BAB IV

NERACA MASSA

Kapasitas Produksi : 91.000 ton/tahun

Operasi Pabrik : 330 hari/tahun

Basis Perhitungan : 1 jam operasi

Bahan baku : Natural Gas

Produk : Methanol

4.1 DESULFURIZER (D-01)

Komponen Massa input Massa output Mol input Mol output
Gas
(kg/jam) (kg/jam) (kmol/jam) (kmol/jam)

CH4 6813,5409 6813,5409 424,7234 424,7234

C2H6 226,6721 226,6721 7,5384 7,5384

C3H8 56,4822 56,4822 1,2809 1,2809

C4H10 19,3229 19,3229 0,3325 0,3325

CO2 89,1825 89,1825 2,0264 2,0264

O2 0,0000 0,0000 0,0000 0,0000

N2 208,0924 208,0924 7,4283 7,4283

H2S 18,5797 0,0037 0,5452 0,0001

ZnO 44,3707 0,0089 0,5452 0,0001

H2O 0,0000 9,8193 0,0000 0,5451

CO 0,0000 0,0000 0,0000 0,0000

H2 0,0000 0,0000 0,0000 0,0000

ZnS 0,0000 53,1185 0,0000 0,5451

Total 7476,2434 7476,2434 444,4203 444,4203

4.2 PRIMARY REFORMER (PR-01)

Komponen Massa input Massa output Mol input Mol output
Gas
(kg/jam) (kg/jam) (kmol/jam) (kmol/jam)

CH4 6813,5409 403,8181 424,7234 25,1721

C2H6 226,6721 2,2667 7,5384 0,0754

C3H8 56,4822 0,5648 1,2809 0,0128

C4H10 19,3229 0,1932 0,3325 0,0033

CO2 89,1825 1058,5427 2,0264 24,0526

O2 0,0000 0,0000 0,0000 0,0000

N2 208,0924 208,0924 7,4283 7,4283

H2O 8334,2566 378,3033 462,6236 20,9991

CO 0,0000 11136,0359 0,0000 397,5722

H2 0,0000 2559,7323 0,0000 1269,8344

H2S 0,0037 0,0037 0,0001 0,0001

Total 15747,5533 15747,5533 905,9537 1745,1503

4.3 CPO CATALYTIC PARTIAL OXIDATION REACTOR (R-01)
Komponen Massa input Massa output Mol input Mol output
Gas
(kg/jam) (kg/jam) (kmol/jam) (kmol/jam)

CH4 403,8181 0,8076 25,1721 0,0503

C2H6 2,2667 0,0453 0,0754 0,0015

C3H8 0,5648 0,0113 0,0128 0,0003

C4H10 0,1932 0,0039 0,0033 0,0001

CO2 1058,5427 1890,2873 24,0526 42,9518

O2 405,9780 8,1196 12,6873 0,2537

N2 208,0924 208,0924 7,4283 7,4283

H2O 378,3033 29,6677 20,9991 1,6468

CO 11136,0359 11315,8882 397,5722 403,9931

H2 2559,7323 2700,6043 1269,8344 1339,7184

H2S 0,0037 0,0037 0,0001 0,0001

Total 16153,5313 16153,5313 1757,8376 1796,0445

4.4 WGS (WATER GAS SHIFT)

Komponen Massa Massa Massa Massa Mol Mol
Gas input (kg) output output output input output
CPO (kg) Boiler (kg) (kg) Boiler

CH4 0,1615 0,1615 0,1615 0,0101

C2H6 0,0091 0,0091 0,0091 0,0003

C3H8 0,0023 0,0023 0,0023 0,0001

 C4H10 0,0008 0,0008 0,0008 0,0000

CO2 378,0575 3578,3739 3578,3739 81,3091

O2 1,6239 1,6239 1,6239 0,0507

N2 41,6185 41,6185 41,6185 1,4857

H2O 5,9335 1449,6698 145,5603 145,5603 80,4693 8,0799

CO 2263,1776 226,3178 226,3178 8,0799

H2 540,1209 686,7073 686,7073 340,6624

H2S 0,0007 0,0007 0,0007 0,0000

Total 4680,3762 4680,3762 439,6782 439,6782

4.5. PSA (PRESSURE SWING ADSOPTION)

Komponen Massa input Massa output Massa output Mol input Mol output
Gas
(kg/jam) (kg/jam) (kg/jam) (kmol/jam) (kmol/jam)

CH4 0,0808 0,0808 0,0000 0,0050 0,0050

C2H6 0,0045 0,0045 0,0000 0,0002 0,0002

C3H8 0,0011 0,0011 0,0000 0,0000 0,0000

C4H10 0,0004 0,0004 0,0000 0,0000 0,0000

CO2 1789,1870 1789,1870 0,0000 40,6546 40,6546

O2 0,8120 0,8120 0,0000 0,0254 0,0254

N2 20,8092 20,8092 0,0000 0,7428 0,7428

H2O 72,7802 0,0000 72,7802 4,0399 4,0399

CO 113,1589 113,1589 0,0000 4,0399 4,0399

H2 343,3537 48,0695 295,2842 170,3312 170,3312

H2S 0,0004 0,0001 0,0003 0,0000 0,0000

1972,1234 368,0646

Total 2340,1881 2340,1881 219,8391 219,8391

4.6. REAKTOR
Komponen Massa input Massa output Mol input Mol output
Gas
(kg/jam) (kg/jam) (kmol/jam) (kmol/jam)

CH4 0,7269 0,7269 0,0453 0,0453

C2H6 0,0408 0,0408 0,0014 0,0014

C3H8 0,0102 0,0102 0,0002 0,0002

C4H10 0,0035 0,0035 0,0001 0,0001

CO2 3301,4168 495,2125 75,0160 11,2524

O2 7,3076 7,3076 0,2284 0,2284

N2 187,2832 187,2832 6,6855 6,6855

H2O 169,2945 1318,0086 9,3973 73,1609

CO 9165,8694 916,5869 327,2344 32,7234

H2 2799,1213 1226,1667 1388,5908 608,2780

H2S 0,0037 0,0037 0,0001 0,0001

CH3OH 0,0000 11479,7273 0 358,2746

 Total 15631,0778 15631,0778 1807,1994 1090,6502

4.7. KOLOM DESTILASI-01 (KD-01)

Kompone Massa Massa Output Output Output Output
n Gas input input Distilat Distilat Bottom Bottom
(kmol/jam) (kg/jam) (kmol/jam) (kg/jam)
(kmol/jam) (kg/jam)

CH3OH 1928,3140 11479,7273 1928,0943 11478,4194 0,2197 1,3078

H2O 393,7684 1318,0086 3,4296 11,4796 390,3388 1306,5290

1931,5239 11489,8990 390,5585 1307,8368

Total 2322,0824 12797,7358 2322,0824 12797,7358

4.8. KONDENSOR
Kompone Massa Massa Output L Output L Output D Output D
n Gas input input (kmol/jam) (kg/jam) (kmol/jam) (kg/jam)

(kmol/jam) (kg/jam)

CH3OH 572,7924 18353,2423 214,5586 6874,8229 358,2338 11478,4194

H2O 1,0189 18,3551 0,3817 6,8755 0,6372 11,4796

214,9403 6881,6984 358,8710 1307,8368

Total 573,8113 18371,5974 573,8113 18371,5974

4.9. REBOILER
Komponen Input (kg/jam) Input (kg/jam) Input (kg/jam)
 Aliran 17 Aliran 18 Aliran 19

CH3OH 20,8501 0,0000 20,8501

H2O 20.829,2799 0,0000 20.829,2799

0,0000 20.850,1300
Total 20.850,1300
20.850,1300

4.10. FLASH DRUM

Kompo Massa Massa Massa Massa Massa Massa
nen Gas input input output output output output

(kg/jam) (kmol/jam) (kg/jam) (kmol/jam) (kg/jam) (kmol/jam)

Aliran 8 Aliran 8 Aliran 9 Aliran 9 Aliran 10 Aliran 10

CH4 0,7269 0,0453 0,7269 0,0453 0,0000 0,0000

C2H6 0,0408 0,0014 0,0408 0,0014 0,0000 0,0000

C3H8 0,0102 0,0002 0,0102 0,0002 0,0000 0,0000

C4H10 0,0035 0,0001 0,0035 0,0001 0,0000 0,0000

CO2 495,2125 11,2524 495,2125 11,2524 0,0000 0,0000

O2 7,3076 0,2284 7,3076 0,2284 0,0000 0,0000

N2 187,2832 6,6855 187,2832 6,6855 0,0000 0,0000

H2O 1318,0086 73,1609 0,0000 0,0000 1318,0086 73,1609

CO 916,5869 32,7234 916,5869 32,7234 0,0000 0,0000

H2 1226,1667 608,2780 1226,1667 608,2780 0,0000 0,0000

H2S 0,0037 0,0001 0,0037 0,0001 0,0000 0,0000

CH3OH 11479,7273 358,2746 0,0000 0,0000 11479,7273 358,2746

2833,3419 659,2147 12797,7358 431,4355

1090,6502 1090,6502

Total 15631,0778 15631,0778