Data Patent 2,529,186

Analisis data Patent 2529186

Komponen BM g gmol rasio
C2H4O 44 48 1.0909 1.0
C7H6O 106 150 1.4151 1.3
H2O 18 1000 55.5556 50.9
NaOH 40 3 0.0750 0.07
58.1366

C2H4O + C7H6O --------------> C9H8O + H2O

C7H6O tersisa = 63.9 g = 0.602830189 gmol

Range suhu = 60 - 80 oC
Suhu reaksi = 70 oC
Waktu reaksi = 1.5 jam

C7H6O bereaksi = 1.4151 - 0.602830189

= 0.8123 gmol

Konversi = 0.8123
1.0909

= 0.7446

REAKTOR

1. Umpan masuk Acetaldehyde ( Kemurnian 99 % berat )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 75.2498 3310.9906
H2O 18 1.8580 33.4443
77.1078 3344.4350

2. Umpan Benzaldehyde ( Kemurnian 99% berat )

Komponen BM Kmol/jam Kg/jam

C7H6O 106 129.9787 13777.7471
H2O 18 7.7316 139.1692
137.7104 13916.9163

3. Recycle Acetaldehyde
 Komponen BM Kmol/jam Kg/jam
C2H4O 44 24.7290 1088.0742 0
H2O 18 0.6106 10.9906 0
25.3396 1099.0649

4. Recycle Benzaldehyde

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.0213 0.9351 0
H2O 18 4.3972 79.1500 0
C7H6O 106 51.4216 5450.6910 0
C9H8O 132 0.7576 100.0000 0
56.5977 5630.7761

5. Umpan katalis NaOH

Komponen BM Kmol/jam Kg/jam

NaOH 40 7.0000 280.0000
H2O 18 5075.4025 91357.2458
5082.4025 91637.2458

6. Total umpan masuk reaktor ( Basis 100 Kmol/jam C2H4O )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 100.0000 4400.0000
C7H6O 106 130.0000 13780.0000
C9H8O 132 0.7576 100.0000
NaOH 40 7.0000 280.0000
H2O 18 5090.0000 91620.0000
5327.7576 110180.0000

Reaksi

C2H4O + C7H6O --------------> C9H8O + H2O

Konversi XA = 0.75
(1 - XA) = 0.25

maka

C2H4O = nAo (1 - XA)

= 100.0000 0.25
= 25 Kmol/jam

C7H6O = nBo - nAo XA

= 130.0000 - 100.0000 0.75
= 55 Kmol/jam

C9H8O = nCo + nAo XA

= 0.7576 + 100.0000 0.75
= 75.75757576 Kmol/jam

H2O = nDo + nAo XA

5090.0000 + 100.0000 0.75
 5165 Kmol/jam

7. Komposisi hasil reaksi

Komponen BM Kmol/jam Kg/jam

C2H4O 44 25.0000 1100.0000
C7H6O 106 55.0000 5830.0000
C9H8O 132 75.7576 10000.0000
NaOH 40 7.0000 280.0000
H2O 18 5165.0000 92970.0000
5327.7576 110180.0000

NEUTRALIZER

1. Umpan masuk

Komponen BM Kmol/jam Kg/jam

C2H4O 44 25.0000 1100.0000
C7H6O 106 55.0000 5830.0000
C9H8O 132 75.7576 10000.0000
NaOH 40 7.0000 280.0000
H2O 18 5165.0000 92970.0000
5327.7576 110180.0000

2. Umpan H2SO4 ( Kemurnian 98 % berat )

H2SO4 stoikiometris = 3.5 Kmol/jam

Komponen BM Kmol/jam Kg/jam

H2SO4 98 3.5000 343.0000
H2O 18 0.3889 7.0000
3.8889 350.0000

Reaksi netralisasi

NaOH + 0,5 H2SO4 -----------> 0,5 Na2SO4 + H2O

Na2SO4 terbentuk = 3.5 Kmol/jam

H2O terbentuk = 5165.0000 + 0.3889 + 7
= 5172.3889 Kmol/jam

3. Komposisi hasil reaksi

Komponen BM Kmol/jam Kg/jam

C2H4O 44 25.0000 1100.0000
C7H6O 106 55.0000 5830.0000
C9H8O 132 75.7576 10000.0000
Na2SO4 142 3.5000 497.0000
H2O 18 5172.3889 93103.0000
5331.6465 110530.0000

DECANTER
1. Umpan masuk

Komponen BM Kmol/jam Kg/jam

C2H4O 44 25.0000 1100.0000
C7H6O 106 55.0000 5830.0000
C9H8O 132 75.7576 10000.0000
Na2SO4 142 3.5000 497.0000
H2O 18 5172.3889 93103.0000
5331.6465 110530.0000

Data kelarutan dalam H2O

C2H4O = tak hingga

C7H6O = 0.3 g /100 g H2O
C9H8O = tidak larut
Na2SO4 = 45.3 g /100 g H2O

Fase berat ( C7H6O + C9H8O) mengandung 0,5 % H2O

Massa fase berat masuk = 15830.0000 Kg/jam

H2O dalam fase berat = 0.005 15830.0000

= 79.15 Kg/jam

C2H4O dalam fase berat = 1100.0000 79.15

93103.0000

= 0.935147095 Kg/jam

Na2SO4 dalam fase berat di abaikan

C7H6O yang terlarut dalam H2O = 0.3 93103.0000

100

= 279.309 Kg/jam

C7H6O yang tidak terlarut dalam H2O = 5830.0000 - 279.309

= 5550.6910 Kg/jam

C9H8O semuanya tidak terlarut dalam H2O

2. Komposisi fase berat

Komponen BM Kmol/jam Kg/jam Densitas Volume

C2H4O 44 0.0213 0.9351 0.7780 1.2020
C7H6O 106 52.3650 5550.6910 1.0450 5311.6660
C9H8O 132 75.7576 10000.0000 1.0500 9523.8095
Na2SO4 142 0.0000 0.0000 2.6600 0.0000
H2O 18 4.3972 79.1500 1.0000 79.1500
132.5411 15630.7761 14915.8275

Densitas rata-rata = 1.047932212 Kg/Lt

3. Komposisi fase ringan

Komponen BM Kmol/jam Kg/jam Densitas Volume

C2H4O 44 24.9787 1099.0649 0.7780 1412.6798
C7H6O 106 2.6350 279.3090 1.0450 267.2813
C9H8O 132 0.0000 0.0000 1.0500 0.0000
Na2SO4 142 3.5000 497.0000 2.6600 186.8421
H2O 18 5167.9917 93023.8500 1.0000 93023.8500
5199.1054 94899.2239 94890.6532

Densitas rata-rata = 1.000090321 Kg/Lt

VAPORIZER

1. Umpan masuk

Komponen BM Kmol/jam Kg/jam

C2H4O 44 24.9787 1099.0649 N1
C7H6O 106 2.6350 279.3090 N2
C9H8O 132 0.0000 0.0000
Na2SO4 142 3.5000 497.0000 N3
H2O 18 5167.9917 93023.8500 N4
5199.1054 94899.2239

C2H4O semuanya menguap

H2O yang menguap ekuimolar terhadap C2H4O menguap

2. Komposisi uap

Komponen BM Kmol/jam Kg/jam

C2H4O 44 24.9787 1099.0649 N5
H2O 18 24.9787 449.6174 N6
49.9575 1548.6823

3. Komposisi fase cair ( Ke UPL )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.0000 0.0000
C7H6O 106 2.6350 279.3090
C9H8O 132 0.0000 0.0000
Na2SO4 142 3.5000 497.0000
H2O 18 5143.0129 92574.2326
5149.1479 93350.5416

MENARA DISTILASI I

1. Umpan masuk

Komponen BM Kmol/jam Kg/jam

C2H4O 44 24.9787 1099.0649 N1
H2O 18 24.9787 449.6174 N2
49.9575 1548.6823

Diharapkan 99% C2H4O sebagai hasil atas dengan kemurnian 99%

2. Komposisi hasil atas ( Recycle )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 24.7290 1088.0742 N3
H2O 18 0.6106 10.9906 N4
25.3396 1099.0649

3. Komposisi hasil bawah ( Ke UPL )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.2498 10.9906 N5
H2O 18 24.3682 438.6268 N6
24.6179 449.6174

MENARA DISTILASI II

1. Umpan masuk

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.0213 0.9351
H2O 18 4.3972 79.1500
C7H6O 106 52.3650 5550.6910
C9H8O 132 75.7576 10000.0000
132.5411 15630.7761

Diharapkan 99 % C9H8O dalam umpan menara, sebagai hasil bawah dengan kemurnian 99%

2. Komposisi hasil bawah ( Produk akhir )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.0000 0.0000
H2O 18 0.0000 0.0000
C7H6O 106 0.9434 100.0000
C9H8O 132 75.0000 9900.0000
75.9434 10000.0000

3. Komposisi hasil atas ( Recycle )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.0213 0.9351
H2O 18 4.3972 79.1500
C7H6O 106 51.4216 5450.6910
C9H8O 132 0.7576 100.0000
56.5977 5630.7761

MIXER I
1. Umpan segar NaOH 48 %

Komponen BM Kmol/jam Kg/jam

NaOH 40 7.0000 280.0000
H2O 18 16.8519 303.3333
23.8519 583.3333

2. Umpan H2O

Komponen BM Kmol/jam Kg/jam

H2O 18 5058.5507 91053.9125

3. Komposisi masuk reaktor

Komponen BM Kmol/jam Kg/jam

NaOH 40 7.0000 280.0000
H2O 18 5075.4025 91357.2458
5082.4025 91637.2458
20.6
179
20.6
20.6
100
II. Neraca massa kapasitas
Kapasitas pabrik = 30000 Ton per Tahun
= 3787.878788 Kg/jam (1 Ton = 1000 Kg; 1 Hari = 24 jam; 1 Tahun = 330 hari)

Dari neraca massa Basis

Kapasitas basis = 10000 Kg/jam

Faktor pengali kapasitas :

F = 3787.878788
10000

= 0.378787879

Neraca massa kapasitas :

REAKTOR

1. Umpan masuk Acetaldehyde ( Kemurnian 99 % berat )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 28.5037 1254.1631
H2O 18 0.7038 12.6683
29.2075 1266.8314

2. Umpan Benzaldehyde ( Kemurnian 99% berat )

Komponen BM Kmol/jam Kg/jam

C7H6O 106 49.2344 5218.8436
H2O 18 2.9286 52.7156
52.1630 5271.5592

3. Recycle Acetaldehyde

Komponen BM Kmol/jam Kg/jam

C2H4O 44 9.3670 412.1493 0
H2O 18 0.2313 4.1631 0
9.5983 416.3124

4. Recycle Benzaldehyde

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.0081 0.3542 0
H2O 18 1.6656 29.9811 0
C7H6O 106 19.4779 2064.6557 0
C9H8O 132 0.2870 37.8788 -3.979E-10
21.4385 2132.8698

5. Umpan katalis NaOH

 Komponen BM Kmol/jam Kg/jam
NaOH 40 2.6515 106.0606
H2O 18 1922.5010 34605.0174
1925.1525 34711.0780

6. Total umpan masuk reaktor ( Basis 100 Kmol/jam C2H4O )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 37.8788 1666.6667
C7H6O 106 49.2424 5219.6970
C9H8O 132 0.2870 37.8788
NaOH 40 2.6515 106.0606
H2O 18 1928.0303 34704.5455
2018.0900 41734.8485

Reaksi

C2H4O + C7H6O --------------> C9H8O + H2O

Konversi XA = 0.75
(1 - XA) = 0.25

maka

C2H4O = nAo (1 - XA)

= 37.8788 0.25
= 9.46969697 Kmol/jam

C7H6O = nBo - nAo XA

= 49.2424 - 37.8788 0.75
= 20.83333333 Kmol/jam

C9H8O = nCo + nAo XA

= 0.2870 + 37.8788 0.75
= 28.69605142 Kmol/jam

H2O = nDo + nAo XA

1928.0303 + 37.8788 0.75
1956.439394 Kmol/jam

7. Komposisi hasil reaksi

Komponen BM Kmol/jam Kg/jam

C2H4O 44 9.4697 416.6667
C7H6O 106 20.8333 2208.3333
C9H8O 132 28.6961 3787.8788
NaOH 40 2.6515 106.0606
H2O 18 1956.4394 35215.9091
2018.0900 41734.8485
NEUTRALIZER

1. Umpan masuk

Komponen BM Kmol/jam Kg/jam

C2H4O 44 9.4697 416.6667
C7H6O 106 20.8333 2208.3333
C9H8O 132 28.6961 3787.8788
NaOH 40 2.6515 106.0606
H2O 18 1956.4394 35215.9091
2018.0900 41734.8485

2. Umpan H2SO4 ( Kemurnian 98 % berat )

H2SO4 stoikiometris = 1.325757576 Kmol/jam

Komponen BM Kmol/jam Kg/jam

H2SO4 98 1.3258 129.9242
H2O 18 0.1473 2.6515
1.4731 132.5758

Reaksi netralisasi

NaOH + 0,5 H2SO4 -----------> 0,5 Na2SO4 + H2O

Na2SO4 terbentuk = 1.325757576 Kmol/jam

H2O terbentuk = 1956.4394 + 0.1473 + 2.651515152
= 1959.2382 Kmol/jam

3. Komposisi hasil reaksi

Komponen BM Kmol/jam Kg/jam

C2H4O 44 9.4697 416.6667
C7H6O 106 20.8333 2208.3333
C9H8O 132 28.6961 3787.8788
Na2SO4 142 1.3258 188.2576
H2O 18 1959.2382 35266.2879
2019.5631 41867.4242

DECANTER

1. Umpan masuk

Komponen BM Kmol/jam Kg/jam

C2H4O 44 9.4697 416.6667
C7H6O 106 20.8333 2208.3333
C9H8O 132 28.6961 3787.8788
Na2SO4 142 1.3258 188.2576
H2O 18 1959.2382 35266.2879
2019.5631 41867.4242

Data kelarutan dalam H2O

C2H4O = tak hingga

C7H6O = 0.3 g /100 g H2O
C9H8O = tidak larut
Na2SO4 = 45.3 g /100 g H2O

Fase berat ( C7H6O + C9H8O) mengandung 0,5 % H2O

Massa fase berat masuk = 5996.2121 Kg/jam

H2O dalam fase berat = 0.005 5996.2121

= 29.98106061 Kg/jam

C2H4O dalam fase berat = 416.6667 29.98106061

35266.2879

= 0.354222385 Kg/jam

Na2SO4 dalam fase berat di abaikan

C7H6O yang terlarut dalam H2O = 0.3 35266.2879

100

= 105.7988636 Kg/jam

C7H6O yang tidak terlarut dalam H2O = 2208.3333 - 105.7988636

= 2102.5345 Kg/jam

C9H8O semuanya tidak terlarut dalam H2O

2. Komposisi fase berat

Komponen BM Kmol/jam Kg/jam Densitas Volume

C2H4O 44 0.0081 0.3542 0.7780 0.4553
C7H6O 106 19.8352 2102.5345 1.0450 2011.9947
C9H8O 132 28.6961 3787.8788 1.0500 3607.5036
Na2SO4 142 0.0000 0.0000 2.6600 0.0000
H2O 18 1.6656 29.9811 1.0000 29.9811
50.2049 5920.7485 5649.9347

Densitas rata-rata = 1.047932212 Kg/Lt

3. Komposisi fase ringan

Komponen BM Kmol/jam Kg/jam Densitas Volume

C2H4O 44 9.4616 416.3124 0.7780 535.1060
C7H6O 106 0.9981 105.7989 1.0450 101.2429
C9H8O 132 0.0000 0.0000 1.0500 0.0000
Na2SO4 142 1.3258 188.2576 2.6600 70.7735
H2O 18 1957.5726 35236.3068 1.0000 35236.3068
1969.3581 35946.6757 35943.4292

Densitas rata-rata = 1.000090321 Kg/Lt

VAPORIZER

1. Umpan masuk

Komponen BM Kmol/jam Kg/jam

C2H4O 44 9.4616 416.3124
C7H6O 106 0.9981 105.7989
C9H8O 132 0.0000 0.0000
Na2SO4 142 1.3258 188.2576
H2O 18 1957.5726 35236.3068
1969.3581 35946.6757

C2H4O semuanya menguap

H2O yang menguap ekuimolar terhadap C2H4O menguap

2. Komposisi uap

Komponen BM Kmol/jam Kg/jam

C2H4O 44 9.4616 416.3124
H2O 18 9.4616 170.3096
18.9233 586.6221

3. Komposisi fase cair ( Ke UPL )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.0000 0.0000
C7H6O 106 0.9981 105.7989
C9H8O 132 0.0000 0.0000
Na2SO4 142 1.3258 188.2576
H2O 18 1948.1110 35065.9972
1950.4348 35360.0536

MENARA DISTILASI I

1. Umpan masuk

Komponen BM Kmol/jam Kg/jam

C2H4O 44 9.4616 416.3124
H2O 18 9.4616 170.3096
18.9233 586.6221

Diharapkan 99% C2H4O sebagai hasil atas dengan kemurnian 99%

2. Komposisi hasil atas ( Recycle )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 9.3670 412.1493
H2O 18 0.2313 4.1631
9.5983 416.3124

3. Komposisi hasil bawah ( Ke UPL )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.0946 4.1631
H2O 18 9.2304 166.1465
9.3250 170.3096

MENARA DISTILASI II

1. Umpan masuk

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.0081 0.3542
H2O 18 1.6656 29.9811
C7H6O 106 19.8352 2102.5345
C9H8O 132 28.6961 3787.8788
50.2049 5920.7485

Diharapkan 99 % C9H8O dalam umpan menara, sebagai hasil bawah dengan kemurnian 99%

2. Komposisi hasil bawah ( Produk akhir )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.0000 0.0000
H2O 18 0.0000 0.0000
C7H6O 106 0.3573 37.8788
C9H8O 132 28.4091 3750.0000
28.7664 3787.8788

3. Komposisi hasil atas ( Recycle )

Komponen BM Kmol/jam Kg/jam

C2H4O 44 0.0081 0.3542
H2O 18 1.6656 29.9811
C7H6O 106 19.4779 2064.6557
C9H8O 132 0.2870 37.8788
21.4385 2132.8698
MIXER I

1. Umpan segar NaOH 48 %

Komponen BM Kmol/jam Kg/jam

NaOH 40 2.6515 106.0606
H2O 18 6.3833 114.8990
9.0348 220.9596

2. Umpan H2O

Komponen BM Kmol/jam Kg/jam

H2O 18 1916.1177 34490.1184

3. Komposisi masuk reaktor

Komponen BM Kmol/jam Kg/jam

NaOH 40 2.6515 106.0606
H2O 18 1922.5010 34605.0174
1925.1525 34711.0780
Tahun = 330 hari)
20.6
179
20.6
20.6
100
 C2H4O = 0.3542
H2O = 29.9811
C7H6O = 2064.6557
C9H8O = 37.8788
2132.8698
C2H4O = 412.1493
H2O = 4.1631
416.3124

H2SO4 = 129.9242
H2O = 2.6515
132.5758 C2H4O = 416.3124
H2O = 170.3096
C2H4O = 0.3542 586.6221
C7H6O = 5218.8436 H2O = 82.6967
H2O = 52.7156 C7H6O = 7283.4993
5271.5592 C9H8O = 37.8788
7404.4290
C2H4O =
C7H6O =
416.3124
105.7989 MD1 MD2
C9H8O = 0.0000
C2H4O = 1254.1631 C2H4O = 1666.3124 Na2SO4= 188.2576
H2O = 12.6683 H2O = 16.8314 H2O = 35236.3068
1266.8314 1683.1439 35946.6757 H2O = 0.0000
C7H6O = 37.8788
VP C9H8O = 3750.0000
H2O = 34490.1184 3787.8788
34490.1184

C2H4O = 4.1631
H2O = 166.1465
NaOH = 106.0606
H2O = 114.8990 M R N D
170.3096

220.9596

C2H4O = 0.0000
C7H6O = 105.7989
C9H8O = 0.0000
Na2SO4= 188.2576
H2O = 35236.3068
35530.3633
NaOH = 106.0606 C2H4O = 416.6667 C2H4O = 416.6667 C2H4O = 0.3542
H2O = 34605.0174 C7H6O = 2208.3333 C7H6O = 2208.3333 C7H6O = 2102.5345
34711.0780 C9H8O = 3787.8788 C9H8O = 3787.8788 C9H8O = 3787.8788
NaOH = 106.0606 Na2SO4= 188.2576 H2O = 29.9811
H2O = 35215.9091 H2O = 35266.2879 5920.7485
41734.8485 41867.4242