CHEMICAL EQUILIBRIUM

1.Write the equilibrium constant expression for each of the following

reactions

(i) 2CO(g)+O2(g)⇌2CO2(g)

(ii) N2O5(g)⇌NO2(g)+NO3(g)

(iii) Zn(s)+2HCl(g)⇌ZnCl2(s)+H2(g)

(iv) 2H2O(l)⇌2H2O(l)+O2(g)

(v) 3Fe(s)+4H2O(g)⇌Fe3O4(s)+4H2(g)
2. What is meant by the statement ‘Equilibrium is dynamic in
nature’?

3. State Henry’s law.

4. Write the chemical equation for the following chemical constant.

5. The equilibrium constant for the reaction H2O+CO⇌H2+CO2 is

0.44 at 1260 K. What will be the value of the equilibrium constant for
the reaction: H2+CO2⇌ H2O + CO at 1260 K.

6. If Qc>Kc, what would be the direction of reaction?

7. What is the unit of equilibrium constant for the reaction N2(g)

+3H2(g)⇌2NH3(g).

8. Derive the relation between Kp and Kc.

2A⇌B+C is 2×10−3. At a given

9. The value of Kc for the reaction

time, the composition of the reaction mixture is A = B =C = 3×10−4 M.

In which direction the reaction will proceed?

10. Write the relation between Kc and Kp for the reaction

PCl5 (g) ⇌ PCl3 (g) + Cl2 (g)