BAB III

NERACA MASSA

Basis perhitungan : 1 jam operasi

Satuan berat : Kilogram (kg)

Kapasitas produksi : 30.000 ton/tahun

Waktu operasi : 330 hari/tahun

Bahan baku : 2-Bromo etil benzena (C8H9Br)

Sulfur trioksida (SO3)

Diketahui :

Tabel 3.1 Berat Molekul Masing-Masing Komponen

Komponen Berat Molekul (BM)

C8H9Br 185
C2H4Br 188
CH2Cl2 85
C6H4Cl2 147
H2SO4 98
SO3 80
B2O3 69,64
H2 O 18
NaOH 40
C8H7SO3 206
C8H9SO3 265

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3.1 Tangki Pencampuran 1 (MT-01)
Tabel 3.2 Neraca Massa Tangki Pencampuran1 (MT-01)
Komponen Massa Masuk (kg) Massa Keluar (kg)
M1 M2 M3

C8H9Br 98,00 0 98,00

C2H4Br2 2,00 0 2,00
CH2Cl2 0 98,50 98,50
C6H4Cl2 0 1,50 1,50
Total 200

3.2 Reaktor (RE-01)

Tabel 3.3 Neraca Massa Reaktor 1 (RE-01)
Komponen Massa Masuk (kg) Massa Keluar (kg)
M3 M4 M5
C8H9Br 98,00 0 9,8
C2H4Br2 2,0 0 2,0
CH2Cl2 98,50 0 98,5
C6H4Cl2 1,50 0 1,5
SO3 0 104,50 66,3595
B2O3 0 5,50 5,5
C8H9SO3Br 0 0 126,3405
Total 200,00 110,00 310
310

3.3 Neraca Massa Sekitar Tangki Pencampuran 2 (MT-02)

Tabel 3.4 Neraca Massa Tangki Pencampuran 2 (MT-02)
Komponen Massa Masuk (kg) Massa Keluar (kg)
M5 M6 M7
C8H9Br 9,8 0 9,8
C2H4Br2 2,0 0 2,0
CH2Cl2 98,5 0 98,5
C6H4Cl2 1,5 0 1,5
SO3 66,3595 0 0

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 B2O3 5,5 0 5,5
C8H9SO3Br 126,3405 0 126,3405
H2O 0 20,2058 17,3132
H2SO4 0 0 69,2526
Total 310 20,2058 330,2058
330,2058

3.4 Neraca Massa Decanter 1 (DC-01)

Tabel 3.5 Neraca Massa Dekanter1 (DC-01)
Komponen Massa Masuk (kg) Massa Keluar (kg)
M7 M8 M9

C8H9Br 9,8 0,6341 9,1659

C2H4Br2 2,0 0,0718 1,9282
CH2Cl2 98,5 98,2749 0,2251
C6H4Cl2 1,5 1,1641 0,3359
B2O3 5,5 0,3809 16,9323
C8H9SO3Br 126,3405 0 126,3405
H2O 17,3132 0,0015 1,9985
H2SO4 69,2526 100,5788 164,9204
Total 330,2058 330,2058

3.5 Neraca Massa Decanter 2 (DC-02)

Tabel 3.6 Neraca Massa Dekanter 2 (DC-02)
Komponen Massa Masuk (kg) Massa Keluar (kg)
M9 M10 M11
C8H9Br 9,1659 9,0927 0,0732
C2H4Br2 1,9282 1,9282 0
CH2Cl2 0,2251 0,2251 0
C6H4Cl2 0,3359 0,3359 0

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 B2O3 16,9323 16,9323 0
C8H9SO3Br 126,3405 0 126,3405
H2O 1,9985 1,9985 0
H2SO4 164,9204 7,9941 0
Total 164,9204 126,4137 38,5067
164,9204

3.6 Neraca Massa Tangki Pencampur 3 (MT-03)

Tabel 3.7 Neraca Massa Tangka Pencampur3 (MT-03)
Komponen Massa Masuk (kg) Massa Keluar (kg)
M11 M12 M13
C8H9Br 0,0732 0 0,0732
C8H9SO3Br 126,3405 0 126,3405
H2O 0 0,0016 0,0016
H2SO4 0 0,0783 0,0783
Total 126,4137 0,0799 126,4937
126,4937

3.7 Neraca Massa Dekanter 3 (DC-03)

Table 3.8 Neraca Massa Dekanter 3 (DC-03)
Komponen Massa Masuk Massa Keluar
M13 (kg) M14 (kg) M15 (kg)
H2O 0,0016 0,0016 0
0,0783 0
H2SO4 0,0783
C8H9SO3Br 126,3405 0 126,3405

C8H9Br 0,0732 0,0732 0

Total 126,4937 126,4937

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3.8 Neraca Massa Reaktor 2 (RE-02)
Table 3.9 Neraca Massa Reaktor 2 (RE-02)
Komponen Massa Masuk (kg) Massa Keluar (kg)
M15 M16 M17
C8H9SO3Br 126,3405 0 25,2681
NaOH 0 100 69,4876
C8H7SO3Na 0 0 78,5695
H2O 0 100 39,2428
NaBr 0 113,7306
Total 126,3405 100 326,3405
326,3405

3.9 Neraca Massa Filter Press (FP-01)

Tabel 3.10 Neraca Massa Filter Press (FP-01)
Komponen Massa Masuk (kg) Massa Keluar (kg)
M17 M18 M19
C8H9SO3Br 25,2681 0 25,2681
NaOH 69,4876 0 69,4876
C8H7SO3Na 78,5695 0 78,5695
H2O 113,7306 11,3731 102,3575
NaBr 39,2428 39,2428 0
Total 326,2986 50,6159 275,6827
326,2986

3.10 Neraca Massa Dekanter 4 (DC-04)

Table 3.11 Neraca Massa Dekanter4 (DC-04)
Komponen Massa Masuk (kg) Massa Keluar (kg)
M19 M20 M21
C8H9SO3Br 25,2681 25,2681 0

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 NaOH 69,4876 69,4876 0
C8H7SO3Na 78,5695 0 78,5695
H2O 102,3575 0 102,3575
Total 275,6827 94,7557 180,9270
275,6827

3.11 Neraca Massa Evaporator (EV-01)

Table 3.12 Neraca Massa Evaporator (EV-01)
Komponen Massa Masuk (kg) Massa Keluar (kg)
M21 M22 M23
C8H7SO3Na 78,5695 0 78,5695
H2O 102,3575 98,2632 4,0943
Total 180,9270 98,2632 82,6638
180,9270

3.12 Neraca Massa Kritalizer (CR-01)

Table 3.13 Neraca Massa Kristalizer (CR-01)
Komponen Massa Masuk (kg) Massa Keluar (kg)
M23 M24
C8H7SO3Na (l) 78,5695 7,8570
C8H7SO3Na (s) 0 70,7126
H2O (l) 4,0943 4,0943
Total 82,6638 82,6638

3.13 Neraca Massa Centrifuge (CE-01)

Table 3.14 Neraca Massa Centifuge (CE-01)
Komponen Massa Masuk (kg) Massa Masuk (kg)
M24 M25 M26
C8H7SO3Na (l) 7,8570 7,8570 0

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C8H7SO3Na (s) 70,7126 0 70,7126
H2O (l) 4,0943 0 4,0943
Total 82,6638 7,8570 72,3326
82,6638

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