CPP - SANKALP_ISOM-19-PH-IV

CPP
ISOMERISM & ITS TYPES – SHEET - 19
LEVEL-1
Q.1 The compounds C2H5OC2H5 and CH3OCH2CH2CH3 are
(A) chain isomers (B) geometrical isomers
(C) metamers (D) conformational isomers
Q.2 The number of primary, secondary and tertiary amines possible with the molecular formula C3H9N
respectively.
(A) 1, 2, 2 (B) 1, 2, 1 (C) 2, 1, 1 (D) 3, 0, 1
Q.3 C7H7Cl shows how many benzenoid aromatic isomers ?
(A) 4 (B) 3 (C) 5 (D) 6
Q.4 Molecular formula C3H6Br2 can have:
(A) Two gem dibromide (B) Three vic dibromide
(C) Two ter.- dibromo alkane (D) Two sec.-dibromo alkane

Br COOH COOH Br

Q.5 and are

HOOC Br Br COOH
(A) Positional (B) Chain (C) Geometrical (D) Functional

Q.6 Which of the following has incorrect relation

Me
Pr Pr
(A) & identical
Me

Me Et
(B) & positional isomers
Pr Pr
Et Et
(C) & positional isomers
Pr
Pr
Me
Me
Et
(D) & homologues
Pr

Q.7 Select the correct choice from the options given below:—
COOH
OCOH
& functional isomer

OMe OEt
Et
& metamers
Me

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CPP - SANKALP_ISOM-19-PH-IV

CH2 – CH2 – OH CH2 – O – CH3

& metamers

Me – N – Me CH2 – NH – CH3

& functional isomers

(A) TFTF (B) FTTF (C) TTFT (D) TFFT

O O
Cl C—O C—O Cl
Q.8 H and CH3
C=C C=C
H CH3 H H
Shows which type of isomerism
(A) Functional group isomerism (B) Geometrical isomerism
(C) Metamerism (D) Position isomerism
Q.9 The type of isomerism observed in urea molecule is
(A) Chain (B) Position (C) Geometrical (D) Functional
Q.10 How many minimum no. of C-atoms are required for position & geometrical isomerism in alkene?
(A) 4, 3 (B) 4, 4 (C) 3, 4 (D) 3, 3

LEVEL-2
Q.11 Which of the following cannot be written in an isomeric form?
(A) CH3–CH(OH)–CH2–CH3 (B) CH3–CHO
(C) CH2=CH–Cl (D) Cl–CH2CH2–Cl
Q.12 Given compound shows which type of isomerism
O O
S—O and S—O
O O
(A) Chain isomerism (B) Positional isomerism
(C) Metamerism (D) Functional group isomerism

Q.13 Ring chain isomer of cyclo pentane is / are:

(A) (B) (C) (D)

Q.14 Which of the following is not the correct relationship

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CPP - SANKALP_ISOM-19-PH-IV

Me Me Me
Me Me

Me Me
O – Me O–Me
OH OH
I II III IV
(A) II & IV are metamer (B) I & II are functional isomer
(C) I & III are chain isomer (D) I and IV are positional isomer

Q.15 Which of the following statements is/are not correct?

(A) Metamerism belongs to the category of structural isomerism
(B) Tautomeric structures are the resonating structures of a molecule
(C) Keto form is always more stable than the enol form
(D) Geometrical isomerism is shown only by alkenes

Q.16 The number of isomers of C3H5Br3 is

(A) 4 (B) 5 (C) 6 (D) 7

Q.17 Only two isomeric monochloro derivatives are possible for (excluding stereo)
(A) n-butane (B) 2, 2-dimethylpentane (C) benzene (D) neopentane
Q.18 The number of isomers of dibromoderivative of an alkene (molar mass 186 g mol–1) is
(A) 2 (B) 3 (C) 4 (D) 6
Q.19 The total number of monochloro product obtained o chlorinatno of isopentane is
(A) 4 (B) 5 (C) 6 (D) 8

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CPP - SANKALP_ISOM-19-PH-IV

ANSWER KEY (ISOMERISM – SHEET - 19)

Q.1 C
Q.2 C
Q.3 A
Q.4 A
Q.5 A
Q.6 B
Q.7 C
Q.8 C
Q.9 D
Q.10 B
Q.11 C
Q.12 C
Q.13 C;D
Q.14 A; D
Q.15 B, C, D
Q.16 C
Q.17 A
Q.18 B
Q.19 C

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