Fin ina EDL OR — aaa Beatty . L t Dip CHAU Viet) TZ ‘ Un fas CO) OT i eit 2 lz | =o t SAY) a I Mn 4-%n- On -H +DYD. = Log —| oe) | 4s (@=Np — Ve] Cela 1 I 7 - | mE 33 = as] Ss ao —f b= Php Cx) = Vee ———_—— . ==) Ce Dp. 0 Ch a ge ——- a2 ain ns ns AE CE b tna OD || 4 65 “ae equation “CRBs ) Pal eR InA-S- in _place_of- at EGE + Ont at 6 tb Oty 8 \ zl _& An ) | @ = - 2 Ain pe Mn EE MH-18 TSF Wa P Sa De bx, te Eb =O CD | Mi ppt ea) | eae mee oma CTS) [2 13 | TES p Cath) + ¢=6 a ta) Take aaa tens Hence’ Ans An + Nn Cc Or §) Eo Chia) 2 9) — ——_| Divide egh Nl \w) | [ots Ana) ne : 2 ea 7s Cb Jos éiiccristesaery Lai af oes 8 aia —— | aiS “bees = a iy — | P= crs bene Cay 7 a Ib -~ 26) pila Put __\ DVO Ee Dee i Morr ; my = |! L120 ae noe 2 ety ~— s Va (at8) il Te Cots Seo ry L Caleula te - LCE SE Tha CES —E ee CCb+5 ) a Wn te) Tp bP) =I eli) Si For Fhe eric oP om Frey nest power _ 9 { ‘italy ‘ete a ne Vr ce ay 34 tN) - _ Eats) Easy ‘aud eROW oe Sat == Ses ! Complete ee is CE +t f Cc A = Cade iu me eee ae bts) CRIES | Les} a ul’ Astiqnmenk _ Bz a eal A_benzene = beluene feed con pining 6 Ln Sno}: = tF Lbenvena ts fod conbimusus ly faa ~ dilation column. Te there are iy “ plates betwen dhe boiler ard Has feed | plate, curd tr toy > prcodl oe - Ie moly benrene. vlad Abe guid — ——____leawi c Vease of he column contol ——__ & mol. is bene : ote the 7 ——leenell glade eitlocily gf Hho. pled clin = The feed mtos theY eolumy ot ibs bn Uy. oe point and He nelahve velatiLity of beer - to toluene can be considered be conskout ot 2:3, The are flu yaho & aL au : food (F ~~ EP let us take a basis of {00 Vo weelal | an D_mele of diskllete, gw males of = gotduel ; 5 - zi oo = ptw : Gy : aad ot Co = oaap oR gw [ry i J 60 = 09D + 0-2 Coa Ry . i ee D) = Gy Tae Ea eee fo = O4vp + 2-0.02D G 6420.6 D_ Be oe bOY Th ok 2.96 1 : | T {| | | | | _) “ia Meak~ byansfer operations — jo _ -k Modeling ytkecke “Unsteady state Aishibutest panarsotere n'g fol! teat model. AP Let us Just considev two Cucebbn'e cylinders : in _suthtch temperature and heat [ew ate - per unit area C flux) (GQ) are ho I bo © c : The heat balance 1 welated to + £foace in berral between Y and » +E Sy - analy % \ | Va \ Le | nw : [ {a AA \\ =F _ - container Radial heat Sloyns throoah & eglindyita| A [Te e “‘tonch hon, of the. system cpr eile sade _ ——A_$. pace _inevem ent Spe a Popevby of sycbem _ at fn. Ate Sy ') Temperature: Te fo. TE ash | jot te 2) eat Transfer. whe . RTCA GA) cata Lunt length nm Fikes tile ti ~_3) Radial cheabs * 6 GQ #td@ fy flu, density ae Cas/ ods phew find Jeo i dormer, Tel eee ra Qu “Le Hee oy ; rr@ Perle sy to ae Nene Ho aT +$r) | SO FABS. ~ se uC ar mM __Cony ot elSmee tlickneys | fle fee lo tlance is - i Heat vrput be inner suvfue . I = 2TA & t [Heal ourtpul from. glhers ie — areca 6a) (4 46-0 Accumulation =o . Trput ~outpub = accumulation « sag — an Cats) COE AG sn) = l Hh Dividing by ae throug out’ we gat 2G = nO! =n dass = QSr “gaa : an CTTy > 2 —~nd6_ £9 — QSr. ag 5) =O = 7 Cis din =) “pre ep GTS — hd @ — da Ss = oO . To day Taking G wail: $k — —rd@ + Qos oO die _— — 1 beg ail ~ Sens = oe Rita fen Pourter ie: Cau) 2 ~~ of heat conduckiowm aS = = kar =I dy , : ig +d ok Flare 3” h ~dnr , J) - Substitute j equation (6)aud(1) 3 ~ ec" (5) _ oe me _é & kn dt tap = 8 —US) ~ ‘ dnt An —AA =“¢r = — Ag = es — feel na Meni ee _ er a pe == _Thtegratug oa CO) tes gate eg Sh Pe eS eee trans formation Salas ce could be hie as 2 z In@ =. 2 Maa ft Dna — 012) (T= Oy A FT 8 : he Putty tae of vor ec (13 ) is yes. ofS panes aA al ai —— (a) Mp —_| ae ae eg C14) La lnk = er B.— Ts) he fe eA 1H) comprises of tas constants \ &B New app lyi 2. boundary candi Wong AR A TET, a UE AR ns bo TT 07) rem gs 5), 0) ¢ (i ST ina = LB tie) eK — : — —__.tnb er KLEE shia lows eqs GR) — 09) rue gel 2 , jana —Inb > KC BY te a : = Tina — 24 Sas? TF Jnb —_—_— eo, — 4 fh, ~ aie — = ek | Gs) a Fling ls of 7 eos Bi gia — nh = “kT Cina ht D+ ig = Tak Cie) — Loa) OT =(hel: tea SET] nat Ink 4 Aading. and ant “alsa Fare ue oO Chae ax (Jeb = Ing \r Tea Rib + al Tafa: Teles =7, Thank _— ek i nb ~Ing Cr Ts Yt 5 om earner a= =) u rT earn YT Ty) ffab bee Iie ‘ “Ge ~ ia to se dn = Ig (24_) oe e rere »wlosy, for, aul show, de vartation of— T with Hes Aah 7 ~ NK J A halle gAunder with cn aukey oliameter F 7 PL 10 tm nel an inner diameter of 5 um: ~~ ho_an _ Taner surface 2 ny* “ nur itis —Staface temperature ~ Determine be tenifreratune “a f tbe liad ~____hal Fy ay bela “tle «Sinner and Surface Tf the thereat to Corductivity » the eg Ado. mateniqh is 70 W y I detuimine Hee heat flow th ot th eg lirs den a. ee smoke 0 Given thee b= > 2! Leven ae 2S MG 1 =a w/e » ach Gore Dn Thi bo' f 1 T. H1ee cw 2 SE Gates 1 le know Feces, a 8 = Er a ¢ - a —@e a x al Xx PoC Yoo 10? ) = ns : To” Tee $eTee 0.643 QS svat Wim Halfusay between b ane a’ the" vac ps SERS = 315m, we) to 2 ¥ 2 [Since = fe mat -— Ui, 3 be YD t TA He EG. aie TE G19 RR aa ea Me fe" The teet5 Apply tiny Eee aay Conditions oy Caen Can alse bes) wajlten fe Tait Cy4n eh EG. He > 5 3 ) “akadting 5 RB Rom C3) TF as —T Ia Yk we = Gian NG =U Cn te = T= —h EO x2) 4 UY “fe (eT) 1d OTe Sty | at = ae Qs) {| In (ao Tag) a e fut Value, wef C, fw 4 "GBs to tt fer : = mS ee A Te ae Chey Bh Fle FG -46_a gy MBY. _ "GRU NEE Ze EE ea SETA Eee bat ChE TAD) ies ria ean eae ety 9} T= = Fh i Cann +e G —_ - Lo ~ qoqe ae OT EAA) [-T — 6. a — A S | dn (ro), ; —_] + S— Cert bid i = __| Yk a Z ada eis, ental) tn T= ae ote) =t J+ a CAS = Fraley bs pat n(hoJy,) Her < Oh — (fo) lobe) —— 2 Te SRT ha Cala) Ty San Chali see = ee We Sachs me “a it — 2. 7 Lae Tae (fi) rs 40% S ee Gh Dar) Qe Gh) — | 7 T-T= a {a= ae arn . Me | tl =T petal - ] 1 . 7 , In a a ~ | “dyhanue., “Luin pe coe igi p iS % pee I shat healing af baa c Ted gle of folal sun facetrsa Am i heated throudl tats a. secre ening, Leah — sa eae k, The as ketl(. is f Gauid wid of bead, feat a he te Geer eal te SHI Bee fer “Mii x Te 2k temperey > ie Pq a ony ee Kine 9 a) Conse ‘devirigi Sa sbimessjater ne Heat | hpul CS) =I hAaeeo — = Heat ol upput Cz) 0 ~Heak accumulation Cp) MOE CpdT.86 (x) “¢s)2 : iC a 2 HEAL 7 apa = aulquk= = acciunatil a bten— hADTSO_— 6 = Me at SC | de: sii Cup Tha CL Sr 36 2 = MGdt 6 a Nas S ? eg ALG EEG 7 ) ' — aes peace sess tae Cue 7 when fae &= 0 yO Te TF. _ = — ts Gy = Ts) 2G, cA ewe eee a - 5H , 7 G 5 SINC ET) rs la “value a fe tia ei CO _ | _ Bart: Tye @. = in (t—T)

ES =v \ > exp (hE “s—F5 LEM Cp L {iP ee a _ vessel. of _tolal surface cores.” of 4b- me dS: . heated throu h Hus surface )yeomdensiing- steam ala. bdmperabune of — i oe : hs “vessel ty thers pe _ at bawids Waving: oa heat copacity ef 251 ot f{kg Peat wtllnp actu by P. Yeo. tf A precast is_controlled_ by o_heat-branider_ “coef freceuck of Val [tile E mod rl Hast gy stenm in limae vsionless: forma cu d —find = eile the Cem perntur. of he Liquid - cuften. 2 ene LAs . JI +i . 2A_clotedl. Sy He =. oak = Uo mo ' T= loo 3 37d ke. w= 600 m ~ Cpa. 2512 Gog T [eg > Toe 2a yk Sete wo Tm Rt Tr - o. 373 _— = a [= 40 X{yr 3606 373 Smet \Goox 22. ; 37g = T= et EB .56 5 ; 75 oe | Z 4 a 373 —T = 2820 y¥ (Oo ne eM ae keg lsee sptulphuniacse satrd oust Che Inet ~cavpact by arid 5 Ft 50% a LK9 eco Fo [be cre lean’ covet Vourerl-A, “ete acd { oY °C is fed bea tank pwherctt i “skimmed whee in cortact witte coaliicg ceil, Mees» continues At se ay 2) Pow the? foul gs SOc flows to tap Ye cond :S bivved texk and leaven ak 4 C . Cooling toate, ak 20°C. .Flasg inh the cold oF i thee ‘second ton saud ‘hens bo te tetl of fine tanle + The wa ben ys ak 7 err os TE teaver the co Bro eee re weal mae f each bank 750 patey bewmpera trie be Ese. a lune! ach tank A kis Wee oa ace aaa wakeup BAe } JJ) II J) PP) eD'C = cae Qo Griven thot | Mp _iv1ass flav vate of acid. 22k 16 _k4liec Cop = sO eT Pega Sete es Tt ah ane Sha aeale t —L_bee = BRiCu atl £ es a Tape jet ho Ga ye co ou w= 2 i _ Vw =? G=if _ Tp 2 °C w= 4536 ks : . My = 2-476 kale = Z Cansideniny the, heat balance onaund Tank. Rake of? ome = yoke of heat oukpul ia Carling water i sulphuric acid MXC XAT = Ma xCp_ X AT 0.476 97) (Go-To 7 =(b.26X1 88 Ve tl 26SEC = 4032.35 us ~ ~ CSUOC IE - Ts = 4c SUIT C Le» Tntermediabe tatex ~tenkptrat ahoee 3) ) ~D Coke te coating eaale suppl fi Skopeed fox yooo' set _o The'rate of coling malty flew = 0 . These favo. Macy is > Cun € ace Leo A nat a fates because — Gere sue flotoiis ue tpor this ce mati ae Bind gm (cl Ter’el pevelure b Bulle crepe tempervatue of tank’-2. ep HF JJ JID) Toa7 = tye B= 360056 | : PFT = Matin Te. = Wf Pn ATi. ie Gy fff ES) f * fe I Fank 2. PV Terry — Slee Ta 7 EN = HM i Vex at) Ma Tan TR) = tae wa dO ATA iin: GT —_— —_ I th inbogqvaling PR “iiae Ce — (Th -TA) Ure cy is _ietiepplifing BCT Jo C= O + Tip = eC SER Se = xe “CF Tht tin = ef) 5 Nevo publing. evolie yf Cine eal ‘Gy MnO ® = Gee SX ) —p . — ~— nGya TA) Ting 8s) Fhe Ga, és =_Ma ©. - a = te ES : From” Easton GE) —i . ff VW ; , ip Ta Mom Tg = Wer EG ip a Tan) = gs a Me E&rp Ch vo =U) = ae Cop Ae : L Ls 5 i Reoamainging &N 2) Ma tia — Mn, = Jp Wp VW) py de zs : ATp Ma hy = Mat, == [13) “db We, Wy Pak ae. value. of Tie De Cy an (0) = | a] dtyg as = Mia LATA BB ean erase) 38 Wa Wa _ 2 I : Ce) io order DE bo be solved ty dsivy, On Integra) Lacbow at —§_!— 4 : ee etd ast fron) ai nl baric ™ oydin DEH = - ee ate ye pg “Ae “ a sor le “(oor EEVERE c tHe y eOd.4n = Cy) whan TP = We howe, j += Tao nt O 6 ZS tendavd form “de dp 2 C8) TP a8 __. te} te} 7ATTF) = Sots): CTE AO + © : i oy ETA) PCO) a8 tka Ie e — MTU. plow em owe tp Find Plo) val + Second od Ae from GWT of nso 216) 7, A_foom_ ail! eave Ste 3, A =) ple) Th Wp bt - Ma = P(e) — (22). or 7 2 fp -O)a.0 Tf = 8 7 m — Fon db fpun 0 MA—O. TfL = pr Gime thal Ma = 6 Wye usst 1.28 of af = st 9.79 po ap Se Fron €a\ UC) and (05 GE) = Ce) (TE Van 4 © VA CIE) = f Ole). ty ¢ AO) +4 ctr) - call ab © {| 7 fal alt the viluen we eg [ye : a a ee ee m [hie 86 enp B19 = : ase 5a pating al values Rou ee Ga) Se ~ = [m pe =eeenp (=2.72Fx1070 ~ Oo = = ~ ise aie ¢ doe \ (zs) | c1.79xi08) c Pia, 6 ~ Ma | hfs et enp( LTA! = ! Wp aor y jo! | te Odeo | C2.1kx\0"@ \ E J 2 @ i 21F X08. | = Me \ ace * as) 1 =¥t np TATE Sy a 7 (eas 4 220x185 oe ete “Tl T = : ee a 3 2] Tp & Ma {108 Ss ee ee i Pr a Seal L I Ae Sees Speen E ee es -_—{ vine | (8 povio 1 e = Ma) 4g Fan HC St EK LO. Tet wy = \_ 4 Net pati benny contin — pt eso bene 65 0, 1,0 = ee : bh Pena} S Fen UC SCH 22.7rY 10 [erie | 15 uc = \03.999 +O A = ro) 12.9 ee! Now puting wokay. _st cin fr Qu) agents’ Oo Fas (Wee, = 366 | i Sar Pre l a rai TEKS UO . 2 - —ty Vap = DABMO \T4 ZS ) rn Taq wen gE “7 | — TCT TIER OS a 4 | Gy eeeyte pu = BE OuE We ee a | ‘ = _1tt4 so Bu — a = Ta eu >< EE0GE Aree \ 2-68] ee YSU ER x Tet Ga = 94.78 sli — 27.102 = bet RR Lap. = 4 =~ $6.06 2-120 Y lo 4 Ta seyle Te = 4 — 3 637— 47.414 Vp = Tame Dhow ite Sanaa : | Enrollment dlumbm 3 4apTolo C4 | Branch 2, B Teh chomical. | Suibjeok iin placy Assignment AQ restecds state UT through tubulay —« \ i ( aes prewedkew: Lo A cupply oo fa hik_atys tos be obkathed , CT es —eald—air through the nbed cy Uindyicat pipe The pipe iy 0-1 min “diameter cand 22 mow awd is maintained al the oall tem perddu, of Thy BIG C Hrpughout tts Length, U6. average values of ax properties ary Jd JJ) heat capacity Cp = loos Tg @.. Thermal, venhuctn by = 0.635 Wier »-densiby R=. ney ‘ Lae _G 3 Craw Fate aT Riss ¢ Zc “ht evaure = 24° cad the heat Teanefer coofteient |= 52.3 she woheve iy the drctauce marasured 1 Alme pipe intel Assuming sUso Al wheal 7 ONSTe™ 1) Conduction within the aac im the anial > Aivection e 7 L Bu mas flew of the gas a th 7 —) antat ¢ ane k Fen <“§ aa 4 nih in co 3) Bu the above mentioned rarvcablos alon From tte will the Heat tran tfer cwefficieurk waolds of the tube. Ch eS PETS PIPE PPPS I PPD PDD i il } | i i | i : evel ma thine A'cad model foc He _temporatine —_disbrybutia n_th_ the awal L differential irechion in the form of equation faxa__skeady bate condibion Creat input ) CHeak oubpui ) = HT Hoo vis fin ERAT “kaa ad Fenor 9; taal) ~ de dc del dt) * LY\) 2) BY mas fla US CT U8G (That sy \. | Gna)? Gan) | ta 3) Wa beat beds) (1 TY _ bonito Corly at te =n wo adh) 3 I Trout output = 0 Gleadap afte) uo~ = EAL usar tb Crosx) Th = 1) 1 Z 4 = ERAT FA] -En aT [Sx_ | Eoghan TUS aR) da 7 r _ Cr yw) } || TARE: a = rane : js! a soi a Loh Cr b Sy (Ty. tT su oe gona a —— = TERA it RUeae eee 7 abn ) a Si Mire ty US aT Sy Sal peer eciaey E ay ei a) a Cra Cs ST esd (ERAT au PEE Eee = + cp dT = 4 2 hepa, oy = =£ Pe tusc - me tse ye \_ 75 dT ft 8Co ‘ar +¢/tr ph VX _F )=6 dye LER dw Ep FinnF ~_ f3) ! Put ~ Toate 2 4 ~ (w8G\ at Syl WE { done Reel Aw Gee) 1 K 4) \ | pul A > Ty \ UG STE | SiR LON ETE ws! Se LO 8: substitut Ung value of Pn ie LA, @ & 52:34 ft utp \ ar (tes AO ia Ant Sess F Jan | usp = TET x fe xO 601 00S cP 25 xX 214 x pmo) q = © 33F QUT xed Da atx! oot Tere a7 STK ya ~ 5.98 x10 ey yk | cae = Cap hh dk t= dE ee eh aL rane ee — ge oe Az = |. toe? Tate ae eee oP else Pail =e a i Se 2d (aT ‘az—_d» \_dn_) a sd Pg dt a { 7 At aide an — tr Ede \ do —_th 2s ti - Je do I 7 ne ae fee | aw OR 7] 2 I as — eee I ot ae 2 Nee zl IZ ete | we _—_| —_—— Ea f TT aT PEE ey Gai dp. dz anil cae ba ae dae dv et =a ‘asa Bete Lt Lae t IxXX Was ac fd Lteee) Cutting us ih eo uation Cu ) : ¢ dxr i . Sue get c Lote gk (ewe IE Got d2tr uzsedz! as dn Sea ek ee fulling 2X =2 a Ly LE esta ts —23\ve dk G22 “daze uz dz “a7 de + secre 7 Lc L£ 424 Lak atest 7 Tam | | Ga» daze dz Lu * a2 | { + 5.4¥ xe E Psy Multiplying by byes Gat qh S tf ate Sa Gee x(ee J cts vit 2A =9 4 z= te ord + = Ty TR i MS dD fe e E | TE : is Uy ep eatia —ha tank ope fel mined Uquid eae in Aig une 1 —intorwhich flours a -_ etreoum, at- a. valet dole sf Z tA mince, wPlmin) od _p with ov rclonsiby 8 SoCllom (FE oc bytrd).. The volwengbne 5 >of bight ne ack is, WCC or oe) _ ma iy. densiby is yd Bi hos “Tho volume flu rake, {yom “Rao 4 sank is Fi, sus “a. Aue in wee tank He tall Hs yore’ _GO_ _Apyose waicroscopte sustem | Since_ ev of deine ond es Size_~~Tho. wort bolance is onoalund ne whele bank nok wale o smal di ferentiah element inside Meg tank. Ks Ro — Ee — Lime yoke af change u—~/1) The ewils of abis cqualion ta Aaa [aia oc kg | erin “Vr : e c a (a +t oe ain BE) EHD MOR Sg paallg aah —_.._shensil. 1S _-bhe scomis every heros tr Elo ~~ Wonk 3 bk cow nol Ws ositlh sot ad ~ pe dake pesibteny ieS thexr ene ta ~ epabiol gradi ants tn “the density nts : ~ tank Se is poly: wt cceun Yat maevos pte. system = TE oben tmeone @ IMrok Alero ict Son g Bhe fyrdeperdunh vowable , bo. ~ Guce © and V ene Eswasbyt of t r ans ondt dont ve oH eed = 2 Aig fallesife B28 L ACsv. sty ts 8 =) ab. Rik: : BO vit) p= FO) Jock) FCE) Ss 5X Fluid it Plowing Verough oo cotton ~ diameten ndutcal ‘jp shebchod ins Ey a ae flow is tunbulenb tad, a there Pane wean esse etn = cond tous/, je.) eoch “slice 'o! guid Fiowr dawn the pipe as _a pris Waone ang -no_radial qyadients in velocity ox any sropertion Lowe ver asta) ——_—§ gxadients Gn auish}t dz teal Is - 7 \Z eZ yz) | Ps Zz zrdz zel — Densily andvelodby can change ar He fuurd 9 Claws alevy Woe awiod or 2 ds vecbton , Thee ano now two yadlepenoent vantables: timo t ond itr sao i functions of ote + : a ee weA va contihurk equation fo a Sustewm that Consists of a emal\ slice The sy Stenq ‘ a - m Lis neu o “waierosecpre owe , The —_ differential element is tocatet at an | ar briva s ob 2 dAoum to pips the L's wa atic ond. |prs an area oq val (a tho Cros secklonal anon of - the bie BCR or mt) : aa Toe rake, of - hosag nos inate o Sy se tm. pa) Cy * ‘Ne Az vis. he, aes. ef 2yten | Sis ens ret Tiwi Teh ey wate I ow kg. Lat TU : Mass. flows ate = inks sytbem Hhreragh — Prunes ak oo _—— teste Ee Seo Gin HE Mass. “flouig ous oft: the, siten ebay eae of 9 21 ae { de VES t 2 da —— — oe above. poe oe then Aend _ Paks Dido ive bes to hewn ian a 7S ata Nog jon va romaibte 4 re pote 9 Aud 2 ce wulue Fancher ob said oP ain - fron Zz to —_ LL ya | df_\ dest (af) dee a Fata Tao QI) tL ae 4 { tay = - Th the ‘dz iis small, the serio Can be truncated en the fivst derivative i korm tetling= Poy svt So gives e @) 4 Salostituking these terme into moun fqrrakien gives \ - s( Ag de) = VAS — (vast adazl Sek =r gaz =] rH — Gxedking ok tHe dz tem, ant BES Wha wa OA ts constant yield YW 4 apse ——é) yb edgy sd 5 25 Consider Ahe same tank ofp erfe lig st cmteed Ue uty Haak -we “Gaeb tn 2 tac PE Mls va chemical "9p BLL In be = —— place in Ae Waut in 4bo tonk = De syckem 1 Wow ob wr Sheuty sine ae é ae S “racks —- a tyevecsbli = aud ah _9| bei Pere, sO a wea kion m sabe k bret ped, bo comperent_B So xn EB —) bet hee Flow oF Ac inbo _surkem =F N Cv) F Flo of A out i =D % Rate of Poxmalt'o of A fro : f-_forma na Aen tela ae Hus__sign comes from the fock thoaf te beige coh sumed, nstiuperduced. Unity are some Mol of A [tiene Zl wak of Vk Een Sensi 7 5 (mit «Pe to Gan? Time rake of— change of A inside tone rc aS —— Censbining 0 ® to alomo gia al Oe) = bla — FG —VK, {ear — ES) Since) Hee systena ti! bina f ea\(S) Can bc also withen Qo Bois_produee ¢ A(t) Fs Ceo = FG VEG, | Ateemok C lu bbe saaty task a Lt MAG F Mp Ca= 9 Oy ES Nge Mal rE REE at Suppase we “Teasressthas samne’ Fmoeyesc epic Siem or a dniersees Dane hol a Corsdcutive acackione occ Reactout . oon to B ae as ste ate clean att ke bul 8 00 ark ok-tin _ = speci fre neachts olen Kes to fw hevel co wp omen ae . Be = Be Cc 7 Covey ments A, B Cane e AVG) . & -EG VEG a 2A C) ACG = FyCgo —EC@p FV KG VRE b> Ear JE Ceo EC AVEC ES = miaubaln ae EEE = Sarg Par AGI J=A— CF. Tnstead of (luutl flawing doun a pipe agin Bh 3.2 tall paola the pipe is an In Which the same heachon AL -=> B sf fx ¢.9 laked place, As ao slice. material mover down thr length ho ae — eackey thee concentoakion af neatkant Ca sdecreases gy AR Ie | Consumed Dene $a an He V4 and oo Meerctr ection) J Cy eae! Lal) ta Qroi tme and anja pasthion. sHUL assume plag flav condittons sa ee teu oe no nadiad eee iy. _velo ct by ralensity- Lox CoWCENn st -—- 5 Gaus 23S et - y=? z Zaz 22 . Tubuloa, : reachy . Co entratto oe Ac fed \ Ane inlok of The tke ak z2=90 defrne A wo Cee = Geet wo Fe vation of. A-in the realtor’ effluen ee at Gace = Carte) == 2

You might also like