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Material Safety Data Sheet

Conforming to 91/155/EWG

1 .) Product and Company Identification :

Product Identification : 2 Chemring Marine Brands-


Comet Day and Night Signal Art.-No . : 9131500
Pains Wessex Day & Night MK8 Item No . 55970

Use of Product:
Sea distress signal - Produces Orange Smoke and Red Flare

Manufacturer's Name :-
Chemring Defence Germany GmbH Supplied By :- Chemring Marine Ltd
VielAnder Weg 147 1500 Parkway
27574 Bremerhaven Whiteley, Fareham
Germany Hampshire . P015 7AF U .K.
Emergency Contact : 24 Hours Tel ++44(0) 1489 884130
Phone : ++49-(0)471-393-0 www .chemringmarine .co m
i nfo@chemringmarine .co m
2 .) Composition / Information on Inqredients :
• Chemical Characterization : Oxidation and combustible mixture
• Description : Pressed, pyrotechnical powder
• Hazardous Ingredients : EC-No . : CAS-No . : R-Sentences : Content :
Flare :
Lighter composition :
- Magnesium 012-002-00-9 7939-95-4 11, 15 30-60%
- Strontium Nitrate 233-131-9 10042-76-9 8,36-38 30-60%
Delay composition :
- Blackpowder 231-818-8 7757-79-1 2 10-30%
- Potassium Nitrate 231-818-8 7757-79-1 none 30-60%
- Potassium Perchlorate 231-912-9 7778-74-7 9,22 1-5%
Ignition Composition :
- Blackpowder 231-818-8 7757-79-1 2 60-100%
- Strontium Nitrate 233-131-9 10042-76-9 8,36-38 10-30%
- Aluminium / Magnesium 231-072-3 7429-90-5 10, 15 5-10%
alloy
Smoke :
Ignition Composition :
- Blackpowder 231-818-8 7757-79-1 2 10-30%
- Barium Nitrate 233-020-5 10022-31-8 20,22 60-100%
- Sulphur 231-722-6 7704-34-9 none 5-10%
Smoke Composition :
- Dihydroxy-Anthrachinon none 30-60%
- Milk Sugar none 10-30%
- Potassium Chlorate 017-004-00-3 3811-04-9 9,22 10-30%

3 .) Hazard Identification :
• Hazard : flammable
Printing date: 01 .08 .2008 Issue: 1 07/2008 Page : 1 of 3


PainsWess -
Material Safety Data Sheet

Conforming to 91/155/EWG
• Special hazards for Health & Environment:
Burn hazard if not used conforming manual instructions
• Classification System : not applicable

4.) First Aid Measures :


• Inhalation : having problems after inhaling smoke, consult a
physician
• Skin contact : flush with water
• Eye contact : flush with water, consult a physician
• Swallowing : having problems after swallowing smoke, consult a
physician

5 .) Fire Fightinq Measures :


• Extinguishing Media : once the signal is ignited, it can not be extinguished
for secondary fires = water
• Special protection gear : none

6 .) Accidential Release Measures :


• Personal Safety Measures : use signal only in emergency cases
• Environmental Measures : not applicable
• Cleaning instructions : not applicable

7 .)Handlinq and Storage :


• Handling : Conform with instructions printed on the signal .
• Indications concerning fire and explosion protection : Not applicable
• Storage : Store in cool and dry environment, avoid heat
• Warehouse and packaging requirements :
Store only in original packing and conform with the directions for storing dangerous goods
• Common storage with other goods :
Only store together with non - dangerous goods, or goods of the same dangerous goods
classification .
• VbF classification : not applicable

8 .) Exposure Controls & Personal Protection :


• Additional information concerning technical installations : not applicable
• Exposure limits : not applicable
• Limiting and surveillance of exposure : not applicable
• Personal protection equipment not applicable
• Repiratory protection : not applicable
• Hand protection : not applicable
• Eye protection : not applicable
• Body protection : not applicable

9 .) Physical&Chemical Properties :
• Form : Steel tube with pressed explosives, ignitor and gripp
• Colour : Outer casing : orange
Pyrotechnical ingredients : black / grey
• Odor : neutral
• pH-value : not applicable
• Change in state: not applicable
• Melting point/ area : not applicable
• Boiling point/ area : not applicable
• Flashpoint: 160°C / 320 ° F
Printing date : 01 .08.2008 Issue : 1 07/2008 Page : 2 of 3

PainsWess .
Material Safety Data Sheet

Conforming to 91/155/EWG
• Self Inflammability : not applicable
• Explosion risk : not applicable
• Density : not applicable
• Solubility / Miscibility in Water : indissoluble

10 .) Stability&Reactivity Data :
• Autoignition / Conditions to avoid :
1)Temperatures >160°C (320°F)
2)Strong mechanical impact, e .g . pushing or throwing
• Hazardous Reactions : During intended use : flames, heat and smoke
• Hazardous Corrosion Products : not applicable

11 .) Toxicological Data :
(for products arising during intended reaction)
• Acute Toxicity : Inhalation of flue gases (fine dust of magnesium oxide)
• Primary Irritation : none
• Sensitisation : none
• Additional toxicological Indications none

12 .) Ecological Data :
• General Indications : none

13 .) Disposal Considerations :
• Disposal via specialised trade

14.) Transport Information :


• Dangerous Goods Classification : 1 .4G UN 0191 Signal Devices, Hand

15.) Reaulatorv Infomation :


• Labelling EWG Restrictions : not applicable .
• National Restrictions : not applicable
• Classification VbF : not applicable
• Water Pollution Class: not applicable

16 .) Other Information :
D R-Sentences :
# 2 = Explosive, due to heavy impact, friction or open fire
# 8 = Inflammable, when in contact with other combustible materials
# 11 = Highly inflammable
# 15 = Highly inflammable gases occure, when reacting with water
# 20 = Harmful to health when inhaled
# 22 = Harmful to health when swallowed
# 36 = Irritating for eyes
# 37 = Irritating for respiratory organ
# 38 = Irritating for skin

Printing date : 01 .08 .2008 Issue: 1 07/2008 Page: 3 of 3


U .S. Department of Justice

Bureau of Alcohol, Tobacco,


Firearms and Explosives

Washington, DC 20226 902030 : MJO


www. atf gov
09-0335
555 .32
5400

Mr. Robert Walther


Revere Supply Co., Inc .
5323 Highway Avenue
Jacksonville, Florida 32254

Dear Mr. Walther :

This is in response to your letter dated June 4, 2009, to the Bureau of Alcohol, Tobacco,
Firearms and Explosives (ATF) . You requested a special explosive device exemption pursuant
to the regulations at 27 CFR 555 .32 .

According to your letter, you import marine safety pyrotechnic products, which the U .S . Coast
Guard and International Maritime laws require on all commercial vessels. You provided the
following information for each device : catalog page, Declaration of Conformity from the
manufacturer, data/technical sheet, U .S . Department of Transportation (DOT) Competent
Authority, U .S . Coast Guard Certificate of Approval, and Material Safety Data Sheet .
Specifically, you are requesting exemptions for the following marine safety products :

Part Number Description UN Code EX number DOT Class


50080 Linethrower 250 Rocket 0453 1997010148A 1 .4G
50050 Speedline 250 Rocket 0453 2001060002 1 .4G
50672 Parachute Red Rocket MK8A 0431 2008070167 1 .4G
50570 Parachute Red Rocket MK3 0431 0010068 1 .4G
52751 White Handflare MK8 0431 2004110193 1 .4G
52900 Red Handflare MK8 0191 2002040261 1 .4G
55970 Day/Night Signal 0191 2004080049 1 .4G
53685 Lifesmoke MK8 0432 2008070055 1 .4G
55630-G Miniflare 3 0312 0011070 1 .4G
55665 Miniflare MK8 Personal Distress 0312 2008020173 1 .4G
55666 Miniflare MK8 Compact Distress 0312 2008020173 1 .4G
53771 Manoverboard 360 0197 2001100050 1 .4G
53826 Buoysmoke MK2 0197 2001100050 1 .4G
50755 Parachute Rocket Illuminating MK8 0431 2008100036 1 .4G

-2 -

Mr. Robert Walther

Chemring Defence, the manufacturer of these devices, certifies that the Speedline 250 Rocket
and Linethrower are lifesaving equipment, not military weapons .

The regulation at 27 CFR 555 .32 states, in part, that "The Director may exempt certain explosive
actuated devices, explosive actuated tools, or similar devices from the requirements of this part .
A person who desires to obtain an exemption under this section for any special explosive device,
which as designed does not constitute a public safety or security hazard, shall submit a written
request to the Director ."

The following devices are self-contained and designed for signaling in emergency or distress
marine situations :

Linethrower 250 Rocket Day/Night Signal


Speedline 250 Rocket Lifesmoke MKS
Parachute Red Rocket MK8A Manoverboard 360
Parachute Red Rocket MK3 Buoysmoke MK2
White Handflare MK8 Parachute Rocket Illuminating MK8
Red Handflare MK8

After careful review, we believe that these devices do not pose a threat to public safety when
possessed and used for their intended purpose. Therefore, we are exempting these products as
special explosive devices.

The following devices are not self-contained and use individual explosive cartridges fired from a
separate firing mechanism :

Miniflare 3 Miniflare MK8 Personal Distress Miniflare MK8 Compact Distress

However, Chernring Defence ships and sells the explosive cartridges and firing mechanisms in
individual water-resistant cases . These devices use a handheld pen-type firing mechanism
(penjector) to fire a flare cartridge that emits a bright light during the day or night . Each
cartridge contains 4'/4 to 5 grams of explosive materials. Each kit contains a firing mechanism
and three to eight flare cartridges, which are designated in the DOT Competent Authority
documents. According to your conversation with ATF Program Manager Mike O'Lena, you
only distribute the cartridges in the complete kit with the firing mechanism .

After careful review, we believe that these devices do not pose a threat to public safety when
possessed and used for their intended purpose. Therefore, we are exempting each kit as a special
explosive device . Keep in mind that any change to the packing methods described in the DOT
Competent Authority documents would require further evaluation by ATF .
- 3-

Mr . Robert Walther

We trust the foregoing has been responsive to your request . If you have additional questions,
please contact the Explosives Industry Programs Branch at 202-648-7120 .

Sincerely yours,

Debra S . Satkowiak
Chief, Explosives Industry
Programs Branch

c : Area Supervisor, Miami Field Office VI


U .S . Department 400 :SeYMtn S/roet: S .W.


of Transportation W snlnglan, 0 C . 20950

Researchand Tito US Department of Transportation


Special Programs Competent Authority for, the United States
Administration.

CLASSIFICATION OFEXPLOSIVES

Based upon a' request by Comet GmbH Pyrotechnik-Apparatebau, Postfach 10 02 67 , D


27302, Brernerhaven, GERMANY, the following items are classed in accordance with
Section 173 .56 Title 49, Code of Federal Regulations , (49 CFR) . A copy' of your
applicaton, all supporting documentation acid a copy o fthis approval must be retained
and made available to DOT upon request.

U .N . PROPER SHIPPING NAME AND NUMBER:


Signal- devices, .hand, TUN0I91

U N CLASSIFICATION CODE' 14G

)ZE ERENCE NUMB 'R PRODUCT DESIGNATION/PART NUMBER


1:12004080049 Licht-Rauchfackel BAM-PTI-1109 (Day and Night
Signal - PIN 9131500)

NOTES:
None

DATED : August 16, 2004


Approved by :

"' R©bert A. McGuire


Associate Administrator for
Hazardous Materials Safety

Tracking No 20040 0182 Page 11 of 1

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