5.

123 A new process has been proposed to produce ethylene (C2H4) gas from
propane (C3H8) gas at atmospheric pressure by the following reaction
C3H8(g) + 2O2(g) --> C2H4(g) + CO2(g) + 2H2O(g)
the products leave the system at 800 K and the C3H8 enters at 450 K while the O2
emters at 300 K. in the process,C3H8(g) is used in 25% excess (of the amount shown
in the equation), but the overall fraction conversion of the C3H8 is only 40%. How
much heat is added to or removed from the process per mole pf C3H8 feed to the
process?

C3H8(g) + 2O2(g) --> C2H4(g) + CO2(g) + 2H2O(g)

basis 1 mol C3H8

Q=?

C3H8 F P 800 K mol

450 K C3H8 0.6
U O2 1.7
excess air 25% N2 9.404762
300 K mol C2H4 0.4
O2 0.21 2.5 CO2 0.4
N2 0.79 9.4047619048 H2O 0.8
Total 11.904761905
App E
0.01 1E-05 1E-09
Cp A B C D
C3H8 68.032 0.2259 -0.0001311 3.171E-08
celcius O2 29.1 0.01158 -6.076E-06 1.311E-09
celcius C2H4 40.75 0.1147 -6.891E-05 1.766E-08
celsius CO2 36.11 0.04233 -2.887E-05 7.464E-09
celcius H2O 33.46 0.00688 7.604E-06 -3.593E-09
celcius N2 29 0.002199 5.723E-06 -2.871E-09

hasil integral
A B C D
C3H8 68.032 0.11295 -4.37E-05 7.9275E-09
O2 29.1 0.00579 -2.02533E-06 3.2775E-10
C2H4 40.75 0.05735 -2.297E-05 4.415E-09
CO2 36.11 0.021165 -9.62333E-06 1.866E-09
H2O 33.46 0.00344 2.534667E-06 -8.9825E-10
N2 29 0.0010995 1.907667E-06 -7.1775E-10

suhu (oC) 25 27 177 527 app F ∆Hf

C3H8 1770.714 1918.349 15345.728759 61437.758461 C3H8 -103.85
O2 731.0872 789.8812 5321.1856534 16672.597148 O2 0
C2H4 1054.237 1141.608 8886.427498 34381.589786 C2H4 52.283
CO2 915.8285 990.2109 7003.0161501 23643.533507 CO2 -393.51
H2O 838.6893 905.9772 6043.3654393 18890.504567 H2O -241.826
N2 725.7167 783.8387 5177.3202155 15812.212705 N2 0

produk
C3H8 nC3H8(∆H 527 -∆H 25 + ∆Hf) 35737.916656
O2 nO2(∆H 527 -∆H 25 + ∆Hf) 27100.566856
C2H4 nC2H4(∆H 527 -∆H 25 + ∆Hf) 313927.53428
CO2 nCO2(∆H 527 -∆H 25 + ∆Hf) 8933.678007
H2O nH2O(∆H 527 -∆H 25 + ∆Hf) 7123.9957255
N2 nN2(∆H 527 -∆H 25 + ∆Hf) 12069.196792

reaktan
C3H8 nC3H8(∆H 177 -∆H 25 + ∆Hf)
O2 nO2(∆H 27 -∆H 25 + ∆Hf)
N2 nN2(∆H 27 -∆H 25 + ∆Hf)
 C3H8 reaksi O2 req 2
% konversi =
C3H8 feed O2 xs 0.5
C3H8 reaksi O2 tot 2.5
40%
1 mol N2 9.404762
C3H8 reaksi 0,4 mol U 11.90476

C3H8(g) + 2O2(g) --> C2H4(g) + CO2(g) + 2H2O(g)

m 1 2.5
r 0.4 0.8 0.4 0.4 0.8
s 0.6 1.7 0.4 0.4 0.8

general energy balance

∆E = Q + W -∆H -∆K -∆P
∆E = 0
W=0
∆P = 0 Q = ∆H
∆K = 0

mol
C3H8 0.6
O2 1.7
N2 9.404762
C2H4 0.4
CO2 0.4
H2O 0.8