M.M. : 40 DPP # 05 TIME : 30 MIN.

1. Column I Column II Column III

(Compound) (Properties) (Number of chiral centre)

(A) (+) (P) Optically active (W) 0

(B) (Q) Optically inactive (X) 1

(C) (R) Plane of symmetry (Y) 2

(D) (S) Centre of symmetry (Z) 3

2. Match the pKa values in Column-II with compounds/ions in Column-I:

Column-I Column-II
(A) PhOH (i) –3
(B) CH3CO2H (ii) 9.95
(C) CH3OH (iii) 4.76
(D) H2SO4 (iv) 15.5

3. For the given compounds, select the correct statements :

(I) (II)

(A) Compound I is optically inactive (B) Compound II is enantiomeric

(C) Compound I and II are non polar (D) Compound I and II are chiral

4. Which of the following statements are correct :

(A) & (Chain isomer)

(B) & (Position isomer)

(C) & (Tautomers)

(D) & (Enantiomer)

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 1
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5. Among 1-heptanol, 2-heptanol, 3-heptanol, 4-heptanol, which of the following heptanols are chiral :
(A) All are chiral (B) 2-heptanol and 3-heptanol
(C) 2-heptanol, 3-heptanol & 4-heptanol (D) 3-heptanol and 4-heptanol
6. Following compound can show :

(A) Optical isomerism (B) Geometrical isomerism

(C) Optical and geometrical isomerism (D) None

7. Correct statement about D-mannitol (in given form):

OH OH
HO
OH
OH OH
(A) C3 axis of symmetry (B) C2 axis of symmetry
(C) Centre of symmetry is present (D) 3-chiral centre are present

8. True statement(s) about this compound is(are) :

Cl Cl

Cl Cl
(A) It is E isomer (B) It is Z isomer
(C) It is optically active (D) It has Centre of Symmetry
9. Arrange the following compounds in order of resonance energy :

(a) (b) (c) (d)

(A) b > c > a > d (B) a > b > c > d (C) d > b > a > c (D) d > a > b > c

10. Arrange the following in the increasing order of their basic strength:

I. II. III. IV.

(A) I < II < III < IV (B) IV < III < II < I (C) IV < I < II < III (D) III < II < IV < I

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 2
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