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  • Organic Chemistry - 1

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    SOHAN DAS
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    1. Markovnikov's rule states that in the addition of an unsymmetrical alkene and a hydrogen halide, the hydrogen atom adds to the carbon atom having the greater number of hydrogen substituents already present. For example, the addition of HCl to propene forms 2-chloropropane as the major product. 2. Saytzeff's rule states that elimination reactions involving halogenoalkanes follow an anti-Markovnikov pattern, forming the alkene with the halogen atom on the carbon with fewer hydrogen substituents. For example, 2-chlorobutane undergoes elimination in the presence of KOH to mainly form 2-methylpropene.

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    1. Markovnikov's rule states that in the addition of an unsymmetrical alkene and a hydrogen halide, the hydrogen atom adds to the carbon atom having the greater number of hydrogen substituents already present. For example, the addition of HCl to propene forms 2-chloropropane as the major product. 2. Saytzeff's rule states that elimination reactions involving halogenoalkanes follow an anti-Markovnikov pattern, forming the alkene with the halogen atom on the carbon with fewer hydrogen substituents. For example, 2-chlorobutane undergoes elimination in the presence of KOH to mainly form 2-methylpropene.

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    38 views4 pages

    Organic Chemistry - 1

    Uploaded by

    SOHAN DAS
    1. Markovnikov's rule states that in the addition of an unsymmetrical alkene and a hydrogen halide, the hydrogen atom adds to the carbon atom having the greater number of hydrogen substituents already present. For example, the addition of HCl to propene forms 2-chloropropane as the major product. 2. Saytzeff's rule states that elimination reactions involving halogenoalkanes follow an anti-Markovnikov pattern, forming the alkene with the halogen atom on the carbon with fewer hydrogen substituents. For example, 2-chlorobutane undergoes elimination in the presence of KOH to mainly form 2-methylpropene.

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    © All Rights Reserved
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    Topic 1: Markovnikov's addition an peroxide effect, Saytzeff Rule

    1. What is Markovnikov's rule? Explain with an example?


    2. Explain the mechanism of (i) Markovnikov’s Rule (ii) Anti
    Markovnikovs rule
    (Refer Class XI text book)

    3. Complete the following

    4. What is Saytzeff Rule Illustrate with suitable Example


    5. According to Saytzeffs rule,2-Chlorobutane on boiling with alc KOH
    yields ----------------as the major product
    (i) But-2-ene (ii) Propene (iii) 2-Methylpropene (iv) But-1-ene
    Topic 2:Directive influence of ortho, para and meta directing
    groups
    ( REFER THE NOTES GIVEN BELOW or refer from class XI Text
    Book) Write in your note book

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